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Home My WebLink AboutPart 3 - Offsite Indoor Air, Sub-Slab Vapor and Outdoor Air (Part 3 - Offsite Indoor Air, Sub-Slab Vapor and Outdoor Air Field Investigative Reportx9E5D1) ( No 42. Are there any cooking appliances in the building? es F]No 42a. If�YES,describe' I,]E 43. Are the cooking appliances vented by use of exhaust hoods? �,J'No 43a. Do the hoods vent to the outdoors? 3' ]Yes !]'No 44. Is there an automatic dishwasher? []No 44a. If YES, is the dishwasher ElCommercial grade, or •',residential grade? 45. Is smoking allowed in the building? Yes t!�Wo 45a. if YES, approximate number of smackers and level of smoking activity: ___-_(number,^,, -_(number of smokers) ..__. ...Light(4 five cigarettes per day) __Moderate (?five cigarettes per day) ,�Neavy(one or more packs per day,?20 cigarettes per day) 4£. Are air fresheners regularly used in the building? 47. Are any of the following activities performed in the building? [_Heating [,Soldering DMIding [ Painting (brush or railer) r-jPainting (spray) []wood or metal finishing ether activity involving chemical usage?(Please describe): 48. Please identify building cleaning and maintenance practices: ❑Busting Dry sweeping acuuming Polishing (furniture, etc) Washing or waxing floors [Carpet cleaning FlOther aLrl'.; +►t�' ,Sr�t . ' � rrr ( !J`;` i t I.✓ cA r� i General building use of consumer products (please circle appropriate): Assume: Never= never used, Hardly ever= less than oncelmorith., Occasionally about or month, Regularly = about oncehveek, and Daily = approximately once/day Product Frequency of Use in Building PrcduEC'- Rarely dcriaislini-a'4-7" "A'sig-u"I'vily CPu=ly Spray-on deodorants Ae.rosoi deodorizers Insecticides Disinfectants Window cleaners Spray-qn oven cleaners j_Na@1 polish or remover I Hair sprays IV/ It SoNents/Degreasers' Paint or paint rerrover Miscellanp9q_k ly_Ls,pe 49. Other comments: Figural Additional Information Plan View: Sketch each floor and if applicable, indicate air sampling locations, possible indoor air pollution sources, preferential pathways and field instrument readings Potential Outdoor Sources of Pollution: ©raw a diagram of the area surrounding the building being sampled_ If applicable, provide information on the spill locations (if known), potential air contamination sources (industries, service stations, repair shops, retail shops, landfills;. etc.), outdoor air sampling locations, and field instrument readings. Also, can the diagram, indicate compass direction, locations of water wells, septic systems, and utility corridors if applicable, and a statement to help locate the site on a topographical map. Complete the attached Chemical Products Inventory Form 1 I Chemical Product Inventory Form Building Occupant Building Address City, State, Zip Code Field investigator --Date Field Instrument Used (commemial name, Quentity Volatile IngreWents in U.'s Mspanser type, container Product ,-Size, wripfacturer, etc.) T M, t vyi 2 1 Z & 0 ig. I 'Sot C 13 4, V_ L/ jv4u iur- / �t- �Vlcwio i. k'A C� 10 Ot 1 v.IN RESIDENTIALICOMMERCIALIRETAIL QUESTIONNAIRE INDOOR AIR ASSESSMENT SURVEY This form must be completed for each building involved in an indoor air investigation. Preparer's name lL. M ��. ?�•.a Date prepared /.3 —/� Preparer's affiliation Telephone number 7G' 2s`) .•/La3 OCCUPANT: Name ViCL Jx Address City. Telephone number Dye y eae What is the best time to call to speak with you? Are you the$Owner, ❑Renter, ❑Other of this Structure? Total number of occupants/persons at this location? Average daily occupant/visito r population: persons. r 71`��"r�IT! �h.klf+'Il11Ld Number of children? _Ages? V (� How long have you occupied this location? M s'A/ OWNER OR LANDLORD: Name (If different from occupant) Address Telephone number Land Use and Building Construction 1. Type (Check appropriate responses): residential ,, f&,X�- .',Commercial [IOffice DWarehouse ❑Strip Mail 2. Age of the building? years. ��a S 3. Number of floors (stories) Q 4. Area of the building (square feet) d,leb, 5. Is the building insulated? Wes ❑No 6. How well is the building sealed? IA)-.e- r'. Number of elevators in the building &A 8. Condition of the elevator pits (sealed, open earth, etc.) S. Above-ground structure construction materials (check all that apply): E!�Vood []B€fck ❑Concrete ❑Cement block ©other 10. General description of building construction materials t&d/Cei0 11. Does the building have windows that can be opened? Yes []No 11 a. If YES, indicate number an type(s) of window(s): 11 b. If YES, describe the frequency and duration of window opening: 12. Does the building have doors? rZnYes No 12a. If YES, indicate number and type(s) of door: 12b. If YES, describe*frequency and duration of door opening: 13. Foundation Construction (check all that apply): Noncrete slab on grade ❑Fieldstone ❑Concrete block ❑Elevated above ground/grade ❑Full Basement ❑Crawispace ❑Other [NOTE: If the building does not have a basement, go to question 24.1 14. Basement?/KYes, ❑No Crawl Space? ❑Yes,ONO 14a. If YES, under how much of the building floor space? e 15. Is the basementQfinished, or❑unfinished? 16. If finished, how many rooms are in the basement? 16a. How many are used for more than 2 hours/day? AY 17. Composition of basement floor (check all that apply) oncrete 9Tile D arpeted f irt ❑Wood ❑Other(describe) ? 17a. If concrete, is the floor ❑Sealed ❑Unsealed ❑Painted Covered Cracked ❑Other(please specify) 18. Are the basementifoundation walls -rcoured concrete ement.block ❑Stone ❑Wood ❑Brick ❑Other ? 19. Are the basement/foundation walls Sealed nsealed 4aA ek;6 Unknown 20. Does the basement have a moisture or water infiltration problem (check one only)? ❑Yes, frequently (3 or more times/yr) ❑Yes, occasionally (1-2 times/yr) ❑Yes, rarely(less than 1 tlme/yr) Po 21. Does the basement ever flood (check one only)? ❑Yes, frequently (3 or more times/yr) ❑Yes, occasionaily (1-2 Vmesfyr) '&Yes, rarely (less than 1 three/yr) Z Sk.al s^eXCW r(h ! o 4ee-� 22. Does the basement have any of the following? (check all that apply) ❑Floor cracks, ❑Wall cracks ❑Sump ❑Floor drain %A ❑Other hole/opening in floor (describe) (Identify all potential soil gas entry points and their size (e.g., cracks, voids, pipes, utility ports, sumps, drain holes, etc.), and any fluid accumulated. 23. Are any of the following used or stored in the basement (check all that apply) ❑Paint x+ ❑Paint stripper/remover ❑Paint thinner ❑Metal degreaser/cleaner ❑Gasoline ❑Diesel fuel ❑Solvents ❑Glue ❑Laundry spot removers ❑Drain cleaners Ix ❑Pesticides Water and Sewage 24. What is the source of drinking water for the building (check all that apply)? ublic water supply ❑Battled water ❑Private Water Well. If private well, please answer following: ❑Drilled Well ❑Driven Well []Dug Well ❑Other (Specify) Water Well Specifications(if applicable) Well Diameter Grouted or Ungrouted Well Depth Type of Storage Tank Depth to Bedrock Size of Storage Tank Feet of Casing Describe type(s) of Treatment []Other, please specify 23. Are there taste and/or odor problems with the water supply? ❑Yes, ❑No If YES, please describe How long has the taste and/or odor problem been present? 24. is the water chlorinated, brominated, or ozonated? []yes, ❑no, ❑unknown 26. Does the building have a private well for purposes other than drinking? ❑Yes No If YES, please describe purpose of the well: 26. Does the building have a septic system? ❑Yes 0 _Not used ❑Unknown 27. How is sewage disposed? Public Sewer ❑Septic ❑Tank ❑Leach Field []Other(Specify) 28. What is the distance from the water supply well to septic system (if applicable)? feet 29a.Are septic tank additives used? Dyes ❑ho [jUnknown. If so, what type? 28. Is there standing water outside the building (pond, ditch, swale)? O.Yes. Plo Heating, Ventilation, and Air Conditioning 30. Heating system fuel or power supply? Check all that apply: T�Aatural Gas 1 Heating ail ❑Kerosene ❑Solar ❑Electric ❑Wood ❑Coal ❑Other 30a. Heat conveyance system: ❑Forced hot air Heat Pump orced hot water Steam ❑Radiant floor heat ❑Wood stove Coal furnace Fireplacepp ,r� Electric Baseboard ❑Unvented Kerosene Heater []Other 31. Where is the heating system located? 32. Does the building have air conditioning? ❑Yes 32a. If YES, please check the appropriate type(s) ❑Central air conditioning ❑Window air conditioning unit(s) ❑Other, please specify 33. Does the building have any of the following? Room fans Ceiling fans ❑Attic fans 34. Is the building ventilated using the fan-only mode of the central HVAC system? ❑Yes ❑No 34a. If YES, What is the rated size of the fan? 35. Water Heater Type: ]Gas ]Electric ]Other 38. Water heater location: (please describe) 'r"` ' Potential Indoor Sources of Pollution 37. Has the building had termite or other pesticide treatment: ]Yes F2NO rl'unknown 37a. If YES, please specify type of pest far which treatment was applied 37b. Approximate date of service 37c. location of treatment within subject building _ 38. Has the building been recently (within the last six months) painted or remodeled? ��Yes ❑No 38a. If YES,c.r�please specify what was don , where in he building, and when: .4eg Liuyr �tx5YY1 -r' 39. Has new carpeting been installed In the building within the last year? Yes No 39a. If YEES, when and where? 40. Is a dry cleaning service present In the building (check only one box)? ]Yes, dry-cleaning performed on-site ]Yes, dry-cleaning sent off site, drop-off only []No 41. Has the building ever had a fire? ❑Yes 0 42. Are there any cooking appliances in the building? Yes No 42a. If YE , describe: 43. Are the cooking appliances vented by use of exhaust hoods? 0Yes ❑ No 43a. Do the hoods vent to the outdoors? ❑Yes [2NO 44. Is there an automatic dishwasher? es ANo 44a. If YES, is the dishwasher Commercial grade, or Residential grade? 45. Is smoking allowed in the building? Yes — ❑No -�45a. If YES, approximate number of smokers and level of smoking activity: (number of smokers) Light (<five cigarettes per day) _X_Moderate (L> five cigarettes per day) Heavy (one or more packs per day, ?20 cigarettes per day) 46. Are air fresheners regularly used in the building? Ryes [-]No 47. Are any of the following: activities performed in the building? ❑bleating P ; /lk, F..-Soldering —!Welding [—[Painting (brush or roller) ElPainting (spray) []Wood or metal finishing ❑Other activlty involving chemical usage? (Please describe): 48. Please identify building cleaning and maintenance practices: ❑Dusting []Dry sweeping ❑Vacuuming EjPolishing (furniture, etc) ❑Washing or waxing floors Oa vlk E]Carpet cleaning I,]Other , General building use of consumer products (please circle appropriate): Assume: Never = never used, Hardly ever = less than once/month, Occasionally = about once/month, Regularly = about oncetweek, and Daily = approximately once/day. Product Frequency of Use in Building Product Never Rarely occasional) Regularly_ Dail Spray-on deodorants Aerosol deodorizers Insecticides Disinfectants Window cleaners Spray-on oven cleaners Nail polish or remover Hairsprays Solvents/De reasers Paint or paint remover Miscellaneous (specify) 49. Other comments: Figures/Additional Information Plan View: Sketch each floor and if applicable, indicate air sampling locations, possible indoor air pollution sources, preferential pathways and field instrument readings. Potential Outdoor Sources of Pollution: Draw a diagram of the area surrounding the building being sampled. If applicable, provide information on the spill locations (if known), potential air contamination sources (industries, service stations, repair shops, retail shops, landfills, etc.), outdoor air sampling locations, and field.instrument readings. Also, on the diagram, Indicate compass direction, locations of water wells, septic systems, and utility corridors if applicable, and a statement to help locate the site on a topographical map. Complete the attached Chemical Products Inventory Form Chemical Product Inventory Form Building Occupant 5A"L4 M Building Address updA City, State, Zip Code Field Investigator L Date Field Instrument Used MA escri .... .. .. 1M. Voj;Rtj1.q....jqgr.ed1ents-in. n duct Pro 9 t-a .......... Lk ..,:::afte"':dianu A6 u r; mT" Fzzj6r i C r a*a- - — I I - 61e-'r sfaw, Vilc 44-1000 4k /A gj-C-6e 46 1 o s4f 5Cr!,Lf3tP.&c.,h e�-- 0,1 A,-,J - J UL#M-tjDJt IJAMiC,0-11-4 /-Z: al'of &k � ag,S�a;,- t je..' 0 U i (i a D Aco- 1>)- 4 ft(Z- j'/M'0 44) Gass IU<A MeVJV-zx' tir- N "a 6 f-4.W-0 0. a&)- 3,1 16 Vr10""- T'lwjd-�- Vrur JL�)4' -N k)', bV,4a.J-0, ('OYV-f . 002 I 0-111,t., Sksip ;-ToA, t h a14,ld dZ41-1 l �/y�/y�zyy�`��y']� /rye�V/14..?4'� ( fr(/y"�"_" fdi.rCl' TJ L� Lee 3 R kvi-I G�� ►rly ��m� �tip, f� ��, irk►��t s�01'�- b. �� o-z"' Gay�s.3 �Ill� wa..5� l eoZ Z04L o� 3/q IV, Ale- /Z .3c 3�9 c z �l �►�- � - Cam- �� Ib i I 2• 1 : I ; , : i :r ! I}} i I t 1 i I I i I : I : /-1-9 c :. ... 1 [ ir E i ; i i 1 r i j N j i APPENDIX B LABORATORY ANALYTICAL DATA VALIDATION SUMMARY KLEINFELDER 14710 NE 87"'Street,Suite A100,Redmond,WA 98052 p1425.536.7900 f l 425.636.7901 i i � i � � K APPENDIX B LABORATORY ANALYTICAL DATA VALIDATION SUMMARY Laboratory analytical data developed in the sub-slab soil vapor, indoor air, and outdoor air investigation performed in the Residential Study Area as part of the Bozeman Solvent Site investigation, has been evaluated in the manner described in this section and in accordance with the Quaiity Assurance Project Pian (QAPP), Off-Site Soil Vapor Investigation, Bozeman Solvent Site; dated Match 9, 2007, revised June 11, 2009 (Kleinfelder, 2009) with guidance from the United States Environmental Protection Agency (USEPA) National Functional Guidelines for Organic Review (June 2008). Soil vapor samples were collected under this investigation and were submitted to a NELAP-accredited analytical laboratory, Air Toxics Limited, located in Folsom, California, for the following analyses: • E etrachloroethylene (PCE) and chloroform by a modified USEPA Method TO-15 • Helium by a modified American Standard Testing Method (ASTM) 1946 D. Data quality is evaluated by reviewing for precision, accuracy, representativeness, completeness, and comparability. Precision is the measure of the data spread when more than one measurement is taken on the same sample. For duplicate measurements, precision can be expressed as the relative percent difference. Accuracy is the assessment of the closeness of a measured value to the true value. Representativeness is the degree to which a sample accurately and precisely represents the actual concentration or distribution of the chemical compounds in the soil vapor sampled for this investigation. Representativeness is influenced by the number and location of the sampling points, sampling timing and frequency of monitoring efforts, and the field and laboratory sampling procedures. Completeness is a ratio of the amount of valid data obtained from the analytical measurement system to the amount of data expected from the field program. Valid data are considered to be those data that are not rejected ("R" qualfflied) thrcugh data validation. Comparability is the level of correlation between two data sets. Comparability evaluates whether the reported data is comparable with similar data reported by other laboratories. Comparability is maintained by using consistent methods and consistent units. APPENDIX B LABORATORY ANALYTICAL DATA Laboratory quality control (QC) is performed in order to establish whether or not the project quality objectives in the QAPP are met. Laboratory QC calls for precision and accuracy. The basic unit of analytical quality control is defined as the batch. The analytical batch contains no more than 20 field samples of the same matrix. All field and QC samples within a batch are handled and processed in exactly the same way, and all data from each analysis are manipulated in exactly the same manner. Batch assignment is made at the time of analysis. All samples within a batch are analyzed on the same instrument. Field samples are analyzed along with the QC samples prepared with them, if applicable. For this investigation, one field blank was collected during field sampling activities. Each batch contains the following QC samples: 1) Method Blank, 2) Laboratory Duplicate samples, and 3) Laboratory Control samples (LCS), and 4) Continuing Calibration Verification samples. Laboratory method blanks are analyte-free samples which are prepared and analyzed in exactly the same manner as routine samples so as to determine laboratory-induced contamination. Laboratory duplicate samples are laboratory replicates of samples that are subjected to the same preparation and analytical scheme as the original sample. The relative percent difference (RPD) between original and duplicate sample analyses is a measure of the batch precision for the given method. The LCS is an analyte-free sample to which known amounts of the target analytes are added. The LCS is subjected to the same sample preparation or extraction procedure and analyzed exactly like a sample. The percent recovery of the target analytes in the LCS assists in determining whether the method is in control and whether the laboratory is capable of making accurate and precise measurements at the required method reporting limit. Comparison of batch-to-batch LCS analyses enables the laboratory to evaluate batch-to-batch precision and accuracy. Additionally, an initial calibration is performed prior to the analysis of samples, along .with a continuing calibration verification sample (CCV). The initial calibration is a multi- point calibration of all target analytes used to evaluate the linearity of the calibration curve for each instrument. The CCV is analyzed prior to the samples, typically mid- APPENDIX B LABORATORY ANALYTICAL DATA point concentration within the calibration curve that is used to verify that the instrument is performing optimally. A.'I FIELD AND LABORATORY QC RESULTS A total of 136 sub-slab soil vapor, indoor air, and outdoor air samples, including field QC, were collected for the investigation in the Residential Study Area as part of the Bozeman Solvent Site investigation. Analytical parameters had no exclusive requirements while sampling other than maintaining the stainless steel SummaTM canisters in the appropriate containers during shipment of the samples to the analytical laboratory. Upon receipt, the laboratory measured pressure of each SummaTM canister. The representativeness of the data was assured by the use of established laboratory procedures and their consistent application. The expected characterization of the sample was compared to results obtained by laboratory analyses, and was used to evaluate t"e correlation between the sample data and the expected result. Field QC samples were integrated into the sampling design to establish representativeness measurements. Field QC samples (i.e., field blanks and duplicates) were integrated into the sampling design to establish representativeness measurements. Laboratory QC samples (i.e., method/laboratory blank, LCS, and laboratory duplicate) were prepared and analyzed to establish laboratory accuracy and precision. An LCS and laboratory duplicate were prepared and analyzed with each batch of analytical samples. Additionally, the CCVs were analyzed with each analytical, batch at the method-specific frequency and reported percent recoveries within the laboratory's acceptable calibration criteria. Some laboratory report case narratives noted that some samples were diluted due to high concentrations of non-target compounds; however, these dilutions did not appear to impact the results. Canisters were S€M-certified with the exception of chloroform. The canisters were not certified for chloroform to 0.02 ppbv. As a result, all chloroform values to be considered estimated ("J"FUJ" qualified). Field QC samples consisted of field blanks and duplicates, which was collected during the soil vapor sampling activities. Field duplicates were collected at a frequency consistent with the QAPP, one per 10 samples. Eight duplicates were collected during the January 2010 field sampling event to accompany the 82 field samples. And, five field duplicates were collected during the March 2010 field sampling event to accompany 41 field samples. APPENDIX B LABORATORY ANALYTICAL DATA The above-mentioned QC samples, by design, helped ascertain representativeness and all samples that were collected are considered to be representative of site conditions. A.2 DATA VALIDATION SUMMARY The analytical data was submitted as Level II data quality deliverables in hard copy and electronic format. One hundred percent of the analytical data underwent data validation, and included the following elements: • Technical holding times • Field and laboratory blanks • Surrogate spike recoveries Laboratory Precision (Laboratory duplicates) Laboratory Accuracy (LCS and CCV). A.2.1 Technical Holding Time The soil vapor samples were submitted and analyzed by the laboratory within the method-specific holding time of 30 days. No qualifications were applied. A.2.2 Field Quality Control Additionally, the field blank submitted for analysis also reported concentrations of target analytes below the laboratory reporting limits; therefore, no qualifications were applied. Field duplicates were collected at a frequency consistent with the QAPP. The relative percent differences (RPDs) for the field duplicate sample pairs were below 10%, which indicates that the results are considered precise. However, it should be noted that one field blank reported an acetone concentration; however, the associated samples did not report acetone concentrations above the laboratory reporting limit. Table A-1 summarizes the reported concentrations of the target analytes in the field duplicate pair along with the associated RPD. A.2.3 Laboratory Quality Control Method blanks were run with each analytical batch per method specifications to assess laboratory contamination. The method blanks reported by the laboratory reported concentrations of target analytes (i.e., PCE; chloroform, and helium) below the laboratory reporting limits; therefore, no qualifications were applied. APPENDIX B LABORATORY ANALYTICAL DATA At a minimum, one LCS was analyzed with each analytical batch. All LCS recoveries were within the quality control limits, which indicate that the laboratory results are accurate. Additionally, the laboratory prepared and analyzed laboratory duplicates by both USEPA Method TO-15 and ASTM 1946-D at the appropriate frequency. The RPDs for the laboratory duplicate samples were below 20% with the exception of one duplicate pair. • In Work Order#1002070D, the RPD for chloroform In sample DUP-012910-CA-0 was 54%, with the ppbv results being 0.069 and 0.12. As a result, the chloroform results would be considered estimated ("J" flagged) for this duplicate pair. Overall, the low RPDs for the laboratory duplicates indicates the laboratory results are precise. Surrogate spikes were performed for USEPA Methods TO-15. The standards used are chemically similar but not identical to the compound in the fraction being analyzed. The purpose of the surrogate spike is to monitor accuracy on every sample by constantly monitoring for unusual matrix effects and gross sample processing errors. Surrogate recoveries were reported within the laboratory's quality control limits; therefore, no qualifications were applied. Instrument calibration was monitored for each analytical batch at a frequency consistent with the analytical method. The CCV recoveries were within the laboratory's quality control limits; therefore, no qualifications were applied. The comparability of the laboratory results was found to be acceptable. All samples have been analyzed by the same laboratory, using the complete list of published methods specified in the work plan. All units were consistent and appropriate for the matrix. No rejected data was found during the cursory (Level II) data validation process; thus, all data are acceptable for the intended use of the project. A.3 DEVIATIONS NOTED IN ANALYTICAL LABORATORY REPORTS The laboratory narratives for analytical reports 1001555A, 10015558, and 1003669A note that the chain-of-custody information for specific samples did not match the sample tag information. Specifically, the following deviations were noted: APPENDIX B LABORATORY ANALYTICAL DATA • The Chain of.Custody (COC) information for sample RSA-18-503-IA-CS did not match the entry on the sample tag with regard to sample identification. The information on the COC was-used to process and report the sample. This issue was resolved, and the sample identity was verified, by the laboratory by matching the canister and flow controller numbers noted on the chain-of-custody form to the identification numbers on the canister and flow controller. • The Chain of Custody (COC) information for sample OA-032610 did not match the information on the canister with regard to canister identification. The information on the canister was used to process and report the sample. This issue was resolved, and the sample identity was verified, by the laboratory by matching the canister and flow controller numbers noted on the chain-of-custody form to the identification numbers on the canister and flow controller. The laboratory narratives for analytical reports 1002070D, 1002070E, and 100207OF note that analyses were cancelled for specific samples. Specifically, the following deviations were noted: • TO-15 analysis of TB-0125-0202-10 was cancelled because this was a trip blank and analysis of a trip blank was not necessary for the quality control program of this investigation as specified in the QAPP. Trip blanks, in general, are not required for air samples collected in SummaTM canisters. See also Section AA of this appendix. • Helium analysis by ASTM D-1946 was cancelled for the following samples: RSA- 16-303-IA-1, RSA-16-303-IA-2, RSA-16-303-IA-3, OA-7, OA-8, DUP-012710-IA- 1, RSA-16-402-IA-0, RSA-16-402-IA-1, RSA-17-314-IA-0, RSA-17-314-IA-1, DUP-012610-IA-1, OA-10 and OA-9. The ASTM D-1946 analysis is appropriate only for sub-slab soil vapor samples where helium is used as the leak detection gas. Helium analysis by ASTM D-1946 was also cancelled for the following samples: RSA-17-416-IA-CS, RSA-17-416-IA-0, RSA-17-416-IA-1, RSA-17-416-IA-2, RSA-17-512-IA-0, RSA-17-512-IA-1, RSA-13-1602-IA-IA, RSA-13-1602-IA-1 B, RSA-16-502-IA-1, RSA-16-502-IA-0, RSA-16-411 D-IA-0, RSA-16-411 B-IA-1, RSA-15-415-IA-0 and RSA-15-415-IA-1. The ASTM D-1946 analysis is appropriate only for sub-slab soil vapor samples where helium is used as the leak detection gas. APPENDIX B LABORATORY ANALYTICAL DATA The laboratory narrative for 1002070D states that there was a significant difference (greater than 5.0 inHg) between the measured canister receipt vacuum and that which was reported on the chain-of-custody for sample DUP-012910-IA-0. A leak test indicated that the valve was functioning properly. Possibiy, an error was made when the vacuum pressure was recorded on the chain-of-custody. In any case, the PCE concentrations in the duplicate and the primary sample (RSA_17-411-IA-0) were nearly identical (0.96 vs. 1.1 pg/m3), which suggests that the vacuum pressure discrepancy did not affect sample or analytical quality. A.4 DEVIATIONS FROM THE QAPP The following deviations from the QAPP were noted during data validation: • Section 3.2.1 listed the analytical methods to be performed under this investigation. Helium was also analyzed far by ASTM 1946-D. Secticin 3.3.2 provided a summary of the information that was to be included in the sample delivery group or data deliverables. A Level IV data package was stated as required for this investigation; however, a modified Level II package was provided. As a result a full data validation was not performed for this investigation. The Level II data package was evaluated during the data validation, and the laboratory QC appears to be within the laboratory's quality control limits. No further action was taken. • Trip blanks were not collected under this investigation, as stated in Section 6.3.2. Soil vapor sampling and analytical methods do not require trip blanks to be collected or analyzed only for solid and aqueous samples. It should be noted that field blanks were collected during the field sampling events in January and March 2010. Per Section 7.2.2, data validation was to be conducted on Level III and Level IV data quality deliverables by an independent data validation subcontmetor. The data validation performed was on a modified Level II data deliverable, and completed by a Kleinfelder chemist independent to project activities. APPENDIX B LABORATORY ANALYTICAL DATA Table A-1 Field Duplicate Summary Table Primary Analyte Result Duplicate Result RPD by by January 2010 RSA-1.5-503-IA-CS CHCI3 0.14 DUP-012710-IA-1 0.14 0 RSA-16-314-IA-1 CHCI3 0.5 DUP-012910-IA-1 0.5 0 RSA-16-411 B-IA-1 CHCI3 0.23 DUP-012610-IA-1 0.26 12 RSA-17-315-IA-1 CHCI3 0.1 DUP-012910-IA-1 0.1 0 RSA-17-315-IA-0 CHCI3 0.09 DUP-012910-IA-G 0.1 0 RSA-17-411-IA-CS CHCI3 0.051 DUP-012910-CS-0 0.069 11 RSA-1 7-411-IA-0 CHCI3 0.22 DUP-012910-IA-0 0.26 17 OA-9 CHCI3 I ND DUP-013010-IA ND 0 March 2010 RSA-16-303-IA-1 PCE 0.055 DUP-032210-IA-1 0.057 3.6 RSA-17=411-SS-0 PCE 2.7 DUP-032310-SS-0 2.8 3.9 RSA-17-411-IA-CS PCE 0.048 DUP-032310-CS 0.046 4.3 RSA-17-314-SS-0 PCE 3.1 DUP-032510-A 2.9 16.7 OA-32510 PCE 0.068 DUP-032510-B ND -- Notes: ppbv—parts per billion by volume CHCI3-Chloroform PCE—Tetrachloroethylene ND—not detected, below laboratory detection limit APPENDIX C METEOROLOGICAL DATA KLEENFELDER 14710 NE 87"'Street,Sulte A100,Redmond,WA 98052 p1425.636.7900 f{425.636.7901 I� } ti - N�1Nfl NN�S�NN`NNN+ rI"N`N`�N``�N-'i N�N 9 N�N�lNNNrN�r+�N`�N�log i N�N N�N�lNN�,cNN�Nn3 NVn3 N�N`�N N�N�Nc�NlNl N�1 �NNl �NNl �NU N~a N�NNfl�N N�1 N�N7 �1NN1 'Q��g N�r`NVN+`NNN+ Pi w 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O F+ F+ rrrrrrrrrrrrrrrr .i 1Nn A NA N N N N 1-' Fpp+ r r 1 r1-.. r V1 Nnt A NA N N N N V r1n1 1-` r r r r 0 0 0 0 0 0 l0 lyy0 10 1D 1D 1D W paa0 W W W W V V V V V V m OAAl mmm O O O O O S O O O O O S O p O 0 0 S o 000 S O 0 0 0 S O 0 0 0 0 S O 0 0 0 0 00900000 0 0 0 A 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 K 3 o � N N N N N N N N N N N F+ r r r r r r r r r r F+ r r r r r r r r r r r A r N N W W A Vl M m m K 3 .4 m m m V V W V V m W In Vn A A <n F,. 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Outdoor Up-Wind Outdoor Down-Wind Sample ID 0,4 Canister serial# 29 Flow Controller# Cz Sample Start Time Time: C Time: Sample Stop Time. Time: C 71Me: Canister Vacuum(In.Hg) N r-0 a 777- .� 7i06 10 M Time Actual ,j 15 L6 la i 613) Z5 1� o jq4 4/jo Air Temperature ,`a c d` in vicini of sample) 2c) ©�_. Barometric Pressure � in-H �.l. JV•a Relative Humidity(%) fm O J in vicinityof saw le (Z -77 Wind Direction 0— COJ C:,,�:�� i�s.1W1 Wind Speed SLJ 00 C J AJ KI Cyr j Precipitation c (none,snow,rain I%K mod.heavy) L A Nbrifl J r;ii PID Reading(ppb) 6 Samplep ( g) rr 11 a + Intake Heightrfinches ale I Cr� I ai 12l45 f Z j u fS Constituents Sampled !i TO-15 TO-15 TO-15 TO-15 Container Description 6 Liter. Summa 6 Liter Summa 6 Liter Summa 6 Liter Summa Potential Vapor Entry Points Observed? r Checked Seams Yes © No Tracer Gas Test o succesdul ❑Unsucxessm: A Sample Type )Inal"Is U ED) lCabe 0 Flow Blanc a Trip Blank i PhotoTaken ©Yes a NO ❑Yes ❑ we o Yes ❑ No 6 Yes ❑M Comments: u - • Ift 1' t • _ 1 •' F 1g S Project Name: Bozeman Solvent Site Offsite Indoor Air,Sub-Slab Vapor,and Outdoor Air KLE/NFELDER Investination grightPeWe.RlghtSolutrons. Date: 111 A4 12010 Samplers: Canister Address►Location: PID Serial#: FRM- 77777 MW Sample Location Outdoor Wind Outdoor 9&Mnd ; Sample ID - Canister serial# 3. -0 j 1 Flow Controller# �y Sample Start Time Time: 3 o i Time: Sample Stop Time Time: L12- Time: o RaO t _/2 b Canister Vacuum(In.Hg) s 2S:r g�°p' s -Zs, stov--3,S I Time Actual 1'� 0a3 27 1D 0$�2. Z10 0153 TamaG � z710 � Air Temperature 2-41 o n vicinityof sam le 1 Barometric Pressure 7X 7Z m-H Relative Humidity(%} in vicinityof sample) 77 ® t Wind Direction Wind Speed /o 4 Uh Precipitation (none,snow,rain/light,mod,heavy) P ;t i 3 L� 0 , � f d i t PID Reading(ppb) s Sample Depth(fbg)1 s Intake Height inches ale ! , Constituents Sampled TO-15 TO-15 TO-15 TO-15 Container Description 6 Liter Summa 6 Liter Summe 6 Liter Summa 6 Liter Summa Potential Vapor Entry " �[ ) /� Points Observed? /V,4 Checked Seals a No Tracer Gas Test ❑suacessfui a unsumesmul 1 Sample Type XAnelysis ❑Dupk ale ❑ Feld Blank o Trip Blank Photo Taken o Yes f9CNo a Yes 9No a Yes xw- o Yes KN. Comments:OA s s , wa r i. I « 0, hd i -F I .......... I Project Name: Bozeman Solvent Site Ofrslte Indoor Air,Sub-Slab Vapor,and Outdoor Air Iny"doation �._,.✓Bright People.Right Soiudons.. Date: P 7 9 12010 Samplers: Canister Address 1 Location: PID Serial X: ' i Sample Location Outdoor Ind Outd Ind Sample ID ' Canister serial;Ir ., Flow Controller; Sample Start Time Time: 114-7 Time: I`4'r16 I IL � rp Sample Stop Time Time: Time: Y2-v 1 143 stlot elm anleterVacuuerc(in. 5.� —,� s seo e�� Toad •,•7:OOA 12C0 Phi. 6A0 PM �. . [0: 00 � Time Actual ow so, J z.g l a t�xv III-. 111 ion) Air Tenpamiture in vIcinl of sam le 4� OF d Jor— Barometric Pressure ln-H v•3 2, ?' .2-1 j-2, I 30.27 ? Relative Humidity(%) , in vicinity of sample) i Wind Direction J I �1 E Wind Speed Precipitation (none,snow,r6dn IfWd,mod,heavy) C.I�1.(Vkda Ov��1�r �j f�►) PID Reading(ppb) t Sample Depth(fbg)l Intake Hel ht inches als j Constituents Sampled TO-15 TO-15 k TO-15 70-15 i Contelner Description 5 Liter Summa 6 Liter Summa 6 Liter Summa a Liter Summa ? Potential Vapor Entry Points Observed? Checked Seals des ❑ No Tracer Gas Test ❑SL=Bssrul ❑uasuccesswi AJ I i Sample Type XAnelysis 0 Dupicate ❑Raid Sim* ❑Trip Blank i Photo Taken metres ❑No !3 Y�-- �Nn xvea ❑ Comments: 1� d 4 a� f i i Project Name: Bozeman Solvent Site Offsite Indoor Air,Sub-Slab Vapor,and Outdoor Air KLE/NF�',�..DER Investi atlon Bright People Right Solutions. Date: 11 1 1�oio Samplers: T C Canister Address/Location: i PID Serial#: ` soft;Mawamw Sample Location Outdo o ind Outdoor Ind Sample ID Canister serial# 4{4 Flow Controller# 3 Sample Start Time Time, Time: O Q ) Sample Stop Time Time: c l) Time: " t drx Canister Vacuum(in.Hg) sub 2(�. (� spa }! - Fr f .:.Tare' .7A AM7207 ., F 7bA0 PIN Time Actual 721 rD R[ tD �� `f/G�-(' 122 �- 0 -0 53 Air Temperature p j� I[Yer © 0F' in vicinityof sample) /'"" 3 Barometric Pressure R 13 -2 30.[5 (In-Ha) Relative Humidity YO �� 1 in vicinityof sample) (1 V �" 4 Wind Direction ("I i'l - Wind Speed y , �at h� C.J P" 5 h Precipitation E (Wane,snow,rain 1 fight mod,heavy) vi 6 PID Reading(pPb) Sample Depth(fbg)1 / 1 , Intake Hei ht inches als "' e,- Z �2 2- Gi. Constituents Sampled TO-15 TO-15 TO-15 TO-15 Container Description 6 Liter Summa 6 Liter Summa 6 Liter Summa 6 Later Summa I' Potential Vapor Entry Points Observed? Checked Seals }Kies 0 No Tracer Gas Test a Suomsrul u Unsuccessibi Sample Type XA'nah ]S o Duplicate ❑field Blank ❑Trip Blank Photo Taken ❑Yes ❑No D Yes U No 0 Yes 0 No 0 Yes G No t F. Comments: ` f I JS ,9 f Il Ft i i Project Name: Bozeman Solvent Site F(KILEINF-ELDER flk`NW Indoor Air,Sub-Slab Vapor,and Oufidoor Air Investigation SrlgdtPoeopfe Righ±sorurtons Date: 11 f 12010 Samplers: Canister Address I Location: PID Serial 9: 102101 Lam W.MW G I Sample Location Outdoor Outdoor nd { Sample IDLAPLd j Canister serial ' Flow Controller# Sample Start Time Time: h6i 'nme: Sample Stop Time' Time_ 'Tgme: ' ! S a Canister Vacuum(in.Hg) V R Time Actual tL: Irk L) 73ob Q Z'9 i 0 f_10m i 1 v 3 Air Temperature o c in vicinity of sample) `U ' e • r� . i Barometric Pressure a Relative Humidity Kin viclni of Sample) 0 b / Q Z 9 ilieind Direction Wlnd Speed �1 (yes,,•� �i p'� Elln� Precipitation f E (none,snow,rain f iW prod,heavy) Novo /✓(!' 6 lal®Reading(ppb) J'— f Sample Depth(fbg)I Intake Hei ht inches als "�"��, w"i •,. �� Constituents Sampled TO-16 TC-1 S TC-15 TO-15 � Container Description 0 Liter Summe S Uter Summa S Liter Summe 0 Leer Summe Potential Vapor Entry Points Observed? R6A-bVVAj Checked Seals ❑Yes '%No Tracer Gas Test o Su«xsau ❑unsuooses[ot , Sample Type Aneiysrs VUpllcd9 a Fleks Bk* o Tdp Blank Photo Taken NKes n No ❑ c es a?3o n leo Comments: / I ° y A y f I '11,_.. s fi�1 -'IQ i ..a d C , t i s Project Name: Bozeman Solvent Site r \ Offsite Indoor Air,Sub-Slab Vapor,and Outdoor Air Investigation KLE/NFELDER BdghtPb*e.R1ghtSolut1— Date: I 1201Q Samplers: t 1-, - -� Address I Location: 7. ` obvepor Purge Pump SIN: He Detector SIN: fi t` f PID SIN: '-() 0,;0/1 Puma Volume, ! Liters Sample Location Sub-Slab Vaporo Crawl Space C5 1st Floor 2nd Floor 5 Sample ID dt5p-!5 31�-g5•G' �SR -IS 3 -` '` F�-�,•-3 �ip- �s�-I5 3iq- i4-�? /s 3 c� Duplicate Sample ID �- --�•—^'" j Canister serial# �'��?jGJ. ,,f Flow Controller d 5 j 5 �(✓ i 3 licttiile< < I Purge Start{hr:min} Time:geb t n... ..:........... . .. .. ..... ; :,:..: ';Nbt App�cable K! 'p uaatSle '," Hat.'. Not lbie:: :PPS`. Purge Stop(hr:min) Time: 12 P. j Purge Rate(avg. ) LPM• 04 91 Sample Start Time Time: (P3a Time: f o Time:L80Time: f 6 - Time: U Sample Stop Time Time:�17 Time: Time: 175$ :Time: 18 Time: jgoa Y Stop Start Slop: Stark Stop Start Stop: Slit: 3rop: } Canister Vacuum(in.Hg) l f i S a .--. Lr s3 r 4-1 MW AM Air Temperature n vicinity of Sample) J U / Barometric Pressure �2 ��7 `I. �O 12%?6 Relative Humidity In vicinity of sample) Q V p ot'.. . I)i )J31e:.:. ,,.:s:Not' stile; : ::':IVot Apprtc8tble::;=: til Applica ppPkrx %He Under Shroud r' � l�;..:-;M.,.._A'PR.t -- He Oietector Reading a Popes — -- from Soll Vapor g(p>b) N W40 5�f9� 55:a q?`f e PID Readin u iot:�4' Itesle'-: ivot'.. licatile Slab Thickness(inches) Sample Depth(fbg)I -1 u stica I/ afs Ji aft 1 1 �� afs �� afs Intake Height Inches afs) 1 Constituents Sampled TO-15 TO-15 TO-15 TO-15 TO-15 Container Description Liter Summa 6 Liter Summa 6 Liter Summa 6 Liter Summa 6 Liter Summa ., .. k Potential Vapor Sources Observed? Checked Seats Yes ❑ NO Tracer Gas TestSucoessful 0 Unsuccesa4ul Sample Type A Analysis n Dupllcete 0 Flekl Blank 11 Trip His k c Photo Taken �(Yes ❑No Yes ❑No r Yea O No Yes r ❑No - n' 11Comments: 51I vim• rar5 '� n ' l itZ 'Le 6 i Project Name: Bozeman Solvent Site \ Oft he Indoor Air,Sub-Slab Vapor,and Outdoor Air IrtiFeetigatlon KLE/NFELDER )) �� fthtpea^Right5oluthxu Date: W 11 1 ;?? 12010 Samplers: ra dress I Location: Purge Pump SIN: He Detester Sdi�: t o1 PID SIN: qq ,��1 $e��ab Vapos Liters J +'1 `�i�fl Purge Volume: MIMM Sample Location Sub-Slab Vapor let Floor 3r-d Floor 3rd Floor i Sammie ID QSA Duplicate Sample ID Canister serki 9 °; 6 Flow Controller# 0SW Purge Start(hr:mrn) Time: .1+�o4:E4 . . :..;., .,; ,. ,....:..,:;::;:.:;•..=:<::;::: : _ It�pt'>fs.?:;;._ : ,:•Not��l�i�abl�.i-:� �:��I�ot..`- il�kil�' . i A .. abNotRPu�a Stop(hr:min) Time: :--:r ;>•.: .._.; f�. Vof�lpphcai�li = iVot fa'. P 1 Rate av LP�II: : 9• e 5 ! SO u _�I� •'•�c�tiEe�°:�'�' `i�iot`.'': :`kilt" , Sample Start Time- Time:IX17 Time:1� Time: q33 Time: Time: Sample Stop Time Time:_(, ') Time:-- ;r 1 Time: a Tame: RTlme: Canis Vacuum(in.Mgj =� �® M' �.° ' � i start: stop: eer•s t3fop: Mw MINN". Air Terf+peraWmw in vlclnftvof sample) Barometric Pressure, CJ n-H Relative Humidity(%) In vIcInityof sam e %He Lander Shroud ;_:... _ ... ..... He Detector Reading finrrr ` �A Sol[Vrt or / j� A d PID Reading(Ppb) f�'.! /V Slab Thickness(inches) : 'NQi A Ili�ble':: Not RR .. .. .. b> Nab Ift�lJ !Rpm ) fbg Sample Depth(fbg)! �/ afs ':a�;::. Intake Wei ht inches afs Constituents Sampled TO-16 TO-15 TO-15 TO-15 TCLI6 Container Description a Liter Summa @ Liter Summe a Liter Summa 6 LMer Summa 6 UW Summa Potential Vapor Sources Observed? Checked Seals ❑No Tracer Gas Test ,[7ySracr sfut o Jrmmcessful F Sample TVPG j elyets upik Ea o Meld Stank ❑Trip Blank Photo Taken Area ❑rro es ON. Xes ❑N. ❑ � i' Comments: s kZSA R pz%aonjn F i