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Home My WebLink About14- June 9, 2014 Hydrocarbon Summary Allied EngineeringANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT The analyses presented in this report were performed by Energy Laboratories, Inc., 3161 E. Lyndale Ave., Helena, MT 59604, unless otherwise noted. Any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, or the Case Narrative. The results as reported relate only to the item(s) submitted for testing. If you have any questions regarding these test results, please call. Lab ID Client Sample ID Collect Date Receive Date Matrix Test Report Approved By: H14050310-001 S2-A@ 0'-1.5' 04/21/14 11:00 05/16/14 Soil EPH-Ultrasonic Extraction Methanol Extraction for Volatiles Hydrocarbons, Extractable Petroleum-Scrn Volatile Petroleum Hydrocarbons Moisture H14050310-002 S3-A @ 0'-1.5' 04/21/14 15:00 05/16/14 Soil Same As Above H14050310-003 S8-A @ 0'-1.5' 04/24/14 13:00 05/16/14 Soil Same As Above Allied Engineering Services Inc Project Name: PDMC Site Work Order: H14050310 32 S Discovery Dr Bozeman, MT 59718-6958 June 09, 2014 Energy Laboratories Inc Helena MT received the following 3 samples for Allied Engineering Services Inc on 5/16/2014 for analysis. Page 1 of 20 Project: PDMC Site CLIENT: Allied Engineering Services Inc Work Order: H14050310 CASE NARRATIVE 06/09/14 Report Date: Prep Comments for Sample H14050310-001A, Test HC-5035-VPH: The prep hold time was exceeded by 21.2 days. Prep Comments for Sample H14050310-002A, Test HC-5035-VPH: The prep hold time was exceeded by 21.0 days. Prep Comments for Sample H14050310-003A, Test HC-5035-VPH: The prep hold time was exceeded by 18.1 days. Prep Comments for Sample H14050310-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 21.2 days. Prep Comments for Sample H14050310-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 21.0 days. Prep Comments for Sample H14050310-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 18.1 days. Page 2 of 20 LABORATORY ANALYTICAL REPORT Client: Allied Engineering Services Inc Project: PDMC Site Lab ID: H14050310-001 Client Sample ID: S2-A@ 0'-1.5' Collection Date: 04/21/14 11:00 Matrix: Soil Report Date: 06/09/14 DateReceived: 05/16/14 Prepared by Helena, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS H 05/20/14 11:40 / edp 0.2 wt% 6.4 Moisture SW3550A PETROLEUM HYDROCARBONS-VOLATILE 05/22/14 13:29 / kjw 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 05/22/14 13:29 / kjw 0.053 mg/kg-dry ND Benzene MA-VPH 0.04 05/22/14 13:29 / kjw 0.053 mg/kg-dry ND Toluene MA-VPH 10 05/22/14 13:29 / kjw 0.053 mg/kg-dry ND Ethylbenzene MA-VPH 10 J 05/22/14 13:29 / kjw 0.053 mg/kg-dry 0.044 m+p-Xylenes MA-VPH 05/22/14 13:29 / kjw 0.053 mg/kg-dry ND o-Xylene MA-VPH J 05/22/14 13:29 / kjw 0.053 mg/kg-dry 0.044 Xylenes, Total MA-VPH 30 05/22/14 13:29 / kjw 0.11 mg/kg-dry ND Naphthalene MA-VPH 9 05/22/14 13:29 / kjw 2.1 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 05/22/14 13:29 / kjw 2.1 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 40 05/22/14 13:29 / kjw 2.1 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 90 05/22/14 13:29 / kjw 2.1 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 05/22/14 13:29 / kjw 70-130 %REC 95.0 Surr: VPH Aromatics Surrogate MA-VPH 05/22/14 13:29 / kjw 70-130 %REC 94.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN ANALYSIS *05/27/14 11:55 / jdh 106 mg/kg-dry 866 Total Extractable Hydrocarbons SW8015M 200 05/27/14 11:55 / jdh 40-140 %REC 70.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. - *=The reported value exceeds the Maximum Contaminant Limit (MCL). The MCLs listed for target analyte and hydrocarbon range values are the most conservative Montana DEQ RBSLs. These limits may not apply to your samples. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. H - Analysis performed past recommended holding time. J - Estimated value. The analyte was present but less than the reporting limit. Page 3 of 20 LABORATORY ANALYTICAL REPORT Client: Allied Engineering Services Inc Project: PDMC Site Lab ID: H14050310-002 Client Sample ID: S3-A @ 0'-1.5' Collection Date: 04/21/14 15:00 Matrix: Soil Report Date: 06/09/14 DateReceived: 05/16/14 Prepared by Helena, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS H 05/20/14 11:40 / edp 0.2 wt% 7.0 Moisture SW3550A PETROLEUM HYDROCARBONS-VOLATILE 05/22/14 14:38 / kjw 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 05/22/14 14:38 / kjw 0.054 mg/kg-dry ND Benzene MA-VPH 0.04 05/22/14 14:38 / kjw 0.054 mg/kg-dry ND Toluene MA-VPH 10 05/22/14 14:38 / kjw 0.054 mg/kg-dry ND Ethylbenzene MA-VPH 10 J 05/22/14 14:38 / kjw 0.054 mg/kg-dry 0.038 m+p-Xylenes MA-VPH 05/22/14 14:38 / kjw 0.054 mg/kg-dry ND o-Xylene MA-VPH J 05/22/14 14:38 / kjw 0.054 mg/kg-dry 0.038 Xylenes, Total MA-VPH 30 05/22/14 14:38 / kjw 0.11 mg/kg-dry ND Naphthalene MA-VPH 9 05/22/14 14:38 / kjw 2.2 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 05/22/14 14:38 / kjw 2.2 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 40 05/22/14 14:38 / kjw 2.2 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 90 05/22/14 14:38 / kjw 2.2 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 05/22/14 14:38 / kjw 70-130 %REC 90.0 Surr: VPH Aromatics Surrogate MA-VPH 05/22/14 14:38 / kjw 70-130 %REC 87.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN ANALYSIS *05/27/14 15:14 / jdh 210 mg/kg-dry 2220 Total Extractable Hydrocarbons SW8015M 200 05/27/14 15:14 / jdh 40-140 %REC 70.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. - *=The reported value exceeds the Maximum Contaminant Limit (MCL). The MCLs listed for target analyte and hydrocarbon range values are the most conservative Montana DEQ RBSLs. These limits may not apply to your samples. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. H - Analysis performed past recommended holding time. J - Estimated value. The analyte was present but less than the reporting limit. Page 4 of 20 LABORATORY ANALYTICAL REPORT Client: Allied Engineering Services Inc Project: PDMC Site Lab ID: H14050310-003 Client Sample ID: S8-A @ 0'-1.5' Collection Date: 04/24/14 13:00 Matrix: Soil Report Date: 06/09/14 DateReceived: 05/16/14 Prepared by Helena, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS H 05/20/14 11:40 / edp 0.2 wt% 10.7 Moisture SW3550A PETROLEUM HYDROCARBONS-VOLATILE 05/22/14 15:47 / kjw 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 05/22/14 15:47 / kjw 0.056 mg/kg-dry ND Benzene MA-VPH 0.04 J 05/22/14 15:47 / kjw 0.056 mg/kg-dry 0.041 Toluene MA-VPH 10 05/22/14 15:47 / kjw 0.056 mg/kg-dry ND Ethylbenzene MA-VPH 10 05/22/14 15:47 / kjw 0.056 mg/kg-dry 0.099 m+p-Xylenes MA-VPH 05/22/14 15:47 / kjw 0.056 mg/kg-dry ND o-Xylene MA-VPH 05/22/14 15:47 / kjw 0.056 mg/kg-dry 0.099 Xylenes, Total MA-VPH 30 05/22/14 15:47 / kjw 0.11 mg/kg-dry ND Naphthalene MA-VPH 9 05/22/14 15:47 / kjw 2.2 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 05/22/14 15:47 / kjw 2.2 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 40 05/22/14 15:47 / kjw 2.2 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 90 05/22/14 15:47 / kjw 2.2 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 05/22/14 15:47 / kjw 70-130 %REC 92.0 Surr: VPH Aromatics Surrogate MA-VPH 05/22/14 15:47 / kjw 70-130 %REC 90.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN ANALYSIS *05/27/14 16:53 / jdh 112 mg/kg-dry 1050 Total Extractable Hydrocarbons SW8015M 200 05/27/14 16:53 / jdh 40-140 %REC 84.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. - *=The reported value exceeds the Maximum Contaminant Limit (MCL). The MCLs listed for target analyte and hydrocarbon range values are the most conservative Montana DEQ RBSLs. These limits may not apply to your samples. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. H - Analysis performed past recommended holding time. J - Estimated value. The analyte was present but less than the reporting limit. Page 5 of 20 Project: PDMC Site Client: Allied Engineering Services Inc Work Order: H14050310 QA/QC Summary Report 06/09/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Helena, MT Branch Method: MA-VPH Batch: 24610 Lab ID: LCS-24610 05/22/14 11:08 Laboratory Control Sample Run: VARIAN1_140522A 2-Methylpentane 85 70 130 0.10 2.12 mg/kg-dry n-Butylcyclohexane 96 70 130 2.41 mg/kg-dry n-Decane 88 70 130 2.20 mg/kg-dry n-Pentane 81 30 130 0.10 2.02 mg/kg-dry Methyl tert-butyl ether (MTBE) 89 70 130 0.10 2.23 mg/kg-dry Benzene 100 70 130 0.050 2.50 mg/kg-dry Toluene 100 70 130 0.050 2.50 mg/kg-dry Ethylbenzene 103 70 130 0.050 2.56 mg/kg-dry m+p-Xylenes 108 70 130 0.050 5.42 mg/kg-dry o-Xylene 107 70 130 0.050 2.67 mg/kg-dry Naphthalene 98 70 130 0.10 2.57 mg/kg-dry Total Purgeable Hydrocarbons 86 70 130 2.0 32.3 mg/kg-dry Surr: VPH Aromatics Surrogate 107 70 130 0.050 Surr: VPH Aliphatics Surrogate 102 70 130 0.050 Lab ID: MB-24610 05/22/14 12:45 Method Blank Run: VARIAN1_140522A Methyl tert-butyl ether (MTBE) 0.10 ND mg/kg-dry Benzene 0.050 ND mg/kg-dry Toluene 0.050 ND mg/kg-dry Ethylbenzene 0.050 ND mg/kg-dry m+p-Xylenes 0.050 ND mg/kg-dry o-Xylene 0.050 ND mg/kg-dry Naphthalene 0.10 ND mg/kg-dry C9 to C10 Aromatics 2.0 ND mg/kg-dry C5 to C8 Aliphatics 2.0 ND mg/kg-dry C9 to C12 Aliphatics 2.0 ND mg/kg-dry Total Purgeable Hydrocarbons 2.0 ND mg/kg-dry Xylenes, Total 0.050 ND mg/kg-dry Surr: VPH Aromatics Surrogate 97 70 130 0.050 Surr: VPH Aliphatics Surrogate 99 70 130 0.050 Lab ID: H14050293-028AMS 05/22/14 17:08 Sample Matrix Spike Run: VARIAN1_140522A Methyl tert-butyl ether (MTBE) 89 70 130 0.12 2.62 mg/kg-dry Benzene 95 70 130 0.059 2.80 mg/kg-dry Toluene 96 70 130 0.059 2.82 mg/kg-dry Ethylbenzene 97 70 130 0.059 2.87 mg/kg-dry m+p-Xylenes 103 70 130 0.059 6.04 mg/kg-dry o-Xylene 100 70 130 0.059 2.95 mg/kg-dry Naphthalene 97 70 130 0.12 2.85 mg/kg-dry Total Purgeable Hydrocarbons 83 70 130 2.4 36.5 mg/kg-dry Surr: VPH Aromatics Surrogate 91 70 130 0.059 Surr: VPH Aliphatics Surrogate 87 70 130 0.059 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 6 of 20 Project: PDMC Site Client: Allied Engineering Services Inc Work Order: H14050310 QA/QC Summary Report 06/09/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Helena, MT Branch Method: MA-VPH Batch: 24610 Lab ID: H14050293-028AMSD 05/22/14 17:42 Sample Matrix Spike Duplicate Run: VARIAN1_140522A Methyl tert-butyl ether (MTBE) 96 70 130 20 0.12 8.1 2.84 mg/kg-dry Benzene 102 70 130 20 0.059 7.3 3.02 mg/kg-dry Toluene 103 70 130 20 0.059 7.3 3.03 mg/kg-dry Ethylbenzene 104 70 130 20 0.059 7.1 3.08 mg/kg-dry m+p-Xylenes 110 70 130 20 0.059 6.9 6.47 mg/kg-dry o-Xylene 108 70 130 20 0.059 7.6 3.18 mg/kg-dry Naphthalene 113 70 130 20 0.12 16 3.34 mg/kg-dry Total Purgeable Hydrocarbons 89 70 130 20 2.4 7.5 39.3 mg/kg-dry Surr: VPH Aromatics Surrogate 87 70 130 0.059 Surr: VPH Aliphatics Surrogate 85 70 130 0.059 Method: MA-VPH Analytical Run: R97349 Lab ID: CCV_0521GC239r-S 05/22/14 10:16 Continuing Calibration Verification Standard 1,2,4-Trimethylbenzene 107 75 125 0.10 2.67 mg/kg-dry 2,2,4-Trimethylpentane 102 75 125 0.10 2.56 mg/kg-dry 2-Methylpentane 94 75 125 0.10 2.35 mg/kg-dry n-Butylcyclohexane 107 75 125 2.66 mg/kg-dry n-Decane 112 75 125 2.79 mg/kg-dry n-Pentane 89 75 125 0.10 2.22 mg/kg-dry Methyl tert-butyl ether (MTBE) 97 75 125 0.10 2.41 mg/kg-dry Benzene 103 75 125 0.050 2.58 mg/kg-dry Toluene 104 75 125 0.050 2.61 mg/kg-dry Ethylbenzene 107 75 125 0.050 2.67 mg/kg-dry m+p-Xylenes 109 75 125 0.050 5.47 mg/kg-dry o-Xylene 108 75 125 0.050 2.71 mg/kg-dry Naphthalene 98 75 125 0.10 2.46 mg/kg-dry Surr: VPH Aromatics Surrogate 87 70 130 0.050 Surr: VPH Aliphatics Surrogate 92 70 130 0.050 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 7 of 20 Project: PDMC Site Client: Allied Engineering Services Inc Work Order: H14050310 QA/QC Summary Report 06/09/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Helena, MT Branch Method: SW3550A Batch: R97252 Lab ID: H14050310-001ADUP 05/20/14 11:40 Sample Duplicate Run: SOIL DRYING OVEN 2_14051 Moisture 20 0.20 12 7.20 wt% Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 8 of 20 Project: PDMC Site Client: Allied Engineering Services Inc Work Order: H14050310 QA/QC Summary Report 06/09/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Helena, MT Branch Method: SW8015M Batch: 24609 Lab ID: MB-24609 05/23/14 19:53 Method Blank Run: HHP_140523A Total Extractable Hydrocarbons 10 ND mg/kg-dry Surr: o-Terphenyl 83 40 140 0.17 Lab ID: LCS-24609 05/23/14 20:40 Laboratory Control Sample Run: HHP_140523A Total Extractable Hydrocarbons 82 60 140 10 167 mg/kg-dry Surr: o-Terphenyl 99 40 140 0.17 Lab ID: H14050327-032AMS 05/25/14 00:00 Sample Matrix Spike Run: HHP2_140524A Total Extractable Hydrocarbons 134 60 140 13 893 mg/kg-dry Surr: o-Terphenyl 94 40 140 0.21 Lab ID: H14050327-032AMSD 05/25/14 00:50 Sample Matrix Spike Duplicate Run: HHP2_140524A Total Extractable Hydrocarbons 74 60 140 20 13 19 735 mg/kg-dry Surr: o-Terphenyl 83 40 140 0.21 Method: SW8015M Analytical Run: R97472 Lab ID: CCV_0527GC401r-S 05/27/14 10:34 Continuing Calibration Verification Standard n-Nonane 83 75 125 5.54 mg/kg-dry n-Decane 84 75 125 5.60 mg/kg-dry n-Dodecane 82 75 125 5.49 mg/kg-dry n-Tetradecane 85 75 125 5.64 mg/kg-dry n-Hexadecane 84 75 125 5.60 mg/kg-dry n-Octadecane 84 75 125 5.60 mg/kg-dry n-Nonadecane 84 75 125 5.60 mg/kg-dry n-Eicosane 84 75 125 5.60 mg/kg-dry n-Docosane 84 75 125 5.57 mg/kg-dry n-Tetracosane 84 75 125 5.59 mg/kg-dry n-Hexacosane 84 75 125 5.61 mg/kg-dry n-Octacosane 84 75 125 5.63 mg/kg-dry n-Triacontane 87 75 125 5.83 mg/kg-dry n-Hexatriacontane 100 75 125 6.66 mg/kg-dry Surr: o-Terphenyl 89 75 125 0.17 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 9 of 20 S2-A@ 0'-1.5'Batch ID: 24609 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: H14050310-001A ;0527GC4 , $HC-EPH-SCRN-S, ,(2,5) Raw File: G:\Org\4GC\DAT\4GC052714_b\0527GC4.0003.RAW Date & Time Acquired: 5/27/2014 11:55:22 AM Method File: G:\Org\4GC\Methods\GC4_2014Methods\05271403.MET Calibration File: G:\Org\4GC\Cals\GC4_2014CALS\SC052414B.CAL Sample Weight: 14.2 Dilution: 10 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 1814.484 Mean RF for C19 to C36 Hydrocarbons: 1763.908 Mean RF for Total Extractable Hydrocarbons: 1789.196 Rt range for Diesel Range Organics: 7.14 to 17.49 Rt range for C9 to C18 Hydrocarbons: 6.19 to 13.02 Rt range for C19 to C36 Hydrocarbons: 13.07 to 20.89 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________13.12 14.085 9.835 69.83 - *1-Chloro-octadecane_____13.895 14.085 10.296 73.1 - DRO Area:391957.5 DRO Amount: 154.274 TEH Area:2199260 TEH Amount: 865.6262 C9-C18 Area:12597.74 C9-C18 Amount: 4.889349 C19-C36 Area:1387185 C19-C36 Amount: 553.8218 1 1 . 3 9 1 2 . 4 7 1 2 . 5 3 1 2 . 9 8 1 3 . 1 2 1 3 . 9 0 1 4 . 9 8 1 5 . 0 6 1 5 . 1 1 1 5 . 2 0 1 5 . 2 7 1 5 . 3 1 1 5 . 3 4 1 5 . 3 9 1 5 . 4 6 1 5 . 4 9 1 5 . 5 4 1 5 . 6 0 1 5 . 6 8 1 5 . 7 3 1 5 . 8 1 1 5 . 8 8 1 5 . 9 3 1 5 . 9 8 1 6 . 0 4 1 6 . 1 2 1 6 . 1 8 1 6 . 2 1 1 6 . 2 6 1 6 . 3 7 1 6 . 4 6 1 6 . 5 9 1 6 . 6 9 1 6 . 7 9 1 6 . 8 2 1 6 . 8 4 1 7 . 0 0 1 7 . 0 6 1 7 . 1 5 1 7 . 2 3 1 7 . 3 1 1 7 . 4 0 1 7 . 4 3 1 7 . 5 1 1 7 . 5 7 1 7 . 6 6 1 7 . 7 4 1 7 . 8 7 1 7 . 9 3 1 8 . 0 6 1 8 . 2 9 1 8 . 3 8 1 8 . 4 7 1 8 . 5 7 1 8 . 6 8 1 8 . 8 1 1 8 . 8 9 1 9 . 0 0 1 9 . 0 6 1 9 . 1 7 1 9 . 2 3 1 9 . 3 5 1 9 . 4 6 1 9 . 5 5 1 9 . 7 1 1 9 . 8 1 1 9 . 9 2 1 9 . 9 5 2 0 . 0 3 2 0 . 0 9 2 0 . 1 5 2 0 . 2 4 2 0 . 2 7 2 0 . 4 8 2 0 . 5 5 2 0 . 6 1 2 0 . 6 8 2 0 . 7 2 2 0 . 8 5 2 0 . 9 0 2 0 . 9 8 2 1 . 0 5 2 1 . 1 0 2 1 . 4 3 2 1 . 5 0 2 1 . 5 6 2 1 . 6 0 2 1 . 6 8 2 1 . 7 6 2 1 . 9 2 2 1 . 9 6 2 2 . 0 0 2 2 . 0 4 2 2 . 0 9 2 2 . 1 2 2 2 . 3 3 2 2 . 5 4 2 2 . 6 9 2 2 . 7 3 2 2 . 8 2 2 2 . 8 5 2 2 . 9 2 2 3 . 0 0 2 3 . 0 4 2 3 . 1 0 2 3 . 5 1 2 3 . 5 4 2 3 . 6 1 2 3 . 7 1 2 3 . 7 8 2 3 . 8 3 2 3 . 9 3 2 3 . 9 6 2 4 . 0 1 2 4 . 1 2 2 4 . 2 3 2 4 . 2 7 2 4 . 3 7 2 4 . 4 3 2 4 . 4 6 2 4 . 5 1 2 4 . 5 4 2 4 . 5 7 2 4 . 6 4 2 4 . 7 0 2 4 . 7 9 2 4 . 8 3 2 5 . 1 0 2 5 . 2 8 2 5 . 3 2 2 5 . 3 8 2 5 . 5 3 2 5 . 6 6 2 5 . 7 9 2 5 . 8 2 2 6 . 0 1 2 6 . 3 0 2 6 . 4 0 2 6 . 4 8 2 6 . 5 7 2 6 . 6 7 2 6 . 7 2 2 6 . 7 4 2 6 . 7 9 2 6 . 9 7 2 7 . 0 3 2 7 . 0 7 2 7 . 1 1 2 7 . 1 6 2 7 . 2 7 2 7 . 3 9 2 7 . 4 6 2 7 . 5 7 2 7 . 6 7 2 7 . 8 5 2 8 . 8 5 2 9 . 1 2 2 9 . 1 5 2 9 . 3 5 2 9 . 6 8 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e IN T - I N T + S B N S B N IN T - G:\Org\4GC\DAT\4GC052714_b\0527GC4.0003.RAW H14050310-001A ;0527GC4 , $HC-EPH-SCRN-S, ,(2,5) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 Page 10 of 20 S3-A @ 0'-1.5'Batch ID: 24609 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: H14050310-002A ;0527GC4 , $HC-EPH-SCRN-S, ,(2,10) Raw File: G:\Org\4GC\DAT\4GC052714_b\0527GC4.0007.RAW Date & Time Acquired: 5/27/2014 3:14:13 PM Method File: G:\Org\4GC\Methods\GC4_2014Methods\05271403.MET Calibration File: G:\Org\4GC\Cals\GC4_2014CALS\SC052414B.CAL Sample Weight: 14.3 Dilution: 20 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 1814.484 Mean RF for C19 to C36 Hydrocarbons: 1763.908 Mean RF for Total Extractable Hydrocarbons: 1789.196 Rt range for Diesel Range Organics: 7.14 to 17.49 Rt range for C9 to C18 Hydrocarbons: 6.19 to 13.02 Rt range for C19 to C36 Hydrocarbons: 13.07 to 20.89 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________13.123 13.986 9.849 70.42 - *1-Chloro-octadecane_____13.896 13.986 11.787 84.28 - DRO Area:741091.8 DRO Amount: 579.306 TEH Area:2835394 TEH Amount: 2216.406 C9-C18 Area:23347.47 C9-C18 Amount: 17.99619 C19-C36 Area:1916279 C19-C36 Amount: 1519.416 5 . 4 3 5 . 7 3 6 . 0 2 7 . 2 5 7 . 7 9 8 . 0 9 8 . 4 3 9 . 5 7 9 . 6 5 1 0 . 3 0 1 0 . 5 3 1 0 . 6 2 1 0 . 7 7 1 0 . 9 4 1 1 . 3 9 1 1 . 7 2 1 2 . 3 4 1 3 . 1 2 1 3 . 8 0 1 3 . 9 0 1 4 . 0 2 1 4 . 0 7 1 4 . 1 7 1 4 . 3 1 1 4 . 3 5 1 4 . 4 0 1 4 . 4 6 1 4 . 5 6 1 4 . 6 6 1 4 . 7 4 1 4 . 7 7 1 4 . 8 3 1 4 . 8 8 1 4 . 9 4 1 4 . 9 9 1 5 . 0 2 1 5 . 0 6 1 5 . 1 1 1 5 . 2 3 1 5 . 2 7 1 5 . 3 1 1 5 . 3 9 1 5 . 4 3 1 5 . 4 6 1 5 . 4 9 1 5 . 6 0 1 5 . 6 3 1 5 . 6 8 1 5 . 7 4 1 5 . 8 1 1 5 . 8 8 1 5 . 9 3 1 6 . 0 1 1 6 . 1 2 1 6 . 1 8 1 6 . 2 6 1 6 . 3 2 1 6 . 3 7 1 6 . 4 7 1 6 . 5 3 1 6 . 5 9 1 6 . 6 9 1 6 . 7 9 1 6 . 8 3 1 6 . 9 1 1 7 . 0 1 1 7 . 1 6 1 7 . 2 4 1 7 . 3 1 1 7 . 3 6 1 7 . 5 2 1 7 . 5 9 1 7 . 6 6 1 7 . 7 4 1 7 . 8 7 1 7 . 9 3 1 8 . 0 7 1 8 . 3 1 1 8 . 4 0 1 8 . 4 7 1 8 . 5 8 1 8 . 6 9 1 8 . 8 2 1 9 . 0 0 1 9 . 0 6 1 9 . 1 8 1 9 . 2 4 1 9 . 3 4 1 9 . 4 6 1 9 . 5 8 1 9 . 7 3 1 9 . 9 0 2 0 . 0 7 2 0 . 2 5 2 0 . 2 8 2 0 . 5 1 2 0 . 5 5 2 0 . 6 3 2 0 . 6 7 2 0 . 7 3 2 0 . 8 4 2 1 . 0 2 2 1 . 0 6 2 1 . 0 9 2 1 . 2 6 2 1 . 4 2 2 1 . 4 8 2 1 . 5 6 2 1 . 6 4 2 1 . 6 9 2 1 . 7 3 2 1 . 9 0 2 1 . 9 8 2 2 . 0 2 2 2 . 1 3 2 2 . 2 7 2 2 . 3 2 2 2 . 4 6 2 2 . 5 6 2 2 . 6 5 2 2 . 7 2 2 2 . 8 4 2 2 . 9 9 2 3 . 0 4 2 3 . 2 5 2 3 . 3 6 2 3 . 4 2 2 3 . 4 8 2 3 . 5 5 2 3 . 5 8 2 3 . 6 5 2 3 . 7 1 2 3 . 7 6 2 3 . 8 0 2 3 . 8 3 2 3 . 9 3 2 3 . 9 6 2 4 . 0 6 2 4 . 1 6 2 4 . 2 7 2 4 . 3 4 2 4 . 4 1 2 4 . 5 1 2 4 . 5 5 2 4 . 5 9 2 4 . 7 1 2 4 . 7 5 2 4 . 8 0 2 4 . 8 6 2 4 . 9 1 2 5 . 0 6 2 5 . 1 1 2 5 . 1 7 2 5 . 2 6 2 5 . 3 1 2 5 . 4 6 2 5 . 5 5 2 5 . 5 9 2 5 . 6 8 2 5 . 7 4 2 5 . 8 1 2 5 . 8 9 2 6 . 2 0 2 6 . 2 3 2 6 . 2 7 2 6 . 5 1 2 6 . 5 6 2 6 . 6 1 2 6 . 6 4 2 6 . 7 0 2 6 . 7 5 2 6 . 8 2 2 6 . 9 6 2 7 . 0 0 2 7 . 0 5 2 7 . 1 0 2 7 . 1 8 2 7 . 2 4 2 7 . 3 0 2 7 . 3 4 2 7 . 3 8 2 7 . 4 2 2 7 . 5 2 2 7 . 5 6 2 7 . 6 2 2 7 . 6 8 2 7 . 7 3 2 7 . 7 8 2 7 . 8 2 2 7 . 8 5 2 8 . 7 4 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e IN T - I N T + S B N S B N IN T - G:\Org\4GC\DAT\4GC052714_b\0527GC4.0007.RAW H14050310-002A ;0527GC4 , $HC-EPH-SCRN-S, ,(2,10) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 Page 11 of 20 S8-A @ 0'-1.5'Batch ID: 24609 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: H14050310-003A ;0527GC4 , $HC-EPH-SCRN-S, ,(2,5) Raw File: G:\Org\4GC\DAT\4GC052714_b\0527GC4.0009.RAW Date & Time Acquired: 5/27/2014 4:53:43 PM Method File: G:\Org\4GC\Methods\GC4_2014Methods\05271403.MET Calibration File: G:\Org\4GC\Cals\GC4_2014CALS\SC052414B.CAL Sample Weight: 13.4 Dilution: 10 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 1814.484 Mean RF for C19 to C36 Hydrocarbons: 1763.908 Mean RF for Total Extractable Hydrocarbons: 1789.196 Rt range for Diesel Range Organics: 7.14 to 17.49 Rt range for C9 to C18 Hydrocarbons: 6.19 to 13.02 Rt range for C19 to C36 Hydrocarbons: 13.07 to 20.89 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________13.126 14.925 12.524 83.91 - *1-Chloro-octadecane_____13.899 14.925 13.54 90.72 - DRO Area:455321.2 DRO Amount: 189.9132 TEH Area:2507996 TEH Amount: 1046.078 C9-C18 Area:24655.43 C9-C18 Amount: 10.14039 C19-C36 Area:1545604 C19-C36 Amount: 653.9093 6 . 9 9 7 . 2 6 7 . 5 9 8 . 4 3 8 . 7 3 8 . 8 8 9 . 0 5 9 . 5 4 9 . 6 5 9 . 9 2 1 0 . 2 9 1 1 . 1 8 1 3 . 1 3 1 3 . 9 0 1 4 . 0 8 1 4 . 3 1 1 4 . 3 7 1 4 . 4 6 1 4 . 5 3 1 4 . 5 7 1 4 . 6 7 1 4 . 7 4 1 4 . 7 9 1 4 . 8 9 1 4 . 9 9 1 5 . 0 6 1 5 . 1 2 1 5 . 2 0 1 5 . 3 5 1 5 . 4 0 1 5 . 4 6 1 5 . 5 0 1 5 . 5 4 1 5 . 6 0 1 5 . 6 8 1 5 . 7 4 1 5 . 8 2 1 5 . 9 4 1 5 . 9 8 1 6 . 0 4 1 6 . 2 2 1 6 . 2 7 1 6 . 3 4 1 6 . 6 1 1 6 . 7 0 1 6 . 8 5 1 7 . 0 1 1 7 . 0 6 1 7 . 1 6 1 7 . 1 9 1 7 . 2 4 1 7 . 3 2 1 7 . 4 0 1 7 . 4 4 1 7 . 5 2 1 7 . 5 8 1 7 . 6 7 1 7 . 7 5 1 7 . 9 4 1 8 . 0 7 1 8 . 1 9 1 8 . 2 7 1 8 . 3 9 1 8 . 4 8 1 8 . 6 0 1 8 . 6 3 1 8 . 7 0 1 8 . 8 1 1 9 . 0 0 1 9 . 0 6 1 9 . 1 7 1 9 . 2 5 1 9 . 4 4 1 9 . 4 8 1 9 . 6 2 1 9 . 7 5 1 9 . 8 0 1 9 . 8 4 1 9 . 9 6 2 0 . 0 8 2 0 . 2 4 2 0 . 2 7 2 0 . 5 1 2 0 . 6 5 2 0 . 7 4 2 0 . 8 4 2 0 . 9 9 2 1 . 0 2 2 1 . 1 0 2 1 . 1 9 2 1 . 3 2 2 1 . 5 1 2 1 . 6 5 2 1 . 7 1 2 1 . 7 7 2 1 . 9 6 2 2 . 0 4 2 2 . 1 3 2 2 . 1 6 2 2 . 2 6 2 2 . 3 2 2 2 . 3 5 2 2 . 6 0 2 2 . 6 5 2 2 . 7 3 2 2 . 9 5 2 3 . 0 1 2 3 . 0 6 2 3 . 1 0 2 3 . 3 8 2 3 . 4 9 2 3 . 5 4 2 3 . 6 3 2 3 . 6 8 2 3 . 7 2 2 3 . 7 9 2 3 . 8 3 2 3 . 8 7 2 3 . 9 5 2 4 . 0 2 2 4 . 0 4 2 4 . 2 4 2 4 . 3 0 2 4 . 3 6 2 4 . 4 1 2 4 . 4 7 2 4 . 5 2 2 4 . 5 5 2 4 . 6 1 2 4 . 6 6 2 4 . 7 3 2 4 . 7 7 2 4 . 9 9 2 5 . 0 9 2 5 . 2 4 2 5 . 3 1 2 5 . 3 7 2 5 . 4 3 2 5 . 4 6 2 5 . 5 4 2 5 . 5 8 2 5 . 6 0 2 5 . 6 4 2 5 . 7 2 2 5 . 7 7 2 5 . 8 2 2 5 . 8 8 2 6 . 0 6 2 6 . 2 6 2 6 . 3 7 2 6 . 4 5 2 6 . 5 4 2 6 . 6 0 2 6 . 6 7 2 6 . 7 4 2 6 . 8 0 2 6 . 8 4 2 6 . 8 8 2 6 . 9 8 2 7 . 0 6 2 7 . 0 8 2 7 . 1 1 2 7 . 4 9 2 7 . 5 7 2 7 . 6 6 2 7 . 7 0 2 7 . 8 2 2 7 . 9 3 2 8 . 0 0 2 8 . 6 7 2 8 . 7 7 2 8 . 8 8 2 9 . 0 6 2 9 . 2 2 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e IN T - I N T + S B N S B N IN T - G:\Org\4GC\DAT\4GC052714_b\0527GC4.0009.RAW H14050310-003A ;0527GC4 , $HC-EPH-SCRN-S, ,(2,5) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 Page 12 of 20 S2-A@ 0'-1.5' Batch ID: 24610 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050310-001A ;0522GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC052214_b\0522GC2.0004.RAW Date & Time Acquired: 5/22/2014 1:29:46 PM Method File: G:\Org\2GC\Methods\05221404.MET Calibration File: G:\Org\2GC\Cals\Vhn042214.cal Sample Weight: 50 Dilution: 1.07 S.A.: 1.07 Mean RF for C9 to C10 Aromatic Hydrocarbons: 420.4557 Rt range for C9 to C10 Aromatics: 14.566 to 20.099 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:10195.95 C9-C10 Aromatics Amount: 0.5189447 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .107 U Benzene__________________. . . .054 U Toluene__________________10.083 10.083 10.083 180 .054 U Ethylbenzene_____________13.495 13.495 13.495 212 .054 U m+p-Xylenes______________13.651 -5.704 -5.7 883 .044 J o-Xylene_________________14.448 14.448 14.448 253 .054 U 124-Trimethylbenzene_____16.5 -8.55 -8.549 837 .041 J Naphthalene______________20.187 20.187 20.187 511 .107 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______7.951 2.675 2.525 94.38 70-130 0 . 1 5 4 . 6 7 5 . 7 6 7 . 9 5 1 0 . 0 8 1 0 . 5 4 1 1 . 5 2 1 3 . 5 0 1 3 . 6 5 1 4 . 4 5 1 4 . 6 2 1 5 . 4 9 1 5 . 6 9 1 5 . 8 5 1 5 . 9 2 1 6 . 2 9 1 6 . 5 0 1 6 . 6 3 1 7 . 0 1 1 7 . 1 6 1 7 . 3 6 1 7 . 4 6 1 7 . 5 9 1 7 . 7 2 1 7 . 8 6 1 7 . 9 7 1 8 . 2 4 1 8 . 4 3 1 8 . 5 4 1 8 . 6 3 1 8 . 9 1 1 9 . 0 3 1 9 . 1 5 1 9 . 2 6 1 9 . 4 6 1 9 . 8 5 1 9 . 9 1 2 0 . 0 5 2 0 . 1 9 2 0 . 3 6 2 0 . 5 3 2 1 . 7 7 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\2GC\DAT\2GC052214_b\0522GC2.0004.RAW H14050310-001A ;0522GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Page 13 of 20 S2-A@ 0'-1.5' Batch ID: 24610 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050310-001A ;0522GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC052214_b\0522GC2B.0004.RAW Date & Time Acquired: 5/22/2014 1:29:46 PM Method File: G:\Org\2GC\Methods\lavar042214B.MET Calibration File: G:\Org\2GC\Cals\Vhn042214B.cal Sample Weight: 50 Dilution: 1.07 S.A.: 1.07 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 431.8487 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 338.7009 Mean RF for all calibrated compounds: 473.2145 Rt range for Gasoline Range Organics: 4.391 to 15.614 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.524 to 13.01 Rt range for C9 to C12 Aliphatic Hydrocarbons: 13.06 to 20.133 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________7.956 2.675 2.509 93.78 - GRO Area:4807.813 GRO Amount: 0.2174219 TPH Area:13451.36 TPH Amount: 0.6083056 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:2251.109 C5-C8 Amount: 0.1115524 C9-C12 Area:10343.15 C9-C12 Amount: 0.6535071 4 . 3 4 4 . 6 7 4 . 9 7 6 . 6 8 7 . 9 6 9 . 5 5 1 0 . 0 8 1 1 . 6 5 1 3 . 0 9 1 3 . 5 1 1 3 . 6 6 1 4 . 0 0 1 4 . 3 0 1 4 . 4 6 1 4 . 6 3 1 5 . 5 0 1 5 . 7 0 1 5 . 8 6 1 6 . 3 1 1 6 . 5 1 1 6 . 6 4 1 6 . 9 5 1 7 . 2 0 1 7 . 3 8 1 7 . 4 7 1 7 . 6 0 1 7 . 8 7 1 7 . 9 8 1 8 . 1 8 1 8 . 2 6 1 8 . 4 5 1 8 . 5 5 1 9 . 1 7 1 9 . 2 8 1 9 . 4 8 1 9 . 8 3 2 0 . 0 5 2 0 . 2 2 2 0 . 5 4 2 1 . 7 1 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n e n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\2GC\DAT\2GC052214_b\0522GC2B.0004.RAW H14050310-001A ;0522GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 Page 14 of 20 S3-A @ 0'-1.5' Batch ID: 24610 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050310-002A ;0522GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC052214_b\0522GC2.0006.RAW Date & Time Acquired: 5/22/2014 2:38:33 PM Method File: G:\Org\2GC\Methods\05221406.MET Calibration File: G:\Org\2GC\Cals\Vhn042214.cal Sample Weight: 50 Dilution: 1.08 S.A.: 1.08 Mean RF for C9 to C10 Aromatic Hydrocarbons: 420.4557 Rt range for C9 to C10 Aromatics: 14.566 to 20.099 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:11030.07 C9-C10 Aromatics Amount: 0.566646 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .108 U Benzene__________________7.203 7.203 7.203 100 .054 U Toluene__________________10.077 10.077 10.077 144 .054 U Ethylbenzene_____________13.498 13.498 13.498 289 .054 U m+p-Xylenes______________13.641 -5.704 -5.693 754 .038 J o-Xylene_________________14.44 14.44 14.44 213 .054 U 124-Trimethylbenzene_____16.494 16.494 16.494 460 .054 U Naphthalene______________20.182 20.182 20.182 457 .108 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______7.949 2.7 2.411 89.31 70-130 3 . 4 6 4 . 0 7 4 . 9 8 5 . 7 8 6 . 4 2 7 . 2 0 7 . 9 5 1 0 . 0 8 1 0 . 2 5 1 3 . 0 7 1 3 . 5 0 1 3 . 6 4 1 4 . 4 4 1 4 . 6 3 1 5 . 5 4 1 5 . 6 8 1 5 . 8 4 1 5 . 9 1 1 6 . 2 7 1 6 . 4 9 1 6 . 6 2 1 6 . 8 1 1 6 . 9 2 1 7 . 1 6 1 7 . 3 6 1 7 . 4 5 1 7 . 5 8 1 7 . 7 1 1 7 . 8 5 1 7 . 9 6 1 8 . 2 3 1 8 . 4 3 1 8 . 5 3 1 8 . 6 2 1 8 . 7 6 1 8 . 9 1 1 9 . 0 1 1 9 . 1 6 1 9 . 4 5 1 9 . 9 3 2 0 . 0 4 2 0 . 1 8 2 0 . 3 5 2 0 . 5 2 2 0 . 6 4 2 0 . 9 2 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\2GC\DAT\2GC052214_b\0522GC2.0006.RAW H14050310-002A ;0522GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Page 15 of 20 S3-A @ 0'-1.5' Batch ID: 24610 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050310-002A ;0522GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC052214_b\0522GC2B.0006.RAW Date & Time Acquired: 5/22/2014 2:38:33 PM Method File: G:\Org\2GC\Methods\lavar042214B.MET Calibration File: G:\Org\2GC\Cals\Vhn042214B.cal Sample Weight: 50 Dilution: 1.08 S.A.: 1.08 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 431.8487 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 338.7009 Mean RF for all calibrated compounds: 473.2145 Rt range for Gasoline Range Organics: 4.391 to 15.614 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.524 to 13.01 Rt range for C9 to C12 Aliphatic Hydrocarbons: 13.06 to 20.133 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________7.954 2.7 2.336 86.53 - GRO Area:9869.313 GRO Amount: 0.4504874 TPH Area:17929.87 TPH Amount: 0.8184137 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:7495.754 C5-C8 Amount: 0.374919 C9-C12 Area:9500.481 C9-C12 Amount: 0.6058751 4 . 3 4 4 . 6 7 4 . 9 7 5 . 7 8 6 . 6 8 7 . 2 0 7 . 9 5 9 . 5 5 1 0 . 0 7 1 1 . 7 3 1 2 . 1 9 1 3 . 0 8 1 3 . 5 0 1 3 . 6 5 1 4 . 4 5 1 4 . 6 3 1 5 . 0 5 1 5 . 4 9 1 5 . 6 9 1 5 . 8 5 1 6 . 2 7 1 6 . 5 0 1 6 . 6 3 1 6 . 9 3 1 7 . 1 8 1 7 . 3 7 1 7 . 4 7 1 7 . 5 9 1 7 . 8 2 1 7 . 9 7 1 8 . 2 5 1 8 . 4 5 1 8 . 5 5 1 9 . 1 8 1 9 . 4 7 1 9 . 7 8 1 9 . 9 3 2 0 . 0 6 2 0 . 2 3 2 0 . 3 8 2 0 . 5 5 2 1 . 6 9 2 2 . 3 2 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n e n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\2GC\DAT\2GC052214_b\0522GC2B.0006.RAW H14050310-002A ;0522GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 Page 16 of 20 S8-A @ 0'-1.5' Batch ID: 24610 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050310-003A ;0522GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC052214_b\0522GC2.0008.RAW Date & Time Acquired: 5/22/2014 3:47:15 PM Method File: G:\Org\2GC\Methods\05221408.MET Calibration File: G:\Org\2GC\Cals\Vhn042214.cal Sample Weight: 50 Dilution: 1.12 S.A.: 1.12 Mean RF for C9 to C10 Aromatic Hydrocarbons: 420.4557 Rt range for C9 to C10 Aromatics: 14.566 to 20.099 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:7875.371 C9-C10 Aromatics Amount: 0.4195646 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .112 U Benzene__________________7.192 7.192 7.192 144 .056 U Toluene__________________10.074 -2.125 -2.121 710 .041 J Ethylbenzene_____________13.5 13.5 13.5 557 .056 U m+p-Xylenes______________13.651 -5.704 -5.699 1906 .099 o-Xylene_________________14.453 14.453 14.453 445 .056 U 124-Trimethylbenzene_____16.501 -8.55 -8.548 749 .038 J Naphthalene______________20.188 20.188 20.188 175 .112 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______7.953 2.8 2.59 92.5 70-130 3 . 7 8 4 . 0 7 4 . 6 8 5 . 5 8 7 . 1 9 7 . 9 5 1 0 . 0 7 1 0 . 5 2 1 1 . 5 5 1 3 . 5 0 1 3 . 6 5 1 4 . 4 5 1 4 . 6 3 1 5 . 4 9 1 5 . 6 9 1 5 . 8 4 1 5 . 9 2 1 6 . 3 0 1 6 . 5 0 1 6 . 6 3 1 6 . 9 4 1 7 . 1 6 1 7 . 3 7 1 7 . 4 6 1 7 . 5 9 1 7 . 7 2 1 7 . 8 6 1 7 . 9 7 1 8 . 1 4 1 8 . 2 4 1 8 . 4 3 1 8 . 5 4 1 8 . 7 8 1 8 . 9 1 1 9 . 0 3 1 9 . 1 2 1 9 . 2 6 1 9 . 5 8 2 0 . 1 9 2 0 . 5 4 2 1 . 7 9 2 2 . 2 2 2 4 . 1 2 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\2GC\DAT\2GC052214_b\0522GC2.0008.RAW H14050310-003A ;0522GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Page 17 of 20 S8-A @ 0'-1.5' Batch ID: 24610 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050310-003A ;0522GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC052214_b\0522GC2B.0008.RAW Date & Time Acquired: 5/22/2014 3:47:15 PM Method File: G:\Org\2GC\Methods\lavar042214B.MET Calibration File: G:\Org\2GC\Cals\Vhn042214B.cal Sample Weight: 50 Dilution: 1.12 S.A.: 1.12 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 431.8487 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 338.7009 Mean RF for all calibrated compounds: 473.2145 Rt range for Gasoline Range Organics: 4.391 to 15.614 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.524 to 13.01 Rt range for C9 to C12 Aliphatic Hydrocarbons: 13.06 to 20.133 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________7.958 2.8 2.54 90.72 - GRO Area:15624 GRO Amount: 0.739575 TPH Area:28468.44 TPH Amount: 1.347577 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:9841.785 C5-C8 Amount: 0.5104936 C9-C12 Area:16130.75 C9-C12 Amount: 1.066808 4 . 4 8 4 . 6 7 4 . 9 8 5 . 7 8 6 . 7 1 6 . 9 7 7 . 1 9 7 . 9 6 8 . 5 3 9 . 5 6 1 0 . 0 8 1 1 . 6 1 1 2 . 1 9 1 3 . 1 0 1 3 . 5 1 1 3 . 6 6 1 4 . 3 0 1 4 . 4 6 1 4 . 6 3 1 4 . 9 3 1 5 . 0 5 1 5 . 3 2 1 5 . 5 0 1 5 . 7 0 1 5 . 8 6 1 6 . 3 1 1 6 . 5 1 1 6 . 6 4 1 6 . 9 4 1 7 . 2 0 1 7 . 3 8 1 7 . 4 8 1 7 . 6 0 1 7 . 7 2 1 7 . 8 7 1 7 . 9 9 1 8 . 1 7 1 8 . 2 6 1 8 . 4 4 1 8 . 5 6 1 8 . 9 3 1 9 . 0 5 1 9 . 1 7 1 9 . 2 7 1 9 . 4 9 1 9 . 6 0 1 9 . 8 1 2 0 . 2 3 2 0 . 3 8 2 1 . 0 9 2 1 . 7 0 2 4 . 2 1 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n e n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\2GC\DAT\2GC052214_b\0522GC2B.0008.RAW H14050310-003A ;0522GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 Page 18 of 20 Shipping container/cooler in good condition? Custody seals intact on all shipping container(s)/cooler(s)? Custody seals intact on all sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? (Exclude analyses that are considered field parameters such as pH, DO, Res Cl, Sulfite, Ferrous Iron, etc.) Container/Temp Blank temperature: Water - VOA vials have zero headspace? Water - pH acceptable upon receipt? Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No No No No No No No No No No No Not Present Not Present Not Present No VOA vials submitted Not Applicable 21.8°C No Ice 5/16/2014 Wanda Johnson FedEx Express eab Date Received: Received by: Login completed by: Carrier name: BL2000\sdull 6/2/2014 Reviewed by: Reviewed Date: Contact and Corrective Action Comments: Samples received in plastic containers, should be collected in amber glass containers. Samples were received past the recommended analysis time. Jon Hager spoke with Lee Evans before we received samples and it is ok to analyze past hold time. Wj 5/16/14. Lee stated do not fractionated samples over the MCL. Wj 6/9/14 Temp Blank received in all shipping container(s)/cooler(s)? Yes No Not Applicable Lab measurement of analytes considered field parameters that require analysis within 15 minutes of sampling such as pH, Dissolved Oxygen and Residual Chlorine, are qualified as being analyzed outside of recommended holding time. Solid/soil samples are reported on a wet weight basis (as received) unless specifically indicated. If moisture corrected, data units are typically noted as –dry. For agricultural and mining soil parameters/characteristics, all samples are dried and ground prior to sample analysis. Standard Reporting Procedures: Workorder Receipt Checklist Allied Engineering Services Inc H14050310 Page 19 of 20 Page 20 of 20