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HomeMy WebLinkAbout14- May, 28, 2014 Hydrocarbon Summary Allied EngineeringANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT The analyses presented in this report were performed by Energy Laboratories, Inc., 3161 E. Lyndale Ave., Helena, MT 59604, unless otherwise noted. Any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, or the Case Narrative. The results as reported relate only to the item(s) submitted for testing. If you have any questions regarding these test results, please call. Lab ID Client Sample ID Collect Date Receive Date Matrix Test Report Approved By: H14050122-001 S2-B @ 2.0'-3.5' 04/21/14 11:00 05/07/14 Soil EPH-Ultrasonic Extraction Methanol Extraction for Volatiles Hydrocarbons, Extractable Petroleum-Scrn Volatile Petroleum Hydrocarbons Moisture H14050122-002 S3-B @ 2.0'-3.5' 04/21/14 15:00 05/07/14 Soil Same As Above H14050122-003 S5-B @ 2.0'-3.5' 04/24/14 10:00 05/07/14 Soil Same As Above Allied Engineering Services Inc Project Name: PDMC Site Work Order: H14050122 32 S Discovery Dr Bozeman, MT 59718-6958 May 28, 2014 Energy Laboratories Inc Helena MT received the following 3 samples for Allied Engineering Services Inc on 5/7/2014 for analysis. Page 1 of 21 Project: PDMC Site CLIENT: Allied Engineering Services Inc Work Order: H14050122 CASE NARRATIVE 05/28/14 Report Date: Prep Comments for Sample H14050122-001A, Test HC-5035-VPH: The prep hold time was exceeded by 11.0 days. Prep Comments for Sample H14050122-002A, Test HC-5035-VPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-003A, Test HC-5035-VPH: The prep hold time was exceeded by 8.07 days. Prep Comments for Sample H14050122-001A, Test HC-5035-VPH: The prep hold time was exceeded by 11.0 days. Prep Comments for Sample H14050122-002A, Test HC-5035-VPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-003A, Test HC-5035-VPH: The prep hold time was exceeded by 8.07 days. Prep Comments for Sample H14050122-001A, Test HC-5035-VPH: The prep hold time was exceeded by 11.0 days. Prep Comments for Sample H14050122-002A, Test HC-5035-VPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-003A, Test HC-5035-VPH: The prep hold time was exceeded by 8.07 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Prep Comments for Sample H14050122-001A, Test HC-5035-VPH: The prep hold time was exceeded by 11.0 days. Prep Comments for Sample H14050122-002A, Test HC-5035-VPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-003A, Test HC-5035-VPH: The prep hold time was exceeded by 8.07 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Prep Comments for Sample H14050122-001A, Test HC-5035-VPH: The prep hold time was exceeded by 11.0 days. Prep Comments for Sample H14050122-002A, Test HC-5035-VPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-003A, Test HC-5035-VPH: The prep hold time was exceeded by 8.07 days. Prep Comments for Sample H14050122-001A, Test HC-5035-VPH: The prep hold time was exceeded by 11.0 days. Prep Comments for Sample H14050122-002A, Test HC-5035-VPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-003A, Test HC-5035-VPH: The prep hold time was exceeded by 8.07 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Prep Comments for Sample H14050122-001A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.9 days. Prep Comments for Sample H14050122-002A, Test HC-3550A-EPH: The prep hold time was exceeded by 10.7 days. Prep Comments for Sample H14050122-003A, Test HC-3550A-EPH: The prep hold time was exceeded by 7.96 days. Page 2 of 21 LABORATORY ANALYTICAL REPORT Client: Allied Engineering Services Inc Project: PDMC Site Lab ID: H14050122-001 Client Sample ID: S2-B @ 2.0'-3.5' Collection Date: 04/21/14 11:00 Matrix: Soil Report Date: 05/28/14 DateReceived: 05/07/14 Prepared by Helena, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 05/10/14 15:32 / cmm 0.2 wt% 19.8 Moisture SW3550A PETROLEUM HYDROCARBONS-VOLATILE 05/12/14 19:39 / kjw 0.12 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 05/12/14 19:39 / kjw 0.062 mg/kg-dry ND Benzene MA-VPH 0.04 05/12/14 19:39 / kjw 0.062 mg/kg-dry ND Toluene MA-VPH 10 05/12/14 19:39 / kjw 0.062 mg/kg-dry ND Ethylbenzene MA-VPH 10 05/12/14 19:39 / kjw 0.062 mg/kg-dry ND m+p-Xylenes MA-VPH 05/12/14 19:39 / kjw 0.062 mg/kg-dry ND o-Xylene MA-VPH 05/12/14 19:39 / kjw 0.062 mg/kg-dry ND Xylenes, Total MA-VPH 30 05/12/14 19:39 / kjw 0.12 mg/kg-dry ND Naphthalene MA-VPH 9 05/12/14 19:39 / kjw 2.5 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 05/12/14 19:39 / kjw 2.5 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 40 05/12/14 19:39 / kjw 2.5 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 90 05/12/14 19:39 / kjw 2.5 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 05/12/14 19:39 / kjw 70-130 %REC 85.0 Surr: VPH Aromatics Surrogate MA-VPH 05/12/14 19:39 / kjw 70-130 %REC 82.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN ANALYSIS *05/13/14 00:57 / jdh 25 mg/kg-dry 225 Total Extractable Hydrocarbons SW8015M 200 05/13/14 00:57 / jdh 40-140 %REC 94.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. - *=The reported value exceeds the Maximum Contaminant Limit (MCL). The MCLs listed for target analyte and hydrocarbon range values are the most conservative Montana DEQ RBSLs. These limits may not apply to your samples. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. Page 3 of 21 LABORATORY ANALYTICAL REPORT Client: Allied Engineering Services Inc Project: PDMC Site Lab ID: H14050122-002 Client Sample ID: S3-B @ 2.0'-3.5' Collection Date: 04/21/14 15:00 Matrix: Soil Report Date: 05/28/14 DateReceived: 05/07/14 Prepared by Helena, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 05/10/14 15:32 / cmm 0.2 wt% 23.1 Moisture SW3550A PETROLEUM HYDROCARBONS-VOLATILE 05/12/14 20:47 / kjw 0.13 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 05/12/14 20:47 / kjw 0.065 mg/kg-dry ND Benzene MA-VPH 0.04 05/12/14 20:47 / kjw 0.065 mg/kg-dry ND Toluene MA-VPH 10 05/12/14 20:47 / kjw 0.065 mg/kg-dry ND Ethylbenzene MA-VPH 10 05/12/14 20:47 / kjw 0.065 mg/kg-dry ND m+p-Xylenes MA-VPH 05/12/14 20:47 / kjw 0.065 mg/kg-dry ND o-Xylene MA-VPH 05/12/14 20:47 / kjw 0.065 mg/kg-dry ND Xylenes, Total MA-VPH 30 05/12/14 20:47 / kjw 0.13 mg/kg-dry ND Naphthalene MA-VPH 9 05/12/14 20:47 / kjw 2.6 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 05/12/14 20:47 / kjw 2.6 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 40 05/12/14 20:47 / kjw 2.6 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 90 05/12/14 20:47 / kjw 2.6 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 05/12/14 20:47 / kjw 70-130 %REC 83.0 Surr: VPH Aromatics Surrogate MA-VPH 05/12/14 20:47 / kjw 70-130 %REC 80.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN ANALYSIS *05/13/14 01:44 / jdh 13 mg/kg-dry 701 Total Extractable Hydrocarbons SW8015M 200 05/13/14 01:44 / jdh 40-140 %REC 105 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. - *=The reported value exceeds the Maximum Contaminant Limit (MCL). The MCLs listed for target analyte and hydrocarbon range values are the most conservative Montana DEQ RBSLs. These limits may not apply to your samples. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. Page 4 of 21 LABORATORY ANALYTICAL REPORT Client: Allied Engineering Services Inc Project: PDMC Site Lab ID: H14050122-003 Client Sample ID: S5-B @ 2.0'-3.5' Collection Date: 04/24/14 10:00 Matrix: Soil Report Date: 05/28/14 DateReceived: 05/07/14 Prepared by Helena, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 05/10/14 15:32 / cmm 0.2 wt% 15.5 Moisture SW3550A PETROLEUM HYDROCARBONS-VOLATILE 05/12/14 21:55 / kjw 0.12 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 05/12/14 21:55 / kjw 0.059 mg/kg-dry ND Benzene MA-VPH 0.04 05/12/14 21:55 / kjw 0.059 mg/kg-dry ND Toluene MA-VPH 10 05/12/14 21:55 / kjw 0.059 mg/kg-dry ND Ethylbenzene MA-VPH 10 05/12/14 21:55 / kjw 0.059 mg/kg-dry ND m+p-Xylenes MA-VPH 05/12/14 21:55 / kjw 0.059 mg/kg-dry ND o-Xylene MA-VPH 05/12/14 21:55 / kjw 0.059 mg/kg-dry ND Xylenes, Total MA-VPH 30 05/12/14 21:55 / kjw 0.12 mg/kg-dry ND Naphthalene MA-VPH 9 J 05/12/14 21:55 / kjw 2.4 mg/kg-dry 2.1 C9 to C10 Aromatics MA-VPH 100 05/12/14 21:55 / kjw 2.4 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 40 J 05/12/14 21:55 / kjw 2.4 mg/kg-dry 0.83 C9 to C12 Aliphatics MA-VPH 90 05/12/14 21:55 / kjw 2.4 mg/kg-dry 2.7 Total Purgeable Hydrocarbons MA-VPH 100 05/12/14 21:55 / kjw 70-130 %REC 83.0 Surr: VPH Aromatics Surrogate MA-VPH 05/12/14 21:55 / kjw 70-130 %REC 81.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN ANALYSIS *05/13/14 03:17 / jdh 12 mg/kg-dry 231 Total Extractable Hydrocarbons SW8015M 200 05/13/14 03:17 / jdh 40-140 %REC 114 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. - *=The reported value exceeds the Maximum Contaminant Limit (MCL). The MCLs listed for target analyte and hydrocarbon range values are the most conservative Montana DEQ RBSLs. These limits may not apply to your samples. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. J - Estimated value. The analyte was present but less than the reporting limit. Page 5 of 21 Project: PDMC Site Client: Allied Engineering Services Inc Work Order: H14050122 QA/QC Summary Report 05/28/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Helena, MT Branch Method: MA-VPH Batch: 24472 Lab ID: LCS-24472 05/12/14 11:50 Laboratory Control Sample Run: VARIAN1_140512A 2-Methylpentane 80 70 130 0.10 1.99 mg/kg-dry n-Butylcyclohexane 85 70 130 2.12 mg/kg-dry n-Decane 77 70 130 1.92 mg/kg-dry n-Pentane 73 30 130 0.10 1.83 mg/kg-dry Methyl tert-butyl ether (MTBE) 91 70 130 0.10 2.26 mg/kg-dry Benzene 97 70 130 0.050 2.44 mg/kg-dry Toluene 98 70 130 0.050 2.45 mg/kg-dry Ethylbenzene 101 70 130 0.050 2.52 mg/kg-dry m+p-Xylenes 106 70 130 0.050 5.29 mg/kg-dry o-Xylene 104 70 130 0.050 2.60 mg/kg-dry Naphthalene 91 70 130 0.10 2.27 mg/kg-dry Total Purgeable Hydrocarbons 84 70 130 2.0 31.6 mg/kg-dry Surr: VPH Aromatics Surrogate 98 70 130 0.050 Surr: VPH Aliphatics Surrogate 97 70 130 0.050 Lab ID: MB-24472 05/12/14 13:18 Method Blank Run: VARIAN1_140512A Methyl tert-butyl ether (MTBE) 0.10 ND mg/kg-dry Benzene 0.050 ND mg/kg-dry Toluene 0.050 ND mg/kg-dry Ethylbenzene 0.050 ND mg/kg-dry m+p-Xylenes 0.050 ND mg/kg-dry o-Xylene 0.050 ND mg/kg-dry Naphthalene 0.10 ND mg/kg-dry C9 to C10 Aromatics 2.0 ND mg/kg-dry C5 to C8 Aliphatics 2.0 ND mg/kg-dry C9 to C12 Aliphatics 2.0 ND mg/kg-dry Total Purgeable Hydrocarbons 2.0 ND mg/kg-dry Xylenes, Total 0.050 ND mg/kg-dry Surr: VPH Aromatics Surrogate 94 70 130 0.050 Surr: VPH Aliphatics Surrogate 93 70 130 0.050 Lab ID: H14050119-022AMS 05/13/14 17:53 Sample Matrix Spike Run: VARIAN1_140513A Methyl tert-butyl ether (MTBE) 88 70 130 0.13 2.86 mg/kg-dry Benzene 93 70 130 0.065 3.03 mg/kg-dry Toluene 94 70 130 0.065 3.06 mg/kg-dry Ethylbenzene 97 70 130 0.065 3.14 mg/kg-dry m+p-Xylenes 102 70 130 0.065 6.60 mg/kg-dry o-Xylene 100 70 130 0.065 3.25 mg/kg-dry Naphthalene 81 70 130 0.13 2.64 mg/kg-dry Total Purgeable Hydrocarbons 75 70 130 2.6 36.7 mg/kg-dry Surr: VPH Aromatics Surrogate 84 70 130 0.065 Surr: VPH Aliphatics Surrogate 82 70 130 0.065 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 6 of 21 Project: PDMC Site Client: Allied Engineering Services Inc Work Order: H14050122 QA/QC Summary Report 05/28/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Helena, MT Branch Method: MA-VPH Batch: 24472 Lab ID: H14050119-022AMSD 05/13/14 18:28 Sample Matrix Spike Duplicate Run: VARIAN1_140513A Methyl tert-butyl ether (MTBE) 104 70 130 20 0.13 17 3.37 mg/kg-dry Benzene 111 70 130 20 0.065 17 3.60 mg/kg-dry Toluene 112 70 130 20 0.065 18 3.65 mg/kg-dry Ethylbenzene 115 70 130 20 0.065 17 3.74 mg/kg-dry m+p-Xylenes 120 70 130 20 0.065 16 7.77 mg/kg-dry o-Xylene 119 70 130 20 0.065 17 3.85 mg/kg-dry Naphthalene 114 70 130 20 0.13 34 3.70 mg/kg-dry R Total Purgeable Hydrocarbons 89 70 130 20 2.6 17 43.4 mg/kg-dry Surr: VPH Aromatics Surrogate 86 70 130 0.065 Surr: VPH Aliphatics Surrogate 82 70 130 0.065 Method: MA-VPH Analytical Run: R97036 Lab ID: CCV_0512GC203r-S 05/12/14 10:51 Continuing Calibration Verification Standard 1,2,4-Trimethylbenzene 99 75 125 0.10 2.48 mg/kg-dry 2,2,4-Trimethylpentane 95 75 125 0.10 2.38 mg/kg-dry 2-Methylpentane 94 75 125 0.10 2.35 mg/kg-dry n-Butylcyclohexane 80 75 125 1.99 mg/kg-dry n-Decane 77 75 125 1.93 mg/kg-dry n-Pentane 96 75 125 0.10 2.41 mg/kg-dry Methyl tert-butyl ether (MTBE) 94 75 125 0.10 2.36 mg/kg-dry Benzene 97 75 125 0.050 2.43 mg/kg-dry Toluene 97 75 125 0.050 2.41 mg/kg-dry Ethylbenzene 99 75 125 0.050 2.47 mg/kg-dry m+p-Xylenes 102 75 125 0.050 5.08 mg/kg-dry o-Xylene 100 75 125 0.050 2.50 mg/kg-dry Naphthalene 81 75 125 0.10 2.03 mg/kg-dry Surr: VPH Aromatics Surrogate 87 70 130 0.050 Surr: VPH Aliphatics Surrogate 93 70 130 0.050 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. R - RPD exceeds advisory limit. Page 7 of 21 Project: PDMC Site Client: Allied Engineering Services Inc Work Order: H14050122 QA/QC Summary Report 05/28/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Helena, MT Branch Method: SW8015M Batch: 24462 Lab ID: MB-24462 05/12/14 18:46 Method Blank Run: HHP_140512A Total Extractable Hydrocarbons 10 ND mg/kg-dry Surr: o-Terphenyl 79 40 140 0.17 Lab ID: LCS-24462 05/12/14 19:33 Laboratory Control Sample Run: HHP_140512A Total Extractable Hydrocarbons 104 60 140 10 215 mg/kg-dry Surr: o-Terphenyl 110 40 140 0.17 Lab ID: H14050155-008AMS 05/14/14 19:31 Sample Matrix Spike Run: HHP_140514A Total Extractable Hydrocarbons 67 60 140 11 149 mg/kg-dry Surr: o-Terphenyl 73 40 140 0.18 Lab ID: H14050155-008AMSD 05/14/14 20:18 Sample Matrix Spike Duplicate Run: HHP_140514A Total Extractable Hydrocarbons 81 60 140 20 11 19 181 mg/kg-dry Surr: o-Terphenyl 79 40 140 0.18 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 8 of 21 Project: PDMC Site Client: Allied Engineering Services Inc Work Order: H14050122 QA/QC Summary Report 05/28/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Helena, MT Branch Method: SW8015M Analytical Run: R97095 Lab ID: CCV_0512GC111r-S 05/12/14 18:00 Continuing Calibration Verification Standard n-Nonane 99 75 125 6.61 mg/kg-dry n-Decane 100 75 125 6.66 mg/kg-dry n-Dodecane 97 75 125 6.46 mg/kg-dry n-Tetradecane 101 75 125 6.70 mg/kg-dry n-Hexadecane 97 75 125 6.50 mg/kg-dry n-Octadecane 98 75 125 6.55 mg/kg-dry n-Nonadecane 99 75 125 6.60 mg/kg-dry n-Eicosane 97 75 125 6.50 mg/kg-dry n-Docosane 99 75 125 6.57 mg/kg-dry n-Tetracosane 99 75 125 6.57 mg/kg-dry n-Hexacosane 99 75 125 6.62 mg/kg-dry n-Octacosane 101 75 125 6.71 mg/kg-dry n-Triacontane 100 75 125 6.66 mg/kg-dry n-Hexatriacontane 101 75 125 6.74 mg/kg-dry Surr: o-Terphenyl 105 75 125 0.17 Lab ID: CCV_0512GC122r-S 05/13/14 02:30 Continuing Calibration Verification Standard n-Nonane 98 75 125 6.53 mg/kg-dry n-Decane 100 75 125 6.66 mg/kg-dry n-Dodecane 99 75 125 6.58 mg/kg-dry n-Tetradecane 106 75 125 7.04 mg/kg-dry n-Hexadecane 100 75 125 6.64 mg/kg-dry n-Octadecane 100 75 125 6.68 mg/kg-dry n-Nonadecane 101 75 125 6.73 mg/kg-dry n-Eicosane 100 75 125 6.64 mg/kg-dry n-Docosane 101 75 125 6.71 mg/kg-dry n-Tetracosane 101 75 125 6.71 mg/kg-dry n-Hexacosane 101 75 125 6.74 mg/kg-dry n-Octacosane 103 75 125 6.84 mg/kg-dry n-Triacontane 102 75 125 6.77 mg/kg-dry n-Hexatriacontane 102 75 125 6.83 mg/kg-dry Surr: o-Terphenyl 107 75 125 0.17 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 9 of 21 S2-B @ 2.0'-3.5'Batch ID: 24462 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: H14050122-001A ;0512GC1 , $HC-EPH-SCRN-S, ,(2,2) Raw File: G:\Org\1GC\DAT\1GC051214_b\0512GC1.0020.RAW Date & Time Acquired: 5/13/2014 12:57:53 AM Method File: G:\Org\1GC\Methods\GC1_2014Methods\05121419.MET Calibration File: G:\Org\1GC\Cals\GC1_2014CALS\SC011314F.CAL Sample Weight: 24.1 Dilution: 4 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 1856.84 Mean RF for C19 to C36 Hydrocarbons: 1896.267 Mean RF for Total Extractable Hydrocarbons: 1876.554 Rt range for Diesel Range Organics: 6.85 to 17.16 Rt range for C9 to C18 Hydrocarbons: 5.87 to 12.72 Rt range for C19 to C36 Hydrocarbons: 12.77 to 20.13 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.822 8.299 7.804 94.03 - *1-Chloro-octadecane_____13.61 8.299 7.81 94.12 - DRO Area:538158.8 DRO Amount: 47.5984 TEH Area:2546789 TEH Amount: 225.2552 C9-C18 Area:19433.75 C9-C18 Amount: 1.737101 C19-C36 Area:1825821 C19-C36 Amount: 159.8091 5 . 0 6 5 . 1 9 5 . 2 4 5 . 4 3 5 . 4 9 9 . 9 3 1 0 . 0 2 1 1 . 1 2 1 1 . 7 0 1 1 . 7 9 1 1 . 8 3 1 1 . 8 7 1 1 . 9 5 1 2 . 0 0 1 2 . 0 4 1 2 . 2 0 1 2 . 2 5 1 2 . 7 0 1 2 . 8 2 1 3 . 0 7 1 3 . 1 8 1 3 . 6 1 1 4 . 0 8 1 4 . 1 5 1 4 . 2 6 1 4 . 4 3 1 4 . 5 0 1 4 . 5 9 1 4 . 6 8 1 4 . 7 4 1 4 . 8 4 1 5 . 0 3 1 5 . 0 9 1 5 . 1 7 1 5 . 2 1 1 5 . 3 0 1 5 . 4 2 1 5 . 5 3 1 5 . 6 8 1 5 . 9 5 1 6 . 0 4 1 6 . 1 5 1 6 . 2 8 1 6 . 4 0 1 6 . 5 4 1 6 . 6 8 1 6 . 7 4 1 6 . 8 1 1 6 . 8 4 1 6 . 9 3 1 7 . 0 7 1 7 . 1 4 1 7 . 2 2 1 7 . 2 9 1 7 . 3 5 1 7 . 4 0 1 7 . 5 2 1 7 . 6 2 1 7 . 8 4 1 7 . 9 2 1 7 . 9 9 1 8 . 4 5 1 8 . 5 5 1 8 . 6 5 1 8 . 7 6 1 8 . 8 0 1 8 . 8 4 1 9 . 2 0 1 9 . 2 5 1 9 . 3 8 1 9 . 4 7 1 9 . 5 5 1 9 . 6 1 1 9 . 8 0 1 9 . 9 1 1 9 . 9 4 1 9 . 9 8 2 0 . 1 1 2 0 . 1 7 2 0 . 2 0 2 0 . 2 4 2 0 . 2 9 2 0 . 4 6 2 0 . 5 9 2 0 . 6 8 2 0 . 7 2 2 0 . 7 9 2 0 . 8 3 2 1 . 1 2 2 1 . 1 9 2 1 . 2 7 2 1 . 3 0 2 1 . 4 4 2 1 . 5 7 2 1 . 6 2 2 1 . 7 5 2 1 . 7 9 2 1 . 8 8 2 1 . 9 4 2 2 . 0 4 2 2 . 1 4 2 2 . 2 1 2 2 . 2 6 2 2 . 3 2 2 2 . 4 1 2 2 . 4 5 2 2 . 5 4 2 2 . 6 6 2 2 . 7 5 2 2 . 8 2 2 2 . 8 9 2 2 . 9 8 2 3 . 0 4 2 3 . 1 3 2 3 . 1 9 2 3 . 2 8 2 3 . 3 6 2 3 . 4 3 2 3 . 4 7 2 3 . 5 1 2 3 . 5 5 2 3 . 6 2 2 3 . 6 9 2 3 . 7 9 2 4 . 1 7 2 4 . 3 0 2 5 . 2 9 2 5 . 5 4 2 5 . 6 7 2 5 . 8 4 2 6 . 0 2 2 6 . 1 6 2 8 . 0 7 2 8 . 2 0 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e IN T - I N T + S B N S B N IN T - G:\Org\1GC\DAT\1GC051214_b\0512GC1.0020.RAW H14050122-001A ;0512GC1 , $HC-EPH-SCRN-S, ,(2,2) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 Page 10 of 21 S3-B @ 2.0'-3.5'Batch ID: 24462 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: H14050122-002A ;0512GC1 , $HC-EPH-SCRN-S, Raw File: G:\Org\1GC\DAT\1GC051214_b\0512GC1.0021.RAW Date & Time Acquired: 5/13/2014 1:44:13 AM Method File: G:\Org\1GC\Methods\GC1_2014Methods\05121421.MET Calibration File: G:\Org\1GC\Cals\GC1_2014CALS\SC011314F.CAL Sample Weight: 23.1 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 1856.84 Mean RF for C19 to C36 Hydrocarbons: 1896.267 Mean RF for Total Extractable Hydrocarbons: 1876.554 Rt range for Diesel Range Organics: 6.85 to 17.16 Rt range for C9 to C18 Hydrocarbons: 5.87 to 12.72 Rt range for C19 to C36 Hydrocarbons: 12.77 to 20.13 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.826 8.658 9.475 109.44 - *1-Chloro-octadecane_____13.612 8.658 10.556 121.92 - DRO Area:7005869 DRO Amount: 323.2354 TEH Area:1.51941E+07 TEH Amount: 701.0225 C9-C18 Area:105561.4 C9-C18 Amount: 4.922079 C19-C36 Area:1.328907E+07C19-C36 Amount: 606.7545 5 . 0 4 5 . 1 0 5 . 2 2 5 . 2 6 5 . 4 1 5 . 4 9 6 . 1 2 8 . 6 6 9 . 2 7 9 . 3 9 9 . 9 2 1 0 . 0 2 1 0 . 2 4 1 0 . 5 4 1 0 . 6 4 1 0 . 8 5 1 0 . 8 9 1 0 . 9 9 1 1 . 1 2 1 1 . 2 5 1 1 . 3 9 1 1 . 4 4 1 1 . 5 3 1 1 . 7 0 1 1 . 7 4 1 1 . 7 9 1 1 . 8 3 1 1 . 8 7 1 1 . 9 5 1 2 . 0 0 1 2 . 0 6 1 2 . 0 8 1 2 . 2 0 1 2 . 3 6 1 2 . 5 1 1 2 . 6 2 1 2 . 7 0 1 2 . 7 5 1 2 . 8 3 1 2 . 9 6 1 3 . 0 7 1 3 . 1 8 1 3 . 2 9 1 3 . 3 3 1 3 . 4 1 1 3 . 4 7 1 3 . 5 2 1 3 . 6 1 1 3 . 7 0 1 3 . 7 7 1 3 . 9 6 1 4 . 0 3 1 4 . 1 8 1 4 . 2 5 1 4 . 3 2 1 4 . 4 4 1 4 . 5 0 1 4 . 5 7 1 4 . 7 4 1 4 . 8 3 1 5 . 0 7 1 5 . 2 1 1 5 . 3 1 1 5 . 4 0 1 5 . 5 1 1 5 . 7 5 1 5 . 8 1 1 5 . 9 1 1 5 . 9 7 1 6 . 0 9 1 6 . 1 2 1 6 . 2 1 1 6 . 3 0 1 6 . 3 3 1 6 . 4 1 1 6 . 4 7 1 6 . 5 5 1 6 . 6 8 1 6 . 8 3 1 7 . 0 1 1 7 . 0 7 1 7 . 1 5 1 7 . 2 1 1 7 . 2 7 1 7 . 3 5 1 7 . 5 3 1 7 . 6 4 1 7 . 9 1 1 7 . 9 9 1 8 . 1 6 1 8 . 2 9 1 8 . 4 6 1 8 . 6 3 1 8 . 6 9 1 8 . 8 5 1 8 . 9 5 1 9 . 2 8 1 9 . 3 8 1 9 . 5 5 2 0 . 0 5 2 0 . 1 9 2 0 . 2 1 2 0 . 4 2 2 0 . 8 1 2 0 . 8 4 2 1 . 0 3 2 1 . 1 2 2 1 . 1 4 2 1 . 1 9 2 1 . 2 7 2 1 . 2 9 2 1 . 3 6 2 1 . 5 4 2 1 . 7 4 2 2 . 1 0 2 2 . 2 6 2 2 . 3 7 2 2 . 4 7 2 2 . 5 7 2 2 . 5 9 2 2 . 7 2 2 2 . 8 2 2 3 . 0 1 2 3 . 1 5 2 3 . 2 9 2 3 . 3 9 2 3 . 4 3 2 3 . 5 7 2 3 . 7 2 2 3 . 8 4 2 3 . 9 6 2 4 . 0 9 2 4 . 1 2 2 4 . 3 0 2 4 . 3 5 2 4 . 4 0 2 4 . 4 9 2 4 . 6 2 2 4 . 7 6 2 4 . 9 3 2 5 . 0 0 2 5 . 1 0 2 5 . 2 1 2 5 . 2 8 2 5 . 5 0 2 5 . 6 1 2 5 . 6 7 2 5 . 7 9 2 5 . 8 6 2 6 . 0 2 2 6 . 2 8 2 6 . 3 6 2 6 . 6 5 2 7 . 9 4 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e IN T - I N T + S B N S B N IN T - G:\Org\1GC\DAT\1GC051214_b\0512GC1.0021.RAW H14050122-002A ;0512GC1 , $HC-EPH-SCRN-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 Page 11 of 21 S5-B @ 2.0'-3.5'Batch ID: 24462 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: H14050122-003A ;0512GC1 , $HC-EPH-SCRN-S, Raw File: G:\Org\1GC\DAT\1GC051214_b\0512GC1.0023.RAW Date & Time Acquired: 5/13/2014 3:17:24 AM Method File: G:\Org\1GC\Methods\GC1_2014Methods\05121414.MET Calibration File: G:\Org\1GC\Cals\GC1_2014CALS\SC011314F.CAL Sample Weight: 25.4 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 1856.84 Mean RF for C19 to C36 Hydrocarbons: 1896.267 Mean RF for Total Extractable Hydrocarbons: 1876.554 Rt range for Diesel Range Organics: 6.85 to 17.16 Rt range for C9 to C18 Hydrocarbons: 5.87 to 12.72 Rt range for C19 to C36 Hydrocarbons: 12.77 to 20.13 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.826 7.874 8.952 113.69 - *1-Chloro-octadecane_____13.61 7.874 9.094 115.49 - DRO Area:2483585 DRO Amount: 104.2112 TEH Area:5514989 TEH Amount: 231.4088 C9-C18 Area:36154.11 C9-C18 Amount: 1.533132 C19-C36 Area:4613991 C19-C36 Amount: 191.5903 5 . 1 1 5 . 1 8 5 . 2 4 5 . 3 0 5 . 3 6 5 . 4 7 6 . 1 3 9 . 0 8 1 0 . 0 2 1 1 . 7 4 1 1 . 7 9 1 1 . 8 3 1 1 . 8 7 1 1 . 9 6 1 2 . 0 0 1 2 . 0 4 1 2 . 0 9 1 2 . 1 9 1 2 . 2 5 1 2 . 6 1 1 2 . 7 0 1 2 . 8 3 1 3 . 0 7 1 3 . 1 8 1 3 . 2 9 1 3 . 5 3 1 3 . 6 1 1 3 . 7 8 1 3 . 8 4 1 3 . 9 0 1 4 . 0 6 1 4 . 1 7 1 4 . 2 4 1 4 . 3 5 1 4 . 4 3 1 4 . 5 0 1 4 . 5 8 1 4 . 6 8 1 4 . 7 5 1 4 . 8 3 1 5 . 0 0 1 5 . 0 9 1 5 . 1 5 1 5 . 2 1 1 5 . 3 0 1 5 . 4 3 1 5 . 5 4 1 5 . 6 9 1 5 . 8 2 1 5 . 9 0 1 5 . 9 9 1 6 . 0 7 1 6 . 1 9 1 6 . 2 8 1 6 . 4 0 1 6 . 4 6 1 6 . 5 4 1 6 . 6 5 1 6 . 6 7 1 6 . 7 2 1 6 . 8 1 1 6 . 9 1 1 6 . 9 9 1 7 . 0 6 1 7 . 1 5 1 7 . 2 6 1 7 . 3 4 1 7 . 5 1 1 7 . 6 3 1 7 . 8 0 1 7 . 9 8 1 8 . 1 7 1 8 . 3 5 1 8 . 3 9 1 8 . 4 3 1 8 . 6 9 1 8 . 8 3 1 9 . 1 0 1 9 . 2 8 1 9 . 3 8 2 0 . 2 0 2 0 . 2 3 2 0 . 5 5 2 0 . 7 6 2 0 . 8 3 2 1 . 1 6 2 1 . 2 1 2 1 . 5 3 2 1 . 6 6 2 1 . 7 4 2 2 . 1 6 2 2 . 2 3 2 2 . 2 8 2 2 . 6 5 2 2 . 6 9 2 2 . 9 1 2 2 . 9 8 2 3 . 1 2 2 3 . 2 3 2 3 . 3 1 2 3 . 4 4 2 3 . 5 1 2 3 . 5 5 2 3 . 6 1 2 3 . 6 8 2 3 . 7 9 2 4 . 3 4 2 4 . 3 7 2 4 . 4 2 2 4 . 6 6 2 4 . 8 8 2 4 . 9 7 2 5 . 0 4 2 5 . 1 3 2 5 . 2 9 2 5 . 4 2 2 5 . 5 8 2 5 . 6 9 2 5 . 9 8 2 6 . 2 0 2 6 . 2 8 2 6 . 3 8 2 6 . 5 7 2 6 . 7 3 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e IN T - I N T + S B N IN T - G:\Org\1GC\DAT\1GC051214_b\0512GC1.0023.RAW H14050122-003A ;0512GC1 , $HC-EPH-SCRN-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 Page 12 of 21 S2-B @ 2.0'-3.5' Batch ID: 24472 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050122-001A ;0512GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC051214_b\0512GC2.0017.RAW Date & Time Acquired: 5/12/2014 7:39:11 PM Method File: G:\Org\2GC\Methods\lavar042214.MET Calibration File: G:\Org\2GC\Cals\Vhn042214.cal Sample Weight: 50 Dilution: 1.25 S.A.: 1.25 Mean RF for C9 to C10 Aromatic Hydrocarbons: 420.4557 Rt range for C9 to C10 Aromatics: 14.566 to 20.099 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:2304.129 C9-C10 Aromatics Amount: 0.1370019 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .125 U Benzene__________________7.194 7.194 7.194 97 .063 U Toluene__________________10.068 10.068 10.068 315 .063 U Ethylbenzene_____________13.506 13.506 13.506 99 .063 U m+p-Xylenes______________13.65 13.65 13.65 441 .125 U o-Xylene_________________14.446 14.446 14.446 155 .063 U 124-Trimethylbenzene_____16.498 16.498 16.498 334 .063 U Naphthalene______________20.183 20.183 20.183 175 .125 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______7.95 3.125 2.653 84.89 70-130 0 . 1 3 4 . 0 8 5 . 0 1 5 . 5 8 5 . 7 7 7 . 1 9 7 . 9 5 9 . 6 8 1 0 . 0 7 1 0 . 4 7 1 2 . 0 7 1 2 . 1 7 1 3 . 1 0 1 3 . 5 1 1 3 . 6 5 1 4 . 4 5 1 4 . 6 0 1 5 . 6 8 1 5 . 8 4 1 6 . 3 0 1 6 . 5 0 1 6 . 6 3 1 6 . 9 2 1 7 . 1 6 1 7 . 9 7 1 8 . 5 3 1 9 . 0 1 1 9 . 4 5 2 0 . 1 8 2 0 . 5 4 2 3 . 1 1 2 3 . 5 9 2 4 . 1 2 2 4 . 8 1 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\2GC\DAT\2GC051214_b\0512GC2.0017.RAW H14050122-001A ;0512GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Page 13 of 21 S2-B @ 2.0'-3.5' Batch ID: 24472 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050122-001A ;0512GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC051214_b\0512GC2B.0017.RAW Date & Time Acquired: 5/12/2014 7:39:11 PM Method File: G:\Org\2GC\Methods\lavar042214B.MET Calibration File: G:\Org\2GC\Cals\Vhn042214B.cal Sample Weight: 50 Dilution: 1.25 S.A.: 1.25 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 431.8487 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 338.7009 Mean RF for all calibrated compounds: 473.2145 Rt range for Gasoline Range Organics: 4.391 to 15.614 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.524 to 13.01 Rt range for C9 to C12 Aliphatic Hydrocarbons: 13.06 to 20.133 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________7.955 3.125 2.559 81.9 - GRO Area:3264.992 GRO Amount: 0.1724901 TPH Area:7764.117 TPH Amount: 0.4101796 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:2057.344 C5-C8 Amount: 0.119101 C9-C12 Area:5118.551 C9-C12 Amount: 0.3778076 4 . 4 8 4 . 6 7 4 . 9 8 5 . 7 7 7 . 1 9 7 . 9 6 9 . 5 6 1 0 . 0 8 1 3 . 0 9 1 3 . 5 1 1 3 . 6 5 1 4 . 4 6 1 4 . 6 0 1 5 . 5 0 1 5 . 7 0 1 5 . 8 5 1 6 . 3 1 1 6 . 5 1 1 6 . 6 3 1 6 . 9 4 1 7 . 1 9 1 7 . 3 7 1 7 . 4 7 1 7 . 5 9 1 7 . 8 5 1 7 . 9 7 1 8 . 4 3 1 8 . 5 5 1 9 . 4 8 1 9 . 8 0 2 0 . 2 2 2 2 . 2 8 2 4 . 3 1 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n e n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\2GC\DAT\2GC051214_b\0512GC2B.0017.RAW H14050122-001A ;0512GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 Page 14 of 21 S3-B @ 2.0'-3.5' Batch ID: 24472 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050122-002A ;0512GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC051214_b\0512GC2.0019.RAW Date & Time Acquired: 5/12/2014 8:47:14 PM Method File: G:\Org\2GC\Methods\lavar042214.MET Calibration File: G:\Org\2GC\Cals\Vhn042214.cal Sample Weight: 50 Dilution: 1.3 S.A.: 1.3 Mean RF for C9 to C10 Aromatic Hydrocarbons: 420.4557 Rt range for C9 to C10 Aromatics: 14.566 to 20.099 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:1762.329 C9-C10 Aromatics Amount: 0.1089783 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .13 U Benzene__________________7.191 7.191 7.191 130 .065 U Toluene__________________10.07 10.07 10.07 364 .065 U Ethylbenzene_____________13.492 13.492 13.492 134 .065 U m+p-Xylenes______________13.639 13.639 13.639 445 .13 U o-Xylene_________________14.441 14.441 14.441 255 .065 U 124-Trimethylbenzene_____16.487 16.487 16.487 256 .065 U Naphthalene______________20.174 20.174 20.174 163 .13 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______7.943 3.25 2.685 82.62 70-130 3 . 4 9 4 . 0 7 4 . 6 7 5 . 7 5 6 . 3 1 7 . 1 9 7 . 9 4 1 0 . 0 7 1 2 . 8 8 1 3 . 1 1 1 3 . 4 9 1 3 . 6 4 1 4 . 3 6 1 4 . 4 4 1 5 . 6 3 1 5 . 8 3 1 6 . 2 8 1 6 . 4 9 1 6 . 6 3 1 6 . 9 2 1 7 . 1 5 1 8 . 2 4 1 8 . 5 2 1 9 . 8 2 2 0 . 1 7 2 1 . 0 1 2 1 . 7 8 2 2 . 5 8 2 4 . 1 1 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\2GC\DAT\2GC051214_b\0512GC2.0019.RAW H14050122-002A ;0512GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Page 15 of 21 S3-B @ 2.0'-3.5' Batch ID: 24472 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050122-002A ;0512GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC051214_b\0512GC2B.0019.RAW Date & Time Acquired: 5/12/2014 8:47:14 PM Method File: G:\Org\2GC\Methods\lavar042214B.MET Calibration File: G:\Org\2GC\Cals\Vhn042214B.cal Sample Weight: 50 Dilution: 1.3 S.A.: 1.3 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 431.8487 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 338.7009 Mean RF for all calibrated compounds: 473.2145 Rt range for Gasoline Range Organics: 4.391 to 15.614 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.524 to 13.01 Rt range for C9 to C12 Aliphatic Hydrocarbons: 13.06 to 20.133 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________7.948 3.25 2.596 79.89 - GRO Area:6862.773 GRO Amount: 0.3770639 TPH Area:11363.23 TPH Amount: 0.6243344 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:5398.816 C5-C8 Amount: 0.3250426 C9-C12 Area:4649.277 C9-C12 Amount: 0.3568967 3 . 2 7 4 . 3 4 4 . 4 8 4 . 6 7 4 . 9 7 5 . 7 8 7 . 1 9 7 . 9 5 9 . 6 5 1 0 . 0 7 1 3 . 0 8 1 3 . 5 0 1 3 . 6 4 1 4 . 4 5 1 4 . 6 4 1 5 . 4 8 1 5 . 6 8 1 5 . 8 4 1 6 . 3 1 1 6 . 5 0 1 6 . 6 3 1 6 . 9 2 1 7 . 1 8 1 7 . 3 6 1 7 . 4 5 1 7 . 6 0 1 7 . 8 4 1 7 . 9 7 1 8 . 4 3 1 8 . 5 4 1 9 . 8 0 2 0 . 2 2 2 2 . 6 3 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n e n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\2GC\DAT\2GC051214_b\0512GC2B.0019.RAW H14050122-002A ;0512GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 Page 16 of 21 S5-B @ 2.0'-3.5' Batch ID: 24472 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050122-003A ;0512GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC051214_b\0512GC2.0021.RAW Date & Time Acquired: 5/12/2014 9:55:22 PM Method File: G:\Org\2GC\Methods\05121421$nap.MET Calibration File: G:\Org\2GC\Cals\Vhn042214.cal Sample Weight: 50 Dilution: 1.18 S.A.: 1.18 Mean RF for C9 to C10 Aromatic Hydrocarbons: 420.4557 Rt range for C9 to C10 Aromatics: 14.566 to 20.099 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:19957.98 C9-C10 Aromatics Amount: 1.120233 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .118 U Benzene__________________7.19 7.19 7.19 77 .059 U Toluene__________________10.049 10.049 10.049 295 .059 U Ethylbenzene_____________13.474 13.474 13.474 139 .059 U m+p-Xylenes______________13.634 13.634 13.634 556 .118 U o-Xylene_________________14.432 14.432 14.432 204 .059 U 124-Trimethylbenzene_____16.483 -8.55 -8.545 751 .04 J Naphthalene______________20.167 20.167 20.167 311 .118 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______7.938 2.95 2.463 83.49 70-130 4 . 0 7 4 . 4 9 4 . 6 6 5 . 4 4 5 . 7 6 7 . 1 9 7 . 9 4 9 . 6 1 1 0 . 0 5 1 0 . 6 0 1 2 . 1 0 1 3 . 3 8 1 3 . 4 7 1 3 . 6 3 1 4 . 0 2 1 4 . 4 3 1 4 . 5 9 1 5 . 2 8 1 5 . 6 1 1 5 . 6 7 1 5 . 8 3 1 5 . 9 0 1 6 . 2 9 1 6 . 4 8 1 6 . 6 1 1 6 . 9 9 1 7 . 1 5 1 7 . 3 4 1 7 . 4 4 1 7 . 5 7 1 7 . 6 9 1 7 . 8 0 1 7 . 9 5 1 8 . 2 2 1 8 . 4 1 1 8 . 5 2 1 8 . 6 0 1 8 . 7 4 1 8 . 8 3 1 8 . 8 9 1 9 . 0 0 1 9 . 1 4 1 9 . 2 3 1 9 . 4 9 1 9 . 5 6 1 9 . 6 4 1 9 . 8 0 1 9 . 8 8 1 9 . 9 6 2 0 . 0 2 2 0 . 1 7 2 0 . 3 1 2 0 . 5 5 2 0 . 8 3 2 0 . 9 2 2 1 . 0 6 2 1 . 3 2 2 1 . 7 6 2 2 . 2 2 2 2 . 5 8 2 3 . 7 7 2 4 . 0 9 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\2GC\DAT\2GC051214_b\0512GC2.0021.RAW H14050122-003A ;0512GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Page 17 of 21 S5-B @ 2.0'-3.5' Batch ID: 24472 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050122-003A ;0512GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC051214_b\0512GC2.0021.RAW Date & Time Acquired: 5/12/2014 9:55:22 PM Method File: G:\Org\2GC\Methods\05121421.MET Calibration File: G:\Org\2GC\Cals\Vhn042214.cal Sample Weight: 50 Dilution: 1.18 S.A.: 1.18 Mean RF for C9 to C10 Aromatic Hydrocarbons: 420.4557 Rt range for C9 to C10 Aromatics: 14.566 to 20.099 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:37406.8 C9-C10 Aromatics Amount: 2.099628 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .118 U Benzene__________________7.19 7.19 7.19 77 .059 U Toluene__________________10.049 10.049 10.049 295 .059 U Ethylbenzene_____________13.474 13.474 13.474 139 .059 U m+p-Xylenes______________13.634 13.634 13.634 556 .118 U o-Xylene_________________14.432 14.432 14.432 204 .059 U 124-Trimethylbenzene_____16.483 -8.55 -8.545 944 .051 J Naphthalene______________20.167 -12.234 -12.229 1499 .129 SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______7.938 2.95 2.463 83.49 70-130 4 . 0 7 4 . 4 9 4 . 6 6 5 . 4 4 5 . 7 6 7 . 1 9 7 . 9 4 9 . 6 1 1 0 . 0 5 1 0 . 6 0 1 2 . 1 0 1 3 . 3 8 1 3 . 4 7 1 3 . 6 3 1 4 . 0 2 1 4 . 4 3 1 4 . 5 9 1 5 . 2 8 1 5 . 6 1 1 5 . 6 7 1 5 . 8 3 1 5 . 9 0 1 6 . 1 4 1 6 . 2 9 1 6 . 4 8 1 6 . 6 1 1 6 . 9 9 1 7 . 1 5 1 7 . 3 4 1 7 . 4 4 1 7 . 5 7 1 7 . 6 9 1 7 . 8 0 1 7 . 9 5 1 8 . 2 2 1 8 . 4 1 1 8 . 5 2 1 8 . 6 0 1 8 . 7 4 1 8 . 8 3 1 8 . 8 9 1 9 . 0 0 1 9 . 1 4 1 9 . 2 3 1 9 . 4 9 1 9 . 5 6 1 9 . 6 4 1 9 . 8 0 1 9 . 8 8 1 9 . 9 6 2 0 . 0 2 2 0 . 1 7 2 0 . 3 1 2 0 . 5 5 2 0 . 8 3 2 0 . 9 2 2 1 . 0 6 2 1 . 3 2 2 1 . 7 6 2 2 . 2 2 2 2 . 5 8 2 3 . 7 7 2 4 . 0 9 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\2GC\DAT\2GC051214_b\0512GC2.0021.RAW H14050122-003A ;0512GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Page 18 of 21 S5-B @ 2.0'-3.5' Batch ID: 24472 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: H14050122-003A ;0512GC2 , $HC-VPH-MA-S, Raw File: G:\Org\2GC\DAT\2GC051214_b\0512GC2b.0021.RAW Date & Time Acquired: 5/12/2014 9:55:22 PM Method File: G:\Org\2GC\Methods\05121421B.MET Calibration File: G:\Org\2GC\Cals\Vhn042214B.cal Sample Weight: 50 Dilution: 1.18 S.A.: 1.18 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 431.8487 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 338.7009 Mean RF for all calibrated compounds: 473.2145 Rt range for Gasoline Range Organics: 4.391 to 15.614 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.524 to 13.01 Rt range for C9 to C12 Aliphatic Hydrocarbons: 13.06 to 20.133 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________7.944 2.95 2.391 81.05 - GRO Area:7794.773 GRO Amount: 0.3887384 TPH Area:54000.45 TPH Amount: 2.693093 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:3437.02 C5-C8 Amount: 0.1878289 C9-C12 Area:42083.72 C9-C12 Amount: 2.932309 3 . 2 7 4 . 3 4 4 . 4 8 4 . 6 7 4 . 9 7 5 . 7 6 6 . 6 9 7 . 1 8 7 . 9 4 8 . 3 1 8 . 5 7 9 . 6 3 1 0 . 0 6 1 0 . 6 9 1 2 . 1 5 1 2 . 5 0 1 3 . 0 7 1 3 . 4 9 1 3 . 6 4 1 3 . 9 8 1 4 . 2 8 1 4 . 4 4 1 4 . 6 1 1 4 . 9 0 1 5 . 0 3 1 5 . 1 6 1 5 . 2 9 1 5 . 4 8 1 5 . 5 7 1 5 . 6 9 1 5 . 8 4 1 5 . 9 1 1 6 . 1 4 1 6 . 2 9 1 6 . 4 9 1 6 . 6 2 1 6 . 7 3 1 6 . 9 3 1 7 . 0 1 1 7 . 1 7 1 7 . 3 5 1 7 . 4 6 1 7 . 5 8 1 7 . 7 0 1 7 . 8 2 1 7 . 9 6 1 8 . 1 6 1 8 . 2 4 1 8 . 4 3 1 8 . 5 4 1 8 . 6 2 1 8 . 7 4 1 8 . 9 1 1 9 . 0 1 1 9 . 1 6 1 9 . 2 6 1 9 . 4 8 1 9 . 5 9 1 9 . 7 3 1 9 . 8 2 1 9 . 9 1 1 9 . 9 9 2 0 . 0 5 2 0 . 1 9 2 0 . 3 4 2 0 . 6 0 2 0 . 8 8 2 0 . 9 5 2 1 . 1 1 2 1 . 5 5 2 1 . 6 8 2 1 . 7 1 2 1 . 8 2 2 2 . 2 7 2 2 . 6 0 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n e n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\2GC\DAT\2GC051214_b\0512GC2b.0021.RAW H14050122-003A ;0512GC2 , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 Page 19 of 21 Shipping container/cooler in good condition? Custody seals intact on all shipping container(s)/cooler(s)? Custody seals intact on all sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? (Exclude analyses that are considered field parameters such as pH, DO, Res Cl, Sulfite, Ferrous Iron, etc.) Container/Temp Blank temperature: Water - VOA vials have zero headspace? Water - pH acceptable upon receipt? Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No No No No No No No No No No No Not Present Not Present Not Present No VOA vials submitted Not Applicable 20.0°C No Ice 5/7/2014 Wanda Johnson FedEx Overnight wjj Date Received: Received by: Login completed by: Carrier name: BL2000\sdull 5/20/2014 Reviewed by: Reviewed Date: Contact and Corrective Action Comments: Samples received in a plastic container & past the recommended analysis time. Jon Hager spoke with Lee Evans regarding sample past hold & improper container. No collection time on sample containers. Wj 5/7/14 Temp Blank received in all shipping container(s)/cooler(s)? Yes No Not Applicable Lab measurement of analytes considered field parameters that require analysis within 15 minutes of sampling such as pH, Dissolved Oxygen and Residual Chlorine, are qualified as being analyzed outside of recommended holding time. Solid/soil samples are reported on a wet weight basis (as received) unless specifically indicated. If moisture corrected, data units are typically noted as –dry. For agricultural and mining soil parameters/characteristics, all samples are dried and ground prior to sample analysis. Standard Reporting Procedures: Workorder Receipt Checklist Allied Engineering Services Inc H14050122 Page 20 of 21 Page 21 of 21