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Home My WebLink About14- 907 North Rouse MDOT Bozeman Maintenance Yard Phase II ESA Final CompletePhase II Environmental Site Assessment Montana Departement of Transportation Bozeman Maintenance Yard 907 North Rouse Avenue Bozeman, Montana Prepared for: The Montana Department of Transportation P.O. Box 201001 Helena, Montana 59620-1001 Prepared by: Resource Technologies, Inc. Under Department of Administration Contract #SPB12-2177V Task Order ESB-10 Submitted: September 23, 2014 RESOURCE TECHNOLOGIES, INC. 1050 EAST MAIN STREET, SUITE 4 BOZEMAN, MT 59715 (406) 585-8005 FAX: (406) 585-0069 TABLE OF CONTENTS 1.0 INTRODUCTION .............................................................................................................. 1 2.0 PHASE II ESA ACTIVITIES ............................................................................................. 1 2.1 Soil Sampling .................................................................................................................. 1 2.2 Groundwater Sampling ................................................................................................... 2 2.3 Soil Vapor Sampling ....................................................................................................... 3 3.0 RESULTS ........................................................................................................................... 4 3.1 Soil Sampling Results ..................................................................................................... 4 3.1.1 EPH Sampling Results ................................................................................................ 4 3.1.2 VPH/VOCs Sampling Results .................................................................................... 4 3.1.3 RCRA Metals Results ................................................................................................. 5 3.2 Groundwater Sampling Results ...................................................................................... 5 3.2.1 EPH Sampling Results ................................................................................................ 5 3.2.2 VPH/VOCs Sampling Results .................................................................................... 5 3.2.3 RCRA Metals Sampling Results ................................................................................. 6 3.3 Soil Vapor Sampling Results .......................................................................................... 6 4.0 DISCUSSION ..................................................................................................................... 6 4.1 Contaminant Distribution – Soil ..................................................................................... 6 4.1.1 TEH ............................................................................................................................. 6 4.1.2 RCRA Metals .............................................................................................................. 7 4.2 Contaminant Distribution – Groundwater ...................................................................... 7 4.2.1 TEH ............................................................................................................................. 7 4.2.2 VOCs........................................................................................................................... 8 4.2.3 Metals .......................................................................................................................... 9 4.3 Soil Vapor ....................................................................................................................... 9 5.0 CONCLUSIONS/RECOMMENDATIONS ..................................................................... 10 REFERENCES CITED ................................................................................................................. 13 LIST OF FIGURES Figure 1. Site Map with Borehole Locations Figure 2. Soil and Groundwater Analytical Results LIST OF TABLES Table 1A. Soil analytical Results – EPH and PAHs Table 1B. Soil Analytical Results – VPH Table 1C. Soil analytical Results – RCRA Metals Table 2A. Groundwater Analytical Results – Organic Compounds Table 2B. Groundwater Analytical Results – RCRA Metals Table 3. Soil Vapor Analytical Results APPENDICES APPENDIX A Soil Borehole Logs and Well Construction Details APPENDIX B Laboratory Analytical Reports – Soil APPENDIX C Laboratory Analytical Reports – Groundwater APPENDIX D Laboratory Analytical Reports – Soil Vapor Phase II Environmental Site Assessment Montana Department of Transportation Bozeman Maintenance Yard 907 North Rouse Avenue, Bozeman, MT Resource Technologies, Inc. September 2014 1.0 INTRODUCTION At the request of the Montana Department of Transportation (MDT), Resource Technologies, Inc. (RTI) has completed Phase II Environmental Assessment (ESA) activities at the MDT maintenance yard located at 907 North Rouse Avenue in Bozeman, Montana (Figure 1). Phase II ESA activities were completed to assess soil and groundwater conditions at the subject property and evaluate the potential for vapor intrusion at the location of a new building planned by the City of Bozeman on the northeastern portion of the site. 2.0 PHASE II ESA ACTIVITIES Work tasks completed during this investigation included installing soil borings; completion of two soil borings as monitoring wells; installation of one soil vapor probe; and collection of soil, groundwater, and soil vapor samples. ESA activities and results are described in the following sections. 2.1 Soil Sampling On July 21, 2014, RTI supervised installation of 10 soil boreholes at the locations shown in Figure 1 using direct push (GeoprobeTM) boring methods. Boreholes B1 through B6 and B8 were emplaced within five feet of geotechnical boreholes with the same designations drilled by Allied Engineering in May 2014. Borehole B7 was not placed adjacent to the Allied Engineering borehole B7 but was placed in a downgradient direction from a dry well known to have existed between garage buildings along the eastern edge of the site (Huntingdon, 1994; Figure 1). Boreholes B9 and B10 do not correspond to Allied Engineering boreholes but were placed adjacent to the active waste-oil tank (B9) and fueling island (B10, Figure 1). Borehole depths ranged from 8.5 to 15 feet below ground surface (bgs). Soil samples were collected continuously in 4-foot long acetate sleeves and were field screened for the presence of volatile organic compounds (VOCs) using a HNu P-101 photoionization detector (PID) and Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 2 Bozeman, Montana, September 2014 heated headspace methods. Soil descriptions and other relevant information were recorded on a soil borehole log by the RTI geologist supervising soil boring activities. Soil borehole logs are included in Appendix A. The soil sample corresponding to the highest PID reading and/or the sample collected immediately above the soil groundwater interface were retained for laboratory analysis. All soil samples were submitted to Energy Laboratories of Billings for the following analyses:  Extractable Petroleum Hydrocarbons (EPH; Massachusetts Department of Environmental Protection Method),  Volatile Petroleum Hydrocarbons (VPH; Massachusetts Department of Environmental Protection Method),  VOCs (EPA Method 8260). Samples exhibiting a total extractable hydrocarbon (TEH) concentration greater than 200 milligrams per kilogram (mg/kg) were further analyzed for EPH aliphatic and aromatic fractions and polynuclear aromatic hydrocarbons (PAHs). In addition, samples collected from boreholes B2, B8, and B9 were also submitted for Resource Conservation and Recovery Act (RCRA) metals analysis. EPH analytical results are shown in Table 1A, VPH and VOCs analytical results are shown in Table 1B, and RCRA metals results are shown in Table 1C. Laboratory analytical reports for soil are included in Appendix B. Please note that with respect to PAH results shown in Table 1A, only PAH compounds detected in at least one sample are shown in the table. Also, with respect to VOCs results presented in Table 1B, only VOCs detected in at least one sample are shown in the table. 2.2 Groundwater Sampling Two soil boreholes were completed as groundwater monitoring wells (B2/MW1 and B8/MW2, Figure 2). Wells were constructed with 1-inch diameter PVC well casing and 10 foot lengths of 0.010 inch slotted screen. Wellheads were completed in cast iron flush mounted manholes. Well construction details are included in Appendix A. Monitoring wells were developed by surging and pumping on August 5, 2014 until water of acceptable clarity was obtained or until the well was bailed dry at least three times. Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 3 Bozeman, Montana, September 2014 Groundwater samples were collected from the monitoring wells on August 7, 2014 by hand bailing methods. Groundwater samples were submitted to Energy Laboratories of Billings for EPH, VPH, VOCs, and RCRA metals analyses. Groundwater analytical results are shown in Table 2A, 2B, and 2C and laboratory analytical reports are included in Appendix C. 2.3 Soil Vapor Sampling One soil vapor probe (V1) was installed at the location shown in Figure 1. A 3/8-inch diameter 6-inch long stainless steel GeoprobeTM soil vapor probe connected to TeflonTM tubing was installed at a depth of 5 feet bgs. Sand was placed around the probe to approximately 1 foot above the top of the probe (4 feet bgs) and the remaining annular space was filled with granular bentonite. The probe tubing that protruded above the ground surface was capped and a traffic cone was placed over the tubing. Soil vapor sampling was completed on August 14, 2014, using a 6.0 liter SUMMA canister. The analytical laboratory (ALS Environmental) supplied the certified SUMMA canister, flow controllers, and vacuum gauges. Sampling was initiated by opening the SUMMA canister valve at the start of sampling and recording the flow controller vacuum reading. The sampling interval was terminated by closing the SUMMA canister valve after recording the flow controller vacuum reading at the conclusion of the approximate 30-minute sampling interval. The initial vacuum in the SUMMA canister was -24.5 inches mercury (hg). The sample collection interval was terminated upon reaching a stage where at least -5 inches hg vacuum, as measured in the field, remained in the canister to detect possible canister leakage during transit to the laboratory. All valves were closed and the sample train manifold was disconnected from the SUMMA canister. A protective cap was then tightened onto the SUMMA canister intake fitting. The SUMMA canister and sample train were returned to the laboratory with chain-of-custody documentation in the same packaging in which they arrived. Soil vapor was analyzed for VOCs by the TO-15 analytical method and for air-phase petroleum hydrocarbons (APH) by the Massachusetts Department of Environmental Protection (MADEP) method. Soil vapor analytical results are shown in Table 3 and laboratory analytical reports are included in Appendix D. Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 4 Bozeman, Montana, September 2014 To check for short-circuiting of ambient air to the soil probe down the probe borehole, a leak- detection cowl was placed over the probe borehole with the probe tubing passing through the top of the cowl. A paper towel soaked with difluoroethane as a tracer was placed under the cowl during sampling. The presence or absence of the tracer in the sample indicates whether any short circuiting occurred during sampling. 3.0 RESULTS 3.1 Soil Sampling Results 3.1.1 EPH Sampling Results TEH was detected in soil samples from boreholes B2, B3, B4, B7, B8, and B9. TEH concentrations reported in samples B3 7-8, B4 9-11, and B7 8-10 were less than 200 mg/kg so fraction and PAH analyses were not completed on those samples. TEH concentrations reported in samples B2 3-4, B2 10-11, B8 9-11, B9 5-7, and B9 8-11 ranged from 527 mg/kg in sample B2 3-4 to 1,790 mg/kg in sample B9 5-7. These samples were further analyzed for EPH fractions and PAHs. In sample that were analyzed for EPH fractions, TEH was composed primarily of C19-C36 aliphatics and C11-C22 aromatics. C9-C18 aliphatics were only detected in sample B9 5-7 at a concentration of 104 mg/kg. Trace concentrations of PAHs were detected in sample B9 5-7 collected adjacent to the waste oil tank. PAHs detected included 2 methylnaphthalene, acenaphthalene, fluorene, phenanthrene, fluoranthene, pyrene, and chrysene. No PAHs were detected in the deeper sample from this borehole (B9 8-11). With respect to EPH and PAHs, only the concentration of C11-C22 aromatics reported in sample B9 5-7 (618 mg/kg) exceeded the applicable Montana Tier 1 risk based screening level (RBSL). 3.1.2 VPH/VOCs Sampling Results VPH range hydrocarbons in soil samples were limited to xylenes and total purgeable hydrocarbons (TPH) detected in samples B9 5-7 and B9 8-11. TPH was composed of C9-C12 aliphatics and C9-C10 aromatics. Reported concentrations of xylenes, TPH, C9-C12 aliphatics, and C9-C10 aromatics were well below applicable soil RBSLs. Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 5 Bozeman, Montana, September 2014 With the exception of xylenes detected in sample B9 5-7 at a concentration lower than the xylene concentration detected via VPH analysis, no VOCs were detected in any of the soil samples. 3.1.3 RCRA Metals Results RCRA metals detected in samples from boreholes B2, B8, and B9 included barium, chromium, and lead (Table 1C). Barium concentrations ranged from 85 mg/kg in sample B2 10-11 to 159 mg/kg in sample B9 5-7. Chromium concentrations ranged from 25 mg/kg in sample B8 9-11 to 34 mg/kg in sample B9 5-7. Lead concentrations ranged from 7 mg/kg in sample B8 9-11 to 15 mg/kg in sample B9 5-7. Arsenic, cadmium, mercury, selenium, and silver were not detected in any of the samples. 3.2 Groundwater Sampling Results 3.2.1 EPH Sampling Results TEH was detected in sample B2/MW1 at a concentration of 861 micrograms per liter (g/l) and in sample B8/MW2 at 373 g/l. Since the concentrations fell below the TEH ceiling value of 1,000 g/l, fraction analysis was not completed. 3.2.2 VPH/VOCs Sampling Results No hydrocarbon compounds were detected in either water sample via VPH analysis; however, trace concentrations of benzene and toluene were detected in sample B2/MW1 and toluene and ethylbenzene were detected in sample B8/MW2 via VOCs (EPA Method 8260) analysis. Reported concentrations of these compounds were “j” qualified by the laboratory since the concentrations fell below the laboratory practical quantitation limit. Other VOCs detected in water samples included 1,1 dichloroethane; chloroform; and tetrachloroethene. 1,1 Dichloroethane was reported in sample B2/MW1 at a “j” qualified concentration of 0.19 g/l. Sample B8/MW2 contained chloroform at a “j” qualified concentration of 0.66 g/l and tetrachloroethene at a concentration of 1.1 g/l. No reported concentrations of TEH, VPH, or VOCs exceeded groundwater RBSLs or DEQ-7 human health standards for groundwater. Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 6 Bozeman, Montana, September 2014 3.2.3 RCRA Metals Sampling Results Dissolved RCRA metals detected in groundwater samples included arsenic detected in sample B2/MW1 at a concentration of 0.003 mg/l, barium detected in sample B2/MW1 at a concentration of 0.32 mg/l and in sample B8/MW2 at a concentration of 0.17 mg/l, and selenium detected in sample B8/MW2 at a concentration of 0.002 mg/l. None of the reported concentrations of dissolved RCRA metals exceeded DEQ-7 human health standards for groundwater. 3.3 Soil Vapor Sampling Results VOCs detected in soil vapor sample BZN-MDT-VP1 included benzene detected at a concentration of 38 micrograms per cubic meter (g/m3), 1,1 dichloroethane detected at a concentration of 32 g/m3, and propene detected at a concentration of 40 g/m3. APH detected in soil vapor sample BZN-MDT-VP1 included C5-C8 aliphatics detected at a concentration of 63,000 g/m3 and C9-C12 aliphatics detected at a concentration of 4,700 g/m3. No difluoroethane was detected in the soil vapor sample indicating no short circuiting of ambient air to the vapor probe during sampling. 4.0 DISCUSSION 4.1 Contaminant Distribution – Soil 4.1.1 TEH TEH impacts in site soils are widespread but are of relatively low magnitude. TEH impacts do not appear to be associated with asphalt millings. Asphalt millings were noted in shallow soils in boreholes B3, B8, B9, and B10 and TEH results for soil samples in those boreholes varied widely from non-detectable at B10 to 1,760 mg/kg at B9. The source of TEH impacts at B9 appears to be accumulated surface releases as indicated by surface staining noted adjacent to the existing waste-oil tank. TEH impacts at B9 decrease with depth supporting the conclusion that the noted impacts resulted from surface releases. TEH soil analytical data are plotted in Figure 2. TEH impacts at B2 may be associated with an underground concrete vault that was used to store road oil (Figure 1). The vault was removed and approximately 225 cubic yards of soil adjacent to the vault were excavated. Monitoring wells were installed in the vicinity of the vault Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 7 Bozeman, Montana, September 2014 excavation and no groundwater impacts were noted. The release was resolved by MDEQ and the monitoring wells were abandoned (Anderson, 2014A). At borehole B8, no TEH was detected in the shallower sample at 3-4 feet bgs while TEH was detected in the 9-11 foot sample. Borehole B8 is situated in the vicinity and downgradient of a 10,000 gallon diesel UST that was removed in 1992. Historic releases from this UST (Release# 1136; Hyalite 2013) may have resulted in low-level TEH impacts in the zone of groundwater fluctuation (smear zone) that persist downgradient of the UST. 4.1.2 RCRA Metals Concentrations of detected metals (barium, chromium, and lead) were generally consistent across the site. All reported metals concentrations were below EPA Region 9 residential soil screening levels (EPA, 2014). Comparing metals analytical results to background metals concentrations in soil from Gallatin County and the State of Montana (Hydrometrics, 2013) indicates that the reported metals concentrations from the MDT site are probably naturally occurring. 4.2 Contaminant Distribution – Groundwater 4.2.1 TEH Groundwater analytical results indicate that groundwater beneath the site has been impacted with TEH at concentrations below the groundwater RBSLs for EPH range aliphatic and aromatic compounds. Insufficient groundwater data were generated during this Phase II investigation to determine if TEH impacts reported in the two groundwater samples (B2/MW1 and B8/MW2) are directly related to vadose zone soil impacts identified at those locations, if the impacts are related to known historic releases at the site, or if the impacts are associated with an unidentified source. Since the early 1990s, numerous environmental investigations have been completed at the site that included installation, sampling, and eventual abandonment of nine groundwater monitoring wells. None of those investigations indicated the presence of a persistent groundwater plume with TEH and associated aliphatic and aromatic fraction concentrations that exceeded groundwater RBSLs. All known releases that resulted in groundwater impacts have been resolved by MDEQ (Hyalite, 2013). Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 8 Bozeman, Montana, September 2014 4.2.2 VOCs VOCs detected at B2/MW1 included trace concentrations of benzene, toluene, and 1,1 dichloroethane. The presence of benzene and toluene may attributable to past UST releases documented at the site (Hyalite, 2013). One of the releases (#1136) was not resolved until 2008 so it is possible that trace concentrations of gasoline range hydrocarbons associated with this release may persist. The chlorinated hydrocarbon 1,1 dichloroethane is primarily used as an intermediate compound in the manufacture of other compounds like 1,1,1 trichloroethane although it has also been used as a metal degreasing solvent. It may be present as a degradation product of 1,1,1 trichloroethane that was widely used in the past as a solvent for degreasing machined metal parts, as propellant in aerosol cans, and as an additive in glues, paints, cleaners, and office products (EPA, 2014). 1,1 Dichloroethane is frequently found in landfill leachate. Data generated during this Phase II investigation did not indicate whether or not 1,1 dichloroethane detected at well B2/MW1 originated on the MDT site. VOCs detected at B8/MW2 included trace concentrations of toluene, ethylbenzene, chloroform, and tetrachloroethene (PCE). The presence of toluene and ethylbenzene may be attributable to past UST releases documented at the site as described above. Chloroform is a common reaction product from chlorination of drinking water and wastewater. A water line servicing buildings along the western margin of the site passes within a few tens of feet to the south of borehole B8/MW2. The presence of chloroform at this location may indicate leaking from this water line. PCE was historically used as a solvent and dry cleaning fluid. There is no obvious source for this compound at the site; however, several of the maintenance buildings have floor drains attached to concrete vaults (Hyalite, 2013). Site personnel interviewed by Hyalite Environmental indicated that the vaults are connected to the city sewer although this could not be verified (Hyalite, 2013). Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 9 Bozeman, Montana, September 2014 4.2.3 RCRA Metals Metals detected in groundwater included arsenic, barium, and selenium reported at concentrations below human health standards. These metals are probably derived from naturally occurring soil materials in the immediate vicinity of the wells. 4.3 Soil Vapor Compounds detected in soil vapor included compounds associated with gasoline (benzene, C5- C8 aliphatics, and C9-C12 aliphatics) as well as 1,1 dichloroethane and propene. The vapor probe was installed a short distance from the fueling island so the presence of compounds associated with gasoline may be associated with fuel that may have been released at the fueling island, either as small overfills that washed off the pad or as a surface release in the vicinity of vapor probe V1. It is unlikely that vapors detected at V1 are attributable to either asphalt millings or tar from the excavated tar vault as asphalt is composed of aliphatic and aromatic compounds in the C20 range and above (Energy Laboratories). Nor do the vapors detected at V1 appear to be associated with TEH impacts detected in soil at nearby B2/MW1 as hydrocarbon impacts in soil were composed primarily of aliphatic compounds in the C19-C36 range. No hydrocarbon compounds were detected in a soil sample collected at B10 located nearer and downgradient of the fueling island indicating that the gasoline range compounds detected in soil vapor are not the result of a subsurface release from the UST system. Removal of the USTs at the northeast corner of the facility is scheduled for November 2014 (Anderson, 2014B), so it is probable that any substantial source of gasoline range hydrocarbons in the area would be discovered during this process. 1,1 Dichloroethane was also detected in groundwater from the nearby well B2/MW1. The source of this compound in soil vapor is probably the same as the source of the compound in groundwater as discussed in the previous section. Propene may be naturally occurring, is a byproduct in the gasoline refining process, and is a component of countless consumer products, especially plastics (Shell, 2014). The potential source for this compound in soil vapor is unknown. Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 10 Bozeman, Montana, September 2014 5.0 CONCLUSIONS/RECOMMENDATIONS Phase II ESA sampling results indicate that soil at the site is impacted with low levels of EPH- range hydrocarbons. The only soil result that exceeded the applicable Tier 1 RBSL for soil was C11-C22 aromatics from sample B9 5-7 collected adjacent to the waste-oil AST adjacent to the southeast corner of the garage. Groundwater sampling results also indicate minor impacts with TEH; however, the possibility that more substantial impacts exist at the site cannot be ruled out. Low levels of benzene, toluene, ethylbenzene, chlorinated solvents (PCE and 1,1 dichloroethane) were also detected in groundwater samples at concentrations below groundwater RBSLs and DEQ-7 human health standards. According to the Phase I ESA completed by Hyalite Environmental in 2013, the Montana Highway Department/Department of Transportation has utilized the facility as far back as 1946. Current and historical activities at the site have included use and storage of tar, fuel, road oil, and lubricating oils; and vehicle maintenance and storage (Hyalite 2013). Given these historical activities, the presence of EPH range impacts in soil and groundwater is not surprising. There have been two documented releases from gasoline USTs at the site and both releases are listed as resolved (Hyalite 2013). The trace concentrations of benzene, toluene, and ethylbenzene detected in groundwater samples may be residual impacts from these releases More problematic, are the detections of PCE and 1,1 dichloroethane in groundwater. Potential sources for these impacts may be discharges or leaks from floor drain sumps, leaching from an old dump site that may be located on the facility (based on anecdotal evidence) or another on- or off-site source. Soil vapor data indicate the presence of elevated concentrations of APH, specifically C5-C8 aliphatics and C9-C12 aliphatics. Lower concentrations of benzene and 1,1 dichloroethane were also detected in soil vapor. Reported concentrations of C5-C8 aliphatics, C9-C12 aliphatics, benzene and 1,1 dichloroethane exceeded DEQ generic screening levels (for C5-C8 and C9-C12 aliphatics (MDEQ, 2011) EPA Region 9 residential and industrial indoor-air screening levels (USEPA, 2014). The reported concentrations of C5-C8 aliphatics and C9-C12 aliphatics are two to three orders of magnitude higher than the DEQ generic screening levels. The reported benzene concentration was one order of magnitude greater than the EPA industrial air-screening Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 11 Bozeman, Montana, September 2014 level. As such, it appears that hydrocarbon compounds in soil vapor within the footprint of the City of Bozeman building proposed at the site could present a vapor-intrusion hazard. The proximity of the vapor probe, V1, to the fueling island at the site suggests that gasoline range soil-vapor impacts may be related to the fueling island. Since no gasoline range hydrocarbons were detected at borehole B10, it appears improbable that gasoline range vapors are the result of a subsurface release, but are more likely attributable to accumulated small surface releases. If gasoline range vapors detected at V1 are associated with the nearby fueling island, it is probable that the source of the vapors will be discovered during removal of the USTs and dispenser island scheduled for November 2014. RTI offers the following recommendations:  Excavate and dispose waste-oil impacted soil adjacent to the waste oil tank at the southeast corner of the garage building.  Install one monitoring well at the upgradient margin of the site, one monitoring well at the downgradient margin of the site, and one monitoring well directly downgradient of the abandoned drywell along the eastern margin of the site (Figure 1). Collect groundwater samples from the wells and analyze samples for EPH and VOCs. Assessing groundwater conditions at the upgradient and downgradient margins of the facility will aid in determining if contaminants are migrating onto the facility from upgradient and determining if contaminants are migrating off site, and determining if more substantial impacts exist elsewhere on site. Assessing groundwater conditions at the location of the drywell will be useful for evaluating the drywell as a potential source of groundwater impacts at the site.  Soils excavated from the footprint of the proposed City of Bozeman building should not be used as fill and should be disposed of at an approved landfill.  Construct the new City of Bozeman building with a sub-slab depressurization system to mitigate any potential vapor intrusion hazard.  If MDT wishes to establish the presence or absence of an old dump site at the facility, perform a geophysical survey of the site using electromagnetic methods or ground- penetrating radar. Phase II Environmental Site Assessment –MDT Bozeman Maintenance Yard Page 13 Bozeman, Montana, September 2014 REFERENCES CITED Allied Engineering Services, Inc., 2014. Geotechnical Report: Police Departments and Municipal Courts Building, 907 North Rouse Avenue, Bozeman, Montana. July. Anderson, Aaron, 2014A. Written communication. Written comments on Draft Phase II Environmental Site Assessment – MDT Bozeman Maintenance Yard. Resource Technologies, Inc., September 12, 2014. Anderson, Aaron, 2014B. E-mail communication, September 17, 2014. Energy Laboratories, Undated. Fingerprint Analysis of Various Hydrocarbons. Huntingdon Engineering and Environmental, Inc., 1994. Environmental Evaluation, Montana Department of Transportation, Bozeman Division Maintenance Facility. July. Hyalite Environmental, LLP, 2013. Phase I Environmental Site Assessment, City of Bozeman MDT Property, 907 North Rouse, Bozeman, MT. June. Hydrometrics, Inc., 2013. Project Report Background Concentrations of Inorganic Constituents in Montana Surface Soils. September. Massachusetts Department of Environmental Protection, 2004. Method for the Determination of Extractable Petroleum Hydrocarbons (EPH). Division of Environmental Analysis, Lawrence Massachusetts. Massachusetts Department of Environmental Protection, 2004. Method for the Determination of Volatile Petroleum Hydrocarbons (VPH). Division of Environmental Analysis, Lawrence Massachusetts. Massachusetts Department of Environmental Protection, 2008. Method for the Determination of Air-Phase Petroleum Hydrocarbons (APH). Office of Research and Standards; Bureau of Waste Site Cleanup, December. Montana Department of Environmental Quality (MDEQ), 2009. Montana Tier 1 Risk Based Corrective Action Guidance for Petroleum Releases, September. Montana Department of Environmental Quality (MDEQ), 2011. Montana Vapor Intrusion Guide. April. Shell Oil, 2014. www.shell.com website visited 9/10/14. USEPA, 2014. Region 9 Screening Levels. May. USEPA, 2014. Basic Information About 1,1,1 Trichloroethane in Drinking Water. At www.water.epa.gov/drink/contaminants/basicinformation/1-1-1-trichloroethane.com. Site visited 9/10/14. Figures P r o j e c t L o c a t i o n R E S O U R C E T E C H N O L O G I E S , I N C . 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 L e g e n d F i g u r e 1 S i t e M a p w i t h S o i l B o r e h o l e L o c a t i o n s M D T M a i n t e n a n c e F a c i l i t y B o z e m a n , M T N 8 0 f t 1 6 0 f t 0 S o i l B o r i n g B- 8 / M W - 2 B - 6 B - 5 B - 1 B - 2 / M W - 1 V 1 B - 1 0 B - 4 B - 7 B-9 B - 3 Building 6 G a s P u m p s R o a d M i x S t o c k p i l e R o a d O i l A S T s 12Building # S o u t h D e - I c i n g T a n k s Building 9 E q u i p m e n t S t o r a g e S t r u c t u r e B u i l d i n g 1 3 M o n i t o r i n g W e l l S o i l V a p o r P r o b e Building 5 Building 7Building 8 1011 N o r t h D e - I c i n g T a n k s Building3Building 4 B u i l d i n g 2 N o r t h R o u s e A v e n u e Tamarack Street Oak Street B u i l d i n g 1 Former 600 gallon g a s and 10,000 gallon d i e s e l UST's resolved by D E Q A p p r o x i m a t e l o c a t i o n s o f f o r m e r m o n i t o r i n g w e l l s i n s t a l l e d a n d a b a n d o n e d w i t h D E Q a p p r o v a l F o r m e r c o n c r e t e t a r p i t ( e x c a v a t e d ) r e s o l v e d b y D E Q Former 3,000 Gall o n W O U S T Former 6,000gallon gas USTresolved by DEQFormer 300 GallonWO UST WO ASTAbandoned Dry Well P r o j e c t L o c a t i o n R E S O U R C E T E C H N O L O G I E S , I N C . 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 L e g e n d F i g u r e 2 S o i l a n d G r o u n d w a t e r A n a l y t i c a l R e s u l t s M D T M a i n t e n a n c e F a c i l i t y B o z e m a n , M T N 8 0 f t 1 6 0 f t 0 S o i l B o r i n g B- 8 / M W - 2 B - 6 B - 5 B - 1 B - 2 / M W - 1 V 1 B - 1 0 B - 4 B - 7 B-9 B - 3 Building 6 G a s P u m p s R o a d M i x S t o c k p i l e R o a d O i l A S T s 12Building # S o u t h D e - I c i n g T a n k s Building 9 E q u i p m e n t S t o r a g e S t r u c t u r e B u i l d i n g 1 3 M o n i t o r i n g W e l l S o i l V a p o r P r o b e Building 5 Building 7Building 8 1011 N o r t h D e - I c i n g T a n k s Building3Building 4 B u i l d i n g 2 N o r t h R o u s e A v e n u e Tamarack Street Oak Street B9 5'-8'TEH 1790 mg/kgTPH 21 mg/kgC9-C124.9 mg/kgC9-C106.8 mg/kgB9 8'-11'TEH 725 mg/kgTPH 16 mg/kgC9-C124.2 mg/kgC9-C106.1 mg/kg Soil TEH 373 g/kg Water T E H 8 6 1 g / k g W a t e r B u i l d i n g 1 T E H = N D T P H = N D S o i l T E H = N D T P H = N D S o i l T E H 2 6 m g / k g T P H N D S o i l T E H = N D T P H = N D S o i l T E H = N D T P H = N D S o i l B 2 3 ' - 4 ' T E H 5 2 7 m g / k g T P H N D B 2 1 0 ' - 1 1 ' T E H 5 6 4 m g / k g T P H N D S o i l T E H 1 0 7 m g / k g T P H N D S o i l T E H 6 2 m g / k g T P H N D S o i l B 8 3 ' - 4 ' T E H N D T P H N D B 8 9 ' - 1 1 ' T E H 6 3 4 m g / k g T P H N D S o i l Tables Ta b l e 1 A . S o i l A n a l y t i c a l R e s u l t s ; E P H a n d P A H s ; M o n t a n a D e p t . o f T r a n s p o r t a t i o n ; B o z e m a n , M T EP H C9 - C 1 8 C 1 9 - C 3 6 C 1 1 - C 2 2 2 M e t h y l- A c e n a p h- P h e n - F l u o r - Sa m p le I D T E H A l i p ha t i c s A l i p ha t i c s A r o m a t i c s n a p th a l e n e t h y le n e F l u o r e n e a n t h r e n e a n t h e n e P y rene Chr y sene an d D e p th D a t e m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g B1 3 - 4 7/ 2 0 / 2 0 1 0 N D - - - - - - - - - - B1 6 - 7 7/ 2 0 / 2 0 1 0 N D - - - - - - - - - - B2 3 - 4 7/ 2 0 / 2 0 1 0 5 2 7 N D 1 8 2 5 6 N D N D N D N D N D N D N D B2 1 0 - 1 1 7/ 2 0 / 2 0 1 0 5 6 4 N D5 8 4 1 N D N D N D N D N D N D N D B3 7 - 8 7/ 2 0 / 2 0 1 0 2 6 - - - - - - - - - - B4 9 - 1 1 7/ 2 0 / 2 0 1 0 1 0 7 - - - - - - - - - - B5 5 - 7 7/ 2 0 / 2 0 1 0 N D - - - - - - - - - - B6 7 - 1 0 7/ 2 0 / 2 0 1 0 N D - - - - - - - - - - B7 8 - 1 0 7/ 2 0 / 2 0 1 0 6 2 - - - - - - - - - - B8 3 - 4 7/ 2 0 / 2 0 1 0 N D - - - - - - - - - - B8 9 - 1 1 7/ 2 0 / 2 0 1 0 6 4 3 N D6 8 8 5 N D N D N D N D N D N D N D B9 5 - 7 7/ 2 0 / 2 0 1 0 1 7 9 0 1 0 4 3 7 1 61 8 0. 1 7 j 0. 4 8 0 . 6 2 0 . 2 8 0 . 6 8 1 . 1 0 . 6 6 B9 8 - 1 1 7/ 2 0 / 2 0 1 0 7 2 5 N D7 5 5 9 N D N D N D N D N D N D N D B1 0 7 - 8 7/ 2 0 / 2 0 1 0 N D - - - - - - - - - - Ti e r 1 R B S L * 2 0 0 0 1 0 0 0 0 0 4 0 0 - - 6 0 0 - 5 0 0 2 0 0 0 2 0 0 0 TE H = t o t a l e x t r a c t a b l e h y dr o c a r b o n s m g /k g = m i l l i g ra m s p er k i l o g ra m N D = N o t d e t e c t e d a b o v e p ra c t i c a l q ua n t i t a t i o n l i m i t Ti e r 1 R B S L s = T i e r 1 R i s k B a s e d S c r e e n i n g L e v e l s f o r s u b s u r f a c e s o i l < 1 0 f e e t t o g ro u n d w a t e r Ta b l e 1 B . S o i l A n a l y t i c a l R e s u l t s ; V P H ; M o n t a n a D e p t . o f T r a n s p o r t a t i o n ; B o z e m a n , M T VPH Et h y l- N a p h- C 5 - C 8 C 9 - C 1 2 C 9 - C 1 0 Sa m p le I D M T B E B e n z e n e T o l u e n e b e n z e n e X y le n e s t h a l e n e T P H A l i p ha t i c s A l i p hatics Aromatics an d D e p th D a t e m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g B1 3 - 4 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B1 6 - 7 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B2 3 - 4 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B2 1 0 - 1 1 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B3 7 - 8 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B4 9 - 1 1 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B5 5 - 7 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B6 7 - 1 0 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B7 8 - 1 0 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B8 3 - 4 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B8 9 - 1 1 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D B9 5 - 7 7/ 2 0 / 2 0 1 0 N D N D N D N D 0 . 2 1 N D2 1 N D 4 . 9 6 . 8 B9 8 - 1 1 7/ 2 0 / 2 0 1 0 N D N D N D N D 0 . 2 9 N D1 6 N D 4 . 2 6 . 1 B1 0 7 - 8 7/ 2 0 / 2 0 1 0 N D N D N D N D N D N D N D N D N D N D Ti e r 1 R B S L * 0 . 0 8 0 . 0 4 1 0 1 0 2 0 0 9 - 2 0 0 1 0 0 0 1 0 0 TP H = t o t a l p ur g ea b l e h y dr o c a r b o n s VP H = v o l a t i l e p et r o l e u m h y dr o c a r b o n s m g /k g = m i l l i g ra m s p er k i l o g ra m N D = N o t d e t e c t e d a b o v e p ra c t i c a l q ua n t i t a t i o n l i m i t Ti e r 1 R B S L s = T i e r 1 R i s k B a s e d S c r e e n i n g L e v e l s f o r s u b s u r f a c e s o i l < 1 0 f e e t t o g ro u n d w a t e r Ta b l e 1 C . S o i l A n a l y t i c a l R e s u l t s ; R C R A M e t a l s ; M o n t a n a D e p t . o f T r a n s p o r t a t i o n ; B o z e m a n , M T Sa m p le I D A r s e n i c B a r i u m C a d m i u m C h r o m i u m L e a d M e r c u r y Se l e n i u m S i l v e r an d D e p th D a t e m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g m g /k g B2 1 0 - 1 1 7/ 2 0 / 2 0 1 0 N D8 5 N D2 9 1 2 N D N D N D B8 9 - 1 1 7/ 2 0 / 2 0 1 0 N D9 5 N D2 5 7 N D N D N D B9 5 - 7 7/ 2 0 / 2 0 1 0 N D 1 5 9 N D3 4 1 5 N D N D N D EP A R e s i d e n t i a l S L 0 . 6 7 1 5 0 0 0 7 0 1 2 0 0 0 0 4 0 0 9 . 4 3 9 0 3 9 0 Ga l l a t i n C o . B a c k g ro u n d 8 1 6 0 0 . 4 2 2 . 2 1 9 < 0 . 0 5 0 . 3 0 . 1 m g /k g = m i l l i g ra m s p er k i l o g ra m N D = N o t d e t e c t e d a b o v e p ra c t i c a l q ua n t i t a t i o n l i m i t Ta b l e 2 A . G r o u n d w a t e r A n a l y t i c a l R e s u l t s ; O r g a n i c C o m p o u n d s ; M o n t a n a D e p t . o f T r a n s p o r t a t i o n ; B o z e m a n , M T VP H Et h y l- N a p h- C 5 - C 8 C 9 - C 1 2 C 9 - C 1 0 1 ,1 Dichloro- Chloro- Tetrachloro- Sa m p le I D M T B E B e n z e n e T o l u e n e b e n z e n e X y le n e s t h a l e n e T P H A l i p ha t i c s A l i p ha t i c s A r o m a t i c s T E H e t h a n e f o r m e t h e n e an d D e p th D a t e g /l g /l g /l g /l g /l g /l g /l g /l g /l g /l g /l g /l g /l g /l B2 / M W 1 8/ 6 / 2 0 1 0 N D 0 . 1 1 j * 0 . 1 9 j * N D N D N D N D N D N D N D 8 6 1 0 . 1 9 j N D N D B8 / M W 2 8/ 6 / 2 0 1 0 N D N D 0 . 4 5 j * 0 . 1 5 j * N D N D N D N D N D N D 3 7 3 N D 0.66 j 1.1 Ti e r 1 R B S L 3 0 5 1 0 0 0 7 0 0 1 0 0 0 0 1 0 0 1 0 0 0 7 0 0 1 0 0 0 1 0 0 0 1 0 0 0 - - - DE Q -7 -7 05 TP H = t o t a l p ur g ea b l e h y dr o c a r b o n s VP H = v o l a t i l e p et r o l e u m h y dr o c a r b o n s g /l = m i l l i g ra m s p er k i l o g ra m N D = N o t d e t e c t e d a b o v e p ra c t i c a l q ua n t i t a t i o n l i m i t Ti e r 1 R B S L s = T i e r 1 R i s k B a s e d S c r e e n i n g L e v e l s f o r g ro u n d w a t e r DE Q -7 = M o n t a n a h u m a n h e a l t h s t a n d a r d f o r g ro u n d w a t e r j = E s t i m a t e d v a l u e . T h e a n a l y te w a s p re s e n t a t a c o n c e n t r a t i o n l e s s t h a n t h e r e p or t i n g l i m i t . * A n a l y te d e t e c t e d b y 8 2 6 0 a n a l y si s (VO C s ). A n a l y te n o t d e t e c t e d b y V P H a n a l y si s . Ta b l e 2 B . G r o u n d w a t e r A n a l y t i c a l R e s u l t s ; R C R A M e t a l s ; M o n t a n a D e p t . o f T r a n s p o r t a t i o n ; B o z e m a n , M T Ar s e n i c B a r i u m C a d m i u m C h r o m i u m L e a d M e r c u r y Se l e n i u m S i l v e r Sa m p le I D D a t e m g /l m g /l m g /l m g /l m g /l m g /l m g /l m g /l B2 / M W 1 7/ 2 0 / 2 0 1 0 0 . 0 0 3 0 . 3 2 N D N D N D N D N D N D B8 / M W 2 7/ 2 0 / 2 0 1 0 N D 0 . 1 7 N D N D N D N D 0 . 0 0 2 N D DE Q -7 * 0 . 0 1 1 0 . 0 0 5 0 . 1 0 . 0 1 5 0 . 0 0 2 0 . 0 5 0 . 1 m g / = m i l l i g ra m s p er l i t e r N D = N o t d e t e c t e d a b o v e p ra c t i c a l q ua n t i t a t i o n l i m i t DE Q -7 = H u m a n H e a l t h S t a n d a r d f o r G r o u n d w a t e r Table 3. Soil Vapor Analytical Results; APH and Detected VOCs Montana Dept. of Transportation; Bozeman, MT APH C5-C8 C9-C12 C9-C10 1,1 Dichloro- Aliphatics Aliphatics Aromatics Benzene ethane Propene* Sample ID Date g/m3 g/m3 g/m3 g/m3 g/m3 BZN-MDT-VP1 8/13/2010 63,000 4,700 ND3 8 3 2 4 0 DEQ Generic Screening Level 73 20.9 5.2 - - - EPA Residential Indoor Air Screening Level - - - 0.36 1.8 3,100 EPA Industrial Indoor Air Screening Level - - - 1.6 7.7 13,000 * also known as propylene APH = air-phase petroleum hydrocarbons g/m3 = micrograms per cubic meter ND = Not detected above practical quantitation limit Appendix A Soil Borehole Logs and Well Construction Details 0 3 f t B o r i n g L o c a t i o n M a p ( n o t t o s c a l e ) 5 1 0 L I T H O L O G Y B - 1 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T R E S O U R C E T E C H N O L O G I E S , I N C . 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Gravelly san d f i l l , t a n t o d a r k b r o w n , d r y - d a m p . Hole 2" dia m e t e r . End of borin g a t 1 2 ' S i l t S a n d G r a v e l 5 8 P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l N D N D Silt and fine s a n d , i n t e r l a m i n a t e d , d a r k g r a y , d a m p . Sand/sandy g r a v e l , i n t e r b e d d e d , f i n e - c o a r s e s a n d , gravel to 72" , d a m p . C l a y 0 3 f t B o r i n g L o c a t i o n M a p ( n o t t o s c a l e ) 5 1 0 L I T H O L O G Y B - 2 / M W - 1 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T R E S O U R C E T E C H N O L O G I E S , I N C . 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Sandy grave l f i l l , t a n - d a r k b r o w n . Hole 2" dia m e t e r . End of borin g a t 1 3 . 5 ' S i l t S a n d G r a v e l P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l Silty clay, da r k b r o w n , m e d i u m p l a s t i c i t y , f i r m - s t i f f , damp.Sandy grave l , l i g h t b r o w n , f i r m - c o a r s e s a n d a n d gravel to >2" d i a m e t e r , d r y - d a m p . Sand and sa n d y g r a v e l i n t e r b e d d e d , f i r m - c o a r s e s a n d and gravel t o > 2 " . Sand, dark g r a y , l a m i n a t e d , d a m p . C l a y Well Construction Diagram Project: Project Number: Location: Well ID: Installation: Geologist: Borehole Diameter: Borehole Depth: Well Diameter Casing Material: Top of Casing Elevation: Drilling Method: A. Well Depth: B. Depth to Screen: C. Screened Interval: D. Surface Seal: E. Backfill: F. Seal: G. Sandpack: H. Bottom Seal: Flush Mount Protective Well Cover Ground Surface A. . D. E. F. G. H. B. C. Resource Technologies, Inc. Material: Material: Material: Material: Material: Type Screen: B2/MW1 0-1’ 1'-1.5’ 1.5'-2.5’ 2” 1” Schedule 40 PVC MDT Yard 14-866 Bozeman, MT 7/21/14 Laudon 13.5’ direct push 13.5’ 3.5’ 3.5’-13.5’’ 0.010 slot pvc Concrete sand bentonite chips 2.5’-13.5’ 10-20 silica sand NA 0 3 f t B o r i n g L o c a t i o n M a p ( n o t t o s c a l e ) 5 1 0 L I T H O L O G Y B - 3 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T R E S O U R C E T E C H N O L O G I E S , I N C . 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Gravelly san d f i l l , g r a y , d a m p . Hole 2" dia m e t e r . Refusal at 1 0 . 5 ' S i l t S a n d G r a v e l P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l N D Sandy grave l , g r a y , a b u n d e n t f i n e s , f i n e - c o a r s e s a n d , gravel to >2" , d e n s e , d a m p . Poor recove r y , w e t a t 1 0 ' - 1 0 . 5 ' At 3' color c h a n g e t o b r o w n . Sandy grave l w i t h a b u n d e n t a s p h a l t m i l l i n g s , d a r k gray-black, m e d i u m d e n s i t y . Silty sand, g r a y , s i l t - p e a s i z e d g r a v e l , d a m p . N D Silt, dark bro w n - b l a c k , l o w p l a s t i c i t y , a b u n d a n t s a n d , wood debris , f i r m , d a m p . C l a y 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 S i l t 0 3 f t B o r i n g L o c a t i o n M a p ( n o t t o s c a l e ) 5 1 0 L I T H O L O G Y B - 4 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T R E S O U R C E T E C H N O L O G I E S , I N C . Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Sandy grave l f i l l , l i g h t t o d a r k b r o w n , f i n e t o c o a r s e sand.Hole 2" dia m e t e r . End of borin g a t 1 2 ' Sandy grave l , l i g h t b r o w n , a b u n d a n t f i n e s , f i n e s a n d , gravel >2". S a n d G r a v e l N D P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l N D N D Gravelly san d , t a n , a b u n d a n t f i n e s , f i n e s a n d , w i t h minor med-c o a r s e s a n d a n d f i n e g r a v e l , l o o s e , d r y Silty clay, da r k b r o w n - b l a c k , l o w p l a s t i c i t y , m i n o r sand, stiff, d a m p . Sandy clay, d a r k b r o w n , m o i s t Silty sand/s a n d y s i l t , b r o w n , m i n o r m e d i u m c o a r s e sand and gr a v e l . C l a y 0 3 f t B o r i n g L o c a t i o n M a p ( n o t t o s c a l e ) 5 8 L I T H O L O G Y B - 5 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T R E S O U R C E T E C H N O L O G I E S , I N C . 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Gravelly san d f i l l , t a n a b u n d a n t f i n e s , f i n e sand-pebble s i z e d g r a v e l , d e n s e , d a m p . Hole 2" dia m e t e r . End of borin g a t r e f u s a l , 8 . 5 ' S i l t S a n d G r a v e l P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l N D N D Silty clay, da r k g r a y t o b l a c k , l o w p l a s t i c i t y , m i n o r sand and gr a v e l , v e r y s t i f f , d a m p . Sand/sandy g r a v e l , i n t e r b e d d e d , f i n e - c o a r s e s a n d , gravel to 72" , d a m p . C l a y 6'-6.5' Zone w i t h a b u n d a n t c l a y . 5 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 S i l t 0 3 f t B o r i n g L o c a t i o n M a p ( n o t t o s c a l e ) B - 6 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T L I T H O L O G Y R E S O U R C E T E C H N O L O G I E S , I N C . Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Hole 2" dia m e t e r . Gravelly san d ( r o a d b a s e ) , g r a y , d r y , f i n e s a n d t o pebble size g r a v e l . End of borin g a t r e f u s a l , 1 0 ' Sand, tan, fi n e t o c o a r s e s a n d , c o a r s e n s d o w n w a r d t o sandy grave l , g r a v e l t o 2 " . S a n d G r a v e l N D P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l N D N D Silty clay, m o l t e d l i g h t g r a y a n d w h i t e , l o w p l a s t i c i t y , very stiff, da m p . Silty clay, da r k b r o w n - b l a c k , v e r y s t i f f , d a m p At 4', color c h a n g e t o b r o w n . C l a y 5 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 G r a v e l S i l t 0 3 f t B o r i n g L o c a t i o n M a p ( n o t t o s c a l e ) L I T H O L O G Y 1 0 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T B - 7 R E S O U R C E T E C H N O L O G I E S , I N C . Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Sandy grave l f i l l . Poor recove r y a t 1 8 " Hole 2" dia m e t e r . End of borin g a t 1 2 ' S a n d N D P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l N D N D Silt, dark bro w n , l o w p l a s t i c i t y , m i n o r s a n d , s t i f f , d a m p Sandy grave l , l i g h t g r a y , f i n e t o c o a r s e s a n d a n d gravel to >2" , d r y t o d a m p . C l a y Asphalt. 3 f t ( n o t t o s c a l e ) L I T H O L O G Y 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 S i l t 0 B o r i n g L o c a t i o n M a p 5 1 0 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T B - 8 / M W - 2 R E S O U R C E T E C H N O L O G I E S , I N C . Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Asphalt milli n g s Hole 2" diameter . End of borin g a t r e f u s a l , 1 2 ' S a n d N D G r a v e l P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l N D N D Gravelly san d r o a d b a s e Sandy grave l , l i g h t t o d a r k b r o w n , a b u n d a n t f i n e s , f i n e to coarse sa n d a n d g r a v e l > 2 " , d r y , d a m p . At 12', fewer f i n e s t h a n a b o v e . At 14.5', abu n d a n t f i n e s . C l a y Silty clay, da r k g r a y - b l a c k , m i n o r s a n d , v e r y s t i f f , damp.At 4'-4.5' col o r c h a n g e t o b r o w n . Well Construction Diagram Project: Project Number: Location: Well ID: Installation: Geologist: Borehole Diameter: Borehole Depth: Well Diameter Casing Material: Top of Casing Elevation: Drilling Method: A. Well Depth: B. Depth to Screen: C. Screened Interval: D. Surface Seal: E. Backfill: F. Seal: G. Sandpack: H. Bottom Seal: Flush Mount Protective Well Cover Ground Surface A. . D. E. F. G. H. B. C. Resource Technologies, Inc. Material: Material: Material: Material: Material: Type Screen: B8/MW2 0-1’ 1'-1.5’ 1.5'-3.5’ 2” 1” Schedule 40 PVC MDT Yard 14-866 Bozeman, MT 7/21/14 Laudon 15’ direct push 14.5’ 4.5’ 4.5’-14.5’’ 0.010 slot pvc Concrete sand bentonite chips 3.5’-15’ 10-20 silica sand NA 5 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 G r a v e l S i l t 0 3 f t B o r i n g L o c a t i o n M a p ( n o t t o s c a l e ) L I T H O L O G Y 1 0 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T B - 9 R E S O U R C E T E C H N O L O G I E S , I N C . Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Sandy grave l f i l l , b r o w n t o b l a c k , a t l e a s t 5 0 % a s p h a l t . Hole 2" dia m e t e r . End of borin g a t 1 2 ' S a n d 1 1 0 P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l 4 0 N D Silt, dark bro w n t o b l a c k , l o w p l a s t i c i t y , m i n o r s a n d , stiff, dampSandy grave l , g r a y , m i n o r f i n e s , f i n e t o c o a r s e s a n d and gravel t o > 2 " , d e n s e , d r y , d a m p . C l a y 5 1 0 5 0 E A S T M A I N S T R E E T , S U I T E 4 B O Z E M A N , M T 5 9 7 1 5 ( 4 0 6 ) 5 8 5 - 8 0 0 5 F A X : ( 4 0 6 ) 5 8 5 - 0 0 6 9 G r a v e l S i l t 0 3 f t B o r i n g L o c a t i o n M a p ( n o t t o s c a l e ) L I T H O L O G Y 1 0 S o i l B o r i n g L o g M o n t a n a D e p a r t m e n t o f T r a n s p o r t a t i o n B o z e m a n , M T B - 1 0 R E S O U R C E T E C H N O L O G I E S , I N C . Installed:J u l y 2 1 , 2 0 1 4 Driller: S t a n t e c 1 2 1 0 0 2 B r o w n s G u l c h R o a d B u t t e , M T 5 9 7 0 1 Method: D i r e c t P u s h G e o p r o b e Fill, gravelly c l a y , s a n d y g r a v e l a n d m i l l e d a s p h a l t . Hole 2" dia m e t e r . End of borin g a t 1 2 ' S a n d P I D ( P P M ) S o i l S a m p l i n g I n t e r v a l N D N D Silt, dark bro w n . C l a y Asphalt.Silty clay, da r k b r o w n - b l a c k , l o w p l a s t i c i t y , s t i f f , d a m p Sandy grave l , b r o w n , a b u n d a n t f i n e s , f i n e t o c o a r s e sand, gravel t o > 2 " . Silt and sand i n t e r b e d d e d . Appendix B Laboratory Analytical Reports - Soil ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT Lab ID Client Sample ID Collect Date Receive Date Matrix Test B14072051-001 B1 3-4 07/21/14 0:00 07/23/14 Soil EPH-Ultrasonic Extraction Methanol Extraction for Volatiles Hydrocarbons, Extractable Petroleum-Scrn Volatile Petroleum Hydrocarbons Moisture Moisture Prep Percent Moisture Volatile Organics, Methanol Extraction 8260-Volatile Organic Compounds - Short List B14072051-002 B1 6-7 07/21/14 0:00 07/23/14 Soil Same As Above B14072051-003 B2 3-4 07/21/14 0:00 07/23/14 Soil EPH-Ultrasonic Extraction Methanol Extraction for Volatiles EPH Fractionation Hydrocarbons, Aliphatic Extractable Petroleum Hydrocarbons, Aromatic Extractable Petroleum Hydrocarbons, Extractable Petroleum-Scrn Volatile Petroleum Hydrocarbons Moisture Moisture Prep Percent Moisture Volatile Organics, Methanol Extraction 8260-Volatile Organic Compounds - Short List MT DEQ-Lust Project Name: Bozeman Mount Yard Work Order: B14072051 PO Box 200901 Helena, MT 59620-0901 August 08, 2014 Energy Laboratories Inc Billings MT received the following 14 samples for MT DEQ-Lust on 7/23/2014 for analysis. Page 1 of 117 ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT B14072051-004 B2 10-11 07/21/14 0:00 07/23/14 Soil Metals by ICP/ICPMS, Total or Soluble Mercury in Solid By CVAA EPH-Ultrasonic Extraction Methanol Extraction for Volatiles EPH Fractionation Hydrocarbons, Aliphatic Extractable Petroleum Hydrocarbons, Aromatic Extractable Petroleum Hydrocarbons, Extractable Petroleum-Scrn Volatile Petroleum Hydrocarbons Moisture Moisture Prep Percent Moisture Digestion, Total Metals Digestion, Mercury by CVAA Volatile Organics, Methanol Extraction 8260-Volatile Organic Compounds - Short List B14072051-005 B3 7-8 07/21/14 0:00 07/23/14 Soil EPH-Ultrasonic Extraction Methanol Extraction for Volatiles Hydrocarbons, Extractable Petroleum-Scrn Volatile Petroleum Hydrocarbons Moisture Moisture Prep Percent Moisture Volatile Organics, Methanol Extraction 8260-Volatile Organic Compounds - Short List B14072051-006 B4 9-11 07/21/14 0:00 07/23/14 Soil Same As Above B14072051-007 B5 5-7 07/21/14 0:00 07/23/14 Soil Same As Above B14072051-008 B6 7-10 07/21/14 0:00 07/23/14 Soil Same As Above B14072051-009 B7 8-10 07/21/14 0:00 07/23/14 Soil Same As Above B14072051-010 B8 9-11 07/21/14 0:00 07/23/14 Soil Metals by ICP/ICPMS, Total or Soluble Mercury in Solid By CVAA EPH-Ultrasonic Extraction Methanol Extraction for Volatiles EPH Fractionation Hydrocarbons, Aliphatic Extractable Petroleum Hydrocarbons, Aromatic Extractable Petroleum Hydrocarbons, Extractable Petroleum-Scrn Volatile Petroleum Hydrocarbons Moisture Moisture Prep Percent Moisture Digestion, Total Metals Digestion, Mercury by CVAA Volatile Organics, Methanol Extraction 8260-Volatile Organic Compounds - Short List Page 2 of 117 ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT The analyses presented in this report were performed by Energy Laboratories, Inc., 1120 S 27th St., Billings, MT 59101, unless otherwise noted. Any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, or the Case Narrative. The results as reported relate only to the item(s) submitted for testing. If you have any questions regarding these test results, please call. Report Approved By: B14072051-011 B9 5-7 07/21/14 0:00 07/23/14 Soil Same As Above B14072051-012 B9 8-11 07/21/14 0:00 07/23/14 Soil EPH-Ultrasonic Extraction Methanol Extraction for Volatiles EPH Fractionation Hydrocarbons, Aliphatic Extractable Petroleum Hydrocarbons, Aromatic Extractable Petroleum Hydrocarbons, Extractable Petroleum-Scrn Volatile Petroleum Hydrocarbons Moisture Moisture Prep Percent Moisture Volatile Organics, Methanol Extraction 8260-Volatile Organic Compounds - Short List B14072051-013 B10 7-8 07/21/14 0:00 07/23/14 Soil EPH-Ultrasonic Extraction Methanol Extraction for Volatiles Hydrocarbons, Extractable Petroleum-Scrn Volatile Petroleum Hydrocarbons Moisture Moisture Prep Percent Moisture Volatile Organics, Methanol Extraction 8260-Volatile Organic Compounds - Short List B14072051-014 B8 3-4 07/21/14 0:00 07/23/14 Soil Same As Above Page 3 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-001 Client Sample ID: B1 3-4 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 12:49 / amn 0.2 wt% 20 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/23/14 20:27 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 4 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-001 Client Sample ID: B1 3-4 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/23/14 20:27 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/23/14 20:27 / nl 78-160 %REC 96.0 Surr: p-Bromofluorobenzene SW8260B 07/23/14 20:27 / nl 70-132 %REC 88.0 Surr: Dibromofluoromethane SW8260B 07/23/14 20:27 / nl 60-136 %REC 86.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/23/14 20:27 / nl 75-138 %REC 93.0 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/25/14 14:09 / pbf 0.12 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/25/14 14:09 / pbf 0.062 mg/kg-dry ND Benzene MA-VPH 0.04 07/25/14 14:09 / pbf 0.062 mg/kg-dry ND Toluene MA-VPH 10 07/25/14 14:09 / pbf 0.062 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/25/14 14:09 / pbf 0.062 mg/kg-dry ND m+p-Xylenes MA-VPH 07/25/14 14:09 / pbf 0.062 mg/kg-dry ND o-Xylene MA-VPH 07/25/14 14:09 / pbf 0.062 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/25/14 14:09 / pbf 0.12 mg/kg-dry ND Naphthalene MA-VPH 4 07/25/14 14:09 / pbf 2.5 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/25/14 14:09 / pbf 2.5 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/25/14 14:09 / pbf 2.5 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/25/14 14:09 / pbf 2.5 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/25/14 14:09 / pbf 70-130 %REC 101 Surr: VPH Aromatics Surrogate MA-VPH 07/25/14 14:09 / pbf 70-130 %REC 97.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 07/25/14 23:04 / amn 12 mg/kg-dry ND Total Extractable Hydrocarbons SW8015M 200 07/25/14 23:04 / amn 40-140 %REC 95.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 5 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-002 Client Sample ID: B1 6-7 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:03 / amn 0.2 wt% 5.0 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 11:43 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 6 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-002 Client Sample ID: B1 6-7 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 11:43 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 11:43 / nl 78-160 %REC 106 Surr: p-Bromofluorobenzene SW8260B 07/24/14 11:43 / nl 70-132 %REC 100 Surr: Dibromofluoromethane SW8260B 07/24/14 11:43 / nl 60-136 %REC 92.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 11:43 / nl 75-138 %REC 104 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/25/14 17:39 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/25/14 17:39 / pbf 0.053 mg/kg-dry ND Benzene MA-VPH 0.04 07/25/14 17:39 / pbf 0.053 mg/kg-dry ND Toluene MA-VPH 10 07/25/14 17:39 / pbf 0.053 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/25/14 17:39 / pbf 0.053 mg/kg-dry ND m+p-Xylenes MA-VPH 07/25/14 17:39 / pbf 0.053 mg/kg-dry ND o-Xylene MA-VPH 07/25/14 17:39 / pbf 0.053 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/25/14 17:39 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/25/14 17:39 / pbf 2.1 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/25/14 17:39 / pbf 2.1 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/25/14 17:39 / pbf 2.1 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/25/14 17:39 / pbf 2.1 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/25/14 17:39 / pbf 70-130 %REC 105 Surr: VPH Aromatics Surrogate MA-VPH 07/25/14 17:39 / pbf 70-130 %REC 99.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 07/26/14 02:52 / amn 11 mg/kg-dry ND Total Extractable Hydrocarbons SW8015M 200 07/26/14 02:52 / amn 40-140 %REC 93.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 7 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-003 Client Sample ID: B2 3-4 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:09 / amn 0.2 wt% 16 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 12:13 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 8 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-003 Client Sample ID: B2 3-4 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 12:13 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 12:13 / nl 78-160 %REC 93.0 Surr: p-Bromofluorobenzene SW8260B 07/24/14 12:13 / nl 70-132 %REC 94.0 Surr: Dibromofluoromethane SW8260B 07/24/14 12:13 / nl 60-136 %REC 85.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 12:13 / nl 75-138 %REC 93.0 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/25/14 19:22 / pbf 0.12 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/25/14 19:22 / pbf 0.059 mg/kg-dry ND Benzene MA-VPH 0.04 07/25/14 19:22 / pbf 0.059 mg/kg-dry ND Toluene MA-VPH 10 07/25/14 19:22 / pbf 0.059 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/25/14 19:22 / pbf 0.059 mg/kg-dry ND m+p-Xylenes MA-VPH 07/25/14 19:22 / pbf 0.059 mg/kg-dry ND o-Xylene MA-VPH 07/25/14 19:22 / pbf 0.059 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/25/14 19:22 / pbf 0.12 mg/kg-dry ND Naphthalene MA-VPH 4 07/25/14 19:22 / pbf 2.4 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/25/14 19:22 / pbf 2.4 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/25/14 19:22 / pbf 2.4 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/25/14 19:22 / pbf 2.4 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/25/14 19:22 / pbf 70-130 %REC 104 Surr: VPH Aromatics Surrogate MA-VPH 07/25/14 19:22 / pbf 70-130 %REC 103 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN *07/27/14 13:49 / amn 238 mg/kg-dry 527 Total Extractable Hydrocarbons SW8015M 200 07/27/14 13:49 / amn 40-140 %REC 91.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. EXTRACTABLE PETROLEUM HYDROCARBONS 08/02/14 15:58 / tmc 12 mg/kg-dry ND C9 to C18 Aliphatics MA-EPH 200 08/02/14 15:58 / tmc 12 mg/kg-dry 182 C19 to C36 Aliphatics MA-EPH 20000 08/02/14 15:58 / tmc 40-140 %REC 93.0 Surr: 1-Chloro-octadecane MA-EPH 08/05/14 11:17 / tmc 12 mg/kg-dry 56 C11 to C22 Aromatics MA-EPH 400 08/05/14 11:17 / tmc 12 mg/kg-dry 391 Total Extractable Hydrocarbons MA-EPH Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. Page 9 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-003 Client Sample ID: B2 3-4 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Naphthalene MA-EPH 4 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND 2-MethylNaphthalene MA-EPH 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Acenaphthylene MA-EPH 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Acenaphthene MA-EPH 200 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Fluorene MA-EPH 300 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Phenanthrene MA-EPH 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Anthracene MA-EPH 2000 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Fluoranthene MA-EPH 300 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Pyrene MA-EPH 200 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Benzo(a)Anthracene MA-EPH 0.2 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Chrysene MA-EPH 20 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Benzo(b)Fluoranthene/Benzo(k)Fluoranthene MA-EPH 0.2 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Benzo(a)Pyrene MA-EPH 0.02 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Dibenz(a,h)anthracene/Indeno(1,2,3-cd)pyrene MA-EPH 0.02 08/05/14 11:17 / tmc 0.20 mg/kg-dry ND Benzo(g,h,I)perylene MA-EPH 08/05/14 11:17 / tmc 40-140 %REC 87.0 Surr: 2-Bromonaphthalene MA-EPH 08/05/14 11:17 / tmc 40-140 %REC 85.0 Surr: 2-Fluorobiphenyl MA-EPH 08/05/14 11:17 / tmc 40-140 %REC 86.0 Surr: o-Terphenyl MA-EPH - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 10 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-004 Client Sample ID: B2 10-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:11 / amn 0.2 wt% 7.2 Moisture SW3550A METALS, TOTAL - EPA SW846 08/02/14 04:31 / rlh 5mg/kg-dry ND Arsenic SW6010B 08/02/14 04:31 / rlh 5mg/kg-dry 85 Barium SW6010B 08/02/14 04:31 / rlh 1mg/kg-dry ND Cadmium SW6010B 08/02/14 04:31 / rlh 5mg/kg-dry 29 Chromium SW6010B 08/02/14 04:31 / rlh 5mg/kg-dry 12 Lead SW6010B 08/05/14 12:56 / eac 1mg/kg-dry ND Mercury SW7471B 08/02/14 04:31 / rlh 5mg/kg-dry ND Selenium SW6010B 08/02/14 04:31 / rlh 5mg/kg-dry ND Silver SW6010B VOLATILE ORGANIC COMPOUNDS 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 11 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-004 Client Sample ID: B2 10-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 12:43 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 12:43 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 12:43 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 12:43 / nl 78-160 %REC 99.0 Surr: p-Bromofluorobenzene SW8260B 07/24/14 12:43 / nl 70-132 %REC 99.0 Surr: Dibromofluoromethane SW8260B 07/24/14 12:43 / nl 60-136 %REC 94.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 12:43 / nl 75-138 %REC 98.0 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/25/14 21:06 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/25/14 21:06 / pbf 0.054 mg/kg-dry ND Benzene MA-VPH 0.04 07/25/14 21:06 / pbf 0.054 mg/kg-dry ND Toluene MA-VPH 10 07/25/14 21:06 / pbf 0.054 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/25/14 21:06 / pbf 0.054 mg/kg-dry ND m+p-Xylenes MA-VPH 07/25/14 21:06 / pbf 0.054 mg/kg-dry ND o-Xylene MA-VPH 07/25/14 21:06 / pbf 0.054 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/25/14 21:06 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/25/14 21:06 / pbf 2.2 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/25/14 21:06 / pbf 2.2 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/25/14 21:06 / pbf 2.2 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/25/14 21:06 / pbf 2.2 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/25/14 21:06 / pbf 70-130 %REC 102 Surr: VPH Aromatics Surrogate MA-VPH 07/25/14 21:06 / pbf 70-130 %REC 97.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. Page 12 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-004 Client Sample ID: B2 10-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN *07/27/14 09:15 / amn 216 mg/kg-dry 564 Total Extractable Hydrocarbons SW8015M 200 07/27/14 09:15 / amn 40-140 %REC 91.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. EXTRACTABLE PETROLEUM HYDROCARBONS 08/02/14 17:29 / tmc 11 mg/kg-dry ND C9 to C18 Aliphatics MA-EPH 200 08/02/14 17:29 / tmc 11 mg/kg-dry 58 C19 to C36 Aliphatics MA-EPH 20000 08/02/14 17:29 / tmc 40-140 %REC 104 Surr: 1-Chloro-octadecane MA-EPH 08/05/14 12:18 / tmc 11 mg/kg-dry 41 C11 to C22 Aromatics MA-EPH 400 08/05/14 12:18 / tmc 11 mg/kg-dry 239 Total Extractable Hydrocarbons MA-EPH 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Naphthalene MA-EPH 4 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND 2-MethylNaphthalene MA-EPH 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Acenaphthylene MA-EPH 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Acenaphthene MA-EPH 200 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Fluorene MA-EPH 300 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Phenanthrene MA-EPH 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Anthracene MA-EPH 2000 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Fluoranthene MA-EPH 300 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Pyrene MA-EPH 200 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Benzo(a)Anthracene MA-EPH 0.2 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Chrysene MA-EPH 20 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Benzo(b)Fluoranthene/Benzo(k)Fluoranthene MA-EPH 0.2 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Benzo(a)Pyrene MA-EPH 0.02 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Dibenz(a,h)anthracene/Indeno(1,2,3-cd)pyrene MA-EPH 0.02 08/05/14 12:18 / tmc 0.18 mg/kg-dry ND Benzo(g,h,I)perylene MA-EPH 08/05/14 12:18 / tmc 40-140 %REC 91.0 Surr: 2-Bromonaphthalene MA-EPH 08/05/14 12:18 / tmc 40-140 %REC 89.0 Surr: 2-Fluorobiphenyl MA-EPH 08/05/14 12:18 / tmc 40-140 %REC 93.0 Surr: o-Terphenyl MA-EPH - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. Page 13 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-005 Client Sample ID: B3 7-8 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:14 / amn 0.2 wt% 18 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 13:12 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 14 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-005 Client Sample ID: B3 7-8 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 13:12 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 13:12 / nl 78-160 %REC 95.0 Surr: p-Bromofluorobenzene SW8260B 07/24/14 13:12 / nl 70-132 %REC 93.0 Surr: Dibromofluoromethane SW8260B 07/24/14 13:12 / nl 60-136 %REC 86.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 13:12 / nl 75-138 %REC 91.0 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/28/14 14:00 / pbf 0.12 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/28/14 14:00 / pbf 0.061 mg/kg-dry ND Benzene MA-VPH 0.04 07/28/14 14:00 / pbf 0.061 mg/kg-dry ND Toluene MA-VPH 10 07/28/14 14:00 / pbf 0.061 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/28/14 14:00 / pbf 0.061 mg/kg-dry ND m+p-Xylenes MA-VPH 07/28/14 14:00 / pbf 0.061 mg/kg-dry ND o-Xylene MA-VPH 07/28/14 14:00 / pbf 0.061 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/28/14 14:00 / pbf 0.12 mg/kg-dry ND Naphthalene MA-VPH 4 07/28/14 14:00 / pbf 2.5 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/28/14 14:00 / pbf 2.5 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/28/14 14:00 / pbf 2.5 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/28/14 14:00 / pbf 2.5 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/28/14 14:00 / pbf 70-130 %REC 92.0 Surr: VPH Aromatics Surrogate MA-VPH 07/28/14 14:00 / pbf 70-130 %REC 92.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 07/26/14 02:06 / amn 12 mg/kg-dry 26 Total Extractable Hydrocarbons SW8015M 200 07/26/14 02:06 / amn 40-140 %REC 92.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 15 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-006 Client Sample ID: B4 9-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:16 / amn 0.2 wt% 9.4 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 13:42 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 16 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-006 Client Sample ID: B4 9-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 13:42 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 13:42 / nl 78-160 %REC 102 Surr: p-Bromofluorobenzene SW8260B 07/24/14 13:42 / nl 70-132 %REC 101 Surr: Dibromofluoromethane SW8260B 07/24/14 13:42 / nl 60-136 %REC 96.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 13:42 / nl 75-138 %REC 106 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/28/14 15:09 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/28/14 15:09 / pbf 0.055 mg/kg-dry ND Benzene MA-VPH 0.04 07/28/14 15:09 / pbf 0.055 mg/kg-dry ND Toluene MA-VPH 10 07/28/14 15:09 / pbf 0.055 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/28/14 15:09 / pbf 0.055 mg/kg-dry ND m+p-Xylenes MA-VPH 07/28/14 15:09 / pbf 0.055 mg/kg-dry ND o-Xylene MA-VPH 07/28/14 15:09 / pbf 0.055 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/28/14 15:09 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/28/14 15:09 / pbf 2.2 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/28/14 15:09 / pbf 2.2 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/28/14 15:09 / pbf 2.2 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/28/14 15:09 / pbf 2.2 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/28/14 15:09 / pbf 70-130 %REC 102 Surr: VPH Aromatics Surrogate MA-VPH 07/28/14 15:09 / pbf 70-130 %REC 97.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 07/26/14 05:56 / amn 33 mg/kg-dry 107 Total Extractable Hydrocarbons SW8015M 200 07/26/14 05:56 / amn 40-140 %REC 93.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 17 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-007 Client Sample ID: B5 5-7 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:19 / amn 0.2 wt% 6.5 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 14:11 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 18 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-007 Client Sample ID: B5 5-7 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 14:11 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 14:11 / nl 78-160 %REC 96.0 Surr: p-Bromofluorobenzene SW8260B 07/24/14 14:11 / nl 70-132 %REC 95.0 Surr: Dibromofluoromethane SW8260B 07/24/14 14:11 / nl 60-136 %REC 87.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 14:11 / nl 75-138 %REC 98.0 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/28/14 16:19 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/28/14 16:19 / pbf 0.053 mg/kg-dry ND Benzene MA-VPH 0.04 07/28/14 16:19 / pbf 0.053 mg/kg-dry ND Toluene MA-VPH 10 07/28/14 16:19 / pbf 0.053 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/28/14 16:19 / pbf 0.053 mg/kg-dry ND m+p-Xylenes MA-VPH 07/28/14 16:19 / pbf 0.053 mg/kg-dry ND o-Xylene MA-VPH 07/28/14 16:19 / pbf 0.053 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/28/14 16:19 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/28/14 16:19 / pbf 2.1 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/28/14 16:19 / pbf 2.1 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/28/14 16:19 / pbf 2.1 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/28/14 16:19 / pbf 2.1 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/28/14 16:19 / pbf 70-130 %REC 102 Surr: VPH Aromatics Surrogate MA-VPH 07/28/14 16:19 / pbf 70-130 %REC 97.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 07/26/14 00:35 / amn 11 mg/kg-dry ND Total Extractable Hydrocarbons SW8015M 200 07/26/14 00:35 / amn 40-140 %REC 96.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 19 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-008 Client Sample ID: B6 7-10 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:21 / amn 0.2 wt% 5.1 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 14:41 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 20 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-008 Client Sample ID: B6 7-10 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 14:41 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 14:41 / nl 78-160 %REC 96.0 Surr: p-Bromofluorobenzene SW8260B 07/24/14 14:41 / nl 70-132 %REC 94.0 Surr: Dibromofluoromethane SW8260B 07/24/14 14:41 / nl 60-136 %REC 91.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 14:41 / nl 75-138 %REC 99.0 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/28/14 17:29 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/28/14 17:29 / pbf 0.053 mg/kg-dry ND Benzene MA-VPH 0.04 07/28/14 17:29 / pbf 0.053 mg/kg-dry ND Toluene MA-VPH 10 07/28/14 17:29 / pbf 0.053 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/28/14 17:29 / pbf 0.053 mg/kg-dry ND m+p-Xylenes MA-VPH 07/28/14 17:29 / pbf 0.053 mg/kg-dry ND o-Xylene MA-VPH 07/28/14 17:29 / pbf 0.053 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/28/14 17:29 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/28/14 17:29 / pbf 2.1 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/28/14 17:29 / pbf 2.1 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/28/14 17:29 / pbf 2.1 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/28/14 17:29 / pbf 2.1 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/28/14 17:29 / pbf 70-130 %REC 104 Surr: VPH Aromatics Surrogate MA-VPH 07/28/14 17:29 / pbf 70-130 %REC 100 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 07/26/14 03:38 / amn 11 mg/kg-dry ND Total Extractable Hydrocarbons SW8015M 200 07/26/14 03:38 / amn 40-140 %REC 97.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 21 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-009 Client Sample ID: B7 8-10 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:23 / amn 0.2 wt% 4.9 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 15:10 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 22 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-009 Client Sample ID: B7 8-10 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 15:10 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 15:10 / nl 78-160 %REC 97.0 Surr: p-Bromofluorobenzene SW8260B 07/24/14 15:10 / nl 70-132 %REC 96.0 Surr: Dibromofluoromethane SW8260B 07/24/14 15:10 / nl 60-136 %REC 90.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 15:10 / nl 75-138 %REC 100 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/28/14 19:13 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/28/14 19:13 / pbf 0.053 mg/kg-dry ND Benzene MA-VPH 0.04 07/28/14 19:13 / pbf 0.053 mg/kg-dry ND Toluene MA-VPH 10 07/28/14 19:13 / pbf 0.053 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/28/14 19:13 / pbf 0.053 mg/kg-dry ND m+p-Xylenes MA-VPH 07/28/14 19:13 / pbf 0.053 mg/kg-dry ND o-Xylene MA-VPH 07/28/14 19:13 / pbf 0.053 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/28/14 19:13 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/28/14 19:13 / pbf 2.1 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/28/14 19:13 / pbf 2.1 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/28/14 19:13 / pbf 2.1 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/28/14 19:13 / pbf 2.1 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/28/14 19:13 / pbf 70-130 %REC 99.0 Surr: VPH Aromatics Surrogate MA-VPH 07/28/14 19:13 / pbf 70-130 %REC 95.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 07/26/14 05:10 / amn 32 mg/kg-dry 62 Total Extractable Hydrocarbons SW8015M 200 07/26/14 05:10 / amn 40-140 %REC 100 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 23 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-010 Client Sample ID: B8 9-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:26 / amn 0.2 wt% 9.0 Moisture SW3550A METALS, TOTAL - EPA SW846 08/02/14 04:41 / rlh 5mg/kg-dry ND Arsenic SW6010B 08/02/14 04:41 / rlh 5mg/kg-dry 95 Barium SW6010B 08/02/14 04:41 / rlh 1mg/kg-dry ND Cadmium SW6010B 08/02/14 04:41 / rlh 5mg/kg-dry 25 Chromium SW6010B 08/02/14 04:41 / rlh 5mg/kg-dry 7Lead SW6010B 08/05/14 12:59 / eac 1mg/kg-dry ND Mercury SW7471B 08/02/14 04:41 / rlh 5mg/kg-dry ND Selenium SW6010B 08/02/14 04:41 / rlh 5mg/kg-dry ND Silver SW6010B VOLATILE ORGANIC COMPOUNDS 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 24 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-010 Client Sample ID: B8 9-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 15:40 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 15:40 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 15:40 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 15:40 / nl 78-160 %REC 102 Surr: p-Bromofluorobenzene SW8260B 07/24/14 15:40 / nl 70-132 %REC 96.0 Surr: Dibromofluoromethane SW8260B 07/24/14 15:40 / nl 60-136 %REC 93.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 15:40 / nl 75-138 %REC 104 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/28/14 20:57 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/28/14 20:57 / pbf 0.055 mg/kg-dry ND Benzene MA-VPH 0.04 07/28/14 20:57 / pbf 0.055 mg/kg-dry ND Toluene MA-VPH 10 07/28/14 20:57 / pbf 0.055 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/28/14 20:57 / pbf 0.055 mg/kg-dry ND m+p-Xylenes MA-VPH 07/28/14 20:57 / pbf 0.055 mg/kg-dry ND o-Xylene MA-VPH 07/28/14 20:57 / pbf 0.055 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/28/14 20:57 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/28/14 20:57 / pbf 2.2 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/28/14 20:57 / pbf 2.2 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/28/14 20:57 / pbf 2.2 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/28/14 20:57 / pbf 2.2 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/28/14 20:57 / pbf 70-130 %REC 99.0 Surr: VPH Aromatics Surrogate MA-VPH 07/28/14 20:57 / pbf 70-130 %REC 95.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. Page 25 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-010 Client Sample ID: B8 9-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN *07/27/14 16:51 / amn 220 mg/kg-dry 643 Total Extractable Hydrocarbons SW8015M 200 07/27/14 16:51 / amn 40-140 %REC 46.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. EXTRACTABLE PETROLEUM HYDROCARBONS 08/02/14 19:00 / tmc 11 mg/kg-dry ND C9 to C18 Aliphatics MA-EPH 200 08/02/14 19:00 / tmc 11 mg/kg-dry 68 C19 to C36 Aliphatics MA-EPH 20000 08/02/14 19:00 / tmc 40-140 %REC 46.0 Surr: 1-Chloro-octadecane MA-EPH 08/05/14 14:12 / tmc 11 mg/kg-dry 85 C11 to C22 Aromatics MA-EPH 400 08/05/14 14:12 / tmc 11 mg/kg-dry 562 Total Extractable Hydrocarbons MA-EPH 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Naphthalene MA-EPH 4 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND 2-MethylNaphthalene MA-EPH 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Acenaphthylene MA-EPH 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Acenaphthene MA-EPH 200 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Fluorene MA-EPH 300 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Phenanthrene MA-EPH 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Anthracene MA-EPH 2000 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Fluoranthene MA-EPH 300 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Pyrene MA-EPH 200 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Benzo(a)Anthracene MA-EPH 0.2 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Chrysene MA-EPH 20 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Benzo(b)Fluoranthene/Benzo(k)Fluoranthene MA-EPH 0.2 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Benzo(a)Pyrene MA-EPH 0.02 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Dibenz(a,h)anthracene/Indeno(1,2,3-cd)pyrene MA-EPH 0.02 08/05/14 14:12 / tmc 0.18 mg/kg-dry ND Benzo(g,h,I)perylene MA-EPH 08/05/14 14:12 / tmc 40-140 %REC 125 Surr: 2-Bromonaphthalene MA-EPH 08/05/14 14:12 / tmc 40-140 %REC 117 Surr: 2-Fluorobiphenyl MA-EPH 08/05/14 14:12 / tmc 40-140 %REC 58.0 Surr: o-Terphenyl MA-EPH - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. Page 26 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-011 Client Sample ID: B9 5-7 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:29 / amn 0.2 wt% 9.1 Moisture SW3550A METALS, TOTAL - EPA SW846 08/02/14 04:44 / rlh 5mg/kg-dry ND Arsenic SW6010B 08/02/14 04:44 / rlh 5mg/kg-dry 159 Barium SW6010B 08/02/14 04:44 / rlh 1mg/kg-dry ND Cadmium SW6010B 08/02/14 04:44 / rlh 5mg/kg-dry 34 Chromium SW6010B 08/02/14 04:44 / rlh 5mg/kg-dry 15 Lead SW6010B 08/05/14 13:01 / eac 1mg/kg-dry ND Mercury SW7471B 08/02/14 04:44 / rlh 5mg/kg-dry ND Selenium SW6010B 08/02/14 04:44 / rlh 5mg/kg-dry ND Silver SW6010B VOLATILE ORGANIC COMPOUNDS 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 27 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-011 Client Sample ID: B9 5-7 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 16:09 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 16:09 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B J 07/24/14 16:09 / nl 0.20 mg/kg-dry 0.076 m+p-Xylenes SW8260B 07/24/14 16:09 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B J 07/24/14 16:09 / nl 0.20 mg/kg-dry 0.076 Xylenes, Total SW8260B 07/24/14 16:09 / nl 78-160 %REC 100 Surr: p-Bromofluorobenzene SW8260B 07/24/14 16:09 / nl 70-132 %REC 91.0 Surr: Dibromofluoromethane SW8260B 07/24/14 16:09 / nl 60-136 %REC 90.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 16:09 / nl 75-138 %REC 91.0 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/28/14 22:41 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/28/14 22:41 / pbf 0.055 mg/kg-dry ND Benzene MA-VPH 0.04 07/28/14 22:41 / pbf 0.055 mg/kg-dry ND Toluene MA-VPH 10 07/28/14 22:41 / pbf 0.055 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/28/14 22:41 / pbf 0.055 mg/kg-dry 0.16 m+p-Xylenes MA-VPH J 07/28/14 22:41 / pbf 0.055 mg/kg-dry 0.054 o-Xylene MA-VPH 07/28/14 22:41 / pbf 0.055 mg/kg-dry 0.21 Xylenes, Total MA-VPH 70 07/28/14 22:41 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/28/14 22:41 / pbf 2.2 mg/kg-dry 6.8 C9 to C10 Aromatics MA-VPH 100 07/28/14 22:41 / pbf 2.2 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/28/14 22:41 / pbf 2.2 mg/kg-dry 4.9 C9 to C12 Aliphatics MA-VPH 100 07/28/14 22:41 / pbf 2.2 mg/kg-dry 21 Total Purgeable Hydrocarbons MA-VPH 100 07/28/14 22:41 / pbf 70-130 %REC 93.0 Surr: VPH Aromatics Surrogate MA-VPH 07/28/14 22:41 / pbf 70-130 %REC 92.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. J - Estimated value. The analyte was present but less than the reporting limit. Page 28 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-011 Client Sample ID: B9 5-7 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN *07/27/14 14:34 / amn 220 mg/kg-dry 1790 Total Extractable Hydrocarbons SW8015M 200 07/27/14 14:34 / amn 40-140 %REC 95.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. EXTRACTABLE PETROLEUM HYDROCARBONS 08/05/14 07:24 / tmc 33 mg/kg-dry 104 C9 to C18 Aliphatics MA-EPH 200 08/05/14 07:24 / tmc 33 mg/kg-dry 371 C19 to C36 Aliphatics MA-EPH 20000 08/05/14 07:24 / tmc 40-140 %REC 80.0 Surr: 1-Chloro-octadecane MA-EPH *08/05/14 15:08 / tmc 11 mg/kg-dry 618 C11 to C22 Aromatics MA-EPH 400 08/05/14 15:08 / tmc 11 mg/kg-dry 1800 Total Extractable Hydrocarbons MA-EPH 08/05/14 15:08 / tmc 0.18 mg/kg-dry ND Naphthalene MA-EPH 4 J 08/05/14 15:08 / tmc 0.18 mg/kg-dry 0.17 2-MethylNaphthalene MA-EPH 08/05/14 15:08 / tmc 0.18 mg/kg-dry 0.48 Acenaphthylene MA-EPH 08/05/14 15:08 / tmc 0.18 mg/kg-dry ND Acenaphthene MA-EPH 200 08/05/14 15:08 / tmc 0.18 mg/kg-dry 0.62 Fluorene MA-EPH 300 08/05/14 15:08 / tmc 0.18 mg/kg-dry 0.28 Phenanthrene MA-EPH 08/05/14 15:08 / tmc 0.18 mg/kg-dry ND Anthracene MA-EPH 2000 08/05/14 15:08 / tmc 0.18 mg/kg-dry 0.68 Fluoranthene MA-EPH 300 08/05/14 15:08 / tmc 0.18 mg/kg-dry 1.1 Pyrene MA-EPH 200 08/05/14 15:08 / tmc 0.18 mg/kg-dry ND Benzo(a)Anthracene MA-EPH 0.2 08/05/14 15:08 / tmc 0.18 mg/kg-dry 0.66 Chrysene MA-EPH 20 08/05/14 15:08 / tmc 0.18 mg/kg-dry ND Benzo(b)Fluoranthene/Benzo(k)Fluoranthene MA-EPH 0.2 08/05/14 15:08 / tmc 0.18 mg/kg-dry ND Benzo(a)Pyrene MA-EPH 0.02 08/05/14 15:08 / tmc 0.18 mg/kg-dry ND Dibenz(a,h)anthracene/Indeno(1,2,3-cd)pyrene MA-EPH 0.02 08/05/14 15:08 / tmc 0.18 mg/kg-dry ND Benzo(g,h,I)perylene MA-EPH 08/05/14 15:08 / tmc 40-140 %REC 109 Surr: 2-Bromonaphthalene MA-EPH 08/05/14 15:08 / tmc 40-140 %REC 90.0 Surr: 2-Fluorobiphenyl MA-EPH 08/05/14 15:08 / tmc 40-140 %REC 85.0 Surr: o-Terphenyl MA-EPH - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. - Note: Quantitation of individual PAHs by GC/FID analyses may be subject to a positive bias due to co-elution of similar hydrocarbons. - *=The reported value exceeds the Maximum Contaminant Limit (MCL). The MCLs listed for target analyte and hydrocarbon range values are the most conservative Montana DEQ RBSLs. These limits may not apply to your samples. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. J - Estimated value. The analyte was present but less than the reporting limit. Page 29 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-012 Client Sample ID: B9 8-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:31 / amn 0.2 wt% 6.7 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 16:39 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 30 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-012 Client Sample ID: B9 8-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 16:39 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 16:39 / nl 78-160 %REC 105 Surr: p-Bromofluorobenzene SW8260B 07/24/14 16:39 / nl 70-132 %REC 96.0 Surr: Dibromofluoromethane SW8260B 07/24/14 16:39 / nl 60-136 %REC 92.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 16:39 / nl 75-138 %REC 105 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/29/14 00:25 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/29/14 00:25 / pbf 0.054 mg/kg-dry ND Benzene MA-VPH 0.04 07/29/14 00:25 / pbf 0.054 mg/kg-dry ND Toluene MA-VPH 10 07/29/14 00:25 / pbf 0.054 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/29/14 00:25 / pbf 0.054 mg/kg-dry 0.23 m+p-Xylenes MA-VPH 07/29/14 00:25 / pbf 0.054 mg/kg-dry 0.067 o-Xylene MA-VPH 07/29/14 00:25 / pbf 0.054 mg/kg-dry 0.29 Xylenes, Total MA-VPH 70 07/29/14 00:25 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/29/14 00:25 / pbf 2.1 mg/kg-dry 6.1 C9 to C10 Aromatics MA-VPH 100 07/29/14 00:25 / pbf 2.1 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/29/14 00:25 / pbf 2.1 mg/kg-dry 4.2 C9 to C12 Aliphatics MA-VPH 100 07/29/14 00:25 / pbf 2.1 mg/kg-dry 16 Total Purgeable Hydrocarbons MA-VPH 100 07/29/14 00:25 / pbf 70-130 %REC 96.0 Surr: VPH Aromatics Surrogate MA-VPH 07/29/14 00:25 / pbf 70-130 %REC 95.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN *07/27/14 15:20 / amn 214 mg/kg-dry 725 Total Extractable Hydrocarbons SW8015M 200 07/27/14 15:20 / amn 40-140 %REC 95.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. EXTRACTABLE PETROLEUM HYDROCARBONS 08/02/14 23:31 / tmc 11 mg/kg-dry ND C9 to C18 Aliphatics MA-EPH 200 08/02/14 23:31 / tmc 11 mg/kg-dry 75 C19 to C36 Aliphatics MA-EPH 20000 08/02/14 23:31 / tmc 40-140 %REC 93.0 Surr: 1-Chloro-octadecane MA-EPH 08/05/14 13:15 / tmc 11 mg/kg-dry 59 C11 to C22 Aromatics MA-EPH 400 08/05/14 13:15 / tmc 11 mg/kg-dry 407 Total Extractable Hydrocarbons MA-EPH Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. * - The result exceeds the MCL. Page 31 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-012 Client Sample ID: B9 8-11 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Naphthalene MA-EPH 4 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND 2-MethylNaphthalene MA-EPH 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Acenaphthylene MA-EPH 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Acenaphthene MA-EPH 200 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Fluorene MA-EPH 300 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Phenanthrene MA-EPH 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Anthracene MA-EPH 2000 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Fluoranthene MA-EPH 300 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Pyrene MA-EPH 200 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Benzo(a)Anthracene MA-EPH 0.2 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Chrysene MA-EPH 20 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Benzo(b)Fluoranthene/Benzo(k)Fluoranthene MA-EPH 0.2 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Benzo(a)Pyrene MA-EPH 0.02 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Dibenz(a,h)anthracene/Indeno(1,2,3-cd)pyrene MA-EPH 0.02 08/05/14 13:15 / tmc 0.18 mg/kg-dry ND Benzo(g,h,I)perylene MA-EPH 08/05/14 13:15 / tmc 40-140 %REC 94.0 Surr: 2-Bromonaphthalene MA-EPH 08/05/14 13:15 / tmc 40-140 %REC 92.0 Surr: 2-Fluorobiphenyl MA-EPH 08/05/14 13:15 / tmc 40-140 %REC 94.0 Surr: o-Terphenyl MA-EPH - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. - Note: Quantitation of individual PAHs by GC/FID analyses may be subject to a positive bias due to co-elution of similar hydrocarbons. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 32 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-013 Client Sample ID: B10 7-8 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/23/14 13:34 / amn 0.2 wt% 10 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Benzene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Bromobenzene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Bromochloromethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Bromodichloromethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Bromoform SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Bromomethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Carbon tetrachloride SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Chlorobenzene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Chloroethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Chloroform SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Chloromethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 2-Chlorotoluene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 4-Chlorotoluene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Chlorodibromomethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,2-Dibromoethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Dibromomethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,2-Dichlorobenzene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,3-Dichlorobenzene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,4-Dichlorobenzene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Dichlorodifluoromethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,2-Dichloroethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND cis-1,2-Dichloroethene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,1-Dichloroethene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND trans-1,2-Dichloroethene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,2-Dichloropropane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,3-Dichloropropane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 2,2-Dichloropropane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,1-Dichloropropene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND cis-1,3-Dichloropropene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND trans-1,3-Dichloropropene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Ethylbenzene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Methylene chloride SW8260B 07/24/14 17:08 / nl 4.0 mg/kg-dry ND Methyl ethyl ketone SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Styrene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 33 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-013 Client Sample ID: B10 7-8 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Toluene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,1,1-Trichloroethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,1,2-Trichloroethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Trichloroethene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Trichlorofluoromethane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND 1,2,3-Trichloropropane SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Vinyl chloride SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND m+p-Xylenes SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND o-Xylene SW8260B 07/24/14 17:08 / nl 0.20 mg/kg-dry ND Xylenes, Total SW8260B 07/24/14 17:08 / nl 78-160 %REC 102 Surr: p-Bromofluorobenzene SW8260B 07/24/14 17:08 / nl 70-132 %REC 94.0 Surr: Dibromofluoromethane SW8260B 07/24/14 17:08 / nl 60-136 %REC 93.0 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 17:08 / nl 75-138 %REC 101 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/29/14 02:08 / pbf 0.11 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/29/14 02:08 / pbf 0.056 mg/kg-dry ND Benzene MA-VPH 0.04 07/29/14 02:08 / pbf 0.056 mg/kg-dry ND Toluene MA-VPH 10 07/29/14 02:08 / pbf 0.056 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/29/14 02:08 / pbf 0.056 mg/kg-dry ND m+p-Xylenes MA-VPH 07/29/14 02:08 / pbf 0.056 mg/kg-dry ND o-Xylene MA-VPH 07/29/14 02:08 / pbf 0.056 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/29/14 02:08 / pbf 0.11 mg/kg-dry ND Naphthalene MA-VPH 4 07/29/14 02:08 / pbf 2.2 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/29/14 02:08 / pbf 2.2 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/29/14 02:08 / pbf 2.2 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/29/14 02:08 / pbf 2.2 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/29/14 02:08 / pbf 70-130 %REC 92.0 Surr: VPH Aromatics Surrogate MA-VPH 07/29/14 02:08 / pbf 70-130 %REC 89.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 07/25/14 23:50 / amn 11 mg/kg-dry ND Total Extractable Hydrocarbons SW8015M 200 07/25/14 23:50 / amn 40-140 %REC 97.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 34 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-014 Client Sample ID: B8 3-4 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers PHYSICAL CHARACTERISTICS 07/25/14 10:08 / amn 0.2 wt% 22 Moisture SW3550A VOLATILE ORGANIC COMPOUNDS 07/24/14 17:38 / nl 0.20 mg/kg ND Benzene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Bromobenzene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Bromochloromethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Bromodichloromethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Bromoform SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Bromomethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Carbon tetrachloride SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Chlorobenzene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Chloroethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 2-Chloroethyl vinyl ether SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Chloroform SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Chloromethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 2-Chlorotoluene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 4-Chlorotoluene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Chlorodibromomethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,2-Dibromoethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Dibromomethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,2-Dichlorobenzene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,3-Dichlorobenzene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,4-Dichlorobenzene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Dichlorodifluoromethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,1-Dichloroethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,2-Dichloroethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND cis-1,2-Dichloroethene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,1-Dichloroethene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND trans-1,2-Dichloroethene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,2-Dichloropropane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,3-Dichloropropane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 2,2-Dichloropropane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,1-Dichloropropene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND cis-1,3-Dichloropropene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND trans-1,3-Dichloropropene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Ethylbenzene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Methyl tert-butyl ether (MTBE) SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Methylene chloride SW8260B 07/24/14 17:38 / nl 4.0 mg/kg ND Methyl ethyl ketone SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Styrene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,1,1,2-Tetrachloroethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,1,2,2-Tetrachloroethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Tetrachloroethene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 35 of 117 LABORATORY ANALYTICAL REPORT Client: MT DEQ-Lust Project: Bozeman Mount Yard Lab ID: B14072051-014 Client Sample ID: B8 3-4 Collection Date: 07/21/14 Matrix: Soil Report Date: 08/08/14 DateReceived: 07/23/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 07/24/14 17:38 / nl 0.20 mg/kg ND Toluene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,1,1-Trichloroethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,1,2-Trichloroethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Trichloroethene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Trichlorofluoromethane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND 1,2,3-Trichloropropane SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Vinyl chloride SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND m+p-Xylenes SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND o-Xylene SW8260B 07/24/14 17:38 / nl 0.20 mg/kg ND Xylenes, Total SW8260B 07/24/14 17:38 / nl 78-160 %REC 118 Surr: p-Bromofluorobenzene SW8260B 07/24/14 17:38 / nl 70-132 %REC 109 Surr: Dibromofluoromethane SW8260B 07/24/14 17:38 / nl 60-136 %REC 102 Surr: 1,2-Dichloroethane-d4 SW8260B 07/24/14 17:38 / nl 75-138 %REC 115 Surr: Toluene-d8 SW8260B PETROLEUM HYDROCARBONS-VOLATILE 07/29/14 03:51 / pbf 0.13 mg/kg-dry ND Methyl tert-butyl ether (MTBE) MA-VPH 0.08 07/29/14 03:51 / pbf 0.064 mg/kg-dry ND Benzene MA-VPH 0.04 07/29/14 03:51 / pbf 0.064 mg/kg-dry ND Toluene MA-VPH 10 07/29/14 03:51 / pbf 0.064 mg/kg-dry ND Ethylbenzene MA-VPH 6 07/29/14 03:51 / pbf 0.064 mg/kg-dry ND m+p-Xylenes MA-VPH 07/29/14 03:51 / pbf 0.064 mg/kg-dry ND o-Xylene MA-VPH 07/29/14 03:51 / pbf 0.064 mg/kg-dry ND Xylenes, Total MA-VPH 70 07/29/14 03:51 / pbf 0.13 mg/kg-dry ND Naphthalene MA-VPH 4 07/29/14 03:51 / pbf 2.6 mg/kg-dry ND C9 to C10 Aromatics MA-VPH 100 07/29/14 03:51 / pbf 2.6 mg/kg-dry ND C5 to C8 Aliphatics MA-VPH 60 07/29/14 03:51 / pbf 2.6 mg/kg-dry ND C9 to C12 Aliphatics MA-VPH 100 07/29/14 03:51 / pbf 2.6 mg/kg-dry ND Total Purgeable Hydrocarbons MA-VPH 100 07/29/14 03:51 / pbf 70-130 %REC 88.0 Surr: VPH Aromatics Surrogate MA-VPH 07/29/14 03:51 / pbf 70-130 %REC 83.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 07/27/14 00:03 / amn 13 mg/kg-dry ND Total Extractable Hydrocarbons SW8015M 200 07/27/14 00:03 / amn 40-140 %REC 76.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 36 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/05/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW6010B Analytical Run: ICP203-B_140801A Lab ID: QCS 08/01/14 11:28 Initial Calibration Verification Standard 7 Arsenic 102 90 110 0.10 0.820 mg/L Barium 102 90 110 0.10 0.815 mg/L Cadmium 100 90 110 0.010 0.400 mg/L Chromium 99 90 110 0.050 0.796 mg/L Lead 102 90 110 0.050 0.814 mg/L Selenium 98 90 110 0.10 0.785 mg/L Silver 98 90 110 0.010 0.391 mg/L Lab ID: ICSA 08/01/14 11:32 Interference Check Sample A 7 Arsenic 0.10 0.00379 mg/L Barium 0.10 0.000480 mg/L Cadmium 0.010 2.00E-05 mg/L Chromium 0.050 -0.00201 mg/L Lead 0.050 0.0303 mg/L Selenium 0.10 -0.0566 mg/L Silver 0.010 0.000140 mg/L Lab ID: ICSAB 08/01/14 11:35 Interference Check Sample AB 7 Arsenic 96 80 120 0.10 0.963 mg/L Barium 96 80 120 0.10 0.481 mg/L Cadmium 89 80 120 0.010 0.888 mg/L Chromium 91 80 120 0.050 0.453 mg/L Lead 93 80 120 0.050 0.934 mg/L Selenium 88 80 120 0.10 0.882 mg/L Silver 97 80 120 0.010 0.975 mg/L Method: SW6010B Batch: 81815 Lab ID: MB-81815 08/02/14 04:21 Method Blank Run: ICP203-B_140801A 7 Arsenic 0.6 ND mg/kg Barium 0.05 ND mg/kg Cadmium 0.03 ND mg/kg Chromium 0.3 ND mg/kg Lead 2ND mg/kg Selenium 2ND mg/kg Silver 0.3 ND mg/kg Lab ID: LCS-81815 08/02/14 04:24 Laboratory Control Sample Run: ICP203-B_140801A 7 Arsenic 104 80 120 5.0 51.8 mg/kg Barium 108 80 120 5.0 54.1 mg/kg Cadmium 98 80 120 5.0 24.6 mg/kg Chromium 103 80 120 5.0 51.7 mg/kg Lead 102 80 120 5.0 51.2 mg/kg Selenium 100 80 120 5.0 49.9 mg/kg Silver 99 80 120 5.0 24.7 mg/kg Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 37 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/05/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW6010B Batch: 81815 Lab ID: SRM-81815 08/02/14 04:28 Standard Reference Material Run: ICP203-B_140801A 7 Arsenic 84 72 120 5.0 287 mg/kg Barium 93 80 120 5.0 573 mg/kg Cadmium 86 73 120 5.0 118 mg/kg Chromium 86 72 120 5.0 65.4 mg/kg Lead 92 75 120 5.0 172 mg/kg Selenium 88 72 120 5.0 173 mg/kg Silver 87 67 120 5.0 60.1 mg/kg Lab ID: B14072483-006ADIL 08/02/14 05:25 Serial Dilution Run: ICP203-B_140801A 7 Arsenic 0 0 10 6.3 ND mg/kg Barium 0 0 10 1.0 0.7 206 mg/kg Cadmium 0 0 10 1.0 0.420 mg/kg N Chromium 0 0 10 2.8 10.4 mg/kg N Lead 0 0 10 13 17.7 mg/kg N Selenium 0 0 10 13 ND mg/kg Silver 0 0 10 2.7 ND mg/kg Lab ID: B14072483-006APDS 08/02/14 05:28 Post Digestion/Distillation Spike Run: ICP203-B_140801A 7 Arsenic 106 75 125 1.0 94.1 mg/kg Barium 93 75 125 1.0 284 mg/kg Cadmium 92 75 125 1.0 39.4 mg/kg Chromium 95 75 125 1.0 91.4 mg/kg Lead 94 75 125 2.6 97.4 mg/kg Selenium 93 75 125 2.6 79.1 mg/kg Silver 94 75 125 1.0 40.3 mg/kg Lab ID: B14072483-006AMS3 08/02/14 05:32 Sample Matrix Spike Run: ICP203-B_140801A 7 Arsenic 103 75 125 1.0 82.4 mg/kg Barium 180 75 125 1.0 342 mg/kg S Cadmium 92 75 125 1.0 35.2 mg/kg Chromium 110 75 125 1.0 94.2 mg/kg Lead 95 75 125 2.4 88.9 mg/kg Selenium 88 75 125 2.4 66.9 mg/kg Silver 95 75 125 1.0 36.3 mg/kg Lab ID: B14072483-006AMSD 08/02/14 05:35 Sample Matrix Spike Duplicate Run: ICP203-B_140801A 7 Arsenic 103 75 125 20 1.0 0.6 81.9 mg/kg Barium 177 75 125 20 1.0 1.1 338 mg/kg S Cadmium 92 75 125 20 1.0 0.7 35.0 mg/kg Chromium 110 75 125 20 1.0 0.6 93.6 mg/kg Lead 92 75 125 20 2.3 2.8 86.4 mg/kg Selenium 89 75 125 20 2.3 1.0 67.6 mg/kg Silver 94 75 125 20 1.0 2.5 35.4 mg/kg Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. N - The analyte concentration was not sufficiently high to calculate a RPD for the serial dilution test. S - Spike recovery outside of advisory limits. Page 38 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/05/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW7471B Analytical Run: HGCV202-B_140805A Lab ID: QCS 08/05/14 12:45 Initial Calibration Verification Standard Mercury 102 90 110 1.0 0.00204 mg/kg Method: SW7471B Batch: 81908 Lab ID: MB-81908 08/05/14 12:50 Method Blank Run: HGCV202-B_140805A Mercury 0.002 0.002 mg/kg Lab ID: SRM-81908 08/05/14 12:52 Standard Reference Material Run: HGCV202-B_140805A Mercury 81 71 127 1.0 4.06 mg/kg Lab ID: LFB-81908 08/05/14 12:54 Laboratory Fortified Blank Run: HGCV202-B_140805A Mercury 104 80 120 1.0 0.211 mg/kg Lab ID: B14072051-004ADIL 08/05/14 12:57 Serial Dilution Run: HGCV202-B_140805A Mercury 0 0 10 1.0 ND mg/kg-dry Lab ID: B14072483-006AMS 08/05/14 13:20 Sample Matrix Spike Run: HGCV202-B_140805A Mercury 95 75 125 1.0 0.255 mg/kg Lab ID: B14072483-006AMSD 08/05/14 13:21 Sample Matrix Spike Duplicate Run: HGCV202-B_140805A Mercury 93 75 125 20 1.0 0.237 mg/kg Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 39 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW8260B Batch: 81606 Lab ID: LCS-81606 07/23/14 11:06 Laboratory Control Sample Run: 5971A.I_140723A 53 Benzene 102 70 127 0.20 1.02 mg/kg Bromobenzene 106 70 135 0.20 1.06 mg/kg Bromochloromethane 118 60 130 0.20 1.18 mg/kg Bromodichloromethane 99 56 136 0.20 0.992 mg/kg Bromoform 100 59 132 0.20 1.00 mg/kg Bromomethane 39 18 134 0.20 0.388 mg/kg Carbon tetrachloride 113 60 140 0.20 1.13 mg/kg Chlorobenzene 100 75 132 0.20 1.00 mg/kg Chlorodibromomethane 99 62 133 0.20 0.992 mg/kg Chloroethane 33 45 139 0.20 0.330 mg/kg S Chloroform 106 62 132 0.20 1.06 mg/kg Chloromethane 89 41 138 0.20 0.888 mg/kg 2-Chloroethyl vinyl ether 91 41 149 0.20 0.912 mg/kg 1,2-Dibromoethane 100 60 135 0.20 1.00 mg/kg 2-Chlorotoluene 91 74 135 0.20 0.912 mg/kg Dibromomethane 112 60 135 0.20 1.12 mg/kg 1,2-Dichlorobenzene 88 70 130 0.20 0.880 mg/kg 4-Chlorotoluene 96 75 136 0.20 0.960 mg/kg 1,3-Dichlorobenzene 89 71 132 0.20 0.888 mg/kg 1,4-Dichlorobenzene 101 71 131 0.20 1.01 mg/kg Dichlorodifluoromethane 72 31 123 0.20 0.718 mg/kg 1,1-Dichloroethane 110 66 130 0.20 1.10 mg/kg 1,2-Dichloroethane 94 51 140 0.20 0.936 mg/kg 1,1-Dichloroethene 106 64 133 0.20 1.06 mg/kg cis-1,2-Dichloroethene 104 63 131 0.20 1.04 mg/kg trans-1,2-Dichloroethene 108 66 133 0.20 1.08 mg/kg 1,2-Dichloropropane 101 60 130 0.20 1.01 mg/kg 1,3-Dichloropropane 95 59 135 0.20 0.952 mg/kg 2,2-Dichloropropane 117 39 157 0.20 1.17 mg/kg 1,1-Dichloropropene 106 65 132 0.20 1.06 mg/kg cis-1,3-Dichloropropene 92 55 134 0.20 0.920 mg/kg trans-1,3-Dichloropropene 98 58 146 0.20 0.976 mg/kg Ethylbenzene 102 74 136 0.20 1.02 mg/kg Methyl tert-butyl ether (MTBE) 88 43 152 0.20 0.880 mg/kg Methyl ethyl ketone 100 43 148 4.0 10.0 mg/kg Methylene chloride 95 51 134 0.20 0.952 mg/kg Styrene 105 70 135 0.20 1.05 mg/kg 1,1,1,2-Tetrachloroethane 105 35 156 0.20 1.05 mg/kg 1,1,2,2-Tetrachloroethane 86 59 135 0.20 0.856 mg/kg Tetrachloroethene 124 64 139 0.20 1.24 mg/kg Toluene 104 73 137 0.20 1.04 mg/kg 1,1,1-Trichloroethane 113 63 134 0.20 1.13 mg/kg 1,1,2-Trichloroethane 94 56 136 0.20 0.936 mg/kg Trichloroethene 105 65 134 0.20 1.05 mg/kg Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. S - Spike recovery outside of advisory limits. Page 40 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW8260B Batch: 81606 Lab ID: LCS-81606 07/23/14 11:06 Laboratory Control Sample Run: 5971A.I_140723A 53 Trichlorofluoromethane 100 48 140 0.20 1.00 mg/kg 1,2,3-Trichloropropane 90 56 142 0.20 0.896 mg/kg Vinyl chloride 99 32 136 0.20 0.992 mg/kg m+p-Xylenes 104 75 136 0.20 2.08 mg/kg o-Xylene 104 72 134 0.20 1.04 mg/kg Surr: 1,2-Dichloroethane-d4 92 60 136 0.20 Surr: Dibromofluoromethane 102 70 132 0.20 Surr: p-Bromofluorobenzene 97 78 160 0.20 Surr: Toluene-d8 104 75 138 0.20 Lab ID: MB-81606 07/23/14 12:05 Method Blank Run: 5971A.I_140723A 54 Benzene 0.20 ND mg/kg Bromobenzene 0.20 ND mg/kg Bromochloromethane 0.20 ND mg/kg Bromodichloromethane 0.20 ND mg/kg Bromoform 0.20 ND mg/kg Bromomethane 0.20 ND mg/kg Carbon tetrachloride 0.20 ND mg/kg Chlorobenzene 0.20 ND mg/kg Chlorodibromomethane 0.20 ND mg/kg Chloroethane 0.20 ND mg/kg Chloroform 0.20 ND mg/kg Chloromethane 0.20 ND mg/kg 2-Chloroethyl vinyl ether 0.20 ND mg/kg 1,2-Dibromoethane 0.20 ND mg/kg 2-Chlorotoluene 0.20 ND mg/kg Dibromomethane 0.20 ND mg/kg 1,2-Dichlorobenzene 0.20 ND mg/kg 4-Chlorotoluene 0.20 ND mg/kg 1,3-Dichlorobenzene 0.20 ND mg/kg 1,4-Dichlorobenzene 0.20 ND mg/kg Dichlorodifluoromethane 0.20 ND mg/kg 1,1-Dichloroethane 0.20 ND mg/kg 1,2-Dichloroethane 0.20 ND mg/kg 1,1-Dichloroethene 0.20 ND mg/kg cis-1,2-Dichloroethene 0.20 ND mg/kg trans-1,2-Dichloroethene 0.20 ND mg/kg 1,2-Dichloropropane 0.20 ND mg/kg 1,3-Dichloropropane 0.20 ND mg/kg 2,2-Dichloropropane 0.20 ND mg/kg 1,1-Dichloropropene 0.20 ND mg/kg cis-1,3-Dichloropropene 0.20 ND mg/kg trans-1,3-Dichloropropene 0.20 ND mg/kg Ethylbenzene 0.20 ND mg/kg Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 41 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW8260B Batch: 81606 Lab ID: MB-81606 07/23/14 12:05 Method Blank Run: 5971A.I_140723A 54 Methyl tert-butyl ether (MTBE) 0.20 ND mg/kg Methyl ethyl ketone 4.0 ND mg/kg Methylene chloride 0.20 ND mg/kg Styrene 0.20 ND mg/kg 1,1,1,2-Tetrachloroethane 0.20 ND mg/kg 1,1,2,2-Tetrachloroethane 0.20 ND mg/kg Tetrachloroethene 0.20 ND mg/kg Toluene 0.20 ND mg/kg 1,1,1-Trichloroethane 0.20 ND mg/kg 1,1,2-Trichloroethane 0.20 ND mg/kg Trichloroethene 0.20 ND mg/kg Trichlorofluoromethane 0.20 ND mg/kg 1,2,3-Trichloropropane 0.20 ND mg/kg Vinyl chloride 0.20 ND mg/kg m+p-Xylenes 0.20 ND mg/kg o-Xylene 0.20 ND mg/kg Xylenes, Total 0.20 ND mg/kg Surr: 1,2-Dichloroethane-d4 116 60 136 0.20 Surr: Dibromofluoromethane 124 70 132 0.20 Surr: p-Bromofluorobenzene 119 78 160 0.20 Surr: Toluene-d8 119 75 138 0.20 Lab ID: B14071972-001A_MS 07/23/14 18:58 Sample Matrix Spike Run: 5971A.I_140723A 53 Benzene 98 70 127 0.20 0.976 mg/kg Bromobenzene 101 70 135 0.20 1.01 mg/kg Bromochloromethane 109 60 130 0.20 1.09 mg/kg Bromodichloromethane 97 56 136 0.20 0.968 mg/kg Bromoform 94 59 132 0.20 0.936 mg/kg Bromomethane 34 18 134 0.20 0.342 mg/kg Carbon tetrachloride 106 60 140 0.20 1.06 mg/kg Chlorobenzene 94 75 132 0.20 0.944 mg/kg Chlorodibromomethane 95 62 133 0.20 0.952 mg/kg Chloroethane 35 45 139 0.20 0.351 mg/kg S Chloroform 102 62 132 0.20 1.02 mg/kg Chloromethane 82 41 138 0.20 0.816 mg/kg 2-Chloroethyl vinyl ether 90 41 149 0.20 0.896 mg/kg 1,2-Dibromoethane 98 60 135 0.20 0.984 mg/kg 2-Chlorotoluene 90 74 135 0.20 0.904 mg/kg Dibromomethane 108 60 135 0.20 1.08 mg/kg 1,2-Dichlorobenzene 88 70 130 0.20 0.880 mg/kg 4-Chlorotoluene 102 75 136 0.20 1.02 mg/kg 1,3-Dichlorobenzene 83 71 132 0.20 0.832 mg/kg 1,4-Dichlorobenzene 101 71 131 0.20 1.01 mg/kg Dichlorodifluoromethane 57 31 123 0.20 0.569 mg/kg Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. S - Spike recovery outside of advisory limits. Page 42 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW8260B Batch: 81606 Lab ID: B14071972-001A_MS 07/23/14 18:58 Sample Matrix Spike Run: 5971A.I_140723A 53 1,1-Dichloroethane 106 66 130 0.20 1.06 mg/kg 1,2-Dichloroethane 94 51 140 0.20 0.936 mg/kg 1,1-Dichloroethene 103 64 133 0.20 1.03 mg/kg cis-1,2-Dichloroethene 99 63 131 0.20 0.992 mg/kg trans-1,2-Dichloroethene 101 66 133 0.20 1.01 mg/kg 1,2-Dichloropropane 99 60 130 0.20 0.992 mg/kg 1,3-Dichloropropane 95 59 135 0.20 0.952 mg/kg 2,2-Dichloropropane 109 39 157 0.20 1.09 mg/kg 1,1-Dichloropropene 97 65 132 0.20 0.968 mg/kg cis-1,3-Dichloropropene 88 55 134 0.20 0.880 mg/kg trans-1,3-Dichloropropene 93 58 146 0.20 0.928 mg/kg Ethylbenzene 101 74 136 0.20 1.01 mg/kg Methyl tert-butyl ether (MTBE) 84 43 152 0.20 0.840 mg/kg Methyl ethyl ketone 96 43 148 4.0 9.60 mg/kg Methylene chloride 91 51 134 0.20 0.912 mg/kg Styrene 101 70 135 0.20 1.01 mg/kg 1,1,1,2-Tetrachloroethane 98 35 156 0.20 0.976 mg/kg 1,1,2,2-Tetrachloroethane 90 59 135 0.20 0.896 mg/kg Tetrachloroethene 120 64 139 0.20 1.96 mg/kg Toluene 100 73 137 0.20 1.04 mg/kg 1,1,1-Trichloroethane 102 63 134 0.20 1.02 mg/kg 1,1,2-Trichloroethane 94 56 136 0.20 0.944 mg/kg Trichloroethene 103 65 134 0.20 1.10 mg/kg Trichlorofluoromethane 90 48 140 0.20 0.904 mg/kg 1,2,3-Trichloropropane 90 56 142 0.20 0.896 mg/kg Vinyl chloride 93 32 136 0.20 0.928 mg/kg m+p-Xylenes 104 75 136 0.20 2.09 mg/kg o-Xylene 97 72 134 0.20 0.968 mg/kg Surr: 1,2-Dichloroethane-d4 92 60 136 0.20 Surr: Dibromofluoromethane 96 70 132 0.20 Surr: p-Bromofluorobenzene 95 78 160 0.20 Surr: Toluene-d8 104 75 138 0.20 Lab ID: B14071972-001A_MS 07/23/14 19:28 Sample Matrix Spike Duplicate Run: 5971A.I_140723A 53 Benzene 97 70 127 20 0.20 0.8 0.968 mg/kg Bromobenzene 106 70 135 20 0.20 5.4 1.06 mg/kg Bromochloromethane 110 60 130 20 0.20 0.7 1.10 mg/kg Bromodichloromethane 90 56 136 20 0.20 7.7 0.896 mg/kg Bromoform 98 59 132 20 0.20 5.0 0.984 mg/kg Bromomethane 33 18 134 20 0.20 3.1 0.332 mg/kg Carbon tetrachloride 105 60 140 20 0.20 0.8 1.05 mg/kg Chlorobenzene 92 75 132 20 0.20 2.6 0.920 mg/kg Chlorodibromomethane 91 62 133 20 0.20 4.3 0.912 mg/kg Chloroethane 35 45 139 20 0.20 1.4 0.346 mg/kg S Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. S - Spike recovery outside of advisory limits. Page 43 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW8260B Batch: 81606 Lab ID: B14071972-001A_MS 07/23/14 19:28 Sample Matrix Spike Duplicate Run: 5971A.I_140723A 53 Chloroform 100 62 132 20 0.20 2.4 1.00 mg/kg Chloromethane 77 41 138 20 0.20 5.9 0.770 mg/kg 2-Chloroethyl vinyl ether 82 41 149 20 0.20 9.3 0.816 mg/kg 1,2-Dibromoethane 96 60 135 20 0.20 2.5 0.960 mg/kg 2-Chlorotoluene 90 74 135 20 0.20 0.0 0.904 mg/kg Dibromomethane 101 60 135 20 0.20 6.9 1.01 mg/kg 1,2-Dichlorobenzene 89 70 130 20 0.20 0.9 0.888 mg/kg 4-Chlorotoluene 104 75 136 20 0.20 2.3 1.04 mg/kg 1,3-Dichlorobenzene 87 71 132 20 0.20 4.7 0.872 mg/kg 1,4-Dichlorobenzene 102 71 131 20 0.20 1.6 1.02 mg/kg Dichlorodifluoromethane 55 31 123 20 0.20 3.4 0.550 mg/kg 1,1-Dichloroethane 103 66 130 20 0.20 3.1 1.03 mg/kg 1,2-Dichloroethane 92 51 140 20 0.20 1.7 0.920 mg/kg 1,1-Dichloroethene 100 64 133 20 0.20 3.1 1.00 mg/kg cis-1,2-Dichloroethene 94 63 131 20 0.20 5.0 0.944 mg/kg trans-1,2-Dichloroethene 102 66 133 20 0.20 0.8 1.02 mg/kg 1,2-Dichloropropane 93 60 130 20 0.20 6.7 0.928 mg/kg 1,3-Dichloropropane 87 59 135 20 0.20 8.8 0.872 mg/kg 2,2-Dichloropropane 105 39 157 20 0.20 3.7 1.05 mg/kg 1,1-Dichloropropene 97 65 132 20 0.20 0.0 0.968 mg/kg cis-1,3-Dichloropropene 85 55 134 20 0.20 3.7 0.848 mg/kg trans-1,3-Dichloropropene 87 58 146 20 0.20 6.2 0.872 mg/kg Ethylbenzene 95 74 136 20 0.20 5.7 0.952 mg/kg Methyl tert-butyl ether (MTBE) 83 43 152 20 0.20 1.0 0.832 mg/kg Methyl ethyl ketone 90 43 148 20 4.0 6.9 8.96 mg/kg Methylene chloride 90 51 134 20 0.20 1.8 0.896 mg/kg Styrene 95 70 135 20 0.20 5.7 0.952 mg/kg 1,1,1,2-Tetrachloroethane 94 35 156 20 0.20 4.2 0.936 mg/kg 1,1,2,2-Tetrachloroethane 96 59 135 20 0.20 6.9 0.960 mg/kg Tetrachloroethene 106 64 139 20 0.20 7.6 1.82 mg/kg Toluene 93 73 137 20 0.20 6.3 0.976 mg/kg 1,1,1-Trichloroethane 101 63 134 20 0.20 1.6 1.01 mg/kg 1,1,2-Trichloroethane 92 56 136 20 0.20 2.6 0.920 mg/kg Trichloroethene 96 65 134 20 0.20 6.7 1.03 mg/kg Trichlorofluoromethane 87 48 140 20 0.20 3.6 0.872 mg/kg 1,2,3-Trichloropropane 95 56 142 20 0.20 6.1 0.952 mg/kg Vinyl chloride 89 32 136 20 0.20 4.4 0.888 mg/kg m+p-Xylenes 96 75 136 20 0.20 8.0 1.93 mg/kg o-Xylene 94 72 134 20 0.20 3.4 0.936 mg/kg Surr: 1,2-Dichloroethane-d4 92 60 136 0.20 Surr: Dibromofluoromethane 94 70 132 0.20 Surr: p-Bromofluorobenzene 100 78 160 0.20 Surr: Toluene-d8 96 75 138 0.20 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 44 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: MA-VPH Batch: 81647 Lab ID: LCS-81647 07/25/14 11:17 Laboratory Control Sample Run: VARIAN1_140725A 16 1,2,4-Trimethylbenzene 100 70 130 0.10 2.49 mg/kg 2,2,4-Trimethylpentane 94 70 130 0.10 2.36 mg/kg 2-Methylpentane 94 70 130 0.10 2.34 mg/kg n-Butylcyclohexane 89 70 130 0.10 2.23 mg/kg n-Decane 85 70 130 0.10 2.13 mg/kg n-Pentane 91 70 130 0.10 2.26 mg/kg Methyl tert-butyl ether (MTBE) 94 70 130 0.10 2.35 mg/kg Benzene 98 70 130 0.050 2.44 mg/kg Toluene 96 70 130 0.050 2.39 mg/kg Ethylbenzene 98 70 130 0.050 2.44 mg/kg m+p-Xylenes 98 70 130 0.050 4.92 mg/kg o-Xylene 97 70 130 0.050 2.43 mg/kg Naphthalene 95 70 130 0.10 2.36 mg/kg Total Purgeable Hydrocarbons 86 70 130 2.0 32.4 mg/kg Surr: VPH Aromatics Surrogate 105 70 130 0.10 Surr: VPH Aliphatics Surrogate 98 70 130 0.10 Lab ID: MB-81647 07/25/14 13:35 Method Blank Run: VARIAN1_140725A 14 Methyl tert-butyl ether (MTBE) 0.10 ND mg/kg Benzene 0.050 ND mg/kg Toluene 0.050 ND mg/kg Ethylbenzene 0.050 ND mg/kg m+p-Xylenes 0.050 ND mg/kg o-Xylene 0.050 ND mg/kg Xylenes, Total 0.050 ND mg/kg Naphthalene 0.10 ND mg/kg C9 to C10 Aromatics 2.0 ND mg/kg C5 to C8 Aliphatics 2.0 ND mg/kg C9 to C12 Aliphatics 2.0 ND mg/kg Total Purgeable Hydrocarbons 2.0 ND mg/kg Surr: VPH Aromatics Surrogate 108 70 130 0.10 Surr: VPH Aliphatics Surrogate 105 70 130 0.10 Lab ID: B14072051-001AMS 07/25/14 15:21 Sample Matrix Spike Run: VARIAN1_140725A 10 Methyl tert-butyl ether (MTBE) 94 70 130 0.12 2.92 mg/kg-dry Benzene 95 70 130 0.062 2.98 mg/kg-dry Toluene 95 70 130 0.062 2.95 mg/kg-dry Ethylbenzene 96 70 130 0.062 3.00 mg/kg-dry m+p-Xylenes 97 70 130 0.062 6.04 mg/kg-dry o-Xylene 96 70 130 0.062 2.98 mg/kg-dry Naphthalene 91 70 130 0.12 2.84 mg/kg-dry Total Purgeable Hydrocarbons 87 70 130 2.5 40.5 mg/kg-dry Surr: VPH Aromatics Surrogate 99 70 130 0.12 Surr: VPH Aliphatics Surrogate 93 70 130 0.12 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 45 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: MA-VPH Batch: 81647 Lab ID: B14072051-001AMSD 07/25/14 15:55 Sample Matrix Spike Duplicate Run: VARIAN1_140725A 10 Methyl tert-butyl ether (MTBE) 93 70 130 20 0.12 0.8 2.89 mg/kg-dry Benzene 95 70 130 20 0.062 0.0 2.97 mg/kg-dry Toluene 95 70 130 20 0.062 0.8 2.97 mg/kg-dry Ethylbenzene 96 70 130 20 0.062 0.0 3.01 mg/kg-dry m+p-Xylenes 97 70 130 20 0.062 0.5 6.07 mg/kg-dry o-Xylene 96 70 130 20 0.062 0.2 2.99 mg/kg-dry Naphthalene 93 70 130 20 0.12 2.1 2.90 mg/kg-dry Total Purgeable Hydrocarbons 87 70 130 20 2.5 0.1 40.5 mg/kg-dry Surr: VPH Aromatics Surrogate 98 70 130 0.12 Surr: VPH Aliphatics Surrogate 90 70 130 0.12 Method: MA-VPH Analytical Run: R227833 Lab ID: CCV_0725VAR03r-S 07/25/14 10:43 Continuing Calibration Verification Standard 15 1,2,4-Trimethylbenzene 102 75 125 0.10 2.54 mg/kg 2,2,4-Trimethylpentane 97 75 125 0.10 2.42 mg/kg 2-Methylpentane 96 75 125 0.10 2.40 mg/kg n-Butylcyclohexane 91 75 125 0.10 2.28 mg/kg n-Decane 83 75 125 0.10 2.08 mg/kg n-Pentane 95 75 125 0.10 2.39 mg/kg Methyl tert-butyl ether (MTBE) 104 75 125 0.10 2.59 mg/kg Benzene 102 75 125 0.050 2.55 mg/kg Toluene 102 75 125 0.050 2.56 mg/kg Ethylbenzene 102 75 125 0.050 2.55 mg/kg m+p-Xylenes 103 75 125 0.050 5.13 mg/kg o-Xylene 102 75 125 0.050 2.55 mg/kg Naphthalene 101 75 125 0.10 2.53 mg/kg Surr: VPH Aromatics Surrogate 108 75 125 0.10 Surr: VPH Aliphatics Surrogate 102 75 125 0.10 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 46 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: MA-VPH Analytical Run: R227910 Lab ID: CCV_0728VAR03r-S 07/28/14 09:26 Continuing Calibration Verification Standard 15 1,2,4-Trimethylbenzene 105 75 125 0.10 2.63 mg/kg 2,2,4-Trimethylpentane 98 75 125 0.10 2.44 mg/kg 2-Methylpentane 100 75 125 0.10 2.49 mg/kg n-Butylcyclohexane 90 75 125 0.10 2.25 mg/kg n-Decane 86 75 125 0.10 2.16 mg/kg n-Pentane 103 75 125 0.10 2.57 mg/kg Methyl tert-butyl ether (MTBE) 108 75 125 0.10 2.69 mg/kg Benzene 106 75 125 0.050 2.65 mg/kg Toluene 105 75 125 0.050 2.62 mg/kg Ethylbenzene 106 75 125 0.050 2.65 mg/kg m+p-Xylenes 106 75 125 0.050 5.31 mg/kg o-Xylene 105 75 125 0.050 2.63 mg/kg Naphthalene 104 75 125 0.10 2.60 mg/kg Surr: VPH Aromatics Surrogate 106 75 125 0.10 Surr: VPH Aliphatics Surrogate 99 75 125 0.10 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 47 of 117 B1 3-4 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-001A ;0725VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072514_b\0725VAR.0009.RAW Date & Time Acquired: 7/25/2014 2:09:45 PM Method File: G:\Org\VAR\Methods\140606M2051-1.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:1316.342 C9-C10 Aromatics Amount: 5.958002E-02 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.321 8.321 8.321 132 .05 U Toluene__________________11.353 11.353 11.353 89 .05 U Ethylbenzene_____________15.12 15.12 15.12 127 .05 U m+p-Xylenes______________15.281 15.281 15.281 603 .05 U o-Xylene_________________16.111 16.111 16.111 144 .05 U 124-Trimethylbenzene_____18.096 18.096 18.096 180 .05 U Naphthalene______________21.182 21.182 21.182 127 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.218 2.5 2.53 101.21 70-130 2 . 7 6 3 . 2 4 4 . 6 0 6 . 4 4 6 . 6 5 8 . 3 2 9 . 2 2 9 . 6 2 9 . 8 5 9 . 9 8 1 0 . 4 0 1 1 . 3 5 1 5 . 1 2 1 5 . 2 8 1 6 . 1 1 1 7 . 5 0 1 8 . 1 0 1 8 . 7 3 1 9 . 4 3 2 0 . 5 2 2 1 . 1 8 2 1 . 3 9 2 1 . 6 2 2 2 . 0 8 2 2 . 4 9 2 2 . 6 5 2 2 . 8 2 2 4 . 0 9 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072514_b\0725VAR.0009.RAW B14072051-001A ;0725VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 48 of 117 B1 3-4 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-001A ;0725VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072514_b\0725VARB.0009.RAW Date & Time Acquired: 7/25/2014 2:09:45 PM Method File: G:\Org\VAR\Methods\140606M2051-1B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.219 2.5 2.425 97.01 - GRO Area:3748.73 GRO Amount: 0.1096421 TPH Area:6735.246 TPH Amount: 0.196991 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:2470.719 C5-C8 Amount: 0.1063177 C9-C12 Area:3601.323 C9-C12 Amount: 0.1343888 4 . 5 7 6 . 6 3 7 . 8 3 8 . 3 2 9 . 2 2 9 . 8 4 1 1 . 1 9 1 1 . 3 5 1 5 . 1 3 1 5 . 2 8 1 7 . 1 8 1 8 . 1 0 1 8 . 7 5 1 9 . 7 8 2 1 . 1 8 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072514_b\0725VARB.0009.RAW B14072051-001A ;0725VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 49 of 117 B1 6-7 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-002A ;0725VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072514_b\0725VAR.0015.RAW Date & Time Acquired: 7/25/2014 5:39:00 PM Method File: G:\Org\VAR\Methods\140606M2051-2.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:1469.893 C9-C10 Aromatics Amount: 6.653005E-02 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.313 8.313 8.313 172 .05 U Toluene__________________11.356 11.356 11.356 261 .05 U Ethylbenzene_____________15.105 15.105 15.105 161 .05 U m+p-Xylenes______________15.277 15.277 15.277 623 .05 U o-Xylene_________________16.118 16.118 16.118 170 .05 U 124-Trimethylbenzene_____18.094 18.094 18.094 209 .05 U Naphthalene______________21.183 21.183 21.183 222 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.217 2.5 2.637 105.46 70-130 2 . 7 4 3 . 2 4 3 . 6 0 4 . 6 0 5 . 3 5 6 . 4 4 6 . 6 4 7 . 8 6 8 . 3 1 8 . 9 2 9 . 2 2 9 . 8 0 9 . 8 3 9 . 9 9 1 0 . 4 0 1 0 . 9 2 1 1 . 0 8 1 1 . 2 0 1 1 . 3 6 1 2 . 4 7 1 5 . 1 1 1 5 . 2 8 1 6 . 1 2 1 7 . 1 8 1 7 . 5 0 1 8 . 0 9 1 8 . 2 3 1 8 . 6 9 1 9 . 0 8 1 9 . 3 1 1 9 . 4 4 2 1 . 1 8 2 2 . 1 1 2 2 . 6 7 2 2 . 7 4 2 3 . 2 2 2 3 . 7 9 2 3 . 9 8 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072514_b\0725VAR.0015.RAW B14072051-002A ;0725VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 50 of 117 B1 6-7 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-002A ;0725VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072514_b\0725VARB.0015.RAW Date & Time Acquired: 7/25/2014 5:39:00 PM Method File: G:\Org\VAR\Methods\140606M2051-2B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.218 2.5 2.481 99.25 - GRO Area:4313.074 GRO Amount: 0.1261479 TPH Area:6946.469 TPH Amount: 0.2031688 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:1882.926 C5-C8 Amount: 8.102436E-02 C9-C12 Area:4593.094 C9-C12 Amount: 0.1713982 4 . 5 9 6 . 6 4 7 . 8 8 8 . 3 1 9 . 2 2 1 1 . 3 6 1 4 . 6 9 1 5 . 1 2 1 5 . 2 8 1 6 . 1 1 1 7 . 1 8 1 8 . 0 9 1 8 . 2 3 1 9 . 7 7 2 1 . 1 8 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072514_b\0725VARB.0015.RAW B14072051-002A ;0725VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 51 of 117 B2 3-4 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-003A ;0725VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072514_b\0725VAR.0018.RAW Date & Time Acquired: 7/25/2014 7:22:23 PM Method File: G:\Org\VAR\Methods\140606M2051-3.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:10227.36 C9-C10 Aromatics Amount: 0.4629092 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.323 8.323 8.323 198 .05 U Toluene__________________11.36 11.36 11.36 346 .05 U Ethylbenzene_____________15.106 15.106 15.106 148 .05 U m+p-Xylenes______________15.277 15.277 15.277 696 .05 U o-Xylene_________________16.109 16.109 16.109 227 .05 U 124-Trimethylbenzene_____18.094 18.094 18.094 396 .05 U Naphthalene______________21.181 21.181 21.181 1093 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.216 2.5 2.61 104.41 70-130 2 . 7 5 3 . 2 5 4 . 6 0 6 . 4 5 6 . 6 4 8 . 3 2 9 . 2 2 1 0 . 3 8 1 0 . 8 9 1 1 . 2 0 1 1 . 3 6 1 1 . 8 6 1 5 . 1 1 1 5 . 2 8 1 6 . 1 1 1 6 . 9 7 1 7 . 1 8 1 7 . 3 3 1 7 . 4 9 1 7 . 5 6 1 7 . 9 2 1 8 . 0 9 1 8 . 5 5 1 8 . 7 0 1 8 . 7 5 1 8 . 8 9 1 8 . 9 8 1 9 . 0 7 1 9 . 1 9 1 9 . 3 3 1 9 . 4 3 1 9 . 5 8 1 9 . 6 4 1 9 . 7 9 1 9 . 9 1 2 0 . 0 0 2 0 . 1 1 2 0 . 2 1 2 0 . 2 4 2 0 . 3 0 2 0 . 3 7 2 0 . 4 2 2 0 . 5 1 2 0 . 6 5 2 0 . 8 5 2 0 . 9 2 2 1 . 0 3 2 1 . 1 8 2 1 . 3 1 2 1 . 3 7 2 1 . 4 7 2 1 . 5 1 2 1 . 7 1 2 1 . 7 7 2 1 . 8 7 2 1 . 9 6 2 2 . 1 0 2 2 . 2 6 2 2 . 4 2 2 2 . 5 8 2 2 . 6 6 2 2 . 7 5 2 2 . 8 2 2 2 . 9 3 2 2 . 9 5 2 3 . 0 6 2 3 . 2 1 2 3 . 3 3 2 3 . 4 3 2 3 . 4 9 2 3 . 7 0 2 3 . 8 0 2 4 . 0 1 2 4 . 0 4 2 4 . 1 2 2 4 . 2 0 2 4 . 3 0 2 4 . 4 4 2 4 . 6 1 2 4 . 7 0 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072514_b\0725VAR.0018.RAW B14072051-003A ;0725VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 52 of 117 B2 3-4 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-003A ;0725VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072514_b\0725VARB.0018.RAW Date & Time Acquired: 7/25/2014 7:22:23 PM Method File: G:\Org\VAR\Methods\140606M2051-3B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.216 2.5 2.583 103.33 - GRO Area:13868.18 GRO Amount: 0.4056134 TPH Area:46131.71 TPH Amount: 1.34925 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:9469.168 C5-C8 Amount: 0.4074687 C9-C12 Area:16452.16 C9-C12 Amount: 0.613937 4 . 6 1 5 . 0 9 5 . 3 3 5 . 6 4 6 . 6 4 8 . 3 2 9 . 2 2 9 . 4 7 9 . 5 4 9 . 8 1 9 . 9 2 1 0 . 8 8 1 1 . 2 1 1 1 . 3 6 1 1 . 8 9 1 2 . 4 6 1 4 . 6 7 1 4 . 6 9 1 5 . 1 0 1 5 . 1 2 1 5 . 2 8 1 5 . 6 5 1 5 . 9 7 1 6 . 1 0 1 6 . 2 7 1 6 . 4 0 1 6 . 9 7 1 7 . 1 8 1 7 . 3 4 1 7 . 4 9 1 7 . 5 3 1 7 . 9 1 1 8 . 0 9 1 8 . 2 3 1 8 . 2 8 1 8 . 5 5 1 8 . 7 0 1 8 . 7 6 1 8 . 8 9 1 8 . 9 7 1 9 . 0 7 1 9 . 4 4 1 9 . 6 4 1 9 . 7 8 1 9 . 9 3 2 0 . 0 0 2 0 . 1 1 2 0 . 1 7 2 0 . 3 0 2 0 . 3 7 2 0 . 4 7 2 0 . 5 2 2 0 . 6 5 2 0 . 9 0 2 1 . 0 4 2 1 . 1 8 2 1 . 3 3 2 1 . 4 5 2 1 . 5 0 2 1 . 6 1 2 1 . 6 5 2 1 . 7 0 2 1 . 7 8 2 1 . 8 8 2 2 . 1 1 2 2 . 3 6 2 2 . 4 2 2 2 . 6 2 2 2 . 6 4 2 2 . 7 6 2 2 . 8 2 2 2 . 9 9 2 3 . 0 6 2 3 . 2 1 2 3 . 3 3 2 3 . 4 1 2 3 . 5 1 2 3 . 8 0 2 4 . 0 4 2 4 . 1 4 2 4 . 2 0 2 4 . 3 1 2 4 . 6 1 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072514_b\0725VARB.0018.RAW B14072051-003A ;0725VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 53 of 117 B2 10-11 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-004A ;0725VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072514_b\0725VAR.0021.RAW Date & Time Acquired: 7/25/2014 9:06:19 PM Method File: G:\Org\VAR\Methods\140606M2051-4.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:2057.628 C9-C10 Aromatics Amount: 0.093132 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.319 8.319 8.319 162 .05 U Toluene__________________11.358 11.358 11.358 189 .05 U Ethylbenzene_____________15.107 15.107 15.107 93 .05 U m+p-Xylenes______________15.275 15.275 15.275 466 .05 U o-Xylene_________________16.113 16.113 16.113 121 .05 U 124-Trimethylbenzene_____18.094 18.094 18.094 188 .05 U Naphthalene______________21.178 21.178 21.178 122 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.214 2.5 2.548 101.9 70-130 1 . 5 4 2 . 2 3 2 . 7 6 3 . 2 5 4 . 6 0 5 . 3 4 6 . 4 5 6 . 6 5 8 . 3 2 8 . 9 4 9 . 2 1 9 . 8 1 9 . 9 2 1 0 . 3 8 1 0 . 9 2 1 1 . 0 8 1 1 . 1 8 1 1 . 3 6 1 5 . 1 1 1 5 . 2 8 1 6 . 1 1 1 7 . 4 9 1 8 . 0 9 1 8 . 2 7 1 9 . 0 7 1 9 . 4 4 2 0 . 1 4 2 0 . 2 4 2 0 . 3 0 2 0 . 3 8 2 0 . 4 4 2 0 . 5 2 2 0 . 6 5 2 1 . 1 8 2 1 . 6 2 2 2 . 4 1 2 3 . 7 8 2 4 . 0 4 2 4 . 2 9 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072514_b\0725VAR.0021.RAW B14072051-004A ;0725VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 54 of 117 B2 10-11 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-004A ;0725VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072514_b\0725VARB.0021.RAW Date & Time Acquired: 7/25/2014 9:06:19 PM Method File: G:\Org\VAR\Methods\140606M2051-4B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.215 2.5 2.432 97.3 - GRO Area:3746.863 GRO Amount: 0.1095875 TPH Area:10044.85 TPH Amount: 0.2937897 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:2897.992 C5-C8 Amount: 0.1247038 C9-C12 Area:4964.377 C9-C12 Amount: 0.1852532 4 . 5 8 5 . 3 3 6 . 4 1 6 . 5 1 6 . 6 3 7 . 8 5 8 . 3 3 9 . 2 1 1 5 . 2 7 1 6 . 1 1 1 7 . 1 7 1 7 . 4 9 1 8 . 0 9 1 8 . 2 8 1 8 . 7 5 1 9 . 7 7 1 9 . 9 3 2 0 . 3 8 2 0 . 5 4 2 0 . 6 5 2 0 . 9 1 2 1 . 0 6 2 1 . 1 8 2 1 . 3 3 2 1 . 5 0 2 1 . 6 2 2 1 . 8 8 2 2 . 8 1 2 2 . 9 7 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072514_b\0725VARB.0021.RAW B14072051-004A ;0725VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 55 of 117 B3 7-8 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-005A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0011.RAW Date & Time Acquired: 7/28/2014 2:00:59 PM Method File: G:\Org\VAR\Methods\140606M2051-5.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:3942.311 C9-C10 Aromatics Amount: 0.1784362 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.311 8.311 8.311 115 .05 U Toluene__________________11.354 11.354 11.354 113 .05 U Ethylbenzene_____________15.096 15.096 15.096 69 .05 U m+p-Xylenes______________15.271 15.271 15.271 282 .05 U o-Xylene_________________16.103 16.103 16.103 96 .05 U 124-Trimethylbenzene_____18.09 18.09 18.09 224 .05 U Naphthalene______________21.177 21.177 21.177 185 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.214 2.5 2.311 92.43 70-130 3 . 2 4 4 . 3 8 4 . 6 0 6 . 4 4 6 . 6 4 8 . 3 1 9 . 2 1 9 . 8 1 9 . 9 0 1 0 . 3 7 1 1 . 3 5 1 2 . 4 8 1 5 . 1 0 1 5 . 2 7 1 6 . 1 0 1 7 . 5 0 1 7 . 5 4 1 7 . 9 1 1 8 . 0 9 1 8 . 2 3 1 8 . 7 5 1 8 . 8 8 1 8 . 9 8 1 9 . 0 7 1 9 . 2 8 1 9 . 4 2 1 9 . 5 5 1 9 . 6 5 1 9 . 8 2 1 9 . 9 0 2 0 . 0 6 2 0 . 2 9 2 0 . 4 7 2 0 . 6 7 2 0 . 7 3 2 0 . 9 1 2 1 . 0 6 2 1 . 1 8 2 1 . 5 0 2 1 . 6 0 2 1 . 6 8 2 1 . 7 9 2 2 . 4 2 2 2 . 9 4 2 3 . 0 5 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0011.RAW B14072051-005A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 56 of 117 B3 7-8 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-005A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0011.RAW Date & Time Acquired: 7/28/2014 2:00:59 PM Method File: G:\Org\VAR\Methods\140606M2051-5B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.215 2.5 2.307 92.26 - GRO Area:7506.863 GRO Amount: 0.2195591 TPH Area:22528.91 TPH Amount: 0.6589206 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:5982.602 C5-C8 Amount: 0.2574379 C9-C12 Area:11943.54 C9-C12 Amount: 0.4456912 4 . 5 8 5 . 0 9 5 . 3 3 6 . 6 4 8 . 3 3 8 . 4 1 9 . 2 1 9 . 8 0 9 . 8 5 1 1 . 2 1 1 1 . 3 5 1 2 . 5 0 1 5 . 2 8 1 6 . 1 1 1 7 . 1 8 1 7 . 5 1 1 7 . 9 0 1 8 . 0 9 1 8 . 2 3 1 8 . 3 3 1 8 . 7 5 1 8 . 8 8 1 8 . 9 8 1 9 . 0 7 1 9 . 2 9 1 9 . 4 2 1 9 . 5 2 1 9 . 6 4 1 9 . 8 2 1 9 . 9 2 2 0 . 0 5 2 0 . 2 9 2 0 . 4 7 2 0 . 5 9 2 0 . 6 6 2 0 . 7 3 2 0 . 9 1 2 1 . 0 6 2 1 . 1 8 2 1 . 3 1 2 1 . 3 6 2 1 . 5 0 2 1 . 6 0 2 1 . 6 9 2 1 . 7 9 2 1 . 8 9 2 1 . 9 9 2 2 . 0 9 2 2 . 4 4 2 3 . 0 5 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0011.RAW B14072051-005A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 57 of 117 B4 9-11 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-006A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0013.RAW Date & Time Acquired: 7/28/2014 3:09:59 PM Method File: G:\Org\VAR\Methods\140606M2051-6.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:2613.735 C9-C10 Aromatics Amount: 0.1183024 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.319 8.319 8.319 130 .05 U Toluene__________________11.35 11.35 11.35 113 .05 U Ethylbenzene_____________. . . .05 U m+p-Xylenes______________15.276 15.276 15.276 253 .05 U o-Xylene_________________16.119 16.119 16.119 140 .05 U 124-Trimethylbenzene_____18.096 18.096 18.096 177 .05 U Naphthalene______________21.177 21.177 21.177 127 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.213 2.5 2.548 101.93 70-130 2 . 7 5 3 . 2 5 3 . 6 3 4 . 3 8 4 . 6 0 6 . 4 4 6 . 6 4 8 . 3 2 9 . 2 1 9 . 8 2 1 1 . 2 0 1 1 . 3 5 1 5 . 2 8 1 6 . 1 2 1 6 . 3 2 1 7 . 4 9 1 7 . 5 6 1 7 . 9 2 1 8 . 1 0 1 8 . 2 9 1 8 . 7 6 1 8 . 9 6 1 9 . 0 9 1 9 . 4 2 1 9 . 6 3 1 9 . 9 2 2 0 . 0 4 2 0 . 2 1 2 0 . 3 1 2 0 . 4 3 2 0 . 5 2 2 0 . 6 5 2 1 . 1 8 2 1 . 5 3 2 1 . 6 1 2 1 . 7 8 2 1 . 8 9 2 2 . 0 9 2 2 . 4 2 2 2 . 6 5 2 2 . 7 5 2 3 . 0 6 2 3 . 3 0 2 3 . 4 1 2 3 . 8 1 2 3 . 9 3 2 4 . 1 1 2 4 . 1 9 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0013.RAW B14072051-006A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 58 of 117 B4 9-11 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-006A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0013.RAW Date & Time Acquired: 7/28/2014 3:09:59 PM Method File: G:\Org\VAR\Methods\140606M2051-6B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.214 2.5 2.427 97.06 - GRO Area:7373.676 GRO Amount: 0.2156637 TPH Area:17486.79 TPH Amount: 0.5114499 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:4842.172 C5-C8 Amount: 0.208364 C9-C12 Area:8762.131 C9-C12 Amount: 0.3269721 6 . 5 0 6 . 6 1 8 . 3 2 9 . 2 1 9 . 5 8 9 . 8 2 1 0 . 8 9 1 1 . 1 8 1 3 . 1 1 1 4 . 6 6 1 5 . 2 7 1 5 . 6 6 1 6 . 1 0 1 6 . 3 3 1 7 . 1 7 1 7 . 5 1 1 8 . 0 9 1 8 . 2 8 1 8 . 7 5 1 8 . 9 3 1 9 . 0 9 1 9 . 4 3 1 9 . 6 2 1 9 . 7 7 1 9 . 9 3 2 0 . 0 4 2 0 . 5 2 2 0 . 5 9 2 0 . 6 6 2 0 . 9 0 2 1 . 0 7 2 1 . 1 8 2 1 . 6 1 2 1 . 8 8 2 2 . 4 1 2 2 . 4 6 2 3 . 7 9 2 4 . 1 4 2 4 . 2 9 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0013.RAW B14072051-006A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 59 of 117 B5 5-7 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-007A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0015.RAW Date & Time Acquired: 7/28/2014 4:19:17 PM Method File: G:\Org\VAR\Methods\140606M2051-7.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:3868.995 C9-C10 Aromatics Amount: 0.1751178 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.312 8.312 8.312 129 .05 U Toluene__________________11.354 11.354 11.354 123 .05 U Ethylbenzene_____________15.11 15.11 15.11 94 .05 U m+p-Xylenes______________15.277 15.277 15.277 310 .05 U o-Xylene_________________16.105 16.105 16.105 99 .05 U 124-Trimethylbenzene_____18.095 18.095 18.095 210 .05 U Naphthalene______________21.179 21.179 21.179 118 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.216 2.5 2.538 101.5 70-130 2 . 4 0 2 . 7 5 3 . 2 5 3 . 6 3 4 . 3 8 4 . 6 0 5 . 3 4 6 . 4 4 6 . 6 5 7 . 7 8 8 . 3 1 8 . 9 4 9 . 2 2 9 . 6 1 9 . 8 4 1 0 . 3 8 1 0 . 9 0 1 1 . 1 8 1 1 . 3 5 1 5 . 1 1 1 5 . 2 8 1 6 . 1 1 1 6 . 3 3 1 7 . 4 9 1 7 . 9 1 1 8 . 0 9 1 8 . 3 1 1 8 . 8 9 1 8 . 9 9 1 9 . 0 7 1 9 . 2 9 1 9 . 4 2 1 9 . 5 6 1 9 . 6 6 1 9 . 8 2 1 9 . 9 4 2 0 . 0 8 2 0 . 1 7 2 0 . 2 9 2 0 . 4 1 2 0 . 4 8 2 0 . 6 9 2 0 . 7 3 2 0 . 9 1 2 1 . 1 8 2 1 . 6 1 2 2 . 1 0 2 4 . 1 3 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0015.RAW B14072051-007A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 60 of 117 B5 5-7 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-007A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0015.RAW Date & Time Acquired: 7/28/2014 4:19:17 PM Method File: G:\Org\VAR\Methods\140606M2051-7B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.217 2.5 2.419 96.74 - GRO Area:13345.61 GRO Amount: 0.3903294 TPH Area:22328.82 TPH Amount: 0.6530684 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:9949.996 C5-C8 Amount: 0.4281593 C9-C12 Area:10032.81 C9-C12 Amount: 0.3743896 5 . 0 9 6 . 4 1 6 . 5 1 6 . 6 4 7 . 4 2 7 . 7 6 7 . 7 8 8 . 3 0 8 . 9 3 9 . 2 2 9 . 6 1 9 . 8 5 1 0 . 1 5 1 0 . 2 0 1 0 . 9 3 1 1 . 1 9 1 1 . 3 6 1 2 . 0 0 1 2 . 9 4 1 3 . 1 6 1 3 . 5 4 1 3 . 6 1 1 3 . 9 4 1 4 . 3 7 1 5 . 1 1 1 5 . 2 8 1 5 . 4 0 1 5 . 6 8 1 6 . 0 1 1 6 . 1 1 1 6 . 3 2 1 6 . 5 9 1 7 . 4 9 1 7 . 9 1 1 8 . 0 9 1 8 . 3 0 1 8 . 7 6 1 8 . 8 8 1 8 . 9 9 1 9 . 0 7 1 9 . 4 2 1 9 . 5 5 1 9 . 6 6 1 9 . 7 8 1 9 . 8 2 1 9 . 9 4 2 0 . 0 5 2 0 . 3 0 2 0 . 4 8 2 0 . 6 8 2 0 . 7 3 2 0 . 9 1 2 1 . 1 8 2 1 . 6 1 2 2 . 4 2 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0015.RAW B14072051-007A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 61 of 117 B6 7-10 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-008A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0017.RAW Date & Time Acquired: 7/28/2014 5:29:02 PM Method File: G:\Org\VAR\Methods\140606M2051-8.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:2082.583 C9-C10 Aromatics Amount: 9.426151E-02 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.316 8.316 8.316 132 .05 U Toluene__________________11.364 11.364 11.364 232 .05 U Ethylbenzene_____________. . . .05 U m+p-Xylenes______________15.277 15.277 15.277 282 .05 U o-Xylene_________________16.118 16.118 16.118 111 .05 U 124-Trimethylbenzene_____18.094 18.094 18.094 142 .05 U Naphthalene______________21.181 21.181 21.181 85 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.217 2.5 2.6 103.98 70-130 3 . 2 5 3 . 6 0 4 . 3 8 4 . 6 1 6 . 4 2 6 . 6 5 7 . 8 6 8 . 3 2 9 . 2 2 9 . 8 1 1 0 . 3 7 1 0 . 9 2 1 1 . 0 9 1 1 . 1 9 1 1 . 3 6 1 1 . 7 7 1 2 . 4 8 1 5 . 2 8 1 6 . 1 2 1 8 . 0 9 1 8 . 7 5 1 9 . 4 3 2 0 . 0 4 2 0 . 1 9 2 0 . 3 0 2 0 . 4 9 2 0 . 5 9 2 0 . 6 6 2 0 . 7 2 2 1 . 1 8 2 1 . 5 6 2 1 . 6 0 2 2 . 4 2 2 2 . 7 5 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0017.RAW B14072051-008A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 62 of 117 B6 7-10 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-008A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0017.RAW Date & Time Acquired: 7/28/2014 5:29:02 PM Method File: G:\Org\VAR\Methods\140606M2051-8B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.217 2.5 2.502 100.09 - GRO Area:7319.668 GRO Amount: 0.2140841 TPH Area:13304.43 TPH Amount: 0.3891252 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:4981.004 C5-C8 Amount: 0.2143381 C9-C12 Area:6313.775 C9-C12 Amount: 0.235608 5 . 3 3 6 . 5 1 6 . 6 3 8 . 3 2 9 . 2 2 9 . 8 2 9 . 9 0 1 1 . 1 9 1 1 . 3 4 1 2 . 4 7 1 4 . 6 7 1 5 . 1 1 1 5 . 2 8 1 6 . 1 0 1 6 . 3 3 1 7 . 1 7 1 7 . 5 0 1 8 . 1 0 1 8 . 2 8 1 8 . 7 5 1 9 . 4 3 1 9 . 7 7 1 9 . 9 3 2 0 . 6 6 2 0 . 9 0 2 1 . 1 8 2 1 . 8 9 2 2 . 4 2 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0017.RAW B14072051-008A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 63 of 117 B7 8-10 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-009A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0020.RAW Date & Time Acquired: 7/28/2014 7:13:34 PM Method File: G:\Org\VAR\Methods\140606M2051-9.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:4292.467 C9-C10 Aromatics Amount: 0.1942849 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.323 8.323 8.323 98 .05 U Toluene__________________11.352 11.352 11.352 128 .05 U Ethylbenzene_____________. . . .05 U m+p-Xylenes______________15.272 15.272 15.272 187 .05 U o-Xylene_________________16.11 16.11 16.11 79 .05 U 124-Trimethylbenzene_____18.091 18.091 18.091 181 .05 U Naphthalene______________21.178 21.178 21.178 229 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.212 2.5 2.476 99.04 70-130 3 . 2 5 3 . 5 8 4 . 3 9 4 . 6 0 5 . 3 5 6 . 4 4 6 . 6 4 8 . 3 2 9 . 2 1 9 . 8 3 1 0 . 3 5 1 0 . 3 8 1 0 . 6 8 1 0 . 9 2 1 1 . 1 8 1 1 . 3 5 1 2 . 4 6 1 5 . 2 7 1 6 . 1 1 1 6 . 3 0 1 7 . 5 3 1 7 . 5 6 1 8 . 0 9 1 8 . 2 8 1 8 . 7 5 1 8 . 8 8 1 8 . 9 7 1 9 . 0 8 1 9 . 3 2 1 9 . 4 2 1 9 . 6 3 1 9 . 7 8 1 9 . 9 2 2 0 . 0 4 2 0 . 1 1 2 0 . 2 1 2 0 . 3 0 2 0 . 3 6 2 0 . 4 7 2 0 . 6 5 2 0 . 7 1 2 0 . 9 1 2 1 . 0 6 2 1 . 1 8 2 1 . 3 1 2 1 . 5 0 2 1 . 6 1 2 1 . 7 0 2 1 . 7 8 2 1 . 8 8 2 2 . 1 5 2 2 . 4 1 2 2 . 7 4 2 3 . 3 9 2 3 . 6 9 2 3 . 7 9 2 4 . 1 2 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0020.RAW B14072051-009A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 64 of 117 B7 8-10 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-009A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0020.RAW Date & Time Acquired: 7/28/2014 7:13:34 PM Method File: G:\Org\VAR\Methods\140606M2051-9B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.212 2.5 2.385 95.39 - GRO Area:6508.055 GRO Amount: 0.1903462 TPH Area:25479.18 TPH Amount: 0.7452096 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:4745.828 C5-C8 Amount: 0.2042182 C9-C12 Area:14370.05 C9-C12 Amount: 0.5362401 4 . 5 8 5 . 3 5 6 . 5 1 6 . 6 3 9 . 2 1 9 . 8 2 1 1 . 1 9 1 2 . 4 8 1 5 . 2 7 1 6 . 1 2 1 6 . 3 9 1 7 . 1 7 1 7 . 5 5 1 8 . 0 9 1 8 . 2 2 1 8 . 2 9 1 8 . 7 5 1 8 . 8 7 1 8 . 9 5 1 9 . 0 9 1 9 . 4 3 1 9 . 5 1 1 9 . 6 2 1 9 . 7 7 1 9 . 9 3 2 0 . 0 3 2 0 . 3 6 2 0 . 4 2 2 0 . 4 7 2 0 . 5 2 2 0 . 5 9 2 0 . 6 5 2 0 . 7 1 2 0 . 9 0 2 0 . 9 8 2 1 . 0 6 2 1 . 1 8 2 1 . 5 0 2 1 . 6 1 2 1 . 7 8 2 1 . 8 8 2 2 . 0 8 2 2 . 4 1 2 2 . 6 5 2 2 . 7 4 2 2 . 9 7 2 3 . 3 9 2 3 . 7 9 2 4 . 1 4 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0020.RAW B14072051-009A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 65 of 117 B8 9-11 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-010A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0023.RAW Date & Time Acquired: 7/28/2014 8:57:55 PM Method File: G:\Org\VAR\Methods\140606M2051-10.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:1965.85 C9-C10 Aromatics Amount: 8.897796E-02 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.314 8.314 8.314 140 .05 U Toluene__________________11.353 11.353 11.353 268 .05 U Ethylbenzene_____________. . . .05 U m+p-Xylenes______________15.272 15.272 15.272 266 .05 U o-Xylene_________________16.102 16.102 16.102 93 .05 U 124-Trimethylbenzene_____18.089 18.089 18.089 144 .05 U Naphthalene______________21.176 21.176 21.176 76 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.212 2.5 2.484 99.34 70-130 2 . 7 5 3 . 2 5 3 . 6 1 4 . 3 9 4 . 6 0 6 . 4 3 6 . 6 4 8 . 3 1 9 . 2 1 9 . 9 6 1 0 . 3 9 1 0 . 9 1 1 1 . 0 7 1 1 . 1 8 1 1 . 3 5 1 2 . 4 6 1 5 . 2 7 1 6 . 1 0 1 6 . 3 4 1 7 . 4 9 1 8 . 0 9 1 8 . 2 8 1 9 . 4 3 1 9 . 7 7 2 0 . 1 2 2 0 . 3 0 2 0 . 5 2 2 0 . 6 6 2 1 . 1 8 2 1 . 5 5 2 1 . 6 0 2 2 . 4 1 2 3 . 7 7 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0023.RAW B14072051-010A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 66 of 117 B8 9-11 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-010A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0023.RAW Date & Time Acquired: 7/28/2014 8:57:55 PM Method File: G:\Org\VAR\Methods\140606M2051-10B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.213 2.5 2.363 94.5 - GRO Area:8165.586 GRO Amount: 0.2388253 TPH Area:14691.24 TPH Amount: 0.4296863 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:6335.57 C5-C8 Amount: 0.2726265 C9-C12 Area:5855.958 C9-C12 Amount: 0.2185239 4 . 5 7 5 . 3 3 5 . 5 2 6 . 5 1 7 . 4 1 8 . 3 1 9 . 2 1 9 . 6 0 9 . 8 1 1 0 . 4 1 1 0 . 8 9 1 1 . 0 4 1 1 . 1 9 1 1 . 3 6 1 2 . 4 6 1 5 . 1 1 1 5 . 2 7 1 5 . 6 2 1 6 . 1 0 1 7 . 1 7 1 7 . 4 9 1 8 . 0 9 1 8 . 2 8 1 8 . 7 5 1 9 . 4 4 1 9 . 7 7 2 0 . 6 6 2 2 . 4 2 2 3 . 4 8 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0023.RAW B14072051-010A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 67 of 117 B9 5-7 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-011A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0026.RAW Date & Time Acquired: 7/28/2014 10:41:25 PM Method File: G:\Org\VAR\Methods\140606M2051-11.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:136860 C9-C10 Aromatics Amount: 6.194534 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.312 8.312 8.312 341 .05 U Toluene__________________11.353 11.353 11.353 314 .05 U Ethylbenzene_____________15.105 15.105 15.105 747 .05 U m+p-Xylenes______________15.272 -6.063 -6.058 3745 .144 o-Xylene_________________16.109 -6.897 -6.896 1127 .049 J 124-Trimethylbenzene_____18.09 -8.875 -8.877 9182 .431 Naphthalene______________21.185 -11.961 -11.971 7920 .359 NO pf7/29/14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.214 2.5 2.332 93.29 70-130 2 . 7 5 3 . 2 5 4 . 3 8 4 . 6 0 6 . 4 4 6 . 6 4 8 . 3 1 8 . 6 4 8 . 9 3 9 . 2 1 9 . 8 1 1 0 . 1 8 1 0 . 3 9 1 0 . 8 6 1 0 . 9 1 1 1 . 1 9 1 1 . 3 5 1 2 . 4 7 1 2 . 9 5 1 3 . 1 2 1 3 . 1 5 1 3 . 5 0 1 4 . 0 0 1 4 . 6 6 1 5 . 0 2 1 5 . 1 0 1 5 . 2 7 1 5 . 4 1 1 5 . 6 7 1 5 . 9 7 1 6 . 1 1 1 6 . 3 0 1 6 . 6 0 1 6 . 7 2 1 6 . 8 5 1 6 . 9 6 1 7 . 3 3 1 7 . 4 9 1 7 . 5 6 1 7 . 6 7 1 7 . 7 7 1 7 . 9 1 1 8 . 0 9 1 8 . 2 3 1 8 . 3 2 1 8 . 4 3 1 8 . 5 5 1 8 . 6 9 1 8 . 8 8 1 8 . 9 7 1 9 . 0 7 1 9 . 1 8 1 9 . 3 2 1 9 . 4 2 1 9 . 4 9 1 9 . 5 5 1 9 . 6 4 1 9 . 8 2 1 9 . 9 0 1 9 . 9 9 2 0 . 0 5 2 0 . 1 0 2 0 . 1 6 2 0 . 2 2 2 0 . 3 0 2 0 . 3 7 2 0 . 4 1 2 0 . 4 7 2 0 . 6 5 2 0 . 7 3 2 0 . 8 4 2 0 . 9 1 2 0 . 9 9 2 1 . 0 7 2 1 . 1 8 2 1 . 3 1 2 1 . 5 0 2 1 . 6 1 2 1 . 6 4 2 1 . 7 0 2 1 . 7 8 2 1 . 8 9 2 2 . 1 0 2 2 . 1 4 2 2 . 4 1 2 2 . 6 5 2 2 . 7 5 2 2 . 9 4 2 3 . 0 9 2 3 . 2 0 2 3 . 3 3 2 3 . 3 9 2 3 . 5 2 2 3 . 6 9 2 3 . 7 9 2 3 . 9 5 2 4 . 1 2 2 4 . 2 9 2 4 . 4 6 2 4 . 6 1 2 4 . 7 1 2 4 . 9 4 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0026.RAW B14072051-011A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 68 of 117 B9 5-7 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-011A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0026.RAW Date & Time Acquired: 7/28/2014 10:41:25 PM Method File: G:\Org\VAR\Methods\140606M2051-11N.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:57567.88 C9-C10 Aromatics Amount: 2.605627 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.312 8.312 8.312 341 .05 U Toluene__________________11.353 11.353 11.353 314 .05 U Ethylbenzene_____________15.105 15.105 15.105 691 .05 U m+p-Xylenes______________15.272 -6.063 -6.058 3635 .139 o-Xylene_________________16.109 -6.897 -6.896 847 .037 J 124-Trimethylbenzene_____18.09 -8.875 -8.877 7838 .368 Naphthalene______________21.185 21.185 21.185 1513 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.214 2.5 2.332 93.29 70-130 2 . 7 5 3 . 2 5 4 . 3 8 4 . 6 0 6 . 4 4 6 . 6 4 8 . 3 1 8 . 6 4 8 . 9 3 9 . 2 1 9 . 8 1 1 0 . 1 8 1 0 . 3 9 1 0 . 8 6 1 0 . 9 1 1 1 . 1 9 1 1 . 3 5 1 2 . 4 7 1 2 . 9 5 1 3 . 1 2 1 3 . 1 5 1 3 . 5 0 1 4 . 0 0 1 4 . 6 6 1 5 . 0 2 1 5 . 1 0 1 5 . 2 7 1 5 . 4 1 1 5 . 6 7 1 5 . 9 7 1 6 . 1 1 1 6 . 3 0 1 6 . 6 0 1 6 . 7 2 1 6 . 9 6 1 7 . 3 3 1 7 . 4 9 1 7 . 5 6 1 7 . 6 7 1 7 . 7 7 1 7 . 9 1 1 8 . 0 9 1 8 . 2 3 1 8 . 3 2 1 8 . 4 3 1 8 . 5 5 1 8 . 6 9 1 8 . 8 8 1 8 . 9 7 1 9 . 0 7 1 9 . 1 8 1 9 . 3 2 1 9 . 4 2 1 9 . 4 9 1 9 . 5 5 1 9 . 6 4 1 9 . 8 2 1 9 . 9 0 1 9 . 9 9 2 0 . 0 5 2 0 . 1 0 2 0 . 1 6 2 0 . 2 2 2 0 . 3 0 2 0 . 3 7 2 0 . 4 1 2 0 . 4 7 2 0 . 6 5 2 0 . 7 3 2 0 . 8 4 2 0 . 9 1 2 0 . 9 9 2 1 . 0 7 2 1 . 1 8 2 1 . 3 1 2 1 . 5 0 2 1 . 6 1 2 1 . 6 4 2 1 . 7 0 2 1 . 7 8 2 1 . 8 9 2 2 . 1 0 2 2 . 1 4 2 2 . 4 1 2 2 . 6 5 2 2 . 7 5 2 2 . 9 4 2 3 . 0 9 2 3 . 2 0 2 3 . 3 3 2 3 . 3 9 2 3 . 5 2 2 3 . 6 9 2 3 . 7 9 2 3 . 9 5 2 4 . 1 2 2 4 . 2 9 2 4 . 4 6 2 4 . 6 1 2 4 . 7 1 2 4 . 9 4 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0026.RAW B14072051-011A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 69 of 117 B9 5-7 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-011A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0026.RAW Date & Time Acquired: 7/28/2014 10:41:25 PM Method File: G:\Org\VAR\Methods\140606M2051-11B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.214 2.5 2.29 91.59 - GRO Area:48234.55 GRO Amount: 1.410754 TPH Area:650528.1 TPH Amount: 19.02651 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:12294.5 C5-C8 Amount: 0.529046 C9-C12 Area:289789.2 C9-C12 Amount: 10.81392 4 . 6 0 5 . 0 9 5 . 3 3 5 . 7 0 6 . 6 3 7 . 2 1 7 . 4 6 7 . 7 8 8 . 0 9 8 . 3 2 9 . 2 1 1 0 . 1 1 1 0 . 8 0 1 0 . 8 8 1 1 . 1 0 1 1 . 1 9 1 1 . 3 6 1 1 . 5 1 1 1 . 7 1 1 2 . 0 3 1 2 . 4 8 1 2 . 7 4 1 2 . 8 6 1 2 . 9 5 1 3 . 0 2 1 3 . 1 4 1 3 . 4 6 1 3 . 5 3 1 3 . 9 6 1 4 . 6 8 1 5 . 1 1 1 5 . 2 7 1 5 . 4 0 1 5 . 6 7 1 5 . 9 7 1 6 . 1 1 1 6 . 3 6 1 6 . 6 0 1 6 . 7 2 1 6 . 8 5 1 6 . 9 6 1 7 . 1 8 1 7 . 3 4 1 7 . 4 9 1 7 . 5 5 1 7 . 6 7 1 7 . 7 7 1 7 . 9 1 1 8 . 0 9 1 8 . 2 2 1 8 . 3 3 1 8 . 4 3 1 8 . 5 5 1 8 . 6 9 1 8 . 7 7 1 8 . 8 8 1 8 . 9 7 1 9 . 0 8 1 9 . 1 8 1 9 . 3 1 1 9 . 4 2 1 9 . 4 8 1 9 . 6 3 1 9 . 8 1 1 9 . 9 1 2 0 . 0 4 2 0 . 2 2 2 0 . 3 0 2 0 . 3 7 2 0 . 4 2 2 0 . 4 8 2 0 . 6 5 2 0 . 7 3 2 0 . 8 4 2 0 . 9 1 2 0 . 9 9 2 1 . 0 7 2 1 . 1 9 2 1 . 3 1 2 1 . 5 0 2 1 . 6 1 2 1 . 7 0 2 1 . 7 8 2 1 . 8 9 2 2 . 1 0 2 2 . 1 4 2 2 . 3 6 2 2 . 4 1 2 2 . 6 5 2 2 . 7 6 2 2 . 9 4 2 3 . 0 9 2 3 . 1 9 2 3 . 3 4 2 3 . 5 3 2 3 . 6 9 2 3 . 7 9 2 4 . 1 2 2 4 . 3 0 2 4 . 4 7 2 4 . 6 1 2 4 . 7 1 2 4 . 9 4 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0026.RAW B14072051-011A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 70 of 117 B9 8-11 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-012A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0029.RAW Date & Time Acquired: 7/29/2014 12:25:30 AM Method File: G:\Org\VAR\Methods\140606M2051-12.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:126243.9 C9-C10 Aromatics Amount: 5.714031 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.314 8.314 8.314 364 .05 U Toluene__________________11.357 11.357 11.357 325 .05 U Ethylbenzene_____________15.106 -5.899 -5.893 897 .04 J m+p-Xylenes______________15.271 -6.063 -6.058 5487 .21 o-Xylene_________________16.109 -6.897 -6.896 1425 .062 124-Trimethylbenzene_____18.089 -8.875 -8.876 10935 .514 Naphthalene______________21.184 -11.961 -11.971 5998 .272 NO pf7/29/14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.213 2.5 2.39 95.61 70-130 3 . 2 5 4 . 6 0 6 . 4 4 6 . 6 4 7 . 4 3 8 . 3 1 9 . 2 1 9 . 8 3 1 0 . 3 7 1 1 . 2 0 1 1 . 3 6 1 2 . 9 3 1 3 . 1 0 1 3 . 1 5 1 3 . 5 0 1 4 . 6 7 1 5 . 0 0 1 5 . 1 1 1 5 . 2 7 1 5 . 4 1 1 5 . 6 7 1 5 . 9 7 1 6 . 1 1 1 6 . 3 0 1 6 . 3 3 1 6 . 5 9 1 6 . 7 2 1 6 . 8 6 1 6 . 9 6 1 7 . 3 3 1 7 . 4 9 1 7 . 5 6 1 7 . 6 7 1 7 . 7 7 1 7 . 9 1 1 8 . 0 9 1 8 . 2 2 1 8 . 3 2 1 8 . 4 3 1 8 . 5 1 1 8 . 5 4 1 8 . 6 9 1 8 . 8 8 1 8 . 9 6 1 9 . 0 6 1 9 . 1 8 1 9 . 3 1 1 9 . 4 1 1 9 . 4 9 1 9 . 5 5 1 9 . 6 5 1 9 . 8 1 1 9 . 9 0 1 9 . 9 9 2 0 . 1 0 2 0 . 1 6 2 0 . 2 1 2 0 . 3 0 2 0 . 3 7 2 0 . 4 1 2 0 . 4 7 2 0 . 6 5 2 0 . 7 3 2 0 . 8 3 2 0 . 9 1 2 0 . 9 9 2 1 . 0 7 2 1 . 1 8 2 1 . 3 1 2 1 . 5 0 2 1 . 6 0 2 1 . 7 1 2 1 . 7 8 2 1 . 8 9 2 2 . 0 9 2 2 . 1 4 2 2 . 3 6 2 2 . 4 1 2 2 . 6 3 2 2 . 7 5 2 2 . 8 0 2 2 . 9 3 2 3 . 0 8 2 3 . 2 0 2 3 . 3 2 2 3 . 3 9 2 3 . 5 4 2 3 . 6 9 2 3 . 7 9 2 3 . 9 4 2 4 . 1 1 2 4 . 2 9 2 4 . 4 6 2 4 . 6 1 2 4 . 7 0 2 4 . 9 3 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0029.RAW B14072051-012A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 71 of 117 B9 8-11 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-012A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0029.RAW Date & Time Acquired: 7/29/2014 12:25:30 AM Method File: G:\Org\VAR\Methods\140606M2051-12N.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:57620.62 C9-C10 Aromatics Amount: 2.608015 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.314 8.314 8.314 364 .05 U Toluene__________________11.357 11.357 11.357 325 .05 U Ethylbenzene_____________15.106 -5.899 -5.893 887 .04 J m+p-Xylenes______________15.271 -6.063 -6.058 5433 .208 o-Xylene_________________16.109 -6.897 -6.896 1187 .052 124-Trimethylbenzene_____18.089 -8.875 -8.876 9580 .45 Naphthalene______________21.184 21.184 21.184 1015 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.213 2.5 2.39 95.61 70-130 3 . 2 5 4 . 6 0 6 . 4 4 6 . 6 4 7 . 4 3 8 . 3 1 9 . 2 1 9 . 8 3 1 0 . 3 7 1 1 . 2 0 1 1 . 3 6 1 2 . 9 3 1 3 . 1 0 1 3 . 1 5 1 3 . 5 0 1 4 . 6 7 1 5 . 0 0 1 5 . 1 1 1 5 . 2 7 1 5 . 4 1 1 5 . 6 7 1 5 . 9 7 1 6 . 1 1 1 6 . 3 0 1 6 . 3 3 1 6 . 5 9 1 6 . 7 2 1 6 . 8 6 1 6 . 9 6 1 7 . 3 3 1 7 . 4 9 1 7 . 5 6 1 7 . 6 7 1 7 . 7 7 1 7 . 9 1 1 8 . 0 9 1 8 . 2 2 1 8 . 3 2 1 8 . 4 3 1 8 . 5 1 1 8 . 5 4 1 8 . 6 9 1 8 . 8 8 1 8 . 9 6 1 9 . 0 6 1 9 . 1 8 1 9 . 3 1 1 9 . 4 1 1 9 . 4 9 1 9 . 5 5 1 9 . 6 5 1 9 . 8 1 1 9 . 9 0 1 9 . 9 9 2 0 . 1 0 2 0 . 1 6 2 0 . 2 1 2 0 . 3 0 2 0 . 3 7 2 0 . 4 1 2 0 . 4 7 2 0 . 6 5 2 0 . 7 3 2 0 . 8 3 2 0 . 9 1 2 0 . 9 9 2 1 . 0 7 2 1 . 1 8 2 1 . 3 1 2 1 . 5 0 2 1 . 6 0 2 1 . 7 1 2 1 . 7 8 2 1 . 8 9 2 2 . 0 9 2 2 . 1 4 2 2 . 3 6 2 2 . 4 1 2 2 . 6 3 2 2 . 7 5 2 2 . 8 0 2 2 . 9 3 2 3 . 0 8 2 3 . 2 0 2 3 . 3 2 2 3 . 3 9 2 3 . 5 4 2 3 . 6 9 2 3 . 7 9 2 3 . 9 4 2 4 . 1 1 2 4 . 2 9 2 4 . 4 6 2 4 . 6 1 2 4 . 7 0 2 4 . 9 3 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0029.RAW B14072051-012A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 72 of 117 B9 8-11 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-012A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0029.RAW Date & Time Acquired: 7/29/2014 12:25:30 AM Method File: G:\Org\VAR\Methods\140606M2051-12B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.214 2.5 2.366 94.66 - GRO Area:50978.07 GRO Amount: 1.490996 TPH Area:518425.8 TPH Amount: 15.1628 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:13472.15 C5-C8 Amount: 0.5797213 C9-C12 Area:267582.1 C9-C12 Amount: 9.985229 4 . 6 0 5 . 0 9 5 . 3 3 5 . 7 0 6 . 5 1 6 . 6 4 7 . 2 1 7 . 4 6 8 . 0 9 8 . 3 1 9 . 2 1 9 . 8 3 1 0 . 1 1 1 0 . 8 9 1 1 . 2 0 1 1 . 3 6 1 1 . 7 6 1 2 . 0 5 1 2 . 1 0 1 2 . 4 8 1 2 . 7 3 1 2 . 9 8 1 3 . 1 6 1 3 . 5 3 1 3 . 9 9 1 4 . 6 7 1 5 . 1 1 1 5 . 2 7 1 5 . 6 7 1 5 . 8 9 1 5 . 9 6 1 6 . 1 1 1 6 . 3 6 1 6 . 6 0 1 6 . 7 2 1 6 . 8 6 1 6 . 9 6 1 7 . 1 8 1 7 . 3 4 1 7 . 4 9 1 7 . 5 5 1 7 . 6 7 1 7 . 7 7 1 7 . 9 1 1 8 . 0 9 1 8 . 2 2 1 8 . 3 2 1 8 . 4 3 1 8 . 5 0 1 8 . 6 9 1 8 . 8 8 1 8 . 9 7 1 9 . 0 7 1 9 . 1 8 1 9 . 3 0 1 9 . 4 2 1 9 . 4 9 1 9 . 5 5 1 9 . 6 5 1 9 . 8 1 1 9 . 9 1 1 9 . 9 9 2 0 . 0 4 2 0 . 1 0 2 0 . 2 2 2 0 . 3 0 2 0 . 3 7 2 0 . 4 1 2 0 . 4 7 2 0 . 6 5 2 0 . 7 3 2 0 . 8 3 2 0 . 9 1 2 0 . 9 9 2 1 . 0 7 2 1 . 1 9 2 1 . 3 1 2 1 . 5 0 2 1 . 6 1 2 1 . 7 0 2 1 . 7 8 2 1 . 8 9 2 2 . 1 0 2 2 . 3 6 2 2 . 4 1 2 2 . 6 4 2 2 . 7 6 2 2 . 9 4 2 3 . 0 2 2 3 . 0 9 2 3 . 2 0 2 3 . 3 3 2 3 . 5 4 2 3 . 7 0 2 3 . 7 9 2 4 . 1 2 2 4 . 3 0 2 4 . 4 4 2 4 . 6 1 2 4 . 7 2 2 4 . 9 3 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0029.RAW B14072051-012A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 73 of 117 B10 7-8 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-013A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0032.RAW Date & Time Acquired: 7/29/2014 2:08:28 AM Method File: G:\Org\VAR\Methods\140606M2051-13.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:1882.874 C9-C10 Aromatics Amount: 8.522233E-02 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.317 8.317 8.317 96 .05 U Toluene__________________11.365 11.365 11.365 65 .05 U Ethylbenzene_____________. . . .05 U m+p-Xylenes______________15.275 15.275 15.275 206 .05 U o-Xylene_________________16.114 16.114 16.114 68 .05 U 124-Trimethylbenzene_____18.092 18.092 18.092 241 .05 U Naphthalene______________21.178 21.178 21.178 122 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.214 2.5 2.31 92.38 70-130 2 . 7 5 3 . 2 4 4 . 5 9 6 . 6 5 8 . 3 2 9 . 2 1 9 . 8 3 1 0 . 3 8 1 0 . 9 2 1 1 . 1 8 1 1 . 3 6 1 5 . 2 8 1 6 . 1 1 1 7 . 4 8 1 7 . 5 6 1 8 . 0 9 1 8 . 7 0 1 8 . 9 7 1 9 . 3 1 2 0 . 4 8 2 0 . 6 5 2 1 . 0 2 2 1 . 0 6 2 1 . 1 8 2 1 . 6 3 2 3 . 8 0 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0032.RAW B14072051-013A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 74 of 117 B10 7-8 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-013A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0032.RAW Date & Time Acquired: 7/29/2014 2:08:28 AM Method File: G:\Org\VAR\Methods\140606M2051-13B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.215 2.5 2.237 89.47 - GRO Area:2216.973 GRO Amount: 6.484154E-02 TPH Area:5598.699 TPH Amount: 0.1637495 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:1342.734 C5-C8 Amount: 5.777933E-02 C9-C12 Area:3052.365 C9-C12 Amount: 0.1139036 9 . 2 1 1 5 . 2 8 1 7 . 4 8 1 8 . 0 9 2 1 . 0 6 2 1 . 1 8 2 1 . 6 2 2 1 . 8 8 2 2 . 4 4 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0032.RAW B14072051-013A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 75 of 117 B8 3-4 Batch ID: 81647 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-014A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VAR.0035.RAW Date & Time Acquired: 7/29/2014 3:51:16 AM Method File: G:\Org\VAR\Methods\140606M2051-14.MET Calibration File: G:\Org\VAR\Cals\140606MAS.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 441.8734 Rt range for C9 to C10 Aromatics: 16.215 to 21.139 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:1096.984 C9-C10 Aromatics Amount: 4.965151E-02 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . .1 U Benzene__________________8.308 8.308 8.308 113 .05 U Toluene__________________11.365 11.365 11.365 116 .05 U Ethylbenzene_____________. . . .05 U m+p-Xylenes______________15.271 15.271 15.271 182 .05 U o-Xylene_________________. . . .05 U 124-Trimethylbenzene_____18.096 18.096 18.096 94 .05 U Naphthalene______________21.187 21.187 21.187 75 .1 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______9.214 2.5 2.193 87.71 70-130 3 . 2 4 4 . 6 0 6 . 4 5 6 . 6 5 7 . 8 8 8 . 3 1 9 . 2 1 9 . 8 1 1 0 . 3 9 1 0 . 9 1 1 1 . 1 8 1 1 . 3 6 1 5 . 2 7 1 8 . 1 0 1 8 . 7 5 2 0 . 5 2 2 1 . 1 9 2 2 . 7 0 2 3 . 3 1 2 3 . 7 7 2 3 . 9 8 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VAR.0035.RAW B14072051-014A ;0728VAR , $HC-VPH-MA-S, 2 4 6 8 10 12 14 16 18 20 22 24 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Page 76 of 117 B8 3-4 Batch ID: 81647 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14072051-014A ;0728VAR , $HC-VPH-MA-S, Raw File: G:\Org\VAR\DAT\VAR072814_b\0728VARB.0035.RAW Date & Time Acquired: 7/29/2014 3:51:16 AM Method File: G:\Org\VAR\Methods\140606M2051-14B.MET Calibration File: G:\Org\VAR\Cals\140606MASB.CAL Sample Weight: 50 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 464.7802 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 535.9558 Mean RF for all calibrated compounds: 683.8125 Rt range for Gasoline Range Organics: 4.999 to 17.28 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.979 to 14.584 Rt range for C9 to C12 Aliphatic Hydrocarbons: 14.634 to 21.14 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________9.214 2.5 2.081 83.25 - GRO Area:2593.105 GRO Amount: 7.584259E-02 TPH Area:4594.719 TPH Amount: 0.1343853 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:1990.223 C5-C8 Amount: 8.564146E-02 C9-C12 Area:2250.64 C9-C12 Amount: 8.398604E-02 8 . 3 3 9 . 2 1 9 . 8 4 1 0 . 8 8 1 1 . 2 2 1 1 . 3 6 1 5 . 2 7 1 8 . 0 9 1 8 . 2 8 1 8 . 7 6 1 9 . 7 7 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\VAR\DAT\VAR072814_b\0728VARB.0035.RAW B14072051-014A ;0728VAR , $HC-VPH-MA-S, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 77 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW8015M Batch: 81615 Lab ID: LCS-81615 07/25/14 11:33 Laboratory Control Sample Run: GCFID-HP3-B_140724C 2 Total Extractable Hydrocarbons 110 60 140 10 226 mg/kg Surr: o-Terphenyl 104 40 140 0.17 Lab ID: MB-81615 07/25/14 12:19 Method Blank Run: GCFID-HP3-B_140724C 2 Total Extractable Hydrocarbons 10 ND mg/kg Surr: o-Terphenyl 96 40 140 0.17 Lab ID: B14071970-001AMS 07/25/14 13:51 Sample Duplicate Run: GCFID-HP3-B_140724C 2 Total Extractable Hydrocarbons 60 140 20 11 11 1430 mg/kg-dry Surr: o-Terphenyl 111 40 140 0.19 Lab ID: B14071970-001AMSD 07/25/14 14:36 Sample Duplicate Run: GCFID-HP3-B_140724C 2 Total Extractable Hydrocarbons 60 140 20 11 2.6 1550 mg/kg-dry Surr: o-Terphenyl 111 40 140 0.19 - Because the sample amount was significantly higher than the spike amount, the MS and MSD spike samples are calculated as Duplicate samples based on the spike amount added plus the original sample concentration. Method: SW8015M Batch: 81681 Lab ID: LCS-81681 07/26/14 07:27 Laboratory Control Sample Run: GCFID-HP3-B_140724C 2 Total Extractable Hydrocarbons 86 60 140 10 176 mg/kg Surr: o-Terphenyl 91 40 140 0.17 Lab ID: MB-81681 07/26/14 08:13 Method Blank Run: GCFID-HP3-B_140724C 2 Total Extractable Hydrocarbons 10 ND mg/kg Surr: o-Terphenyl 91 40 140 0.17 Lab ID: B14072101-001AMS 07/27/14 11:32 Sample Duplicate Run: GCFID-HP3-B_140727A 2 Total Extractable Hydrocarbons 60 140 20 220 10 2270 mg/kg-dry Surr: o-Terphenyl 82 40 140 3.7 Lab ID: B14072101-001AMSD 07/27/14 12:18 Sample Duplicate Run: GCFID-HP3-B_140727A 2 Total Extractable Hydrocarbons 60 140 20 220 13 2220 mg/kg-dry Surr: o-Terphenyl 87 40 140 3.7 - Because the sample amount was significantly higher than the spike amount, the MS and MSD spike samples are calculated as Duplicate samples based on the spike amount added plus the original sample concentration. Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 78 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW8015M Analytical Run: R227772 Lab ID: CCV_0724HP342r-S 07/25/14 21:33 Continuing Calibration Verification Standard 15 n-Nonane 107 75 125 7.13 mg/kg n-Decane 106 75 125 7.09 mg/kg n-Dodecane 104 75 125 6.96 mg/kg n-Tetradecane 103 75 125 6.88 mg/kg n-Hexadecane 105 75 125 6.98 mg/kg n-Octadecane 105 75 125 7.00 mg/kg n-Nonadecane 105 75 125 7.03 mg/kg n-Eicosane 105 75 125 7.01 mg/kg n-Docosane 105 75 125 7.02 mg/kg n-Tetracosane 106 75 125 7.05 mg/kg n-Hexacosane 106 75 125 7.08 mg/kg n-Octacosane 106 75 125 7.05 mg/kg n-Triacontane 106 75 125 7.10 mg/kg n-Hexatriacontane 105 75 125 6.99 mg/kg Surr: o-Terphenyl 107 75 125 0.17 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 79 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW8015M Analytical Run: R227784 Lab ID: CCV_0727HP301r-S 07/26/14 22:32 Continuing Calibration Verification Standard 15 n-Nonane 104 75 125 6.92 mg/kg n-Decane 104 75 125 6.94 mg/kg n-Dodecane 103 75 125 6.86 mg/kg n-Tetradecane 102 75 125 6.78 mg/kg n-Hexadecane 103 75 125 6.86 mg/kg n-Octadecane 103 75 125 6.86 mg/kg n-Nonadecane 103 75 125 6.88 mg/kg n-Eicosane 103 75 125 6.87 mg/kg n-Docosane 103 75 125 6.87 mg/kg n-Tetracosane 104 75 125 6.91 mg/kg n-Hexacosane 104 75 125 6.92 mg/kg n-Octacosane 103 75 125 6.89 mg/kg n-Triacontane 104 75 125 6.94 mg/kg n-Hexatriacontane 102 75 125 6.83 mg/kg Surr: o-Terphenyl 105 75 125 0.17 Lab ID: CCV_0727HP316r-S 07/27/14 10:01 Continuing Calibration Verification Standard 15 n-Nonane 104 75 125 6.91 mg/kg n-Decane 104 75 125 6.91 mg/kg n-Dodecane 102 75 125 6.83 mg/kg n-Tetradecane 102 75 125 6.78 mg/kg n-Hexadecane 103 75 125 6.86 mg/kg n-Octadecane 103 75 125 6.87 mg/kg n-Nonadecane 103 75 125 6.89 mg/kg n-Eicosane 103 75 125 6.88 mg/kg n-Docosane 103 75 125 6.88 mg/kg n-Tetracosane 104 75 125 6.90 mg/kg n-Hexacosane 104 75 125 6.92 mg/kg n-Octacosane 103 75 125 6.90 mg/kg n-Triacontane 104 75 125 6.95 mg/kg n-Hexatriacontane 103 75 125 6.87 mg/kg Surr: o-Terphenyl 105 75 125 0.17 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 80 of 117 B1 3-4 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-001A ;0724HP3 , $HC-EPH-SCRN-S, V44 Raw File: G:\org\HP3\DAT\HP3072414_b\0724HP3.0044.RAW Date & Time Acquired: 7/25/2014 11:04:49 PM Method File: g:\org\HP3\Methods\SR_SCN-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.429 6.667 6.313 94.69 - *1-Chloro-octadecane_____13.249 6.667 6.891 103.37 - DRO Area:470529.3 DRO Amount: 1.01231 TEH Area:1206576 TEH Amount: 2.595863 C9-C18 Area:643083.5 C9-C18 Amount: 1.383887 C19-C36 Area:352365.8 C19-C36 Amount: 0.7579042 4 . 2 2 4 . 4 1 4 . 5 2 4 . 7 1 4 . 8 0 4 . 8 8 4 . 9 9 5 . 1 0 5 . 2 5 5 . 3 3 5 . 4 8 5 . 5 6 5 . 6 5 5 . 7 3 5 . 8 3 5 . 9 2 6 . 0 5 6 . 1 5 6 . 2 6 6 . 4 5 6 . 5 2 6 . 9 9 7 . 0 7 7 . 1 2 7 . 2 1 7 . 2 6 7 . 3 9 7 . 4 5 7 . 4 9 7 . 5 5 7 . 8 2 8 . 3 9 8 . 5 5 8 . 6 7 8 . 7 8 8 . 8 2 8 . 8 7 8 . 9 2 9 . 0 5 9 . 1 5 9 . 3 3 9 . 4 6 9 . 5 7 9 . 6 1 9 . 6 7 9 . 8 3 1 0 . 1 7 1 0 . 2 7 1 0 . 3 3 1 0 . 4 3 1 0 . 4 9 1 0 . 5 3 1 0 . 6 1 1 0 . 7 9 1 0 . 9 2 1 1 . 0 5 1 1 . 2 5 1 1 . 3 2 1 1 . 3 8 1 1 . 4 8 1 1 . 5 5 1 1 . 6 1 1 1 . 6 7 1 1 . 8 4 1 1 . 9 8 1 2 . 0 1 1 2 . 0 9 1 2 . 1 7 1 2 . 2 8 1 2 . 3 4 1 2 . 4 3 1 2 . 5 6 1 2 . 6 5 1 2 . 7 7 1 2 . 8 2 1 2 . 9 1 1 2 . 9 9 1 3 . 1 2 1 3 . 2 5 1 3 . 4 8 1 3 . 5 8 1 3 . 7 3 1 3 . 9 3 1 3 . 9 7 1 4 . 0 4 1 4 . 0 8 1 4 . 1 5 1 4 . 4 4 1 4 . 5 2 1 4 . 5 6 1 4 . 7 1 1 4 . 8 9 1 4 . 9 5 1 5 . 1 9 1 5 . 2 4 1 5 . 3 4 1 5 . 4 8 1 5 . 6 2 1 5 . 7 1 1 5 . 9 7 1 6 . 0 5 1 6 . 2 0 1 6 . 4 1 1 6 . 4 8 1 6 . 7 3 1 6 . 8 4 1 6 . 8 8 1 7 . 0 5 1 7 . 0 8 1 7 . 1 4 1 7 . 2 2 1 7 . 2 8 1 7 . 3 2 1 7 . 5 8 1 7 . 7 3 1 7 . 7 9 1 7 . 8 5 1 7 . 9 2 1 8 . 1 0 1 8 . 2 5 1 8 . 3 6 1 8 . 5 9 1 8 . 6 8 1 8 . 7 7 1 8 . 9 4 1 9 . 1 6 1 9 . 3 1 1 9 . 4 7 1 9 . 7 9 2 0 . 0 3 2 0 . 1 9 2 1 . 2 1 2 2 . 1 7 2 4 . 8 0 2 8 . 4 7 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072414_b\0724HP3.0044.RAW B14072051-001A ;0724HP3 , $HC-EPH-SCRN-S, V44 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 81 of 117 B1 6-7 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-002A ;0724HP3 , $HC-EPH-SCRN-S, V49 Raw File: G:\org\HP3\DAT\HP3072414_b\0724HP3.0049.RAW Date & Time Acquired: 7/26/2014 2:52:27 AM Method File: g:\org\HP3\Methods\SR_SCN-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.43 6.667 6.188 92.82 - *1-Chloro-octadecane_____13.249 6.667 6.667 100. - DRO Area:314323.3 DRO Amount: 0.6762441 TEH Area:888828.3 TEH Amount: 1.912251 C9-C18 Area:564713.6 C9-C18 Amount: 1.215239 C19-C36 Area:155254.3 C19-C36 Amount: 0.3339367 4 . 2 2 4 . 4 1 4 . 5 3 4 . 7 1 4 . 8 0 4 . 8 9 5 . 0 0 5 . 1 0 5 . 2 5 5 . 3 3 5 . 4 7 5 . 5 6 5 . 6 5 5 . 7 0 5 . 8 3 5 . 9 2 6 . 0 6 6 . 1 6 6 . 2 7 6 . 4 6 6 . 5 2 6 . 6 2 6 . 6 7 6 . 8 6 7 . 0 1 7 . 0 8 7 . 1 2 7 . 2 1 7 . 2 6 7 . 3 9 7 . 4 5 7 . 5 6 7 . 8 2 8 . 0 1 8 . 4 0 8 . 4 9 8 . 7 1 8 . 7 8 8 . 8 3 8 . 8 7 8 . 9 6 9 . 0 5 9 . 0 9 9 . 3 3 9 . 4 6 9 . 6 7 9 . 8 2 1 0 . 1 7 1 0 . 2 7 1 0 . 4 3 1 0 . 5 4 1 0 . 6 1 1 0 . 8 0 1 1 . 0 6 1 1 . 3 2 1 1 . 3 8 1 1 . 4 8 1 1 . 6 1 1 1 . 6 8 1 1 . 8 2 1 1 . 8 9 1 1 . 9 7 1 2 . 0 9 1 2 . 2 8 1 2 . 3 5 1 2 . 4 3 1 2 . 6 6 1 2 . 7 7 1 2 . 9 1 1 2 . 9 9 1 3 . 2 5 1 3 . 5 0 1 3 . 5 8 1 3 . 6 8 1 4 . 0 9 1 4 . 1 5 1 4 . 4 5 1 4 . 5 3 1 4 . 5 6 1 4 . 9 6 1 5 . 1 9 1 5 . 2 6 1 5 . 3 4 1 5 . 5 7 1 5 . 7 1 1 5 . 9 9 1 6 . 0 6 1 6 . 2 0 1 6 . 4 0 1 6 . 8 9 1 7 . 0 5 1 7 . 0 8 1 7 . 3 3 1 7 . 5 9 1 7 . 7 3 1 7 . 8 5 1 7 . 9 2 1 8 . 1 1 1 8 . 1 5 1 8 . 2 6 1 8 . 3 6 1 8 . 6 0 1 8 . 6 9 1 9 . 1 6 1 9 . 3 7 1 9 . 4 6 1 9 . 6 0 2 0 . 1 9 2 7 . 1 2 2 7 . 3 0 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072414_b\0724HP3.0049.RAW B14072051-002A ;0724HP3 , $HC-EPH-SCRN-S, V49 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 82 of 117 B2 3-4 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-003A ;0727HP3 , $HC-EPH-SCRN-S, V88,(2,20) Raw File: G:\org\HP3\DAT\HP3072714_b\0727HP3.0021.RAW Date & Time Acquired: 7/27/2014 1:49:03 PM Method File: g:\org\HP3\Methods\SR_SCN-072721-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 40 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.436 6.667 6.049 90.73 - *1-Chloro-octadecane_____13.253 6.667 5.947 89.2 - DRO Area:2571085 DRO Amount: 110.6301 TEH Area:1.030471E+07 TEH Amount: 443.3968 C9-C18 Area:54554.41 C9-C18 Amount: 2.347973 C19-C36 Area:7355034 C19-C36 Amount: 316.3992 4 . 3 0 4 . 3 7 4 . 4 2 4 . 5 3 4 . 7 5 4 . 8 1 4 . 9 0 5 . 1 0 7 . 5 9 7 . 8 3 8 . 7 9 8 . 9 8 9 . 0 5 9 . 2 3 9 . 3 1 9 . 6 2 9 . 9 6 1 0 . 0 2 1 0 . 1 4 1 0 . 2 0 1 0 . 3 2 1 0 . 4 3 1 0 . 5 2 1 0 . 5 7 1 0 . 6 5 1 0 . 7 8 1 0 . 8 8 1 1 . 0 4 1 1 . 1 2 1 1 . 3 5 1 1 . 5 6 1 1 . 7 2 1 1 . 8 5 1 2 . 1 0 1 2 . 2 1 1 2 . 3 5 1 2 . 4 4 1 2 . 6 1 1 2 . 6 8 1 2 . 8 3 1 3 . 0 0 1 3 . 2 5 1 3 . 5 1 1 3 . 6 0 1 3 . 6 4 1 3 . 6 7 1 3 . 7 3 1 4 . 0 7 1 4 . 1 6 1 4 . 3 4 1 4 . 4 6 1 4 . 5 6 1 4 . 6 6 1 4 . 7 2 1 4 . 8 1 1 4 . 8 5 1 4 . 9 6 1 5 . 2 0 1 5 . 2 7 1 5 . 3 4 1 5 . 3 9 1 5 . 5 1 1 5 . 5 5 1 5 . 7 1 1 5 . 8 2 1 5 . 8 9 1 6 . 0 1 1 6 . 0 6 1 6 . 1 5 1 6 . 2 2 1 6 . 2 8 1 6 . 3 3 1 6 . 4 2 1 6 . 5 8 1 6 . 7 1 1 6 . 8 3 1 6 . 8 7 1 6 . 9 3 1 6 . 9 9 1 7 . 0 5 1 7 . 0 9 1 7 . 1 5 1 7 . 3 3 1 7 . 3 6 1 7 . 4 5 1 7 . 5 0 1 7 . 7 3 1 7 . 7 9 1 7 . 8 3 1 7 . 8 6 1 7 . 9 2 1 8 . 1 1 1 8 . 3 5 1 8 . 5 3 1 8 . 5 8 1 8 . 6 8 1 8 . 7 7 1 8 . 8 8 1 9 . 1 2 1 9 . 1 5 1 9 . 3 0 1 9 . 4 8 1 9 . 6 5 1 9 . 7 4 1 9 . 9 2 2 0 . 0 1 2 0 . 1 1 2 0 . 3 7 2 0 . 5 0 2 0 . 6 2 2 0 . 7 6 2 0 . 8 0 2 0 . 8 5 2 0 . 9 2 2 1 . 0 1 2 1 . 1 6 2 1 . 2 8 2 1 . 3 9 2 1 . 5 9 2 1 . 6 7 2 1 . 9 8 2 2 . 0 2 2 2 . 0 9 2 2 . 2 0 2 2 . 3 2 2 2 . 3 7 2 2 . 4 6 2 2 . 5 2 2 2 . 5 7 2 2 . 7 1 2 2 . 7 9 2 2 . 8 4 2 2 . 9 4 2 3 . 0 8 2 3 . 1 8 2 3 . 2 2 2 3 . 3 1 2 3 . 3 8 2 3 . 4 4 2 3 . 5 0 2 3 . 5 8 2 3 . 7 2 2 3 . 7 8 2 4 . 0 0 2 4 . 1 3 2 4 . 2 9 2 4 . 6 0 2 4 . 8 9 2 4 . 9 7 2 5 . 1 7 2 5 . 3 2 2 5 . 4 7 2 5 . 6 4 2 5 . 6 9 2 5 . 8 2 2 5 . 9 8 2 6 . 0 9 2 6 . 1 7 2 6 . 5 2 2 6 . 9 0 2 7 . 1 4 2 7 . 5 5 2 8 . 1 3 2 8 . 2 7 2 8 . 4 3 2 8 . 6 1 2 8 . 7 7 2 9 . 1 4 2 9 . 3 5 2 9 . 5 1 2 9 . 7 6 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072714_b\0727HP3.0021.RAW B14072051-003A ;0727HP3 , $HC-EPH-SCRN-S, V88,(2,20) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 220 240 Page 83 of 117 B2 10-11 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-004A ;0727HP3 , $HC-EPH-SCRN-S, V89,(2,20) Raw File: G:\org\HP3\DAT\HP3072714_b\0727HP3.0015.RAW Date & Time Acquired: 7/27/2014 9:15:49 AM Method File: g:\org\HP3\Methods\SR_SCN-072715-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 40 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.43 6.667 6.201 93.02 - *1-Chloro-octadecane_____13.247 6.667 5.808 87.13 - DRO Area:1130083 DRO Amount: 48.62588 TEH Area:1.216137E+07 TEH Amount: 523.2866 C9-C18 Area:28419.31 C9-C18 Amount: 1.223142 C19-C36 Area:5614668 C19-C36 Amount: 241.532 4 . 3 5 4 . 4 3 4 . 5 3 4 . 6 4 4 . 7 0 4 . 8 0 4 . 8 5 4 . 9 0 5 . 0 0 5 . 1 1 6 . 5 2 7 . 1 3 7 . 8 2 8 . 9 9 9 . 0 4 1 0 . 1 4 1 0 . 2 1 1 0 . 7 9 1 1 . 0 4 1 1 . 3 5 1 1 . 5 7 1 1 . 7 1 1 1 . 8 9 1 2 . 1 3 1 2 . 3 1 1 2 . 3 5 1 2 . 4 3 1 2 . 6 9 1 2 . 8 2 1 3 . 2 5 1 3 . 5 3 1 3 . 5 6 1 3 . 6 0 1 3 . 6 4 1 3 . 6 9 1 3 . 9 0 1 4 . 0 2 1 4 . 0 7 1 4 . 1 5 1 4 . 2 0 1 4 . 2 3 1 4 . 3 3 1 4 . 4 0 1 4 . 4 7 1 4 . 6 9 1 4 . 8 0 1 4 . 9 5 1 5 . 3 4 1 5 . 4 2 1 5 . 5 6 1 5 . 7 0 1 5 . 8 2 1 6 . 0 1 1 6 . 1 8 1 6 . 2 2 1 6 . 2 7 1 6 . 3 4 1 6 . 4 2 1 6 . 6 8 1 6 . 7 2 1 6 . 9 4 1 7 . 0 4 1 7 . 0 9 1 7 . 1 5 1 7 . 2 2 1 7 . 3 1 1 7 . 4 4 1 7 . 5 2 1 7 . 5 8 1 7 . 9 2 1 7 . 9 8 1 8 . 1 0 1 8 . 2 6 1 8 . 3 4 1 8 . 5 8 1 8 . 6 1 1 8 . 7 0 1 8 . 7 6 1 8 . 8 5 1 9 . 1 5 1 9 . 1 9 1 9 . 2 6 1 9 . 3 1 1 9 . 4 4 1 9 . 5 9 1 9 . 6 2 1 9 . 6 7 1 9 . 7 0 1 9 . 8 5 1 9 . 9 3 2 0 . 0 1 2 0 . 0 8 2 0 . 1 1 2 0 . 1 7 2 0 . 5 0 2 0 . 5 5 2 0 . 7 7 2 1 . 0 4 2 1 . 0 8 2 1 . 1 3 2 1 . 1 6 2 1 . 2 3 2 1 . 3 1 2 1 . 3 6 2 1 . 4 4 2 1 . 5 5 2 1 . 6 5 2 1 . 7 6 2 1 . 9 7 2 2 . 0 3 2 2 . 0 9 2 2 . 2 2 2 2 . 3 0 2 2 . 3 6 2 2 . 4 4 2 2 . 5 0 2 2 . 6 4 2 2 . 6 9 2 2 . 7 7 2 2 . 8 3 2 2 . 9 4 2 3 . 0 5 2 3 . 1 8 2 3 . 2 3 2 3 . 3 3 2 3 . 4 5 2 3 . 5 8 2 3 . 6 8 2 3 . 7 2 2 3 . 8 0 2 3 . 9 7 2 4 . 0 2 2 4 . 1 5 2 4 . 2 3 2 4 . 3 3 2 4 . 4 5 2 4 . 6 1 2 4 . 6 9 2 4 . 7 7 2 4 . 8 0 2 4 . 8 8 2 5 . 0 6 2 5 . 1 5 2 5 . 2 0 2 5 . 2 7 2 5 . 3 8 2 5 . 4 3 2 5 . 4 6 2 5 . 5 6 2 5 . 6 4 2 5 . 6 8 2 5 . 7 6 2 5 . 8 8 2 5 . 9 2 2 5 . 9 7 2 6 . 0 8 2 6 . 1 4 2 6 . 1 7 2 6 . 2 3 2 6 . 2 8 2 6 . 3 1 2 6 . 4 2 2 6 . 4 6 2 6 . 6 3 2 6 . 7 1 2 6 . 8 5 2 6 . 8 8 2 6 . 9 8 2 7 . 0 0 2 7 . 2 0 2 7 . 2 5 2 7 . 2 9 2 7 . 3 2 2 7 . 4 3 2 7 . 5 5 2 7 . 6 4 2 7 . 7 0 2 7 . 7 3 2 7 . 8 4 2 7 . 9 2 2 8 . 0 3 2 8 . 1 5 2 8 . 2 5 2 8 . 8 9 2 9 . 0 8 2 9 . 2 2 2 9 . 5 7 2 9 . 7 0 2 9 . 8 3 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072714_b\0727HP3.0015.RAW B14072051-004A ;0727HP3 , $HC-EPH-SCRN-S, V89,(2,20) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 220 240 Page 84 of 117 B3 7-8 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-005A ;0724HP3 , $HC-EPH-SCRN-S, V48 Raw File: G:\org\HP3\DAT\HP3072414_b\0724HP3.0048.RAW Date & Time Acquired: 7/26/2014 2:06:30 AM Method File: g:\org\HP3\Methods\SR_SCN-072448-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.428 6.667 6.16 92.4 - *1-Chloro-octadecane_____13.248 6.667 6.62 99.3 - DRO Area:1554196 DRO Amount: 3.343742 TEH Area:9768952 TEH Amount: 21.01721 C9-C18 Area:873708.8 C9-C18 Amount: 1.880183 C19-C36 Area:5014564 C19-C36 Amount: 10.78584 4 . 2 2 4 . 4 1 4 . 5 2 4 . 7 1 4 . 8 0 4 . 8 9 5 . 0 0 5 . 1 0 5 . 2 5 5 . 3 3 5 . 4 7 5 . 5 6 5 . 6 5 5 . 7 3 5 . 8 3 6 . 0 6 6 . 1 5 6 . 2 7 6 . 5 2 6 . 6 1 6 . 6 7 7 . 0 0 7 . 0 7 7 . 1 2 7 . 2 6 7 . 3 9 7 . 4 5 7 . 4 9 7 . 5 5 7 . 8 2 8 . 2 0 8 . 2 7 8 . 6 8 8 . 7 8 8 . 8 3 8 . 9 3 9 . 0 5 9 . 1 6 9 . 3 3 9 . 4 6 9 . 5 7 9 . 6 1 9 . 7 6 1 0 . 1 4 1 0 . 1 7 1 0 . 4 3 1 0 . 5 1 1 0 . 5 7 1 0 . 6 1 1 0 . 7 7 1 0 . 9 1 1 1 . 0 5 1 1 . 1 1 1 1 . 2 1 1 1 . 3 2 1 1 . 4 8 1 1 . 5 5 1 1 . 6 1 1 1 . 6 7 1 1 . 8 4 1 1 . 8 9 1 1 . 9 7 1 2 . 0 1 1 2 . 0 8 1 2 . 1 9 1 2 . 2 7 1 2 . 3 4 1 2 . 4 3 1 2 . 5 6 1 2 . 6 4 1 2 . 7 7 1 2 . 8 5 1 2 . 9 4 1 2 . 9 9 1 3 . 0 7 1 3 . 1 3 1 3 . 2 5 1 3 . 4 8 1 3 . 5 7 1 3 . 7 3 1 3 . 8 9 1 3 . 9 7 1 4 . 1 4 1 4 . 3 4 1 4 . 4 3 1 4 . 5 6 1 4 . 7 0 1 4 . 8 7 1 4 . 9 5 1 5 . 0 9 1 5 . 2 2 1 5 . 3 3 1 5 . 4 8 1 5 . 6 0 1 5 . 7 0 1 5 . 8 5 1 5 . 9 6 1 6 . 0 5 1 6 . 2 0 1 6 . 3 2 1 6 . 4 1 1 6 . 5 5 1 6 . 6 5 1 6 . 7 5 1 6 . 8 8 1 6 . 9 9 1 7 . 0 5 1 7 . 2 1 1 7 . 2 7 1 7 . 3 2 1 7 . 4 1 1 7 . 5 0 1 7 . 5 5 1 7 . 6 5 1 7 . 7 3 1 7 . 8 5 1 7 . 9 2 1 8 . 0 9 1 8 . 2 4 1 8 . 3 5 1 8 . 4 9 1 8 . 5 6 1 8 . 6 8 1 8 . 7 6 1 8 . 9 3 1 9 . 1 5 1 9 . 3 1 1 9 . 4 7 1 9 . 7 8 1 9 . 8 1 2 0 . 0 0 2 0 . 1 9 2 0 . 6 2 2 0 . 6 7 2 0 . 8 4 2 1 . 1 3 2 1 . 1 6 2 1 . 2 0 2 1 . 2 7 2 1 . 5 5 2 1 . 5 8 2 1 . 6 9 2 1 . 8 1 2 1 . 8 6 2 1 . 9 1 2 2 . 0 1 2 2 . 1 2 2 2 . 4 8 2 2 . 5 4 2 2 . 5 8 2 2 . 8 7 2 3 . 0 6 2 3 . 2 9 2 3 . 4 0 2 3 . 4 7 2 3 . 5 0 2 3 . 7 0 2 3 . 7 4 2 3 . 8 6 2 3 . 9 8 2 4 . 0 7 2 4 . 3 1 2 4 . 3 7 2 4 . 3 9 2 4 . 4 3 2 4 . 4 6 2 4 . 5 6 2 4 . 7 5 2 5 . 1 0 2 5 . 2 0 2 5 . 4 5 2 5 . 7 3 2 5 . 9 3 2 6 . 1 1 2 6 . 4 3 2 7 . 1 4 2 7 . 6 9 2 7 . 7 5 2 7 . 9 5 2 8 . 0 5 2 8 . 1 3 2 8 . 4 2 2 8 . 4 5 2 8 . 4 8 2 9 . 1 3 2 9 . 2 9 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072414_b\0724HP3.0048.RAW B14072051-005A ;0724HP3 , $HC-EPH-SCRN-S, V48 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 85 of 117 B4 9-11 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-006A ;0724HP3 , $HC-EPH-SCRN-S, V53,(2,3) Raw File: G:\org\HP3\DAT\HP3072414_b\0724HP3.0053.RAW Date & Time Acquired: 7/26/2014 5:56:06 AM Method File: g:\org\HP3\Methods\S3_SCN-072453-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 6 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.43 6.667 6.266 93.99 - *1-Chloro-octadecane_____13.249 6.667 6.424 96.36 - DRO Area:1451583 DRO Amount: 9.36893 TEH Area:1.497133E+07 TEH Amount: 96.62928 C9-C18 Area:287177.8 C9-C18 Amount: 1.853982 C19-C36 Area:5890011 C19-C36 Amount: 38.00651 4 . 2 6 4 . 3 4 4 . 4 1 4 . 5 2 4 . 7 1 4 . 8 0 4 . 8 9 5 . 0 0 5 . 1 0 5 . 2 6 5 . 3 3 5 . 4 6 5 . 6 2 5 . 6 6 5 . 7 3 5 . 8 4 6 . 0 3 6 . 1 0 6 . 2 3 6 . 2 8 6 . 5 2 7 . 0 8 7 . 2 6 7 . 4 0 7 . 4 5 7 . 5 0 7 . 5 6 7 . 8 2 8 . 7 8 8 . 8 3 8 . 9 1 8 . 9 7 9 . 0 5 9 . 0 9 9 . 1 5 9 . 3 3 9 . 4 1 9 . 4 5 9 . 5 5 9 . 6 6 9 . 8 4 9 . 9 5 1 0 . 0 8 1 0 . 1 4 1 0 . 2 2 1 0 . 2 6 1 0 . 4 3 1 0 . 5 0 1 0 . 5 7 1 0 . 6 6 1 0 . 8 0 1 0 . 8 9 1 0 . 9 6 1 1 . 0 4 1 1 . 1 3 1 1 . 2 4 1 1 . 3 5 1 1 . 4 6 1 1 . 5 0 1 1 . 5 6 1 1 . 7 2 1 1 . 8 4 1 1 . 8 9 1 2 . 0 3 1 2 . 0 9 1 2 . 1 2 1 2 . 2 1 1 2 . 3 1 1 2 . 3 5 1 2 . 4 3 1 2 . 6 6 1 2 . 8 2 1 2 . 9 2 1 3 . 0 1 1 3 . 1 8 1 3 . 2 5 1 3 . 4 3 1 3 . 4 9 1 3 . 5 8 1 3 . 6 8 1 3 . 7 3 1 3 . 8 9 1 4 . 0 2 1 4 . 0 9 1 4 . 1 5 1 4 . 2 2 1 4 . 2 6 1 4 . 3 3 1 4 . 4 0 1 4 . 4 5 1 4 . 5 7 1 4 . 7 4 1 4 . 8 1 1 4 . 8 9 1 4 . 9 5 1 5 . 1 0 1 5 . 1 8 1 5 . 3 4 1 5 . 4 8 1 5 . 5 6 1 5 . 6 1 1 5 . 6 4 1 5 . 7 0 1 5 . 8 1 1 5 . 8 9 1 5 . 9 9 1 6 . 0 5 1 6 . 1 9 1 6 . 2 8 1 6 . 4 2 1 6 . 5 2 1 6 . 5 8 1 6 . 6 6 1 6 . 7 2 1 6 . 8 7 1 6 . 9 4 1 6 . 9 9 1 7 . 0 8 1 7 . 1 6 1 7 . 2 1 1 7 . 2 8 1 7 . 3 2 1 7 . 4 5 1 7 . 5 9 1 7 . 6 3 1 7 . 6 7 1 7 . 7 2 1 7 . 8 4 1 7 . 8 8 1 7 . 9 2 1 7 . 9 9 1 8 . 1 5 1 8 . 2 4 1 8 . 3 5 1 8 . 3 8 1 8 . 6 0 1 8 . 6 7 1 8 . 7 2 1 8 . 8 9 1 9 . 0 3 1 9 . 1 3 1 9 . 2 3 1 9 . 3 1 1 9 . 4 9 1 9 . 7 3 1 9 . 7 8 1 9 . 8 4 1 9 . 9 3 2 0 . 0 0 2 0 . 0 5 2 0 . 0 9 2 0 . 1 4 2 0 . 2 0 2 0 . 3 3 2 0 . 4 3 2 0 . 4 9 2 0 . 5 8 2 0 . 6 5 2 0 . 7 7 2 0 . 8 4 2 0 . 9 2 2 0 . 9 7 2 1 . 0 3 2 1 . 1 0 2 1 . 1 9 2 1 . 2 3 2 1 . 3 4 2 1 . 4 5 2 1 . 6 4 2 1 . 7 5 2 1 . 8 3 2 1 . 8 6 2 1 . 9 7 2 2 . 0 7 2 2 . 1 9 2 2 . 2 4 2 2 . 3 8 2 2 . 4 3 2 2 . 5 0 2 2 . 5 4 2 2 . 7 6 2 2 . 8 8 2 2 . 9 4 2 3 . 1 0 2 3 . 1 4 2 3 . 1 8 2 3 . 2 6 2 3 . 3 0 2 3 . 4 0 2 3 . 5 6 2 3 . 6 4 2 3 . 7 2 2 3 . 8 6 2 3 . 9 4 2 4 . 0 8 2 4 . 2 1 2 4 . 2 9 2 4 . 3 6 2 4 . 4 4 2 4 . 4 8 2 4 . 6 4 2 4 . 7 1 2 4 . 8 0 2 4 . 8 5 2 4 . 9 4 2 5 . 0 2 2 5 . 1 4 2 5 . 2 3 2 5 . 2 9 2 5 . 4 1 2 5 . 5 0 2 5 . 5 6 2 5 . 6 4 2 5 . 7 5 2 5 . 8 3 2 6 . 0 4 2 6 . 1 0 2 6 . 1 8 2 6 . 2 2 2 6 . 2 7 2 6 . 3 0 2 6 . 3 8 2 6 . 4 8 2 6 . 5 9 2 6 . 6 9 2 6 . 8 1 2 6 . 8 5 2 6 . 8 8 2 7 . 0 3 2 7 . 2 4 2 7 . 2 8 2 7 . 4 1 2 7 . 6 3 2 7 . 7 3 2 7 . 8 2 2 7 . 8 6 2 7 . 9 3 2 8 . 0 0 2 8 . 1 0 2 8 . 3 9 2 8 . 4 7 2 8 . 5 7 2 8 . 6 8 2 8 . 7 6 2 8 . 8 0 2 8 . 8 8 2 8 . 9 3 2 9 . 0 5 2 9 . 1 2 2 9 . 1 7 2 9 . 4 2 2 9 . 5 7 2 9 . 6 3 2 9 . 6 6 2 9 . 7 0 2 9 . 8 3 2 9 . 8 7 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072414_b\0724HP3.0053.RAW B14072051-006A ;0724HP3 , $HC-EPH-SCRN-S, V53,(2,3) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 100 200 300 400 500 600 700 800 900 1000 Page 86 of 117 B5 5-7 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-007A ;0724HP3 , $HC-EPH-SCRN-S, V46 Raw File: G:\org\HP3\DAT\HP3072414_b\0724HP3.0046.RAW Date & Time Acquired: 7/26/2014 12:35:55 AM Method File: g:\org\HP3\Methods\SR_SCN-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.428 6.667 6.409 96.13 - *1-Chloro-octadecane_____13.248 6.667 6.966 104.49 - DRO Area:609691.5 DRO Amount: 1.311708 TEH Area:1420691 TEH Amount: 3.056516 C9-C18 Area:652031.8 C9-C18 Amount: 1.403143 C19-C36 Area:555918.5 C19-C36 Amount: 1.195726 4 . 2 2 4 . 4 1 4 . 5 2 4 . 7 1 4 . 8 0 4 . 8 8 4 . 9 9 5 . 1 0 5 . 2 5 5 . 3 3 5 . 5 6 5 . 6 5 5 . 7 2 5 . 8 3 5 . 9 2 6 . 0 6 6 . 1 5 6 . 2 6 6 . 4 6 6 . 5 2 6 . 6 1 7 . 0 1 7 . 0 7 7 . 1 2 7 . 2 6 7 . 3 9 7 . 4 5 7 . 4 9 7 . 5 5 7 . 8 2 8 . 0 1 8 . 3 9 8 . 4 5 8 . 7 8 8 . 8 3 8 . 8 7 8 . 9 3 9 . 0 5 9 . 3 3 9 . 4 6 9 . 5 7 9 . 6 1 9 . 6 7 9 . 7 5 9 . 8 2 1 0 . 1 3 1 0 . 3 2 1 0 . 4 3 1 0 . 4 8 1 0 . 5 8 1 0 . 6 0 1 0 . 7 8 1 0 . 9 1 1 1 . 0 5 1 1 . 1 1 1 1 . 2 2 1 1 . 3 2 1 1 . 3 8 1 1 . 4 5 1 1 . 5 6 1 1 . 6 5 1 1 . 8 1 1 1 . 8 8 1 1 . 9 6 1 2 . 0 0 1 2 . 0 8 1 2 . 1 6 1 2 . 2 7 1 2 . 4 3 1 2 . 5 6 1 2 . 6 4 1 2 . 7 7 1 2 . 8 5 1 2 . 9 4 1 2 . 9 9 1 3 . 0 7 1 3 . 1 4 1 3 . 2 5 1 3 . 4 8 1 3 . 5 8 1 3 . 7 6 1 3 . 9 2 1 3 . 9 8 1 4 . 1 5 1 4 . 4 4 1 4 . 5 2 1 4 . 5 7 1 4 . 7 3 1 4 . 9 5 1 5 . 1 9 1 5 . 2 4 1 5 . 3 4 1 5 . 4 0 1 5 . 4 9 1 5 . 5 6 1 5 . 6 2 1 5 . 7 1 1 5 . 8 5 1 5 . 9 7 1 6 . 0 4 1 6 . 2 0 1 6 . 4 1 1 6 . 6 7 1 6 . 7 6 1 6 . 8 8 1 6 . 9 8 1 7 . 0 5 1 7 . 3 3 1 7 . 5 0 1 7 . 5 5 1 7 . 6 5 1 7 . 7 3 1 7 . 8 5 1 7 . 9 2 1 8 . 1 0 1 8 . 2 4 1 8 . 3 6 1 8 . 4 6 1 8 . 6 1 1 8 . 6 8 1 8 . 7 7 1 8 . 9 5 1 9 . 1 6 1 9 . 3 1 1 9 . 4 7 1 9 . 7 7 2 0 . 0 0 2 0 . 1 9 2 2 . 1 3 2 7 . 3 8 2 8 . 4 5 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072414_b\0724HP3.0046.RAW B14072051-007A ;0724HP3 , $HC-EPH-SCRN-S, V46 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 87 of 117 B6 7-10 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-008A ;0724HP3 , $HC-EPH-SCRN-S, V51 Raw File: G:\org\HP3\DAT\HP3072414_b\0724HP3.0050.RAW Date & Time Acquired: 7/26/2014 3:38:19 AM Method File: g:\org\HP3\Methods\SR_SCN-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.43 6.667 6.447 96.71 - *1-Chloro-octadecane_____13.249 6.667 6.897 103.46 - DRO Area:349109.3 DRO Amount: 0.7510837 TEH Area:963814.3 TEH Amount: 2.073578 C9-C18 Area:572268.1 C9-C18 Amount: 1.231495 C19-C36 Area:198235.3 C19-C36 Amount: 0.4263846 4 . 2 2 4 . 4 1 4 . 5 2 4 . 7 1 4 . 8 0 4 . 8 8 5 . 0 0 5 . 1 0 5 . 2 5 5 . 3 3 5 . 4 7 5 . 5 6 5 . 6 5 5 . 7 0 5 . 8 3 6 . 0 6 6 . 1 6 6 . 2 7 6 . 5 2 6 . 6 2 6 . 6 7 6 . 8 5 7 . 0 1 7 . 0 8 7 . 1 2 7 . 2 7 7 . 4 0 7 . 4 5 7 . 5 6 7 . 8 2 8 . 0 3 8 . 4 7 8 . 7 8 8 . 8 3 8 . 8 7 8 . 9 3 8 . 9 6 9 . 0 5 9 . 3 3 9 . 4 6 9 . 6 7 1 0 . 1 3 1 0 . 4 3 1 0 . 5 4 1 0 . 6 1 1 0 . 6 7 1 0 . 7 9 1 1 . 0 6 1 1 . 1 1 1 1 . 3 3 1 1 . 4 8 1 1 . 5 5 1 1 . 6 1 1 1 . 6 8 1 1 . 8 4 1 1 . 8 9 1 1 . 9 7 1 2 . 0 9 1 2 . 2 8 1 2 . 3 5 1 2 . 4 3 1 2 . 5 7 1 2 . 6 5 1 2 . 7 7 1 2 . 8 2 1 2 . 9 1 1 2 . 9 9 1 3 . 2 5 1 3 . 4 9 1 3 . 5 8 1 3 . 6 8 1 3 . 9 0 1 4 . 0 1 1 4 . 0 8 1 4 . 1 5 1 4 . 5 3 1 4 . 5 6 1 4 . 9 6 1 5 . 1 9 1 5 . 2 4 1 5 . 3 4 1 5 . 4 9 1 5 . 5 7 1 5 . 7 0 1 6 . 0 5 1 6 . 1 9 1 6 . 4 0 1 6 . 5 8 1 6 . 7 2 1 6 . 9 4 1 7 . 0 5 1 7 . 1 5 1 7 . 3 3 1 7 . 4 5 1 7 . 6 1 1 7 . 7 3 1 7 . 8 3 1 7 . 9 7 1 8 . 1 5 1 8 . 2 5 1 8 . 3 7 1 8 . 6 0 1 8 . 6 8 1 8 . 8 8 1 9 . 1 4 1 9 . 3 9 1 9 . 7 6 2 0 . 1 7 2 2 . 0 3 2 2 . 5 2 2 4 . 0 2 2 4 . 7 4 2 8 . 4 6 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072414_b\0724HP3.0050.RAW B14072051-008A ;0724HP3 , $HC-EPH-SCRN-S, V51 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 88 of 117 B7 8-10 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-009A ;0724HP3 , $HC-EPH-SCRN-S, V52,(2,3) Raw File: G:\org\HP3\DAT\HP3072414_b\0724HP3.0052.RAW Date & Time Acquired: 7/26/2014 5:10:10 AM Method File: g:\org\HP3\Methods\SR_SCN-072452-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 6 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.429 6.667 6.716 100.74 - *1-Chloro-octadecane_____13.248 6.667 6.984 104.75 - DRO Area:820984.8 DRO Amount: 5.298872 TEH Area:9086303 TEH Amount: 58.6456 C9-C18 Area:230923.5 C9-C18 Amount: 1.490811 C19-C36 Area:4076166 C19-C36 Amount: 26.30231 4 . 2 6 4 . 3 2 4 . 4 2 4 . 5 2 4 . 7 0 4 . 8 0 4 . 8 9 5 . 0 0 5 . 1 0 5 . 3 2 5 . 4 7 5 . 6 2 5 . 6 6 5 . 7 3 5 . 8 4 6 . 1 0 6 . 2 2 6 . 2 8 6 . 5 2 7 . 0 2 7 . 0 8 7 . 2 7 7 . 3 9 7 . 4 5 7 . 6 2 7 . 6 9 7 . 8 2 8 . 5 5 8 . 7 2 8 . 7 8 8 . 8 3 8 . 8 9 8 . 9 3 8 . 9 8 9 . 0 5 9 . 1 9 9 . 2 3 9 . 3 3 9 . 4 6 9 . 6 7 9 . 7 7 9 . 9 5 1 0 . 1 4 1 0 . 5 7 1 0 . 7 9 1 1 . 0 5 1 1 . 1 2 1 1 . 3 5 1 1 . 6 1 1 1 . 7 0 1 1 . 8 4 1 1 . 8 9 1 2 . 2 8 1 2 . 3 5 1 2 . 4 3 1 2 . 6 7 1 2 . 7 8 1 2 . 8 3 1 3 . 2 5 1 3 . 5 1 1 3 . 5 9 1 3 . 6 8 1 3 . 8 9 1 4 . 0 1 1 4 . 0 5 1 4 . 1 5 1 4 . 2 2 1 4 . 3 4 1 4 . 4 4 1 4 . 5 2 1 4 . 6 4 1 4 . 6 7 1 4 . 7 1 1 4 . 8 2 1 4 . 9 0 1 4 . 9 5 1 5 . 1 1 1 5 . 1 9 1 5 . 2 5 1 5 . 3 4 1 5 . 4 9 1 5 . 5 7 1 5 . 7 0 1 5 . 8 2 1 5 . 8 6 1 6 . 0 5 1 6 . 1 9 1 6 . 3 0 1 6 . 4 0 1 6 . 5 8 1 6 . 6 6 1 6 . 7 2 1 6 . 8 9 1 6 . 9 3 1 7 . 0 5 1 7 . 0 8 1 7 . 1 6 1 7 . 2 8 1 7 . 3 3 1 7 . 3 7 1 7 . 4 5 1 7 . 5 5 1 7 . 6 5 1 7 . 7 3 1 7 . 8 4 1 7 . 8 7 1 7 . 9 2 1 7 . 9 9 1 8 . 0 4 1 8 . 1 4 1 8 . 2 4 1 8 . 3 7 1 8 . 6 1 1 8 . 7 2 1 8 . 8 3 1 8 . 8 8 1 8 . 9 4 1 9 . 1 6 1 9 . 2 5 1 9 . 3 5 1 9 . 7 9 1 9 . 9 2 1 9 . 9 6 2 0 . 0 2 2 0 . 1 0 2 0 . 1 3 2 0 . 1 8 2 0 . 3 6 2 0 . 4 5 2 0 . 5 4 2 0 . 7 4 2 0 . 9 2 2 0 . 9 7 2 1 . 0 3 2 1 . 1 3 2 1 . 2 2 2 1 . 2 8 2 1 . 3 2 2 1 . 3 8 2 1 . 4 2 2 1 . 6 3 2 1 . 7 4 2 1 . 8 4 2 1 . 8 8 2 1 . 9 4 2 2 . 0 0 2 2 . 2 1 2 2 . 2 5 2 2 . 3 3 2 2 . 3 8 2 2 . 4 5 2 2 . 5 2 2 2 . 6 1 2 2 . 6 7 2 2 . 8 1 2 2 . 8 9 2 3 . 0 3 2 3 . 1 0 2 3 . 1 9 2 3 . 2 2 2 3 . 3 4 2 3 . 4 4 2 3 . 4 9 2 3 . 5 4 2 3 . 6 1 2 3 . 6 7 2 3 . 7 3 2 3 . 7 8 2 3 . 9 4 2 3 . 9 8 2 4 . 0 3 2 4 . 0 9 2 4 . 1 6 2 4 . 2 6 2 4 . 3 1 2 4 . 3 6 2 4 . 4 5 2 4 . 5 4 2 4 . 6 1 2 4 . 6 8 2 4 . 8 4 2 5 . 0 0 2 5 . 1 3 2 5 . 1 7 2 5 . 2 4 2 5 . 3 4 2 5 . 4 4 2 5 . 5 1 2 5 . 8 1 2 5 . 8 6 2 6 . 0 1 2 6 . 0 5 2 6 . 1 5 2 6 . 2 0 2 6 . 2 7 2 6 . 3 4 2 6 . 4 2 2 6 . 4 7 2 6 . 5 9 2 6 . 6 4 2 6 . 7 0 2 7 . 0 4 2 7 . 4 7 2 8 . 2 3 2 8 . 2 6 2 8 . 3 6 2 8 . 4 6 2 8 . 7 5 2 9 . 0 4 2 9 . 1 5 2 9 . 3 0 2 9 . 7 0 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072414_b\0724HP3.0052.RAW B14072051-009A ;0724HP3 , $HC-EPH-SCRN-S, V52,(2,3) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 100 200 300 400 500 600 700 800 900 1000 Page 89 of 117 B8 9-11 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-010A ;0727HP3 , $HC-EPH-SCRN-S, V95,(2,20) Raw File: G:\org\HP3\DAT\HP3072714_b\0727HP3.0025.RAW Date & Time Acquired: 7/27/2014 4:51:40 PM Method File: g:\org\HP3\Methods\SR_SCN-072725-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 40 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.441 6.667 3.074 46.1 - *1-Chloro-octadecane_____13.259 6.667 2.811 42.16 - DRO Area:1007265 DRO Amount: 43.34117 TEH Area:1.36107E+07 TEH Amount: 585.649 C9-C18 Area:38931.26 C9-C18 Amount: 1.675567 C19-C36 Area:6255575 C19-C36 Amount: 269.1026 4 . 2 9 4 . 4 3 4 . 5 4 4 . 8 1 4 . 8 6 4 . 8 9 7 . 4 3 7 . 8 3 8 . 7 4 8 . 9 1 9 . 0 5 9 . 3 4 9 . 4 7 1 0 . 8 0 1 2 . 4 4 1 2 . 6 2 1 2 . 7 2 1 3 . 0 3 1 3 . 2 6 1 3 . 5 2 1 3 . 7 4 1 4 . 0 2 1 4 . 1 0 1 4 . 1 6 1 4 . 3 4 1 4 . 4 9 1 4 . 6 2 1 4 . 7 2 1 4 . 8 1 1 4 . 9 7 1 5 . 1 1 1 5 . 3 5 1 5 . 4 3 1 5 . 4 9 1 5 . 5 8 1 5 . 7 6 1 6 . 1 1 1 6 . 2 8 1 6 . 4 2 1 6 . 5 1 1 6 . 5 8 1 6 . 6 8 1 6 . 7 4 1 6 . 8 8 1 6 . 9 4 1 7 . 0 1 1 7 . 1 0 1 7 . 1 6 1 7 . 2 1 1 7 . 3 9 1 7 . 4 6 1 7 . 5 1 1 7 . 5 5 1 7 . 8 5 1 7 . 8 9 1 7 . 9 6 1 8 . 0 0 1 8 . 0 3 1 8 . 1 5 1 8 . 2 3 1 8 . 2 8 1 8 . 4 0 1 8 . 5 9 1 8 . 8 6 1 8 . 8 9 1 9 . 0 8 1 9 . 1 4 1 9 . 2 8 1 9 . 3 6 1 9 . 5 8 1 9 . 7 3 1 9 . 7 8 2 0 . 0 0 2 0 . 0 3 2 0 . 1 2 2 0 . 1 5 2 0 . 1 9 2 0 . 3 6 2 0 . 5 6 2 0 . 6 3 2 0 . 7 8 2 1 . 0 1 2 1 . 0 6 2 1 . 1 5 2 1 . 2 6 2 1 . 3 2 2 1 . 4 0 2 1 . 4 5 2 1 . 7 5 2 1 . 8 5 2 1 . 9 6 2 1 . 9 8 2 2 . 0 5 2 2 . 1 7 2 2 . 2 1 2 2 . 3 3 2 2 . 4 1 2 2 . 4 5 2 2 . 5 6 2 2 . 6 3 2 2 . 8 0 2 2 . 9 4 2 3 . 0 7 2 3 . 2 2 2 3 . 3 1 2 3 . 3 5 2 3 . 4 6 2 3 . 5 0 2 3 . 5 7 2 3 . 6 4 2 3 . 7 0 2 3 . 8 4 2 3 . 9 1 2 4 . 0 3 2 4 . 0 7 2 4 . 2 2 2 4 . 3 5 2 4 . 3 8 2 4 . 4 9 2 4 . 5 4 2 4 . 6 4 2 4 . 7 0 2 4 . 7 6 2 4 . 9 0 2 5 . 0 2 2 5 . 1 7 2 5 . 2 7 2 5 . 3 4 2 5 . 4 5 2 5 . 5 0 2 5 . 5 5 2 5 . 6 2 2 5 . 8 3 2 5 . 9 4 2 6 . 0 1 2 6 . 1 1 2 6 . 1 5 2 6 . 2 0 2 6 . 2 9 2 6 . 5 8 2 6 . 6 9 2 6 . 7 8 2 6 . 8 9 2 7 . 0 1 2 7 . 0 6 2 7 . 1 1 2 7 . 2 1 2 7 . 3 8 2 7 . 4 2 2 7 . 5 4 2 7 . 7 4 2 7 . 8 0 2 7 . 8 7 2 7 . 9 6 2 8 . 0 7 2 8 . 1 2 2 8 . 2 1 2 8 . 3 0 2 8 . 4 4 2 8 . 4 8 2 8 . 5 5 2 8 . 6 3 2 8 . 7 0 2 8 . 7 2 2 8 . 7 7 2 8 . 8 3 2 8 . 9 2 2 9 . 0 9 2 9 . 2 3 2 9 . 3 6 2 9 . 4 1 2 9 . 4 9 2 9 . 5 7 2 9 . 6 2 2 9 . 7 0 2 9 . 8 4 2 9 . 9 2 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072714_b\0727HP3.0025.RAW B14072051-010A ;0727HP3 , $HC-EPH-SCRN-S, V95,(2,20) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 Page 90 of 117 B9 5-7 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-011A ;0727HP3 , $HC-EPH-SCRN-S, V92,(2,20) Raw File: G:\org\HP3\DAT\HP3072714_b\0727HP3.0022.RAW Date & Time Acquired: 7/27/2014 2:34:43 PM Method File: g:\org\HP3\Methods\S3_SCN-072710-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 40 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.434 6.667 12.454 186.82 - *1-Chloro-octadecane_____13.25 6.667 15.349 230.24 - DRO Area:1.469112E+07 DRO Amount: 632.1378 TEH Area:3.778732E+07 TEH Amount: 1625.935 C9-C18 Area:3237237 C9-C18 Amount: 139.3278 C19-C36 Area:2.268144E+07C19-C36 Amount: 975.7112 4 . 2 7 4 . 4 2 4 . 5 4 4 . 8 2 4 . 9 0 5 . 0 0 5 . 1 0 6 . 9 2 7 . 0 0 7 . 1 3 7 . 3 0 7 . 5 9 7 . 6 5 7 . 7 2 7 . 9 4 7 . 9 9 8 . 0 3 8 . 1 3 8 . 3 0 8 . 4 3 8 . 5 3 8 . 6 0 8 . 7 2 8 . 7 8 8 . 8 2 8 . 8 8 8 . 9 8 9 . 0 2 9 . 1 3 9 . 2 4 9 . 2 9 9 . 4 1 9 . 5 5 9 . 5 8 9 . 6 5 9 . 7 9 9 . 8 7 9 . 9 8 1 0 . 0 7 1 0 . 1 4 1 0 . 1 8 1 0 . 2 3 1 0 . 2 6 1 0 . 3 0 1 0 . 3 6 1 0 . 4 1 1 0 . 4 6 1 0 . 5 7 1 0 . 7 2 1 0 . 8 1 1 0 . 9 1 1 0 . 9 5 1 1 . 0 4 1 1 . 1 2 1 1 . 1 8 1 1 . 2 4 1 1 . 3 1 1 1 . 3 9 1 1 . 5 6 1 1 . 5 9 1 1 . 6 8 1 1 . 8 1 1 1 . 9 6 1 2 . 0 3 1 2 . 0 9 1 2 . 1 3 1 2 . 2 1 1 2 . 3 4 1 2 . 4 3 1 2 . 5 6 1 2 . 6 8 1 2 . 7 8 1 2 . 8 2 1 2 . 9 4 1 3 . 0 5 1 3 . 1 1 1 3 . 2 0 1 3 . 2 5 1 3 . 3 6 1 3 . 4 5 1 3 . 5 2 1 3 . 6 1 1 3 . 6 8 1 3 . 7 4 1 3 . 8 0 1 3 . 8 5 1 3 . 9 4 1 4 . 0 1 1 4 . 0 6 1 4 . 1 2 1 4 . 1 6 1 4 . 2 5 1 4 . 3 0 1 4 . 3 3 1 4 . 3 9 1 4 . 4 8 1 4 . 5 1 1 4 . 5 7 1 4 . 6 6 1 4 . 7 1 1 4 . 8 1 1 4 . 8 7 1 4 . 9 0 1 4 . 9 5 1 5 . 0 0 1 5 . 0 8 1 5 . 1 8 1 5 . 2 4 1 5 . 2 9 1 5 . 3 9 1 5 . 4 7 1 5 . 5 3 1 5 . 5 6 1 5 . 6 5 1 5 . 7 0 1 5 . 8 0 1 5 . 8 6 1 5 . 9 4 1 5 . 9 7 1 6 . 0 7 1 6 . 1 8 1 6 . 2 2 1 6 . 2 7 1 6 . 4 2 1 6 . 4 8 1 6 . 6 2 1 6 . 6 6 1 6 . 7 3 1 6 . 8 0 1 6 . 8 8 1 6 . 9 4 1 6 . 9 9 1 7 . 0 5 1 7 . 0 8 1 7 . 1 5 1 7 . 2 3 1 7 . 3 3 1 7 . 3 8 1 7 . 4 5 1 7 . 5 0 1 7 . 7 3 1 7 . 8 0 1 7 . 8 4 1 7 . 9 0 1 8 . 1 4 1 8 . 2 4 1 8 . 4 5 1 8 . 5 4 1 8 . 6 0 1 8 . 8 4 1 8 . 8 9 1 9 . 0 2 1 9 . 1 6 1 9 . 2 7 1 9 . 4 6 1 9 . 5 4 1 9 . 6 5 1 9 . 7 0 1 9 . 7 6 1 9 . 8 9 2 0 . 0 0 2 0 . 0 5 2 0 . 1 2 2 0 . 1 7 2 0 . 2 0 2 0 . 3 3 2 0 . 5 4 2 0 . 6 0 2 0 . 7 1 2 0 . 8 0 2 0 . 8 5 2 0 . 9 9 2 1 . 0 2 2 1 . 0 5 2 1 . 1 8 2 1 . 2 5 2 1 . 2 8 2 1 . 3 4 2 1 . 3 8 2 1 . 7 1 2 1 . 7 8 2 1 . 8 1 2 1 . 9 3 2 2 . 0 0 2 2 . 0 3 2 2 . 1 5 2 2 . 2 6 2 2 . 3 7 2 2 . 4 1 2 2 . 4 9 2 2 . 5 4 2 2 . 7 3 2 2 . 8 0 2 2 . 8 5 2 2 . 9 6 2 3 . 0 2 2 3 . 0 8 2 3 . 1 1 2 3 . 2 0 2 3 . 3 0 2 3 . 3 9 2 3 . 4 7 2 3 . 6 2 2 3 . 7 3 2 3 . 8 1 2 3 . 8 9 2 3 . 9 7 2 4 . 0 0 2 4 . 1 6 2 4 . 2 5 2 4 . 3 2 2 4 . 4 3 2 4 . 4 6 2 4 . 5 7 2 4 . 6 2 2 4 . 7 1 2 4 . 7 8 2 4 . 8 7 2 4 . 9 8 2 5 . 1 7 2 5 . 3 1 2 5 . 3 8 2 5 . 4 6 2 5 . 5 4 2 5 . 6 3 2 5 . 7 0 2 5 . 8 4 2 6 . 0 1 2 6 . 1 0 2 6 . 1 9 2 6 . 2 8 2 6 . 3 7 2 6 . 4 7 2 6 . 5 0 2 6 . 6 8 2 6 . 7 2 2 6 . 7 6 2 6 . 8 6 2 6 . 9 0 2 6 . 9 6 2 7 . 0 4 2 7 . 0 9 2 7 . 1 9 2 7 . 3 9 2 7 . 4 1 2 7 . 5 0 2 7 . 5 8 2 7 . 8 0 2 7 . 8 8 2 8 . 0 2 2 8 . 0 8 2 8 . 1 4 2 8 . 1 7 2 8 . 2 5 2 8 . 3 4 2 8 . 4 1 2 8 . 4 7 2 8 . 5 9 2 8 . 7 6 2 8 . 8 6 2 8 . 9 7 2 9 . 0 6 2 9 . 0 9 2 9 . 2 0 2 9 . 4 2 2 9 . 5 1 2 9 . 5 7 2 9 . 6 6 2 9 . 7 3 2 9 . 7 6 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072714_b\0727HP3.0022.RAW B14072051-011A ;0727HP3 , $HC-EPH-SCRN-S, V92,(2,20) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 50 100 150 200 250 300 350 400 Page 91 of 117 B9 8-11 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-012A ;0727HP3 , $HC-EPH-SCRN-S, V93,(2,20) Raw File: G:\org\HP3\DAT\HP3072714_b\0727HP3.0023.RAW Date & Time Acquired: 7/27/2014 3:20:15 PM Method File: g:\org\HP3\Methods\SR_SCN-072723-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 40 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.437 6.667 6.329 94.93 - *1-Chloro-octadecane_____13.254 6.667 6.025 90.38 - DRO Area:1272103 DRO Amount: 54.73678 TEH Area:1.572217E+07 TEH Amount: 676.5026 C9-C18 Area:149439.8 C9-C18 Amount: 6.431758 C19-C36 Area:6542106 C19-C36 Amount: 281.4286 4 . 4 4 4 . 5 4 4 . 8 2 4 . 8 9 5 . 1 0 7 . 1 4 8 . 3 4 8 . 4 7 8 . 6 2 8 . 6 5 8 . 7 3 8 . 7 9 8 . 8 3 8 . 9 7 9 . 0 4 9 . 1 4 9 . 3 0 9 . 4 2 9 . 5 5 9 . 6 4 9 . 7 6 9 . 8 0 9 . 8 5 9 . 9 5 1 0 . 1 0 1 0 . 1 4 1 0 . 2 2 1 0 . 2 7 1 0 . 3 6 1 0 . 4 5 1 0 . 5 0 1 0 . 5 7 1 0 . 8 2 1 0 . 9 5 1 1 . 0 4 1 1 . 2 3 1 1 . 3 5 1 1 . 4 0 1 1 . 5 6 1 1 . 8 5 1 1 . 8 9 1 2 . 1 3 1 2 . 2 2 1 2 . 3 1 1 2 . 4 4 1 2 . 7 2 1 2 . 8 3 1 3 . 0 1 1 3 . 2 5 1 3 . 4 6 1 3 . 5 4 1 3 . 6 1 1 3 . 6 7 1 3 . 7 0 1 3 . 7 6 1 3 . 8 9 1 4 . 0 2 1 4 . 0 7 1 4 . 1 7 1 4 . 2 4 1 4 . 3 4 1 4 . 4 8 1 4 . 5 2 1 4 . 5 5 1 4 . 6 1 1 4 . 7 2 1 4 . 7 6 1 4 . 8 0 1 4 . 8 8 1 4 . 9 6 1 5 . 0 1 1 5 . 1 1 1 5 . 2 0 1 5 . 3 9 1 5 . 4 8 1 5 . 5 6 1 5 . 7 1 1 5 . 8 1 1 6 . 0 7 1 6 . 2 1 1 6 . 2 9 1 6 . 4 2 1 6 . 6 2 1 6 . 7 2 1 6 . 8 9 1 7 . 0 8 1 7 . 1 6 1 7 . 2 3 1 7 . 2 7 1 7 . 3 3 1 7 . 3 7 1 7 . 4 5 1 7 . 5 5 1 7 . 6 6 1 7 . 7 3 1 7 . 8 2 1 7 . 9 0 1 8 . 1 4 1 8 . 2 5 1 8 . 3 6 1 8 . 6 0 1 8 . 6 5 1 8 . 7 1 1 8 . 7 5 1 8 . 9 3 1 9 . 0 1 1 9 . 1 3 1 9 . 2 4 1 9 . 3 1 1 9 . 4 7 1 9 . 5 4 1 9 . 6 1 1 9 . 7 1 1 9 . 7 5 1 9 . 9 5 2 0 . 0 1 2 0 . 1 6 2 0 . 3 8 2 0 . 4 6 2 0 . 5 0 2 0 . 6 0 2 0 . 6 8 2 0 . 7 6 2 0 . 8 7 2 0 . 9 6 2 1 . 0 9 2 1 . 1 6 2 1 . 2 1 2 1 . 2 7 2 1 . 4 2 2 1 . 4 8 2 1 . 7 2 2 1 . 8 6 2 1 . 9 6 2 2 . 0 1 2 2 . 0 8 2 2 . 1 5 2 2 . 2 1 2 2 . 3 0 2 2 . 3 3 2 2 . 3 9 2 2 . 4 5 2 2 . 5 0 2 2 . 6 7 2 2 . 8 0 2 2 . 8 5 2 2 . 9 3 2 2 . 9 7 2 3 . 1 1 2 3 . 3 3 2 3 . 4 2 2 3 . 4 9 2 3 . 6 2 2 3 . 7 0 2 3 . 7 3 2 3 . 7 7 2 4 . 1 4 2 4 . 1 8 2 4 . 3 1 2 4 . 4 1 2 4 . 4 4 2 4 . 5 7 2 4 . 6 3 2 4 . 7 1 2 4 . 7 8 2 4 . 8 4 2 5 . 0 2 2 5 . 0 8 2 5 . 1 2 2 5 . 1 7 2 5 . 2 4 2 5 . 3 1 2 5 . 4 4 2 5 . 5 7 2 5 . 7 4 2 5 . 8 1 2 5 . 8 9 2 5 . 9 6 2 6 . 0 8 2 6 . 1 3 2 6 . 2 1 2 6 . 3 0 2 6 . 3 8 2 6 . 4 4 2 6 . 5 4 2 6 . 6 0 2 6 . 7 5 2 6 . 9 4 2 7 . 0 9 2 7 . 1 4 2 7 . 3 6 2 7 . 3 9 2 7 . 5 2 2 7 . 6 0 2 7 . 6 9 2 7 . 7 3 2 7 . 8 0 2 8 . 2 1 2 8 . 3 9 2 8 . 4 4 2 8 . 6 3 2 8 . 6 9 2 8 . 7 7 2 8 . 8 5 2 9 . 0 0 2 9 . 1 4 2 9 . 2 7 2 9 . 3 9 2 9 . 7 6 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072714_b\0727HP3.0023.RAW B14072051-012A ;0727HP3 , $HC-EPH-SCRN-S, V93,(2,20) 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 20 40 60 80 100 120 140 160 180 200 220 240 Page 92 of 117 B10 7-8 Batch ID: 81615 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-013A ;0724HP3 , $HC-EPH-SCRN-S, V45 Raw File: G:\org\HP3\DAT\HP3072414_b\0724HP3.0045.RAW Date & Time Acquired: 7/25/2014 11:50:25 PM Method File: g:\org\HP3\Methods\SR_SCN-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.429 6.667 6.473 97.1 - *1-Chloro-octadecane_____13.249 6.667 6.88 103.2 - DRO Area:407763.5 DRO Amount: 0.8772742 TEH Area:1126157 TEH Amount: 2.422846 C9-C18 Area:564419.7 C9-C18 Amount: 1.214606 C19-C36 Area:357613.5 C19-C36 Amount: 0.7691917 4 . 2 2 4 . 4 1 4 . 5 2 4 . 7 1 4 . 8 0 4 . 8 9 4 . 9 9 5 . 1 0 5 . 3 2 5 . 4 7 5 . 5 6 5 . 6 5 5 . 7 3 5 . 8 3 5 . 9 2 6 . 0 6 6 . 1 6 6 . 2 6 6 . 5 2 6 . 6 7 6 . 8 5 7 . 0 1 7 . 0 7 7 . 1 2 7 . 2 6 7 . 3 9 7 . 4 5 7 . 5 5 7 . 8 2 8 . 5 0 8 . 6 8 8 . 7 8 8 . 8 3 8 . 8 8 8 . 9 3 9 . 0 5 9 . 0 9 9 . 1 5 9 . 2 1 9 . 3 3 9 . 4 6 9 . 5 7 9 . 6 1 9 . 6 7 9 . 8 3 1 0 . 1 4 1 0 . 1 6 1 0 . 3 6 1 0 . 4 3 1 0 . 5 4 1 0 . 6 1 1 0 . 6 7 1 0 . 7 9 1 1 . 0 6 1 1 . 3 3 1 1 . 3 8 1 1 . 4 8 1 1 . 6 1 1 1 . 6 7 1 1 . 8 2 1 1 . 9 7 1 2 . 0 3 1 2 . 0 9 1 2 . 2 8 1 2 . 3 4 1 2 . 4 3 1 2 . 6 6 1 2 . 7 7 1 2 . 8 6 1 2 . 9 1 1 2 . 9 9 1 3 . 2 5 1 3 . 5 0 1 3 . 5 8 1 3 . 6 8 1 3 . 9 7 1 4 . 0 8 1 4 . 1 5 1 4 . 4 5 1 4 . 5 3 1 4 . 5 6 1 4 . 7 1 1 4 . 7 6 1 4 . 8 9 1 4 . 9 5 1 5 . 1 9 1 5 . 3 4 1 5 . 4 9 1 5 . 5 7 1 5 . 6 2 1 5 . 7 0 1 5 . 8 5 1 5 . 9 7 1 6 . 0 5 1 6 . 2 0 1 6 . 4 1 1 6 . 6 7 1 6 . 7 6 1 6 . 8 4 1 6 . 8 8 1 7 . 0 8 1 7 . 2 2 1 7 . 3 3 1 7 . 4 9 1 7 . 5 5 1 7 . 7 3 1 7 . 7 9 1 7 . 8 5 1 7 . 9 2 1 8 . 1 0 1 8 . 2 5 1 8 . 3 6 1 8 . 6 0 1 8 . 6 8 1 8 . 7 8 1 8 . 8 5 1 8 . 9 6 1 9 . 1 6 1 9 . 3 2 1 9 . 4 7 1 9 . 7 7 2 0 . 1 9 2 0 . 3 1 2 4 . 7 7 2 7 . 4 1 2 8 . 4 8 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072414_b\0724HP3.0045.RAW B14072051-013A ;0724HP3 , $HC-EPH-SCRN-S, V45 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 93 of 117 B8 3-4 Batch ID: 81681 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14072051-014A ;0727HP3 , $HC-EPH-SCRN-S, V77 Raw File: G:\org\HP3\DAT\HP3072714_b\0727HP3.0003.RAW Date & Time Acquired: 7/27/2014 12:03:11 AM Method File: g:\org\HP3\Methods\SR_SCN-JU-L%.met Calibration File: G:\Org\HP3\Cals\SC140226Ju.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 30979.57 Mean RF for C19 to C36 Hydrocarbons: 30994.75 Mean RF for Total Extractable Hydrocarbons: 30987.16 Rt range for Diesel Range Organics: 6.442 to 16.785 Rt range for C9 to C18 Hydrocarbons: 5.412 to 12.363 Rt range for C19 to C36 Hydrocarbons: 12.398 to 19.284 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.43 6.667 5.074 76.1 - *1-Chloro-octadecane_____13.25 6.667 6.031 90.47 - DRO Area:274558.3 DRO Amount: 0.5906925 TEH Area:823663.8 TEH Amount: 1.772054 C9-C18 Area:457972.8 C9-C18 Amount: 0.9855371 C19-C36 Area:145352.8 C19-C36 Amount: 0.3126395 4 . 2 6 4 . 4 2 4 . 5 3 4 . 7 1 4 . 8 1 4 . 8 9 5 . 0 0 5 . 1 1 5 . 5 9 5 . 6 7 5 . 7 2 5 . 8 4 6 . 0 8 6 . 1 8 6 . 2 7 6 . 5 2 7 . 0 2 7 . 0 8 7 . 1 3 7 . 2 7 7 . 4 0 7 . 4 6 7 . 5 1 7 . 5 7 7 . 8 3 8 . 7 9 8 . 8 4 8 . 8 9 8 . 9 4 9 . 0 5 9 . 1 5 9 . 2 2 9 . 3 1 9 . 6 2 9 . 6 8 9 . 7 6 1 0 . 1 4 1 0 . 2 1 1 0 . 3 4 1 0 . 4 3 1 0 . 5 5 1 0 . 6 1 1 0 . 8 0 1 1 . 0 6 1 1 . 1 2 1 1 . 3 3 1 1 . 3 9 1 1 . 4 5 1 1 . 6 1 1 1 . 7 4 1 1 . 8 3 1 1 . 9 7 1 2 . 2 9 1 2 . 4 3 1 2 . 6 8 1 2 . 7 8 1 2 . 9 9 1 3 . 1 0 1 3 . 2 5 1 3 . 5 2 1 3 . 6 1 1 3 . 6 8 1 3 . 9 7 1 4 . 0 5 1 4 . 1 5 1 4 . 5 7 1 4 . 6 4 1 4 . 9 6 1 5 . 1 9 1 5 . 3 4 1 5 . 7 1 1 6 . 0 6 1 6 . 1 9 1 6 . 4 0 1 6 . 8 4 1 7 . 0 5 1 7 . 3 3 1 7 . 5 6 1 7 . 7 3 1 7 . 8 5 1 7 . 9 3 1 8 . 1 1 1 8 . 2 5 1 8 . 3 6 1 8 . 6 0 1 8 . 6 8 1 8 . 8 5 1 9 . 1 6 1 9 . 3 7 1 9 . 4 6 1 9 . 8 1 2 1 . 2 5 2 2 . 0 0 2 3 . 6 8 2 4 . 2 5 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3072714_b\0727HP3.0003.RAW B14072051-014A ;0727HP3 , $HC-EPH-SCRN-S, V77 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 94 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: MA-EPH Batch: 81798 Lab ID: LCS-81798-81615 08/01/14 00:04 Laboratory Control Sample Run: GCFID-HP3-B_140729F 17 C9 to C18 Aliphatics 76 40 140 10 30.6 mg/kg C19 to C36 Aliphatics 107 40 140 10 56.9 mg/kg n-Nonane 46 30 140 0.17 3.04 mg/kg n-Decane 57 40 140 0.17 3.82 mg/kg n-Dodecane 70 40 140 0.17 4.68 mg/kg n-Tetradecane 80 40 140 0.17 5.30 mg/kg n-Hexadecane 88 40 140 0.17 5.87 mg/kg n-Octadecane 99 40 140 0.17 6.63 mg/kg n-Nonadecane 110 40 140 0.17 7.35 mg/kg n-Eicosane 100 40 140 0.17 6.64 mg/kg n-Docosane 106 40 140 0.17 7.03 mg/kg n-Tetracosane 107 40 140 0.17 7.11 mg/kg n-Hexacosane 107 40 140 0.17 7.12 mg/kg n-Octacosane 98 40 140 0.17 6.54 mg/kg n-Triacontane 105 40 140 0.17 7.03 mg/kg n-Hexatriacontane 111 40 140 0.17 7.42 mg/kg Surr: 1-Chloro-octadecane 98 40 140 0.17 Lab ID: MB-81798-81615 08/01/14 00:50 Method Blank Run: GCFID-HP3-B_140729F 3 C9 to C18 Aliphatics 10 ND mg/kg C19 to C36 Aliphatics 10 ND mg/kg Surr: 1-Chloro-octadecane 88 40 140 0.17 Lab ID: B14071970-001AMS 08/01/14 02:21 Sample Duplicate Run: GCFID-HP3-B_140729F 3 C9 to C18 Aliphatics 20 11 22 706 mg/kg-dry R n-Tetradecane 20 0.18 22 26.5 mg/kg-dry R n-Hexadecane 20 0.18 9.6 23.8 mg/kg-dry - Because the sample amount was significantly higher than the spike amount for some analytes, the MS and MSD spike samples for these analytes are calculated as Duplicate samples based on the spike amount added plus the original sample concentration. Lab ID: B14071970-001AMS 08/01/14 02:21 Sample Matrix Spike Run: GCFID-HP3-B_140729F 14 C19 to C36 Aliphatics 70 40 140 11 145 mg/kg-dry n-Nonane 42 30 140 0.18 3.06 mg/kg-dry n-Decane 50 40 140 0.18 4.48 mg/kg-dry n-Dodecane 29 40 140 0.18 14.9 mg/kg-dry S n-Octadecane 66 40 140 0.18 15.4 mg/kg-dry n-Nonadecane 76 40 140 0.18 15.3 mg/kg-dry n-Eicosane 75 40 140 0.18 10.9 mg/kg-dry n-Docosane 89 40 140 0.18 8.15 mg/kg-dry n-Tetracosane 93 40 140 0.18 7.34 mg/kg-dry n-Hexacosane 94 40 140 0.18 7.05 mg/kg-dry n-Octacosane 87 40 140 0.18 6.41 mg/kg-dry n-Triacontane 96 40 140 0.18 7.07 mg/kg-dry n-Hexatriacontane 103 40 140 0.18 7.58 mg/kg-dry Surr: 1-Chloro-octadecane 92 40 140 0.18 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. R - RPD exceeds advisory limit. S - Spike recovery outside of advisory limits. Page 95 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: MA-EPH Batch: 81798 Lab ID: B14071970-001AMSD 08/01/14 05:03 Sample Duplicate Run: GCFID-HP3-B_140729F 3 C9 to C18 Aliphatics 20 11 9.9 798 mg/kg-dry n-Tetradecane 20 0.18 12 29.2 mg/kg-dry n-Hexadecane 20 0.18 1.2 26.5 mg/kg-dry - Because the sample amount was significantly higher than the spike amount for some analytes, the MS and MSD spike samples for these analytes are calculated as Duplicate samples based on the spike amount added plus the original sample concentration. Lab ID: B14071970-001AMSD 08/01/14 05:03 Sample Matrix Spike Duplicate Run: GCFID-HP3-B_140729F 14 C19 to C36 Aliphatics 92 40 140 20 11 8.5 158 mg/kg-dry n-Nonane 40 30 140 30 0.18 4.4 2.93 mg/kg-dry n-Decane 50 40 140 20 0.18 1.3 4.54 mg/kg-dry n-Dodecane 47 40 140 20 0.18 8.6 16.2 mg/kg-dry n-Octadecane 90 40 140 20 0.18 11 17.1 mg/kg-dry n-Nonadecane 99 40 140 20 0.18 11 17.0 mg/kg-dry n-Eicosane 90 40 140 20 0.18 9.9 12.0 mg/kg-dry n-Docosane 97 40 140 20 0.18 7.6 8.79 mg/kg-dry n-Tetracosane 100 40 140 20 0.18 7.1 7.88 mg/kg-dry n-Hexacosane 100 40 140 20 0.18 6.4 7.51 mg/kg-dry n-Octacosane 93 40 140 20 0.18 5.9 6.80 mg/kg-dry n-Triacontane 100 40 140 20 0.18 4.0 7.36 mg/kg-dry n-Hexatriacontane 106 40 140 20 0.18 2.3 7.75 mg/kg-dry Surr: 1-Chloro-octadecane 96 40 140 0.18 Lab ID: MB-81798-81615 08/01/14 12:11 Method Blank Run: GCFID-HP3-B_140729F 20 C11 to C22 Aromatics 10 ND mg/kg Total Extractable Hydrocarbons 10 ND mg/kg Naphthalene 0.17 ND mg/kg 2-MethylNaphthalene 0.17 ND mg/kg Acenaphthylene 0.17 ND mg/kg Acenaphthene 0.17 ND mg/kg Fluorene 0.17 ND mg/kg Phenanthrene 0.17 ND mg/kg Anthracene 0.17 ND mg/kg Fluoranthene 0.17 ND mg/kg Pyrene 0.17 ND mg/kg Benzo(a)Anthracene 0.17 ND mg/kg Chrysene 0.17 ND mg/kg Benzo(b)Fluoranthene/Benzo(k)Fluorant 0.17 ND mg/kg Benzo(a)Pyrene 0.17 ND mg/kg Dibenz(a,h)anthracene/Indeno(1,2,3-cd) 0.17 ND mg/kg Benzo(g,h,I)perylene 0.17 ND mg/kg Surr: 2-Bromonaphthalene 94 40 140 0.17 Surr: 2-Fluorobiphenyl 90 40 140 0.17 Surr: o-Terphenyl 90 40 140 0.17 Lab ID: B14071970-001AMS 08/01/14 13:43 Sample Duplicate Run: GCFID-HP3-B_140729F Total Extractable Hydrocarbons 20 11 20 1160 mg/kg-dry Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 96 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: MA-EPH Batch: 81798 Lab ID: B14071970-001AMS 08/01/14 13:43 Sample Duplicate Run: GCFID-HP3-B_140729F - Because the sample amount was significantly higher than the spike amount for some analytes, the MS and MSD spike samples for these analytes are calculated as Duplicate samples based on the spike amount added plus the original sample concentration. Lab ID: B14071970-001AMS 08/01/14 13:43 Sample Matrix Spike Run: GCFID-HP3-B_140729F 19 C11 to C22 Aromatics 55 40 140 11 293 mg/kg-dry Naphthalene 52 40 140 0.18 7.29 mg/kg-dry 2-MethylNaphthalene 72 40 140 0.18 9.61 mg/kg-dry Acenaphthylene 75 40 140 0.18 6.75 mg/kg-dry Acenaphthene 90 40 140 0.18 7.13 mg/kg-dry Fluorene 81 40 140 0.18 7.49 mg/kg-dry Phenanthrene 90 40 140 0.18 6.68 mg/kg-dry Anthracene 86 40 140 0.18 6.48 mg/kg-dry Fluoranthene 91 40 140 0.18 6.81 mg/kg-dry Pyrene 95 40 140 0.18 7.10 mg/kg-dry Benzo(a)Anthracene 90 40 140 0.18 6.58 mg/kg-dry Chrysene 102 40 140 0.18 7.50 mg/kg-dry Benzo(b)Fluoranthene/Benzo(k)Fluorant 93 40 140 0.18 13.6 mg/kg-dry Benzo(a)Pyrene 100 40 140 0.18 7.36 mg/kg-dry Dibenz(a,h)anthracene/Indeno(1,2,3-cd) 92 40 140 0.18 13.5 mg/kg-dry Benzo(g,h,I)perylene 91 40 140 0.18 6.65 mg/kg-dry Surr: 2-Bromonaphthalene 89 40 140 0.18 Surr: 2-Fluorobiphenyl 86 40 140 0.18 Surr: o-Terphenyl 87 40 140 0.18 Lab ID: B14071970-001AMSD 08/01/14 14:29 Sample Duplicate Run: GCFID-HP3-B_140729F Total Extractable Hydrocarbons 20 11 8.6 1300 mg/kg-dry - Because the sample amount was significantly higher than the spike amount for some analytes, the MS and MSD spike samples for these analytes are calculated as Duplicate samples based on the spike amount added plus the original sample concentration. Lab ID: B14071970-001AMSD 08/01/14 14:29 Sample Matrix Spike Duplicate Run: GCFID-HP3-B_140729F 19 C11 to C22 Aromatics 85 40 140 20 11 12 331 mg/kg-dry Naphthalene 58 40 140 20 0.18 5.3 7.69 mg/kg-dry 2-MethylNaphthalene 80 40 140 20 0.18 6.2 10.2 mg/kg-dry Acenaphthylene 80 40 140 20 0.18 5.5 7.13 mg/kg-dry Acenaphthene 96 40 140 20 0.18 5.9 7.56 mg/kg-dry Fluorene 88 40 140 20 0.18 6.2 7.97 mg/kg-dry Phenanthrene 97 40 140 20 0.18 7.0 7.16 mg/kg-dry Anthracene 92 40 140 20 0.18 6.4 6.90 mg/kg-dry Fluoranthene 99 40 140 20 0.18 8.0 7.37 mg/kg-dry Pyrene 104 40 140 20 0.18 8.2 7.71 mg/kg-dry Benzo(a)Anthracene 96 40 140 20 0.18 7.2 7.07 mg/kg-dry Chrysene 107 40 140 20 0.18 4.8 7.87 mg/kg-dry Benzo(b)Fluoranthene/Benzo(k)Fluorant 99 40 140 20 0.18 6.4 14.5 mg/kg-dry Benzo(a)Pyrene 108 40 140 20 0.18 7.2 7.91 mg/kg-dry Dibenz(a,h)anthracene/Indeno(1,2,3-cd) 99 40 140 20 0.18 6.6 14.5 mg/kg-dry Benzo(g,h,I)perylene 98 40 140 20 0.18 7.9 7.20 mg/kg-dry Surr: 2-Bromonaphthalene 94 40 140 0.18 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 97 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: MA-EPH Batch: 81798 Lab ID: B14071970-001AMSD 08/01/14 14:29 Sample Matrix Spike Duplicate Run: GCFID-HP3-B_140729F 19 Surr: 2-Fluorobiphenyl 90 40 140 0.18 Surr: o-Terphenyl 92 40 140 0.18 Lab ID: LCS-81798-81615 08/01/14 11:26 Laboratory Control Sample Run: GCFID-HP3-B_140729G 20 C11 to C22 Aromatics 101 40 140 10 115 mg/kg Total Extractable Hydrocarbons 99 40 140 10 205 mg/kg Naphthalene 63 40 140 0.17 4.22 mg/kg 2-MethylNaphthalene 80 40 140 0.17 5.37 mg/kg Acenaphthylene 80 40 140 0.17 5.30 mg/kg Acenaphthene 91 40 140 0.17 6.05 mg/kg Fluorene 93 40 140 0.17 6.21 mg/kg Phenanthrene 99 40 140 0.17 6.58 mg/kg Anthracene 105 40 140 0.17 6.99 mg/kg Fluoranthene 107 40 140 0.17 7.12 mg/kg Pyrene 111 40 140 0.17 7.41 mg/kg Benzo(a)Anthracene 105 40 140 0.17 7.02 mg/kg Chrysene 116 40 140 0.17 7.74 mg/kg Benzo(b)Fluoranthene/Benzo(k)Fluorant 110 40 140 0.17 14.7 mg/kg Benzo(a)Pyrene 114 40 140 0.17 7.57 mg/kg Dibenz(a,h)anthracene/Indeno(1,2,3-cd) 108 40 140 0.17 14.4 mg/kg Benzo(g,h,I)perylene 106 40 140 0.17 7.06 mg/kg Surr: 2-Bromonaphthalene 82 40 140 0.17 Surr: 2-Fluorobiphenyl 90 40 140 0.17 Surr: o-Terphenyl 100 40 140 0.17 Method: MA-EPH Analytical Run: R228239 Lab ID: CCV_0801HP325r-S 08/02/14 12:12 Continuing Calibration Verification Standard 15 n-Nonane 115 75 125 0.17 7.65 mg/kg n-Decane 117 75 125 0.17 7.82 mg/kg n-Dodecane 117 75 125 0.17 7.80 mg/kg n-Tetradecane 117 75 125 0.17 7.81 mg/kg n-Hexadecane 118 75 125 0.17 7.87 mg/kg n-Octadecane 118 75 125 0.17 7.84 mg/kg n-Nonadecane 118 75 125 0.17 7.89 mg/kg n-Eicosane 112 75 125 0.17 7.46 mg/kg n-Docosane 117 75 125 0.17 7.77 mg/kg n-Tetracosane 118 75 125 0.17 7.84 mg/kg n-Hexacosane 118 75 125 0.17 7.84 mg/kg n-Octacosane 109 75 125 0.17 7.25 mg/kg n-Triacontane 115 75 125 0.17 7.69 mg/kg n-Hexatriacontane 115 75 125 0.17 7.70 mg/kg Surr: 1-Chloro-octadecane 113 75 125 0.17 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 98 of 117 Project: Bozeman Mount Yard Client: MT DEQ-Lust Work Order: B14072051 QA/QC Summary Report 08/08/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: MA-EPH Analytical Run: R228416 Lab ID: CCV_0804HP338r-S 08/05/14 00:00 Continuing Calibration Verification Standard 15 n-Nonane 110 75 125 0.17 7.31 mg/kg n-Decane 113 75 125 0.17 7.52 mg/kg n-Dodecane 112 75 125 0.17 7.46 mg/kg n-Tetradecane 113 75 125 0.17 7.50 mg/kg n-Hexadecane 113 75 125 0.17 7.55 mg/kg n-Octadecane 113 75 125 0.17 7.52 mg/kg n-Nonadecane 114 75 125 0.17 7.57 mg/kg n-Eicosane 107 75 125 0.17 7.16 mg/kg n-Docosane 112 75 125 0.17 7.44 mg/kg n-Tetracosane 112 75 125 0.17 7.48 mg/kg n-Hexacosane 113 75 125 0.17 7.51 mg/kg n-Octacosane 104 75 125 0.17 6.95 mg/kg n-Triacontane 111 75 125 0.17 7.39 mg/kg n-Hexatriacontane 110 75 125 0.17 7.33 mg/kg Surr: 1-Chloro-octadecane 109 75 125 0.17 Lab ID: CCV_0804HP325r-S 08/05/14 09:21 Continuing Calibration Verification Standard 18 Naphthalene 111 75 125 0.17 7.42 mg/kg 2-MethylNaphthalene 112 75 125 0.17 7.44 mg/kg Acenaphthylene 108 75 125 0.17 7.22 mg/kg Acenaphthene 118 75 125 0.17 7.84 mg/kg Fluorene 112 75 125 0.17 7.47 mg/kg Phenanthrene 109 75 125 0.17 7.27 mg/kg Anthracene 116 75 125 0.17 7.75 mg/kg Fluoranthene 112 75 125 0.17 7.50 mg/kg Pyrene 113 75 125 0.17 7.55 mg/kg Benzo(a)Anthracene 102 75 125 0.17 6.78 mg/kg Chrysene 121 75 125 0.17 8.07 mg/kg Benzo(b)Fluoranthene/Benzo(k)Fluorant 113 75 125 0.17 15.1 mg/kg Benzo(a)Pyrene 111 75 125 0.17 7.37 mg/kg Dibenz(a,h)anthracene/Indeno(1,2,3-cd) 112 75 125 0.17 14.9 mg/kg Benzo(g,h,I)perylene 108 75 125 0.17 7.23 mg/kg Surr: 2-Bromonaphthalene 102 75 125 0.17 Surr: 2-Fluorobiphenyl 112 75 125 0.17 Surr: o-Terphenyl 111 75 125 0.17 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 99 of 117 B2 3-4 Batch ID: 81798 EPH ALIPHATICS (FID) ANALYSIS REPORT Sample Name: B14072051-003A ;0801HP3 , $HC-ALI-GRP-S, V29 Raw File: G:\org\HP3\DAT\HP3080114_b\0801HP3.0030.RAW Date & Time Acquired: 8/2/2014 3:58:26 PM Method File: g:\org\HP3\Methods\L3_EPH-LB-L%.met Calibration File: G:\Org\HP3\Cals\AL130823LB.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Aliphatic Hydrocarbons: 30415.23 Mean RF for C19 to C36 Aliphatic Hydrocarbons: 31274 Mean RF for Total Extractable Hydrocarbons: 30905.96 Rt range for Diesel Range Organics: 8.427999 to 20.231 Rt range for C9 to C18 Aliphatic Hydrocarbons: 6.638 to 16.417 Rt range for C19 to C36 Aliphatic Hydrocarbons: 16.442 to 23.523 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *1-Chloro-octadecane_____17.369 6.667 6.338 95.07 - DRO Area:2.359008E+07 DRO Amount: 50.88572 TEH Area:8.434979E+07 TEH Amount: 181.9494 Aliphatic Hydrocarbon Areas and Amounts: C9-C18 Area:1220781 C9-C18 Amount: 2.675812 C19-C36 Area:7.193922E+07C19-C36 Amount: 153.3526 4 . 2 9 4 . 7 7 4 . 8 4 4 . 9 4 5 . 0 5 5 . 2 0 5 . 4 1 5 . 4 7 5 . 6 0 5 . 7 3 5 . 8 9 6 . 0 5 6 . 7 6 7 . 0 9 7 . 2 8 7 . 3 8 7 . 5 0 7 . 5 9 7 . 7 6 8 . 0 7 8 . 2 6 8 . 5 5 8 . 8 7 8 . 9 3 9 . 1 1 9 . 2 0 9 . 3 0 9 . 3 9 9 . 5 0 9 . 5 9 9 . 8 4 1 0 . 0 8 1 0 . 2 0 1 0 . 2 8 1 0 . 3 7 1 0 . 5 9 1 0 . 9 1 1 0 . 9 8 1 1 . 1 0 1 1 . 2 0 1 1 . 6 2 1 1 . 7 6 1 1 . 9 0 1 2 . 0 6 1 2 . 2 1 1 2 . 3 2 1 2 . 3 9 1 2 . 4 9 1 2 . 6 0 1 2 . 6 7 1 2 . 8 2 1 2 . 8 9 1 2 . 9 7 1 3 . 0 9 1 3 . 2 2 1 3 . 2 6 1 3 . 3 1 1 3 . 4 4 1 3 . 5 0 1 3 . 7 5 1 3 . 9 4 1 3 . 9 8 1 4 . 0 4 1 4 . 0 9 1 4 . 1 2 1 4 . 2 0 1 4 . 4 5 1 4 . 5 4 1 4 . 6 1 1 4 . 7 0 1 4 . 8 3 1 5 . 0 4 1 5 . 1 2 1 5 . 2 0 1 5 . 3 2 1 5 . 4 4 1 5 . 5 9 1 5 . 6 5 1 5 . 7 0 1 5 . 7 6 1 5 . 8 5 1 5 . 9 5 1 6 . 0 0 1 6 . 0 8 1 6 . 1 4 1 6 . 1 7 1 6 . 2 4 1 6 . 3 2 1 6 . 4 6 1 6 . 5 8 1 6 . 6 7 1 6 . 7 3 1 6 . 8 1 1 6 . 8 7 1 6 . 9 4 1 7 . 0 3 1 7 . 1 2 1 7 . 2 6 1 7 . 3 0 1 7 . 3 7 1 7 . 6 0 1 7 . 7 2 1 7 . 7 8 1 7 . 8 5 1 7 . 9 4 1 8 . 0 1 1 8 . 1 3 1 8 . 1 6 1 8 . 2 7 1 8 . 3 6 1 8 . 4 0 1 8 . 4 6 1 8 . 5 5 1 8 . 6 8 1 8 . 7 6 1 8 . 8 8 1 8 . 9 3 1 8 . 9 8 1 9 . 0 7 1 9 . 1 6 1 9 . 2 2 1 9 . 3 5 1 9 . 4 5 1 9 . 5 3 1 9 . 5 9 1 9 . 6 9 1 9 . 8 1 1 9 . 9 4 2 0 . 0 7 2 0 . 1 4 2 0 . 2 7 2 0 . 3 7 2 0 . 4 1 2 0 . 4 5 2 0 . 5 1 2 0 . 6 3 2 0 . 7 1 2 0 . 7 7 2 0 . 8 4 2 0 . 9 4 2 1 . 0 6 2 1 . 1 6 2 1 . 2 3 2 1 . 2 9 2 1 . 4 9 2 1 . 6 1 2 1 . 7 7 2 1 . 8 7 2 1 . 9 5 2 2 . 0 0 2 2 . 0 5 2 2 . 3 3 2 2 . 4 2 2 2 . 5 9 2 2 . 8 1 2 2 . 9 4 2 3 . 0 7 2 3 . 3 7 2 3 . 5 6 2 3 . 7 0 2 3 . 7 7 2 3 . 8 4 2 3 . 9 6 2 4 . 0 4 2 4 . 3 3 2 4 . 4 5 2 4 . 5 1 2 4 . 8 8 2 5 . 1 4 2 5 . 4 1 2 5 . 6 2 2 5 . 7 3 2 5 . 8 1 2 5 . 9 4 2 5 . 9 7 2 6 . 0 3 2 6 . 0 8 2 6 . 2 8 2 6 . 4 5 2 6 . 5 8 2 6 . 6 9 2 6 . 7 8 2 6 . 8 2 2 6 . 9 1 2 6 . 9 5 2 7 . 5 5 2 7 . 5 9 2 7 . 7 4 2 7 . 7 7 2 7 . 8 5 2 7 . 9 0 2 8 . 0 1 2 8 . 0 8 2 8 . 1 7 2 8 . 2 6 2 8 . 3 3 2 8 . 4 9 2 8 . 5 5 2 8 . 6 8 2 8 . 7 7 2 8 . 9 1 2 9 . 0 1 2 9 . 0 6 2 9 . 1 3 2 9 . 1 7 2 9 . 2 3 2 9 . 2 7 2 9 . 3 2 2 9 . 3 8 2 9 . 4 2 2 9 . 5 0 2 9 . 6 1 2 9 . 7 4 2 9 . 7 9 2 9 . 8 3 2 9 . 9 6 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e * 2 - B r o m o n a p h t h a l e n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3080114_b\0801HP3.0030.RAW B14072051-003A ;0801HP3 , $HC-ALI-GRP-S, V29 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 100 of 117 B2 3-4 Batch ID: 81798 EPH AROMATICS RANGE VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-003A ;0804HP3 , $HC-ARO-GRP-S, RR2-V27 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0027.RAW Date & Time Acquired: 8/5/2014 11:17:50 AM Method File: g:\org\HP3\Methods\R3_EPH-080427-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF EPH Aromatics: 32892.63 Rt range for EPH C11 to C22 Aromatics: 11.327 to 22.281 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *2-Fluorobiphenyl________13.288 6.667 5.673 85.1 - *2-Bromonaphthalene______14.155 6.667 5.791 86.86 - *o-Terphenyl_____________16.535 6.667 5.801 87.01 - *1-Chlorooctadecane______17.357 6.667 .327 4.91 - C11-C22 Aromatics Area:2.328404E+07 C11-C22 Aromatics Amount: 47.192 EPH Aromatics total Area:7.254211E+07 EPH Aromatics Total Amount: 147.0281 4 . 5 2 4 . 6 8 4 . 8 0 4 . 8 7 4 . 8 9 4 . 9 4 4 . 9 8 5 . 0 3 5 . 1 9 5 . 5 8 5 . 8 8 6 . 0 4 7 . 4 7 8 . 8 5 8 . 9 9 9 . 0 6 9 . 1 1 9 . 4 9 9 . 5 8 9 . 6 4 9 . 7 2 9 . 9 3 1 0 . 0 8 1 0 . 2 0 1 0 . 2 9 1 0 . 4 3 1 0 . 5 8 1 0 . 6 3 1 0 . 9 1 1 0 . 9 7 1 1 . 0 9 1 1 . 2 1 1 1 . 6 7 1 1 . 9 5 1 2 . 0 8 1 2 . 1 6 1 2 . 4 5 1 2 . 5 4 1 2 . 6 7 1 2 . 7 7 1 2 . 8 9 1 3 . 0 6 1 3 . 1 5 1 3 . 2 9 1 3 . 6 5 1 3 . 7 8 1 3 . 9 2 1 4 . 0 1 1 4 . 1 5 1 4 . 4 2 1 4 . 6 3 1 4 . 7 4 1 4 . 8 6 1 4 . 9 1 1 5 . 1 4 1 5 . 2 3 1 5 . 3 9 1 5 . 4 7 1 5 . 5 0 1 5 . 6 2 1 5 . 7 7 1 5 . 9 1 1 5 . 9 3 1 6 . 0 8 1 6 . 3 3 1 6 . 4 5 1 6 . 5 3 1 6 . 6 6 1 6 . 7 0 1 6 . 8 1 1 6 . 9 3 1 7 . 0 6 1 7 . 1 8 1 7 . 2 5 1 7 . 3 6 1 7 . 4 9 1 7 . 5 9 1 7 . 7 5 1 7 . 8 1 1 7 . 8 7 1 7 . 9 7 1 8 . 0 4 1 8 . 0 8 1 8 . 1 3 1 8 . 2 4 1 8 . 3 0 1 8 . 4 0 1 8 . 5 1 1 8 . 6 4 1 8 . 7 0 1 8 . 7 3 1 8 . 8 2 1 8 . 9 2 1 9 . 0 2 1 9 . 2 1 1 9 . 3 0 1 9 . 3 6 1 9 . 4 2 1 9 . 4 8 1 9 . 5 6 1 9 . 6 7 1 9 . 7 8 1 9 . 8 7 1 9 . 9 4 2 0 . 0 0 2 0 . 0 7 2 0 . 1 6 2 0 . 2 1 2 0 . 2 9 2 0 . 3 9 2 0 . 4 6 2 0 . 5 0 2 0 . 6 2 2 0 . 6 8 2 0 . 7 4 2 0 . 8 4 2 0 . 9 1 2 0 . 9 7 2 1 . 1 8 2 1 . 2 8 2 1 . 3 2 2 1 . 4 2 2 1 . 5 4 2 1 . 6 6 2 1 . 7 8 2 1 . 8 3 2 2 . 0 0 2 2 . 0 7 2 2 . 2 8 2 2 . 3 7 2 2 . 4 5 2 2 . 6 1 2 2 . 7 7 2 2 . 8 7 2 2 . 9 8 2 3 . 0 3 2 3 . 2 1 2 3 . 3 3 2 3 . 3 8 2 3 . 4 6 2 3 . 5 6 2 3 . 6 8 2 3 . 7 1 2 3 . 7 9 2 3 . 8 5 2 3 . 9 2 2 3 . 9 7 2 4 . 1 4 2 4 . 2 7 2 4 . 3 0 2 4 . 3 6 2 4 . 5 2 2 4 . 6 1 2 4 . 7 6 2 4 . 8 2 2 4 . 9 1 2 4 . 9 9 2 5 . 2 0 2 5 . 2 9 2 5 . 4 9 2 5 . 6 0 2 5 . 6 3 2 5 . 6 8 2 5 . 7 5 2 5 . 7 8 2 5 . 8 4 2 5 . 9 7 2 6 . 1 5 2 6 . 4 2 2 6 . 4 5 2 6 . 4 9 2 6 . 6 6 2 6 . 7 2 2 6 . 7 5 2 6 . 9 5 2 7 . 0 1 2 7 . 1 7 2 7 . 2 1 2 7 . 2 5 2 7 . 3 2 2 7 . 4 0 2 7 . 4 9 2 7 . 5 4 2 7 . 6 8 2 7 . 7 2 2 7 . 8 7 2 7 . 9 6 2 7 . 9 9 2 8 . 0 6 2 8 . 1 2 2 8 . 2 1 2 8 . 2 5 2 8 . 3 7 2 8 . 4 9 2 8 . 7 7 2 8 . 8 5 2 8 . 9 6 2 9 . 0 1 2 9 . 0 4 2 9 . 1 8 2 9 . 2 4 2 9 . 3 4 2 9 . 4 3 2 9 . 5 1 2 9 . 5 8 2 9 . 6 2 2 9 . 6 8 2 9 . 7 2 2 9 . 7 6 2 9 . 8 1 2 9 . 8 5 2 9 . 9 1 2 9 . 9 6 3 0 . 0 6 3 0 . 1 2 3 0 . 2 7 3 0 . 3 1 3 0 . 3 5 3 0 . 4 2 3 0 . 5 3 3 0 . 6 5 3 0 . 7 0 3 0 . 7 4 3 0 . 8 2 3 0 . 9 0 3 0 . 9 2 3 1 . 0 5 3 1 . 1 1 3 1 . 1 5 3 1 . 2 1 3 1 . 2 6 3 1 . 4 0 3 1 . 4 7 3 1 . 5 4 3 1 . 6 3 3 1 . 6 9 3 1 . 7 6 3 1 . 8 0 3 1 . 8 8 3 1 . 9 2 3 1 . 9 7 3 2 . 0 1 3 2 . 1 2 3 2 . 2 4 3 2 . 2 9 3 2 . 3 5 3 2 . 4 1 3 2 . 5 2 3 2 . 6 6 3 2 . 7 2 3 2 . 8 5 3 2 . 9 7 3 3 . 0 7 3 3 . 1 9 3 3 . 2 4 3 3 . 2 8 3 3 . 3 3 3 3 . 4 4 3 3 . 5 3 3 3 . 5 9 3 3 . 7 0 3 3 . 7 6 3 3 . 8 2 3 3 . 8 8 3 3 . 9 4 3 4 . 0 3 3 4 . 0 8 3 4 . 1 6 3 4 . 2 2 3 4 . 2 8 3 4 . 3 2 3 4 . 3 8 3 4 . 4 5 3 4 . 5 1 3 4 . 5 6 3 4 . 6 3 3 4 . 6 8 3 4 . 7 7 3 4 . 8 5 3 4 . 9 0 3 4 . 9 8 3 5 . 0 5 3 5 . 1 2 3 5 . 1 7 3 5 . 2 4 3 5 . 2 8 3 5 . 3 2 3 5 . 3 9 3 5 . 4 8 3 5 . 5 5 3 5 . 6 1 3 5 . 6 8 3 5 . 7 8 3 5 . 9 1 3 6 . 0 3 3 6 . 1 1 3 6 . 1 9 3 6 . 2 9 3 6 . 3 3 3 6 . 4 2 3 6 . 4 6 3 6 . 5 1 3 6 . 5 8 3 6 . 6 7 3 6 . 7 7 3 6 . 8 2 3 6 . 8 8 3 6 . 9 6 3 7 . 0 3 3 7 . 3 1 3 7 . 3 9 3 7 . 4 9 3 7 . 5 7 3 7 . 6 7 3 7 . 7 4 3 7 . 8 6 3 7 . 9 7 3 8 . 0 6 3 8 . 1 0 3 8 . 1 5 3 8 . 2 9 3 8 . 3 3 3 8 . 3 9 3 8 . 4 7 3 8 . 6 0 3 8 . 6 4 3 8 . 7 0 3 8 . 8 2 3 8 . 9 0 3 9 . 0 0 3 9 . 0 8 3 9 . 2 0 3 9 . 2 9 3 9 . 3 8 3 9 . 4 4 3 9 . 5 4 3 9 . 6 0 3 9 . 6 7 3 9 . 7 0 3 9 . 7 8 3 9 . 8 3 3 9 . 8 8 3 9 . 9 7 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0027.RAW B14072051-003A ;0804HP3 , $HC-ARO-GRP-S, RR2-V27 0 5 10 15 20 25 30 35 40 0 500 1000 1500 2000 2500 3000 Page 101 of 117 B2 3-4 Batch ID: 81798 EPH AROMATICS TARGET VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-003A ;0804HP3 , $HC-ARO-GRP-S, RR2-V27 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0027.RAW Date & Time Acquired: 8/5/2014 11:17:50 AM Method File: g:\org\HP3\Methods\RT_EPH-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG Naphthalene______________. . . .067 U 2-Methylnaphthalene______12.671 12.671 12.671 4293 .067 U Acenaphthylene___________13.921 13.921 13.921 23319 .067 U Acenaphthene_____________. . . .067 U Fluorene_________________14.861 14.861 14.861 16932 .067 U Phenanthrene_____________. . . .067 U Anthracene_______________16.079 -1.94 -1.924 35571 .071 Fluoranthene_____________17.49 -3.297 -3.335 32097 .064 J Pyrene___________________17.745 -3.558 -3.591 39811 .079 Benzo(a)Anthracene_______. . . .067 U Chrysene_________________19.206 -5.055 -5.051 38292 .078 Benzo(b&k)Fluoranthe_____20.388 20.388 20.388 20927 .133 U Benzo(a)Pyrene___________20.679 20.679 20.679 12058 .067 U Indeno-Dibenzo___________21.826 21.826 21.826 19728 .133 U Benzo(g,h,i)Perylene_____. . . .067 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS *2-Fluorobiphenyl________13.288 6.667 5.673 85.09 40-140 *2-Bromonaphthalene______14.155 6.667 5.784 86.76 40-140 *o-Terphenyl_____________16.535 6.667 5.757 86.35 40-140 *1-Chlorooctadecane______17.357 6.667 .213 3.2 40-140 1 0 . 5 8 1 0 . 6 3 1 0 . 9 1 1 0 . 9 7 1 1 . 0 9 1 1 . 2 1 1 1 . 6 7 1 1 . 9 5 1 2 . 0 8 1 2 . 1 6 1 2 . 4 5 1 2 . 5 4 1 2 . 6 7 1 2 . 7 7 1 2 . 8 9 1 3 . 0 6 1 3 . 1 5 1 3 . 2 2 1 3 . 2 9 1 3 . 6 5 1 3 . 7 8 1 3 . 9 2 1 4 . 0 1 1 4 . 1 5 1 4 . 4 2 1 4 . 6 3 1 4 . 7 4 1 4 . 8 6 1 4 . 9 1 1 5 . 1 4 1 5 . 2 3 1 5 . 3 9 1 5 . 4 7 1 5 . 5 0 1 5 . 6 2 1 5 . 7 7 1 5 . 9 1 1 5 . 9 3 1 6 . 0 8 1 6 . 3 3 1 6 . 4 5 1 6 . 5 3 1 6 . 6 6 1 6 . 7 0 1 6 . 8 1 1 6 . 9 3 1 7 . 0 6 1 7 . 1 8 1 7 . 2 5 1 7 . 3 6 1 7 . 4 9 1 7 . 5 9 1 7 . 7 5 1 7 . 8 1 1 7 . 8 7 1 7 . 9 7 1 8 . 0 4 1 8 . 0 8 1 8 . 1 3 1 8 . 2 4 1 8 . 3 0 1 8 . 4 0 1 8 . 5 1 1 8 . 6 4 1 8 . 7 0 1 8 . 7 3 1 8 . 8 2 1 8 . 9 2 1 9 . 0 2 1 9 . 2 1 1 9 . 3 0 1 9 . 3 6 1 9 . 4 2 1 9 . 4 8 1 9 . 5 6 1 9 . 6 7 1 9 . 7 8 1 9 . 8 7 1 9 . 9 4 2 0 . 0 0 2 0 . 0 7 2 0 . 1 6 2 0 . 2 1 2 0 . 2 9 2 0 . 3 9 2 0 . 4 6 2 0 . 5 0 2 0 . 5 9 2 0 . 6 8 2 0 . 7 4 2 0 . 8 0 2 0 . 9 1 2 0 . 9 7 2 1 . 0 7 2 1 . 2 8 2 1 . 3 2 2 1 . 4 2 2 1 . 5 4 2 1 . 6 6 2 1 . 7 8 2 1 . 8 3 2 2 . 0 0 2 2 . 0 7 2 2 . 2 8 2 2 . 3 7 2 2 . 4 5 2 2 . 6 1 2 2 . 7 7 2 2 . 8 7 2 2 . 9 8 2 3 . 0 3 2 3 . 2 1 2 3 . 3 3 2 3 . 3 8 2 3 . 4 6 2 3 . 5 6 2 3 . 6 8 2 3 . 7 1 2 3 . 7 9 2 3 . 8 5 2 3 . 9 2 2 3 . 9 7 2 4 . 1 4 2 4 . 2 7 2 4 . 3 0 2 4 . 3 6 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0027.RAW B14072051-003A ;0804HP3 , $HC-ARO-GRP-S, RR2-V27 11 12 13 14 15 16 17 18 19 20 21 22 23 24 -200 0 200 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400 Page 102 of 117 B2 10-11 Batch ID: 81798 EPH ALIPHATICS (FID) ANALYSIS REPORT Sample Name: B14072051-004A ;0801HP3 , $HC-ALI-GRP-S, V31 Raw File: G:\org\HP3\DAT\HP3080114_b\0801HP3.0032.RAW Date & Time Acquired: 8/2/2014 5:29:12 PM Method File: g:\org\HP3\Methods\L3_EPH-LB-L%.met Calibration File: G:\Org\HP3\Cals\AL130823LB.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Aliphatic Hydrocarbons: 30415.23 Mean RF for C19 to C36 Aliphatic Hydrocarbons: 31274 Mean RF for Total Extractable Hydrocarbons: 30905.96 Rt range for Diesel Range Organics: 8.427999 to 20.231 Rt range for C9 to C18 Aliphatic Hydrocarbons: 6.638 to 16.417 Rt range for C19 to C36 Aliphatic Hydrocarbons: 16.442 to 23.523 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *1-Chloro-octadecane_____17.37 6.667 6.949 104.23 - DRO Area:4903836 DRO Amount: 10.57797 TEH Area:3.990398E+07 TEH Amount: 86.07613 Aliphatic Hydrocarbon Areas and Amounts: C9-C18 Area:665531.2 C9-C18 Amount: 1.458767 C19-C36 Area:2.526381E+07C19-C36 Amount: 53.85478 4 . 2 0 4 . 6 9 4 . 7 5 4 . 7 8 4 . 8 4 5 . 0 5 5 . 2 1 5 . 4 6 5 . 6 1 5 . 7 4 5 . 9 0 6 . 0 5 7 . 0 7 7 . 2 8 7 . 5 9 7 . 6 3 8 . 0 0 8 . 1 2 8 . 5 4 8 . 9 2 9 . 3 9 9 . 5 0 9 . 5 9 9 . 8 5 9 . 9 9 1 0 . 0 9 1 0 . 2 0 1 0 . 2 9 1 0 . 4 0 1 0 . 6 0 1 0 . 7 0 1 0 . 9 1 1 0 . 9 9 1 1 . 6 6 1 1 . 7 2 1 1 . 7 6 1 1 . 9 1 1 2 . 0 7 1 2 . 2 1 1 2 . 3 2 1 2 . 4 0 1 2 . 4 7 1 2 . 6 0 1 2 . 6 8 1 2 . 8 2 1 2 . 8 9 1 2 . 9 8 1 3 . 1 0 1 3 . 1 9 1 3 . 2 7 1 3 . 3 1 1 3 . 4 4 1 3 . 5 0 1 3 . 6 5 1 3 . 7 8 1 3 . 8 9 1 3 . 9 4 1 4 . 0 5 1 4 . 0 8 1 4 . 1 2 1 4 . 2 1 1 4 . 2 5 1 4 . 4 6 1 4 . 5 4 1 4 . 6 2 1 4 . 7 0 1 4 . 8 3 1 4 . 9 6 1 5 . 0 4 1 5 . 1 2 1 5 . 2 1 1 5 . 3 2 1 5 . 4 4 1 5 . 5 3 1 5 . 6 0 1 5 . 6 6 1 5 . 7 6 1 5 . 8 5 1 5 . 9 5 1 6 . 0 0 1 6 . 0 8 1 6 . 1 3 1 6 . 2 4 1 6 . 4 3 1 6 . 4 6 1 6 . 5 3 1 6 . 5 8 1 6 . 6 8 1 6 . 8 1 1 6 . 9 4 1 7 . 0 3 1 7 . 1 3 1 7 . 2 3 1 7 . 3 0 1 7 . 3 7 1 7 . 5 4 1 7 . 6 0 1 7 . 7 0 1 7 . 7 8 1 7 . 8 4 1 7 . 9 4 1 8 . 0 1 1 8 . 1 4 1 8 . 2 2 1 8 . 2 7 1 8 . 3 6 1 8 . 4 7 1 8 . 5 4 1 8 . 6 2 1 8 . 6 8 1 8 . 7 7 1 8 . 8 5 1 8 . 8 8 1 8 . 9 2 1 8 . 9 8 1 9 . 0 7 1 9 . 1 3 1 9 . 2 1 1 9 . 3 2 1 9 . 4 5 1 9 . 5 3 1 9 . 6 0 1 9 . 6 8 1 9 . 8 1 1 9 . 9 4 2 0 . 0 2 2 0 . 0 7 2 0 . 1 5 2 0 . 2 8 2 0 . 3 7 2 0 . 4 1 2 0 . 5 1 2 0 . 6 3 2 0 . 7 2 2 0 . 8 1 2 0 . 9 5 2 1 . 0 0 2 1 . 0 6 2 1 . 1 6 2 1 . 2 3 2 1 . 3 0 2 1 . 5 0 2 1 . 6 1 2 1 . 7 7 2 1 . 8 3 2 1 . 8 8 2 2 . 0 1 2 2 . 0 5 2 2 . 2 0 2 2 . 2 5 2 2 . 3 4 2 2 . 4 3 2 2 . 5 3 2 2 . 8 2 2 2 . 9 5 2 3 . 2 4 2 3 . 4 0 2 3 . 5 4 2 3 . 5 7 2 3 . 6 5 2 3 . 7 1 2 3 . 7 9 2 3 . 8 6 2 3 . 9 4 2 4 . 0 6 2 4 . 2 4 2 4 . 3 2 2 4 . 3 6 2 4 . 4 1 2 4 . 5 1 2 4 . 7 2 2 4 . 8 8 2 4 . 9 8 2 5 . 0 1 2 5 . 0 9 2 5 . 2 1 2 5 . 3 6 2 5 . 4 1 2 5 . 4 8 2 5 . 6 0 2 5 . 6 5 2 5 . 7 6 2 5 . 7 9 2 5 . 8 3 2 5 . 9 6 2 6 . 1 6 2 6 . 3 9 2 6 . 4 7 2 6 . 5 4 2 6 . 6 3 2 6 . 7 7 2 6 . 8 7 2 6 . 9 2 2 6 . 9 6 2 6 . 9 9 2 7 . 1 5 2 7 . 3 7 2 7 . 4 0 2 7 . 4 3 2 7 . 5 1 2 7 . 6 0 2 7 . 7 5 2 7 . 8 2 2 7 . 9 3 2 7 . 9 7 2 8 . 0 8 2 8 . 1 1 2 8 . 1 8 2 8 . 2 3 2 8 . 2 6 2 8 . 3 0 2 8 . 3 5 2 8 . 4 7 2 8 . 5 5 2 8 . 6 5 2 8 . 6 9 2 8 . 7 6 2 8 . 8 4 2 8 . 9 5 2 9 . 0 6 2 9 . 1 0 2 9 . 1 4 2 9 . 2 0 2 9 . 3 2 2 9 . 4 1 2 9 . 5 6 2 9 . 7 0 2 9 . 8 1 2 9 . 8 5 2 9 . 9 0 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e * 2 - B r o m o n a p h t h a l e n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3080114_b\0801HP3.0032.RAW B14072051-004A ;0801HP3 , $HC-ALI-GRP-S, V31 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 103 of 117 B2 10-11 Batch ID: 81798 EPH AROMATICS RANGE VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-004A ;0804HP3 , $HC-ARO-GRP-S, RR2-V28 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0028.RAW Date & Time Acquired: 8/5/2014 12:18:58 PM Method File: g:\org\HP3\Methods\R3_EPH-080427-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF EPH Aromatics: 32892.63 Rt range for EPH C11 to C22 Aromatics: 11.327 to 22.281 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *2-Fluorobiphenyl________13.281 6.667 5.943 89.15 - *2-Bromonaphthalene______14.147 6.667 6.07 91.05 - *o-Terphenyl_____________16.531 6.667 6.215 93.23 - *1-Chlorooctadecane______17.351 6.667 .203 3.05 - C11-C22 Aromatics Area:1.864973E+07 C11-C22 Aromatics Amount: 37.79921 EPH Aromatics total Area:6.699603E+07 EPH Aromatics Total Amount: 135.7873 4 . 6 2 4 . 6 8 4 . 7 4 4 . 8 3 4 . 8 7 4 . 9 6 5 . 0 2 5 . 1 8 5 . 4 0 5 . 4 3 5 . 5 8 5 . 8 6 6 . 0 3 7 . 0 1 9 . 1 2 9 . 4 9 9 . 5 6 9 . 6 3 1 0 . 1 9 1 0 . 2 9 1 0 . 6 5 1 0 . 9 5 1 1 . 0 3 1 1 . 2 4 1 1 . 6 3 1 1 . 6 7 1 1 . 7 3 1 1 . 7 9 1 1 . 8 4 1 1 . 9 0 1 1 . 9 6 1 2 . 3 7 1 2 . 4 4 1 2 . 6 6 1 2 . 7 9 1 2 . 8 8 1 3 . 0 5 1 3 . 1 6 1 3 . 2 8 1 3 . 7 5 1 3 . 8 6 1 3 . 9 2 1 3 . 9 9 1 4 . 0 7 1 4 . 1 5 1 4 . 7 2 1 4 . 7 8 1 4 . 8 4 1 4 . 9 3 1 4 . 9 8 1 5 . 0 9 1 5 . 1 4 1 5 . 2 0 1 5 . 2 5 1 5 . 4 0 1 5 . 5 0 1 5 . 6 2 1 5 . 7 3 1 5 . 8 0 1 5 . 8 6 1 5 . 9 0 1 5 . 9 5 1 6 . 0 8 1 6 . 1 3 1 6 . 1 9 1 6 . 2 4 1 6 . 3 1 1 6 . 4 5 1 6 . 5 3 1 6 . 7 7 1 6 . 9 1 1 7 . 0 5 1 7 . 1 8 1 7 . 2 5 1 7 . 3 5 1 7 . 4 7 1 7 . 5 7 1 7 . 6 4 1 7 . 7 3 1 7 . 7 8 1 7 . 8 6 1 7 . 9 7 1 8 . 1 7 1 8 . 2 3 1 8 . 2 8 1 8 . 3 8 1 8 . 4 1 1 8 . 5 1 1 8 . 5 8 1 8 . 6 3 1 8 . 6 9 1 8 . 7 7 1 8 . 8 4 1 8 . 8 8 1 9 . 0 1 1 9 . 0 6 1 9 . 1 2 1 9 . 2 0 1 9 . 3 1 1 9 . 4 1 1 9 . 4 9 1 9 . 5 5 1 9 . 5 9 1 9 . 6 5 1 9 . 7 5 1 9 . 7 8 1 9 . 8 5 1 9 . 9 1 1 9 . 9 7 2 0 . 0 7 2 0 . 1 6 2 0 . 2 1 2 0 . 2 8 2 0 . 3 8 2 0 . 4 3 2 0 . 4 9 2 0 . 6 2 2 0 . 6 7 2 0 . 8 2 2 0 . 8 6 2 0 . 9 2 2 0 . 9 8 2 1 . 0 4 2 1 . 0 7 2 1 . 1 7 2 1 . 2 7 2 1 . 3 3 2 1 . 3 9 2 1 . 4 7 2 1 . 5 6 2 1 . 6 5 2 1 . 7 8 2 1 . 8 2 2 1 . 8 6 2 1 . 9 1 2 2 . 0 6 2 2 . 1 6 2 2 . 2 6 2 2 . 3 0 2 2 . 3 5 2 2 . 4 7 2 2 . 6 4 2 2 . 7 2 2 2 . 7 6 2 2 . 8 5 2 3 . 1 5 2 3 . 1 9 2 3 . 2 5 2 3 . 3 2 2 3 . 4 8 2 3 . 5 4 2 3 . 6 8 2 3 . 8 4 2 3 . 8 9 2 3 . 9 3 2 4 . 0 7 2 4 . 1 4 2 4 . 2 0 2 4 . 3 4 2 4 . 3 8 2 4 . 6 0 2 4 . 6 6 2 4 . 7 6 2 4 . 8 4 2 4 . 9 1 2 4 . 9 3 2 4 . 9 7 2 5 . 2 5 2 5 . 3 6 2 5 . 4 5 2 5 . 5 0 2 5 . 5 6 2 5 . 6 1 2 5 . 6 6 2 5 . 7 2 2 5 . 7 6 2 5 . 8 3 2 5 . 8 9 2 5 . 9 5 2 6 . 0 3 2 6 . 1 2 2 6 . 1 6 2 6 . 2 8 2 6 . 4 1 2 6 . 5 6 2 6 . 6 0 2 6 . 6 8 2 6 . 7 7 2 6 . 9 1 2 6 . 9 5 2 6 . 9 9 2 7 . 0 3 2 7 . 2 0 2 7 . 2 5 2 7 . 2 8 2 7 . 4 2 2 7 . 4 9 2 7 . 5 9 2 7 . 7 7 2 7 . 8 8 2 7 . 9 6 2 8 . 0 1 2 8 . 0 9 2 8 . 1 5 2 8 . 2 0 2 8 . 2 6 2 8 . 3 0 2 8 . 3 8 2 8 . 4 2 2 8 . 4 5 2 8 . 4 8 2 8 . 5 8 2 8 . 6 2 2 8 . 7 4 2 8 . 8 0 2 8 . 9 0 2 8 . 9 3 2 8 . 9 8 2 9 . 0 4 2 9 . 0 7 2 9 . 2 5 2 9 . 3 6 2 9 . 4 7 2 9 . 5 5 2 9 . 6 0 2 9 . 7 1 2 9 . 7 5 2 9 . 8 1 2 9 . 8 4 2 9 . 8 8 2 9 . 9 6 3 0 . 0 5 3 0 . 1 2 3 0 . 1 6 3 0 . 2 2 3 0 . 2 8 3 0 . 3 3 3 0 . 4 6 3 0 . 5 1 3 0 . 6 3 3 0 . 6 6 3 0 . 7 6 3 0 . 8 2 3 0 . 8 6 3 0 . 9 0 3 0 . 9 5 3 1 . 0 1 3 1 . 0 6 3 1 . 1 0 3 1 . 1 6 3 1 . 2 7 3 1 . 3 7 3 1 . 4 2 3 1 . 5 4 3 1 . 5 8 3 1 . 6 3 3 1 . 6 8 3 1 . 7 2 3 1 . 8 0 3 1 . 8 4 3 1 . 8 8 3 1 . 9 7 3 2 . 0 3 3 2 . 0 7 3 2 . 1 8 3 2 . 3 1 3 2 . 3 9 3 2 . 5 0 3 2 . 5 9 3 2 . 7 0 3 2 . 7 8 3 2 . 8 3 3 2 . 9 3 3 2 . 9 7 3 3 . 0 1 3 3 . 1 4 3 3 . 2 3 3 3 . 3 5 3 3 . 4 0 3 3 . 4 6 3 3 . 5 1 3 3 . 6 1 3 3 . 7 0 3 3 . 7 7 3 3 . 8 3 3 3 . 9 6 3 4 . 0 2 3 4 . 0 9 3 4 . 1 6 3 4 . 2 2 3 4 . 3 1 3 4 . 3 5 3 4 . 4 1 3 4 . 6 0 3 4 . 6 2 3 4 . 7 0 3 4 . 7 7 3 4 . 8 4 3 4 . 9 5 3 5 . 0 1 3 5 . 0 5 3 5 . 1 8 3 5 . 2 3 3 5 . 3 0 3 5 . 3 4 3 5 . 4 0 3 5 . 4 7 3 5 . 5 0 3 5 . 5 8 3 5 . 7 4 3 5 . 8 2 3 5 . 9 1 3 5 . 9 9 3 6 . 1 4 3 6 . 2 3 3 6 . 2 8 3 6 . 4 2 3 6 . 4 6 3 6 . 4 9 3 6 . 5 8 3 6 . 7 8 3 6 . 8 6 3 6 . 9 2 3 6 . 9 9 3 7 . 1 1 3 7 . 1 9 3 7 . 2 6 3 7 . 3 4 3 7 . 4 1 3 7 . 4 4 3 7 . 5 3 3 7 . 5 9 3 7 . 6 9 3 7 . 7 5 3 7 . 8 5 3 8 . 0 3 3 8 . 1 4 3 8 . 1 8 3 8 . 3 0 3 8 . 3 8 3 8 . 5 1 3 8 . 5 9 3 8 . 6 3 3 8 . 7 0 3 8 . 7 4 3 8 . 8 6 3 8 . 9 5 3 9 . 0 7 3 9 . 1 4 3 9 . 2 3 3 9 . 2 7 3 9 . 3 7 3 9 . 4 2 3 9 . 5 1 3 9 . 6 0 3 9 . 6 7 3 9 . 8 0 3 9 . 8 5 3 9 . 8 9 3 9 . 9 6 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0028.RAW B14072051-004A ;0804HP3 , $HC-ARO-GRP-S, RR2-V28 0 5 10 15 20 25 30 35 40 0 500 1000 1500 2000 2500 3000 Page 104 of 117 B2 10-11 Batch ID: 81798 EPH AROMATICS TARGET VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-004A ;0804HP3 , $HC-ARO-GRP-S, RR2-V28 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0028.RAW Date & Time Acquired: 8/5/2014 12:18:58 PM Method File: g:\org\HP3\Methods\RT_EPH-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG Naphthalene______________. . . .067 U 2-Methylnaphthalene______12.656 12.656 12.656 2177 .067 U Acenaphthylene___________13.991 13.991 13.991 4361 .067 U Acenaphthene_____________. . . .067 U Fluorene_________________14.836 14.836 14.836 14176 .067 U Phenanthrene_____________16.085 16.085 16.085 1943 .067 U Anthracene_______________16.125 16.125 16.125 2792 .067 U Fluoranthene_____________17.472 17.472 17.472 4873 .067 U Pyrene___________________17.733 17.733 17.733 14356 .067 U Benzo(a)Anthracene_______. . . .067 U Chrysene_________________19.197 -5.055 -5.05 34205 .069 Benzo(b&k)Fluoranthe_____20.427 20.427 20.427 1777 .133 U Benzo(a)Pyrene___________20.671 20.671 20.671 14233 .067 U Indeno-Dibenzo___________21.908 21.908 21.908 1719 .133 U Benzo(g,h,i)Perylene_____22.162 22.162 22.162 10414 .067 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS *2-Fluorobiphenyl________13.281 6.667 5.943 89.15 40-140 *2-Bromonaphthalene______14.147 6.667 6.07 91.05 40-140 *o-Terphenyl_____________16.531 6.667 6.215 93.23 40-140 *1-Chlorooctadecane______17.351 6.667 .158 2.37 40-140 1 0 . 6 5 1 0 . 9 5 1 1 . 1 2 1 1 . 2 4 1 1 . 6 3 1 1 . 6 7 1 1 . 7 5 1 1 . 7 9 1 1 . 8 4 1 1 . 9 0 1 1 . 9 6 1 2 . 3 7 1 2 . 4 4 1 2 . 6 6 1 2 . 7 9 1 2 . 8 8 1 3 . 0 5 1 3 . 1 6 1 3 . 2 8 1 3 . 7 5 1 3 . 8 6 1 3 . 9 2 1 3 . 9 9 1 4 . 0 7 1 4 . 1 5 1 4 . 7 2 1 4 . 7 8 1 4 . 8 4 1 4 . 9 3 1 4 . 9 8 1 5 . 0 9 1 5 . 1 4 1 5 . 2 0 1 5 . 2 5 1 5 . 4 0 1 5 . 5 0 1 5 . 6 2 1 5 . 7 3 1 5 . 8 0 1 5 . 9 0 1 5 . 9 5 1 6 . 0 8 1 6 . 1 3 1 6 . 1 9 1 6 . 2 4 1 6 . 3 1 1 6 . 4 5 1 6 . 5 3 1 6 . 7 7 1 6 . 9 1 1 7 . 0 5 1 7 . 1 8 1 7 . 2 5 1 7 . 3 5 1 7 . 4 7 1 7 . 5 7 1 7 . 6 4 1 7 . 7 3 1 7 . 7 8 1 7 . 8 6 1 7 . 9 7 1 8 . 1 7 1 8 . 2 3 1 8 . 2 8 1 8 . 3 8 1 8 . 4 1 1 8 . 5 1 1 8 . 5 8 1 8 . 6 3 1 8 . 6 9 1 8 . 7 7 1 8 . 8 4 1 8 . 8 8 1 9 . 0 1 1 9 . 0 6 1 9 . 1 2 1 9 . 2 0 1 9 . 3 1 1 9 . 4 1 1 9 . 4 9 1 9 . 5 5 1 9 . 5 9 1 9 . 6 5 1 9 . 7 5 1 9 . 7 8 1 9 . 8 5 1 9 . 9 1 1 9 . 9 7 2 0 . 0 7 2 0 . 1 6 2 0 . 2 1 2 0 . 2 8 2 0 . 3 8 2 0 . 4 3 2 0 . 4 9 2 0 . 6 2 2 0 . 6 7 2 0 . 8 2 2 0 . 8 6 2 0 . 9 2 2 0 . 9 8 2 1 . 0 4 2 1 . 0 7 2 1 . 1 7 2 1 . 2 7 2 1 . 3 3 2 1 . 3 9 2 1 . 4 7 2 1 . 5 6 2 1 . 6 5 2 1 . 7 8 2 1 . 8 2 2 1 . 8 6 2 1 . 9 1 2 2 . 0 6 2 2 . 1 6 2 2 . 2 6 2 2 . 3 0 2 2 . 3 5 2 2 . 4 7 2 2 . 6 4 2 2 . 7 2 2 2 . 7 6 2 2 . 8 5 2 3 . 1 5 2 3 . 1 9 2 3 . 2 5 2 3 . 3 2 2 3 . 4 8 2 3 . 5 4 2 3 . 6 8 2 3 . 8 4 2 3 . 8 9 2 3 . 9 3 2 4 . 0 7 2 4 . 1 4 2 4 . 2 0 2 4 . 3 4 2 4 . 3 8 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0028.RAW B14072051-004A ;0804HP3 , $HC-ARO-GRP-S, RR2-V28 11 12 13 14 15 16 17 18 19 20 21 22 23 24 0 500 1000 1500 2000 2500 Page 105 of 117 B8 9-11 Batch ID: 81798 EPH ALIPHATICS (FID) ANALYSIS REPORT Sample Name: B14072051-010A ;0801HP3 , $HC-ALI-GRP-S, V34 Raw File: G:\org\HP3\DAT\HP3080114_b\0801HP3.0034.RAW Date & Time Acquired: 8/2/2014 7:00:11 PM Method File: g:\org\HP3\Methods\L3_EPH-LB-L%.met Calibration File: G:\Org\HP3\Cals\AL130823LB.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Aliphatic Hydrocarbons: 30415.23 Mean RF for C19 to C36 Aliphatic Hydrocarbons: 31274 Mean RF for Total Extractable Hydrocarbons: 30905.96 Rt range for Diesel Range Organics: 8.427999 to 20.231 Rt range for C9 to C18 Aliphatic Hydrocarbons: 6.638 to 16.417 Rt range for C19 to C36 Aliphatic Hydrocarbons: 16.442 to 23.523 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *1-Chloro-octadecane_____17.373 6.667 3.064 45.96 - DRO Area:4244628 DRO Amount: 9.156008 TEH Area:5.343148E+07 TEH Amount: 115.2561 Aliphatic Hydrocarbon Areas and Amounts: C9-C18 Area:667651 C9-C18 Amount: 1.463414 C19-C36 Area:2.922339E+07C19-C36 Amount: 62.2954 4 . 7 1 4 . 8 4 4 . 9 6 5 . 0 5 5 . 2 1 5 . 6 1 5 . 8 9 6 . 0 5 6 . 7 6 7 . 0 7 8 . 5 6 8 . 9 3 9 . 1 1 9 . 1 9 9 . 3 9 9 . 5 0 9 . 5 9 9 . 6 9 9 . 8 4 1 0 . 0 9 1 0 . 2 0 1 0 . 2 8 1 0 . 3 8 1 0 . 4 2 1 0 . 5 9 1 0 . 7 1 1 0 . 9 2 1 0 . 9 9 1 1 . 1 3 1 1 . 2 1 1 1 . 4 3 1 1 . 6 1 1 1 . 7 6 1 1 . 8 6 1 1 . 9 1 1 2 . 0 7 1 2 . 2 0 1 2 . 2 6 1 2 . 3 1 1 2 . 3 9 1 2 . 5 0 1 2 . 6 0 1 2 . 6 7 1 2 . 8 2 1 2 . 8 9 1 2 . 9 8 1 3 . 1 0 1 3 . 1 9 1 3 . 2 6 1 3 . 3 1 1 3 . 4 5 1 3 . 5 0 1 3 . 7 4 1 3 . 7 8 1 3 . 8 8 1 3 . 9 4 1 4 . 0 5 1 4 . 1 3 1 4 . 2 0 1 4 . 2 6 1 4 . 4 7 1 4 . 5 5 1 4 . 6 2 1 4 . 7 0 1 4 . 8 4 1 5 . 0 4 1 5 . 1 2 1 5 . 2 2 1 5 . 3 2 1 5 . 4 4 1 5 . 6 6 1 5 . 7 2 1 5 . 7 6 1 5 . 9 6 1 6 . 0 0 1 6 . 0 8 1 6 . 2 2 1 6 . 2 5 1 6 . 4 2 1 6 . 4 7 1 6 . 5 7 1 6 . 6 6 1 6 . 8 2 1 6 . 9 2 1 7 . 0 3 1 7 . 1 3 1 7 . 1 9 1 7 . 2 3 1 7 . 3 1 1 7 . 3 7 1 7 . 5 5 1 7 . 6 1 1 7 . 6 5 1 7 . 7 1 1 7 . 7 9 1 7 . 8 4 1 7 . 9 6 1 8 . 0 2 1 8 . 0 7 1 8 . 1 4 1 8 . 2 8 1 8 . 3 6 1 8 . 4 7 1 8 . 5 4 1 8 . 6 2 1 8 . 6 8 1 8 . 7 5 1 8 . 7 7 1 8 . 8 4 1 8 . 9 4 1 9 . 0 0 1 9 . 0 9 1 9 . 1 4 1 9 . 2 4 1 9 . 3 2 1 9 . 4 6 1 9 . 5 2 1 9 . 6 2 1 9 . 7 1 1 9 . 7 4 1 9 . 8 3 1 9 . 9 7 2 0 . 1 7 2 0 . 2 1 2 0 . 2 8 2 0 . 4 2 2 0 . 4 9 2 0 . 5 6 2 0 . 6 3 2 0 . 7 2 2 0 . 8 2 2 0 . 9 4 2 1 . 0 1 2 1 . 0 7 2 1 . 2 3 2 1 . 3 0 2 1 . 3 8 2 1 . 5 3 2 1 . 6 2 2 1 . 7 7 2 1 . 8 6 2 1 . 9 0 2 1 . 9 6 2 2 . 0 2 2 2 . 1 5 2 2 . 2 0 2 2 . 3 6 2 2 . 4 5 2 2 . 5 6 2 2 . 6 0 2 2 . 7 2 2 2 . 8 3 2 2 . 9 7 2 3 . 1 3 2 3 . 2 0 2 3 . 2 6 2 3 . 3 2 2 3 . 4 0 2 3 . 5 2 2 3 . 6 0 2 3 . 7 6 2 3 . 8 3 2 3 . 9 5 2 4 . 0 8 2 4 . 3 8 2 4 . 5 4 2 4 . 7 4 2 4 . 9 4 2 5 . 0 3 2 5 . 1 2 2 5 . 1 6 2 5 . 2 2 2 5 . 3 7 2 5 . 3 9 2 5 . 5 0 2 5 . 5 8 2 5 . 6 2 2 5 . 6 9 2 5 . 8 0 2 5 . 8 3 2 5 . 9 6 2 6 . 0 5 2 6 . 1 7 2 6 . 2 8 2 6 . 3 9 2 6 . 5 1 2 6 . 5 6 2 6 . 6 3 2 6 . 6 9 2 6 . 7 3 2 6 . 7 6 2 6 . 8 9 2 7 . 0 3 2 7 . 0 7 2 7 . 2 0 2 7 . 3 4 2 7 . 3 9 2 7 . 4 8 2 7 . 5 4 2 7 . 7 0 2 7 . 9 1 2 7 . 9 8 2 8 . 0 2 2 8 . 1 0 2 8 . 1 6 2 8 . 2 3 2 8 . 3 2 2 8 . 3 6 2 8 . 4 2 2 8 . 5 7 2 8 . 7 2 2 8 . 8 0 2 8 . 8 3 2 8 . 8 8 2 8 . 9 4 2 9 . 0 3 2 9 . 1 4 2 9 . 1 9 2 9 . 2 4 2 9 . 3 3 2 9 . 4 5 2 9 . 5 1 2 9 . 6 1 2 9 . 6 6 2 9 . 7 3 2 9 . 7 7 2 9 . 8 2 2 9 . 8 7 2 9 . 9 7 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e * 2 - B r o m o n a p h t h a l e n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3080114_b\0801HP3.0034.RAW B14072051-010A ;0801HP3 , $HC-ALI-GRP-S, V34 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 106 of 117 B8 9-11 Batch ID: 81798 EPH AROMATICS RANGE VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-010A ;0804HP3 , $HC-ARO-GRP-S, RR-V30 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0030.RAW Date & Time Acquired: 8/5/2014 2:12:18 PM Method File: g:\org\HP3\Methods\R3_EPH-080430-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF EPH Aromatics: 32892.63 Rt range for EPH C11 to C22 Aromatics: 11.327 to 22.281 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *2-Fluorobiphenyl________13.296 6.667 7.82 117.3 - *2-Bromonaphthalene______14.167 6.667 8.317 124.75 - *o-Terphenyl_____________16.547 6.667 3.897 58.46 - *1-Chlorooctadecane______17.368 6.667 .086 1.3 - C11-C22 Aromatics Area:3.797666E+07 C11-C22 Aromatics Amount: 76.97095 EPH Aromatics total Area:1.955202E+08 EPH Aromatics Total Amount: 396.2795 4 . 5 6 4 . 6 1 4 . 6 4 4 . 6 7 4 . 7 0 4 . 7 5 4 . 8 0 4 . 8 3 4 . 8 6 4 . 9 2 4 . 9 6 4 . 9 8 5 . 0 4 5 . 0 9 5 . 2 0 5 . 4 3 5 . 7 9 5 . 8 5 5 . 8 8 6 . 0 5 7 . 0 2 8 . 5 4 9 . 1 5 9 . 5 0 9 . 5 9 9 . 7 2 1 0 . 2 1 1 0 . 2 9 1 0 . 3 5 1 0 . 4 3 1 0 . 6 0 1 0 . 9 7 1 1 . 2 7 1 1 . 6 4 1 1 . 7 8 1 1 . 9 6 1 2 . 3 8 1 2 . 4 6 1 2 . 6 6 1 2 . 7 5 1 2 . 8 1 1 2 . 8 8 1 2 . 9 6 1 3 . 0 7 1 3 . 1 7 1 3 . 3 0 1 3 . 7 7 1 3 . 9 3 1 4 . 0 2 1 4 . 1 7 1 4 . 7 8 1 4 . 8 3 1 4 . 8 6 1 4 . 9 4 1 5 . 1 1 1 5 . 1 5 1 5 . 2 0 1 5 . 4 2 1 5 . 5 2 1 5 . 5 8 1 5 . 6 3 1 5 . 7 5 1 5 . 8 0 1 5 . 9 5 1 6 . 0 8 1 6 . 1 3 1 6 . 2 0 1 6 . 2 5 1 6 . 3 5 1 6 . 4 6 1 6 . 5 5 1 6 . 7 8 1 6 . 9 3 1 7 . 0 6 1 7 . 2 2 1 7 . 2 9 1 7 . 3 7 1 7 . 4 4 1 7 . 5 1 1 7 . 6 2 1 7 . 6 6 1 7 . 8 3 1 7 . 8 8 1 7 . 9 3 1 7 . 9 9 1 8 . 1 1 1 8 . 1 9 1 8 . 2 2 1 8 . 2 5 1 8 . 3 2 1 8 . 3 5 1 8 . 4 4 1 8 . 5 3 1 8 . 6 6 1 8 . 7 4 1 8 . 8 4 1 8 . 9 3 1 9 . 0 4 1 9 . 0 8 1 9 . 1 5 1 9 . 1 8 1 9 . 2 3 1 9 . 3 8 1 9 . 4 4 1 9 . 5 7 1 9 . 6 1 1 9 . 6 5 1 9 . 6 8 1 9 . 7 0 1 9 . 7 4 1 9 . 8 0 1 9 . 8 9 1 9 . 9 5 1 9 . 9 9 2 0 . 0 1 2 0 . 0 5 2 0 . 1 2 2 0 . 1 6 2 0 . 1 9 2 0 . 2 3 2 0 . 2 6 2 0 . 3 3 2 0 . 4 3 2 0 . 4 7 2 0 . 5 1 2 0 . 5 3 2 0 . 5 7 2 0 . 6 0 2 0 . 6 4 2 0 . 6 7 2 0 . 7 3 2 0 . 7 8 2 0 . 8 2 2 0 . 8 6 2 1 . 0 1 2 1 . 0 8 2 1 . 1 1 2 1 . 1 7 2 1 . 2 1 2 1 . 2 4 2 1 . 2 8 2 1 . 3 2 2 1 . 3 5 2 1 . 3 8 2 1 . 4 3 2 1 . 4 9 2 1 . 5 4 2 1 . 5 9 2 1 . 6 3 2 1 . 6 7 2 1 . 7 5 2 1 . 7 9 2 1 . 8 5 2 1 . 8 7 2 1 . 9 4 2 1 . 9 8 2 2 . 0 3 2 2 . 1 7 2 2 . 2 2 2 2 . 2 5 2 2 . 3 0 2 2 . 3 5 2 2 . 3 9 2 2 . 4 3 2 2 . 4 6 2 2 . 5 5 2 2 . 5 9 2 2 . 6 6 2 2 . 6 8 2 2 . 7 1 2 2 . 7 3 2 2 . 7 9 2 2 . 8 5 2 2 . 9 0 2 2 . 9 6 2 3 . 0 1 2 3 . 0 8 2 3 . 1 2 2 3 . 1 7 2 3 . 2 2 2 3 . 2 8 2 3 . 3 2 2 3 . 3 7 2 3 . 4 5 2 3 . 5 2 2 3 . 5 8 2 3 . 6 8 2 3 . 7 1 2 3 . 7 8 2 3 . 8 0 2 3 . 8 7 2 3 . 9 0 2 3 . 9 4 2 3 . 9 9 2 4 . 0 1 2 4 . 0 6 2 4 . 0 9 2 4 . 1 6 2 4 . 2 6 2 4 . 3 1 2 4 . 3 8 2 4 . 4 5 2 4 . 5 6 2 4 . 6 1 2 4 . 6 4 2 4 . 7 0 2 4 . 8 1 2 4 . 8 8 2 4 . 9 1 2 4 . 9 5 2 4 . 9 8 2 5 . 0 3 2 5 . 0 6 2 5 . 2 3 2 5 . 2 9 2 5 . 3 9 2 5 . 4 2 2 5 . 4 8 2 5 . 5 9 2 5 . 6 6 2 5 . 7 1 2 5 . 7 6 2 5 . 8 0 2 5 . 8 5 2 5 . 9 6 2 6 . 0 0 2 6 . 0 4 2 6 . 0 9 2 6 . 1 4 2 6 . 2 0 2 6 . 2 4 2 6 . 3 3 2 6 . 3 7 2 6 . 4 3 2 6 . 5 2 2 6 . 5 5 2 6 . 6 0 2 6 . 6 6 2 6 . 6 8 2 6 . 7 9 2 6 . 8 4 2 6 . 9 2 2 6 . 9 5 2 7 . 0 1 2 7 . 0 4 2 7 . 1 0 2 7 . 1 4 2 7 . 1 8 2 7 . 2 6 2 7 . 2 9 2 7 . 3 3 2 7 . 3 9 2 7 . 4 7 2 7 . 5 1 2 7 . 5 8 2 7 . 6 4 2 7 . 7 0 2 7 . 7 3 2 7 . 8 1 2 7 . 9 1 2 7 . 9 4 2 7 . 9 7 2 7 . 9 9 2 8 . 0 8 2 8 . 1 8 2 8 . 2 4 2 8 . 2 8 2 8 . 3 7 2 8 . 4 0 2 8 . 4 3 2 8 . 4 9 2 8 . 5 5 2 8 . 5 9 2 8 . 6 4 2 8 . 6 8 2 8 . 8 1 2 8 . 8 7 2 8 . 9 2 2 9 . 0 0 2 9 . 0 3 2 9 . 0 7 2 9 . 2 1 2 9 . 2 7 2 9 . 3 3 2 9 . 3 7 2 9 . 4 2 2 9 . 4 7 2 9 . 5 0 2 9 . 5 3 2 9 . 5 6 2 9 . 6 0 2 9 . 6 8 2 9 . 7 1 2 9 . 7 6 2 9 . 8 0 2 9 . 9 5 3 0 . 0 1 3 0 . 0 8 3 0 . 1 1 3 0 . 1 6 3 0 . 1 9 3 0 . 2 6 3 0 . 3 4 3 0 . 4 9 3 0 . 5 4 3 0 . 6 5 3 0 . 6 9 3 0 . 7 3 3 0 . 7 9 3 0 . 8 4 3 0 . 8 6 3 0 . 8 9 3 0 . 9 5 3 1 . 0 1 3 1 . 0 9 3 1 . 1 7 3 1 . 2 0 3 1 . 2 7 3 1 . 3 5 3 1 . 4 2 3 1 . 4 6 3 1 . 5 8 3 1 . 6 2 3 1 . 6 7 3 1 . 7 0 3 1 . 7 7 3 1 . 8 3 3 1 . 8 7 3 1 . 9 1 3 1 . 9 5 3 2 . 0 0 3 2 . 0 5 3 2 . 1 6 3 2 . 2 1 3 2 . 3 0 3 2 . 3 9 3 2 . 4 6 3 2 . 5 4 3 2 . 6 1 3 2 . 7 0 3 2 . 7 4 3 2 . 7 9 3 2 . 8 2 3 2 . 8 8 3 2 . 9 3 3 2 . 9 8 3 3 . 0 4 3 3 . 1 1 3 3 . 1 7 3 3 . 2 3 3 3 . 2 7 3 3 . 3 6 3 3 . 3 9 3 3 . 4 7 3 3 . 5 1 3 3 . 5 5 3 3 . 5 9 3 3 . 6 2 3 3 . 6 7 3 3 . 7 7 3 3 . 8 3 3 3 . 8 9 3 3 . 9 4 3 3 . 9 9 3 4 . 0 4 3 4 . 0 9 3 4 . 1 7 3 4 . 2 1 3 4 . 2 8 3 4 . 3 3 3 4 . 3 7 3 4 . 4 2 3 4 . 4 7 3 4 . 5 1 3 4 . 5 7 3 4 . 6 1 3 4 . 6 9 3 4 . 7 7 3 4 . 8 9 3 4 . 9 4 3 5 . 0 0 3 5 . 0 6 3 5 . 0 8 3 5 . 1 6 3 5 . 2 1 3 5 . 2 5 3 5 . 3 1 3 5 . 4 3 3 5 . 4 7 3 5 . 5 8 3 5 . 6 5 3 5 . 7 2 3 5 . 8 1 3 5 . 8 6 3 5 . 9 7 3 6 . 0 9 3 6 . 1 7 3 6 . 2 4 3 6 . 2 7 3 6 . 3 4 3 6 . 4 0 3 6 . 4 8 3 6 . 5 4 3 6 . 5 8 3 6 . 6 1 3 6 . 7 0 3 6 . 7 3 3 6 . 8 0 3 6 . 8 5 3 6 . 9 1 3 6 . 9 5 3 7 . 0 3 3 7 . 0 7 3 7 . 1 2 3 7 . 2 1 3 7 . 3 0 3 7 . 3 5 3 7 . 4 0 3 7 . 4 8 3 7 . 6 2 3 7 . 7 2 3 7 . 7 9 3 7 . 8 6 3 7 . 8 9 3 7 . 9 5 3 7 . 9 8 3 8 . 0 4 3 8 . 1 6 3 8 . 2 3 3 8 . 2 9 3 8 . 3 6 3 8 . 4 3 3 8 . 4 5 3 8 . 5 1 3 8 . 5 5 3 8 . 6 2 3 8 . 6 9 3 8 . 7 8 3 8 . 8 6 3 8 . 8 9 3 8 . 9 4 3 9 . 0 0 3 9 . 0 8 3 9 . 1 1 3 9 . 1 7 3 9 . 2 1 3 9 . 2 7 3 9 . 3 3 3 9 . 3 9 3 9 . 4 6 3 9 . 5 2 3 9 . 5 6 3 9 . 6 4 3 9 . 7 5 3 9 . 8 2 3 9 . 9 0 3 9 . 9 5 3 9 . 9 9 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0030.RAW B14072051-010A ;0804HP3 , $HC-ARO-GRP-S, RR-V30 0 5 10 15 20 25 30 35 40 0 500 1000 1500 2000 2500 3000 Page 107 of 117 B8 9-11 Batch ID: 81798 EPH AROMATICS TARGET VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-010A ;0804HP3 , $HC-ARO-GRP-S, RR-V30 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0030.RAW Date & Time Acquired: 8/5/2014 2:12:18 PM Method File: g:\org\HP3\Methods\RT_EPH-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG Naphthalene______________. . . .067 U 2-Methylnaphthalene______12.66 12.66 12.66 3725 .067 U Acenaphthylene___________13.933 13.933 13.933 4659 .067 U Acenaphthene_____________. . . .067 U Fluorene_________________14.857 14.857 14.857 23074 .067 U Phenanthrene_____________16.077 16.077 16.077 1778 .067 U Anthracene_______________16.127 16.127 16.127 566 .067 U Fluoranthene_____________17.506 17.506 17.506 2879 .067 U Pyrene___________________. . . .067 U Benzo(a)Anthracene_______. . . .067 U Chrysene_________________19.232 19.232 19.232 17335 .067 U Benzo(b&k)Fluoranthe_____20.431 20.431 20.431 21259 .133 U Benzo(a)Pyrene___________20.728 20.728 20.728 8278 .067 U Indeno-Dibenzo___________21.941 21.941 21.941 25716 .133 U Benzo(g,h,i)Perylene_____22.175 22.175 22.175 7881 .067 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS *2-Fluorobiphenyl________13.296 6.667 7.82 117.3 40-140 *2-Bromonaphthalene______14.167 6.667 8.317 124.75 40-140 *o-Terphenyl_____________16.547 6.667 3.897 58.46 40-140 *1-Chlorooctadecane______17.368 6.667 .065 .98 40-140 1 0 . 5 4 1 0 . 9 7 1 1 . 2 7 1 1 . 6 4 1 1 . 7 8 1 1 . 9 6 1 2 . 0 9 1 2 . 3 8 1 2 . 4 6 1 2 . 6 6 1 2 . 8 1 1 2 . 8 8 1 3 . 0 7 1 3 . 1 7 1 3 . 3 0 1 3 . 7 7 1 3 . 9 3 1 4 . 0 2 1 4 . 1 7 1 4 . 7 8 1 4 . 8 6 1 5 . 1 1 1 5 . 1 5 1 5 . 2 0 1 5 . 4 2 1 5 . 5 2 1 5 . 6 3 1 5 . 7 5 1 5 . 8 0 1 5 . 9 5 1 6 . 0 8 1 6 . 1 3 1 6 . 2 0 1 6 . 2 5 1 6 . 3 5 1 6 . 4 6 1 6 . 5 5 1 6 . 7 8 1 6 . 9 3 1 7 . 0 6 1 7 . 2 2 1 7 . 2 9 1 7 . 3 7 1 7 . 5 1 1 7 . 6 2 1 7 . 6 6 1 7 . 8 3 1 7 . 8 8 1 7 . 9 9 1 8 . 1 1 1 8 . 1 9 1 8 . 2 2 1 8 . 3 5 1 8 . 4 4 1 8 . 5 3 1 8 . 6 6 1 8 . 7 4 1 8 . 8 4 1 8 . 9 3 1 9 . 0 4 1 9 . 2 3 1 9 . 3 8 1 9 . 4 4 1 9 . 5 7 1 9 . 6 8 1 9 . 7 0 1 9 . 8 0 1 9 . 8 9 1 9 . 9 5 2 0 . 0 1 2 0 . 0 5 2 0 . 1 2 2 0 . 1 6 2 0 . 2 6 2 0 . 3 3 2 0 . 4 3 2 0 . 4 7 2 0 . 5 1 2 0 . 5 7 2 0 . 6 0 2 0 . 6 4 2 0 . 6 7 2 0 . 7 3 2 0 . 7 8 2 0 . 8 2 2 0 . 8 6 2 1 . 0 1 2 1 . 1 1 2 1 . 2 1 2 1 . 2 8 2 1 . 3 2 2 1 . 3 5 2 1 . 3 8 2 1 . 4 3 2 1 . 5 4 2 1 . 5 9 2 1 . 6 3 2 1 . 6 7 2 1 . 7 1 2 1 . 7 5 2 1 . 7 9 2 1 . 9 4 2 1 . 9 8 2 2 . 0 3 2 2 . 1 7 2 2 . 2 2 2 2 . 3 0 2 2 . 4 3 2 2 . 5 9 2 2 . 6 6 2 2 . 7 3 2 2 . 7 9 2 2 . 8 5 2 2 . 9 6 2 3 . 0 1 2 3 . 1 2 2 3 . 1 7 2 3 . 2 2 2 3 . 2 8 2 3 . 4 5 2 3 . 5 2 2 3 . 5 8 2 3 . 6 4 2 3 . 7 1 2 3 . 8 0 2 3 . 8 7 2 3 . 9 0 2 3 . 9 4 2 3 . 9 9 2 4 . 0 6 2 4 . 3 1 2 4 . 3 8 2 4 . 4 5 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0030.RAW B14072051-010A ;0804HP3 , $HC-ARO-GRP-S, RR-V30 11 12 13 14 15 16 17 18 19 20 21 22 23 24 -200 0 200 400 600 800 1000 1200 1400 1600 1800 2000 Page 108 of 117 B9 5-7 Batch ID: 81798 EPH ALIPHATICS (FID) ANALYSIS REPORT Sample Name: B14072051-011A ;0804HP3 , $HC-ALI-GRP-S, V23,(2,3) Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0023.RAW Date & Time Acquired: 8/5/2014 7:24:55 AM Method File: g:\org\HP3\Methods\LR_EPH-080423-LC-L%.met Calibration File: G:\Org\HP3\Cals\AL130823LC.CAL Sample Weight: 30 Dilution: 6 S.A.: 1 Mean RF for C9 to C18 Aliphatic Hydrocarbons: 30415.23 Mean RF for C19 to C36 Aliphatic Hydrocarbons: 31274 Mean RF for Total Extractable Hydrocarbons: 30905.96 Rt range for Diesel Range Organics: 8.417999 to 20.205 Rt range for C9 to C18 Aliphatic Hydrocarbons: 6.63 to 16.397 Rt range for C19 to C36 Aliphatic Hydrocarbons: 16.422 to 23.466 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *1-Chloro-octadecane_____17.351 6.667 9.204 138.07 - DRO Area:3.743438E+07 DRO Amount: 242.247 TEH Area:9.706968E+07 TEH Amount: 628.1616 Aliphatic Hydrocarbon Areas and Amounts: C9-C18 Area:1.439336E+07 C9-C18 Amount: 94.64572 C19-C36 Area:5.272436E+07C19-C36 Amount: 337.177 4 . 6 3 4 . 7 0 4 . 9 0 4 . 9 5 5 . 0 3 5 . 1 9 5 . 4 7 5 . 5 9 5 . 7 2 5 . 8 8 6 . 0 4 6 . 4 8 7 . 0 5 7 . 2 8 7 . 3 7 7 . 4 9 7 . 7 5 7 . 8 5 8 . 0 7 8 . 2 5 8 . 3 0 8 . 4 8 8 . 5 5 8 . 7 6 8 . 9 1 8 . 9 8 9 . 0 9 9 . 1 7 9 . 2 6 9 . 4 0 9 . 4 7 9 . 5 9 9 . 6 9 9 . 7 9 9 . 9 9 1 0 . 0 9 1 0 . 1 8 1 0 . 2 6 1 0 . 3 5 1 0 . 4 1 1 0 . 5 8 1 0 . 6 8 1 0 . 8 0 1 0 . 8 9 1 0 . 9 6 1 1 . 0 3 1 1 . 1 2 1 1 . 1 8 1 1 . 2 7 1 1 . 3 9 1 1 . 4 7 1 1 . 5 9 1 1 . 7 4 1 1 . 8 8 1 2 . 0 4 1 2 . 1 7 1 2 . 2 4 1 2 . 3 0 1 2 . 3 6 1 2 . 4 7 1 2 . 5 7 1 2 . 6 6 1 2 . 7 5 1 2 . 7 9 1 2 . 8 7 1 2 . 9 4 1 2 . 9 8 1 3 . 0 7 1 3 . 1 4 1 3 . 1 9 1 3 . 2 4 1 3 . 2 8 1 3 . 4 2 1 3 . 4 9 1 3 . 5 5 1 3 . 6 3 1 3 . 7 2 1 3 . 7 5 1 3 . 8 5 1 3 . 9 1 1 3 . 9 5 1 4 . 0 6 1 4 . 1 1 1 4 . 1 8 1 4 . 2 3 1 4 . 3 6 1 4 . 4 2 1 4 . 5 1 1 4 . 5 5 1 4 . 6 0 1 4 . 6 8 1 4 . 7 6 1 4 . 8 1 1 4 . 8 7 1 4 . 9 5 1 5 . 0 2 1 5 . 1 1 1 5 . 1 9 1 5 . 3 0 1 5 . 3 8 1 5 . 4 4 1 5 . 5 2 1 5 . 5 9 1 5 . 6 4 1 5 . 6 8 1 5 . 7 4 1 5 . 8 5 1 5 . 9 3 1 5 . 9 8 1 6 . 0 3 1 6 . 0 6 1 6 . 1 2 1 6 . 1 8 1 6 . 2 2 1 6 . 3 1 1 6 . 3 5 1 6 . 4 4 1 6 . 5 1 1 6 . 5 6 1 6 . 6 6 1 6 . 7 7 1 6 . 8 1 1 6 . 9 2 1 7 . 0 2 1 7 . 1 1 1 7 . 2 1 1 7 . 2 8 1 7 . 3 5 1 7 . 4 6 1 7 . 5 0 1 7 . 5 8 1 7 . 6 8 1 7 . 7 5 1 7 . 8 3 1 7 . 9 1 1 7 . 9 9 1 8 . 0 3 1 8 . 1 1 1 8 . 2 6 1 8 . 3 2 1 8 . 3 5 1 8 . 4 4 1 8 . 5 1 1 8 . 5 9 1 8 . 6 6 1 8 . 7 2 1 8 . 7 5 1 8 . 8 4 1 8 . 9 0 1 8 . 9 5 1 9 . 0 6 1 9 . 1 9 1 9 . 2 8 1 9 . 3 7 1 9 . 4 4 1 9 . 5 7 1 9 . 6 7 1 9 . 8 0 1 9 . 9 5 2 0 . 0 2 2 0 . 1 5 2 0 . 3 0 2 0 . 4 0 2 0 . 4 9 2 0 . 5 3 2 0 . 5 6 2 0 . 6 9 2 0 . 7 6 2 0 . 8 3 2 0 . 9 0 2 0 . 9 8 2 1 . 0 4 2 1 . 1 4 2 1 . 1 9 2 1 . 2 7 2 1 . 3 4 2 1 . 4 8 2 1 . 5 8 2 1 . 7 4 2 1 . 7 8 2 1 . 8 5 2 1 . 9 8 2 2 . 0 2 2 2 . 1 4 2 2 . 2 8 2 2 . 3 9 2 2 . 5 6 2 2 . 7 8 2 3 . 0 3 2 3 . 1 5 2 3 . 2 1 2 3 . 3 5 2 3 . 5 0 2 3 . 6 5 2 3 . 7 3 2 3 . 7 6 2 3 . 9 9 2 4 . 2 0 2 4 . 2 7 2 4 . 3 8 2 4 . 4 1 2 4 . 4 5 2 4 . 6 1 2 4 . 8 1 2 5 . 0 7 2 5 . 2 0 2 5 . 2 9 2 5 . 4 1 2 5 . 4 6 2 5 . 6 0 2 5 . 6 6 2 5 . 7 3 2 5 . 7 6 2 5 . 8 2 2 5 . 8 7 2 5 . 9 1 2 6 . 2 7 2 6 . 3 3 2 6 . 3 8 2 6 . 5 1 2 6 . 7 7 2 6 . 8 3 2 6 . 8 8 2 7 . 0 0 2 7 . 0 5 2 7 . 2 0 2 7 . 4 5 2 7 . 6 0 2 7 . 6 4 2 7 . 7 2 2 7 . 7 9 2 7 . 8 8 2 7 . 9 5 2 8 . 0 4 2 8 . 1 2 2 8 . 2 0 2 8 . 5 1 2 8 . 6 0 2 8 . 7 9 2 8 . 8 7 2 8 . 9 1 2 8 . 9 5 2 9 . 0 8 2 9 . 2 4 2 9 . 2 9 2 9 . 4 1 2 9 . 6 3 2 9 . 6 8 2 9 . 7 9 2 9 . 8 6 2 9 . 9 8 3 0 . 0 0 3 0 . 1 4 3 0 . 1 8 3 0 . 2 3 3 0 . 3 2 3 0 . 4 3 3 0 . 5 7 3 0 . 6 2 3 0 . 6 7 3 0 . 7 1 3 0 . 7 6 3 0 . 8 7 3 0 . 9 4 3 1 . 0 0 3 1 . 0 4 3 1 . 1 1 3 1 . 2 4 3 1 . 2 7 3 1 . 3 2 3 1 . 5 0 3 1 . 5 5 3 1 . 6 1 3 1 . 6 5 3 1 . 7 5 3 1 . 8 8 3 1 . 9 3 3 1 . 9 7 3 2 . 0 4 3 2 . 1 1 3 2 . 1 8 3 2 . 2 4 3 2 . 3 7 3 2 . 4 7 3 2 . 5 8 3 2 . 6 2 3 2 . 6 8 3 2 . 7 2 3 2 . 8 0 3 2 . 9 2 3 2 . 9 5 3 3 . 0 2 3 3 . 0 7 3 3 . 1 7 3 3 . 2 4 3 3 . 3 4 3 3 . 4 2 3 3 . 4 6 3 3 . 5 4 3 3 . 6 0 3 3 . 6 4 3 3 . 7 3 3 3 . 8 0 3 3 . 8 7 3 3 . 9 7 3 4 . 1 1 3 4 . 1 7 3 4 . 2 4 3 4 . 3 8 3 4 . 4 6 3 4 . 5 5 3 4 . 6 0 3 4 . 6 6 3 4 . 7 5 3 4 . 7 9 3 4 . 9 1 3 5 . 0 2 3 5 . 0 6 3 5 . 1 0 3 5 . 1 4 3 5 . 2 0 3 5 . 3 5 3 5 . 4 2 3 5 . 4 6 3 5 . 5 8 3 5 . 6 9 3 5 . 7 7 3 5 . 8 6 3 5 . 9 3 3 6 . 0 3 3 6 . 1 5 3 6 . 2 1 3 6 . 3 2 3 6 . 3 8 3 6 . 4 5 3 6 . 4 8 3 6 . 5 9 3 6 . 6 4 3 6 . 7 3 3 6 . 8 1 3 6 . 8 5 3 6 . 8 9 3 6 . 9 8 3 7 . 0 7 3 7 . 1 2 3 7 . 1 9 3 7 . 3 1 3 7 . 4 3 3 7 . 4 7 3 7 . 6 0 3 7 . 7 0 3 7 . 7 4 3 7 . 7 9 3 7 . 8 5 3 7 . 9 3 3 7 . 9 7 3 8 . 0 6 3 8 . 1 5 3 8 . 2 4 3 8 . 3 2 3 8 . 4 1 3 8 . 4 9 3 8 . 5 6 3 8 . 6 2 3 8 . 7 1 3 8 . 8 3 3 8 . 9 2 3 8 . 9 6 3 9 . 0 6 3 9 . 1 0 3 9 . 1 4 3 9 . 2 1 3 9 . 2 8 3 9 . 3 1 3 9 . 4 6 3 9 . 5 2 3 9 . 5 6 3 9 . 6 9 3 9 . 7 9 3 9 . 9 1 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e * 2 - B r o m o n a p h t h a l e n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0023.RAW B14072051-011A ;0804HP3 , $HC-ALI-GRP-S, V23,(2,3) 0 5 10 15 20 25 30 35 40 0 100 200 300 400 500 600 700 800 900 1000 Page 109 of 117 B9 5-7 Batch ID: 81798 EPH AROMATICS RANGE VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-011A ;0804HP3 , $HC-ARO-GRP-S, RR-V31 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0031.RAW Date & Time Acquired: 8/5/2014 3:08:25 PM Method File: g:\org\HP3\Methods\R3_EPH-080427-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF EPH Aromatics: 32892.63 Rt range for EPH C11 to C22 Aromatics: 11.327 to 22.281 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *2-Fluorobiphenyl________13.3 6.667 6.881 103.21 - *2-Bromonaphthalene______14.176 6.667 9.922 148.83 - *o-Terphenyl_____________16.553 6.667 9.944 149.17 - *1-Chlorooctadecane______17.371 6.667 10.133 151.99 - C11-C22 Aromatics Area:2.790901E+08 C11-C22 Aromatics Amount: 565.6588 EPH Aromatics total Area:4.955463E+08 EPH Aromatics Total Amount: 1004.371 4 . 5 4 4 . 6 3 4 . 6 7 4 . 7 2 4 . 8 1 4 . 8 9 4 . 9 4 5 . 0 3 5 . 0 5 5 . 2 0 5 . 3 4 6 . 0 4 7 . 9 5 8 . 0 4 8 . 2 3 8 . 5 0 8 . 9 6 9 . 1 9 9 . 5 5 9 . 6 8 9 . 8 8 1 0 . 0 0 1 0 . 2 0 1 0 . 2 6 1 0 . 4 6 1 0 . 5 2 1 0 . 7 9 1 0 . 8 7 1 1 . 0 1 1 1 . 1 1 1 1 . 2 2 1 1 . 4 2 1 1 . 5 5 1 1 . 6 3 1 1 . 7 9 1 1 . 8 6 1 1 . 9 4 1 2 . 0 7 1 2 . 1 4 1 2 . 2 3 1 2 . 3 2 1 2 . 3 8 1 2 . 4 6 1 2 . 5 3 1 2 . 6 7 1 2 . 7 4 1 2 . 8 1 1 2 . 9 0 1 2 . 9 7 1 3 . 0 6 1 3 . 1 4 1 3 . 2 3 1 3 . 3 0 1 3 . 5 2 1 3 . 6 4 1 3 . 7 7 1 3 . 9 2 1 4 . 0 1 1 4 . 0 9 1 4 . 1 8 1 4 . 3 5 1 4 . 4 7 1 4 . 5 3 1 4 . 5 8 1 4 . 6 4 1 4 . 7 4 1 4 . 8 7 1 4 . 9 1 1 4 . 9 6 1 5 . 0 1 1 5 . 0 6 1 5 . 1 1 1 5 . 2 0 1 5 . 2 7 1 5 . 3 9 1 5 . 4 8 1 5 . 6 2 1 5 . 7 8 1 5 . 9 2 1 6 . 0 7 1 6 . 1 5 1 6 . 2 5 1 6 . 3 3 1 6 . 4 5 1 6 . 5 5 1 6 . 6 9 1 6 . 8 1 1 6 . 9 5 1 7 . 0 6 1 7 . 1 8 1 7 . 2 5 1 7 . 3 7 1 7 . 4 9 1 7 . 5 9 1 7 . 6 6 1 7 . 7 4 1 7 . 8 1 1 7 . 8 9 1 8 . 0 0 1 8 . 1 2 1 8 . 2 1 1 8 . 2 8 1 8 . 3 7 1 8 . 4 4 1 8 . 5 5 1 8 . 6 7 1 8 . 7 4 1 8 . 8 6 1 8 . 9 1 1 9 . 0 5 1 9 . 1 5 1 9 . 2 4 1 9 . 3 1 1 9 . 3 7 1 9 . 4 4 1 9 . 5 4 1 9 . 5 7 1 9 . 6 6 1 9 . 7 3 1 9 . 7 6 1 9 . 8 2 1 9 . 8 9 1 9 . 9 5 2 0 . 1 2 2 0 . 1 6 2 0 . 2 3 2 0 . 3 2 2 0 . 3 5 2 0 . 4 1 2 0 . 5 5 2 0 . 6 1 2 0 . 7 0 2 0 . 7 4 2 0 . 7 7 2 0 . 8 7 2 0 . 9 5 2 1 . 0 1 2 1 . 3 1 2 1 . 3 7 2 1 . 5 5 2 1 . 5 9 2 1 . 6 8 2 1 . 7 1 2 1 . 7 6 2 1 . 8 5 2 1 . 8 9 2 1 . 9 8 2 2 . 1 1 2 2 . 4 3 2 2 . 6 8 2 2 . 8 4 2 3 . 0 8 2 3 . 1 8 2 3 . 2 5 2 3 . 6 4 2 3 . 9 1 2 3 . 9 5 2 4 . 0 4 2 4 . 1 8 2 4 . 2 7 2 4 . 4 5 2 4 . 6 1 2 4 . 8 0 2 4 . 9 9 2 5 . 0 8 2 5 . 3 4 2 5 . 4 8 2 5 . 6 0 2 5 . 7 1 2 6 . 0 3 2 6 . 1 3 2 6 . 1 8 2 6 . 2 4 2 6 . 2 8 2 6 . 5 8 2 6 . 6 3 2 6 . 7 4 2 6 . 9 4 2 7 . 0 1 2 7 . 0 9 2 7 . 1 8 2 7 . 2 7 2 7 . 4 3 2 7 . 4 9 2 7 . 5 6 2 7 . 6 0 2 7 . 6 4 2 7 . 6 8 2 7 . 7 3 2 7 . 8 1 2 7 . 9 5 2 7 . 9 9 2 8 . 0 8 2 8 . 2 3 2 8 . 3 4 2 8 . 4 4 2 8 . 6 1 2 8 . 6 9 2 8 . 7 4 2 8 . 8 3 2 8 . 8 6 2 8 . 9 6 2 9 . 0 4 2 9 . 1 1 2 9 . 1 7 2 9 . 2 1 2 9 . 2 5 2 9 . 2 9 2 9 . 3 5 2 9 . 4 1 2 9 . 5 6 2 9 . 6 9 2 9 . 7 6 2 9 . 8 6 2 9 . 9 2 2 9 . 9 5 3 0 . 1 3 3 0 . 1 6 3 0 . 2 1 3 0 . 3 2 3 0 . 4 2 3 0 . 5 5 3 0 . 6 5 3 0 . 7 8 3 0 . 8 2 3 0 . 8 8 3 0 . 9 8 3 1 . 0 2 3 1 . 1 1 3 1 . 1 9 3 1 . 2 3 3 1 . 3 3 3 1 . 4 5 3 1 . 5 1 3 1 . 6 2 3 1 . 7 3 3 1 . 8 6 3 2 . 0 0 3 2 . 0 7 3 2 . 1 2 3 2 . 1 8 3 2 . 2 4 3 2 . 2 8 3 2 . 3 7 3 2 . 4 7 3 2 . 5 7 3 2 . 7 0 3 2 . 7 5 3 2 . 7 9 3 2 . 8 4 3 2 . 9 5 3 3 . 0 2 3 3 . 1 4 3 3 . 2 6 3 3 . 3 5 3 3 . 3 9 3 3 . 5 7 3 3 . 6 7 3 3 . 7 0 3 3 . 7 5 3 3 . 8 3 3 3 . 9 2 3 3 . 9 7 3 4 . 0 6 3 4 . 1 8 3 4 . 2 2 3 4 . 2 8 3 4 . 3 5 3 4 . 4 6 3 4 . 5 0 3 4 . 6 2 3 4 . 6 6 3 4 . 7 3 3 4 . 8 0 3 4 . 9 1 3 4 . 9 9 3 5 . 0 4 3 5 . 1 3 3 5 . 2 2 3 5 . 2 9 3 5 . 3 4 3 5 . 4 0 3 5 . 4 7 3 5 . 5 7 3 5 . 6 0 3 5 . 6 7 3 5 . 7 0 3 5 . 8 6 3 5 . 9 9 3 6 . 0 2 3 6 . 0 9 3 6 . 1 5 3 6 . 2 2 3 6 . 3 0 3 6 . 3 6 3 6 . 4 7 3 6 . 5 3 3 6 . 6 0 3 6 . 8 1 3 6 . 9 0 3 6 . 9 6 3 7 . 0 4 3 7 . 1 0 3 7 . 1 6 3 7 . 2 1 3 7 . 3 0 3 7 . 3 4 3 7 . 3 7 3 7 . 4 4 3 7 . 5 3 3 7 . 6 2 3 7 . 6 9 3 7 . 7 6 3 7 . 8 0 3 7 . 9 9 3 8 . 0 7 3 8 . 1 3 3 8 . 2 5 3 8 . 3 0 3 8 . 3 8 3 8 . 4 3 3 8 . 5 0 3 8 . 5 7 3 8 . 6 0 3 8 . 7 0 3 8 . 7 8 3 8 . 8 8 3 8 . 9 9 3 9 . 0 3 3 9 . 1 4 3 9 . 2 2 3 9 . 2 6 3 9 . 3 5 3 9 . 4 2 3 9 . 4 6 3 9 . 5 3 3 9 . 6 0 3 9 . 6 4 3 9 . 7 4 3 9 . 8 2 3 9 . 9 0 3 9 . 9 6 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0031.RAW B14072051-011A ;0804HP3 , $HC-ARO-GRP-S, RR-V31 0 5 10 15 20 25 30 35 40 0 500 1000 1500 2000 2500 3000 Page 110 of 117 B9 5-7 Batch ID: 81798 EPH AROMATICS TARGET VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-011A ;0804HP3 , $HC-ARO-GRP-S, RR-V31 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0031.RAW Date & Time Acquired: 8/5/2014 3:08:25 PM Method File: g:\org\HP3\Methods\RT_EPH-080431-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG Naphthalene______________11.422 11.422 11.422 1954 .067 U 2-Methylnaphthalene______12.665 1.5 1.51 73195 .153 Acenaphthylene___________13.916 .205 .259 211512 .434 Acenaphthene_____________. . . .067 U Fluorene_________________14.867 -.698 -.691 275390 .563 Phenanthrene_____________16.074 -1.885 -1.898 124282 .259 Anthracene_______________. . . .067 U Fluoranthene_____________17.49 -3.297 -3.314 309954 .621 Pyrene___________________17.742 -3.558 -3.566 500759 .989 Benzo(a)Anthracene_______19.173 19.173 19.173 11792 .067 U Chrysene_________________19.241 -5.055 -5.065 296780 .602 Benzo(b&k)Fluoranthe_____20.413 20.413 20.413 16938 .133 U Benzo(a)Pyrene___________20.704 20.704 20.704 6221 .067 U Indeno-Dibenzo___________21.889 21.889 21.889 8928 .133 U Benzo(g,h,i)Perylene_____22.203 22.203 22.203 8466 .067 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS *2-Fluorobiphenyl________13.3 6.667 6.022 90.32 40-140 *2-Bromonaphthalene______14.176 6.667 7.255 108.82 40-140 *o-Terphenyl_____________16.553 6.667 5.634 84.51 40-140 *1-Chlorooctadecane______17.371 6.667 1.758 26.36 40-140 1 0 . 5 2 1 0 . 7 9 1 0 . 8 7 1 1 . 0 1 1 1 . 1 1 1 1 . 2 2 1 1 . 4 2 1 1 . 5 5 1 1 . 6 3 1 1 . 7 9 1 1 . 8 6 1 1 . 9 4 1 2 . 0 7 1 2 . 1 4 1 2 . 2 3 1 2 . 3 2 1 2 . 3 8 1 2 . 4 6 1 2 . 5 3 1 2 . 6 7 1 2 . 7 4 1 2 . 8 1 1 2 . 9 0 1 2 . 9 7 1 3 . 0 6 1 3 . 1 4 1 3 . 2 3 1 3 . 3 0 1 3 . 5 2 1 3 . 6 4 1 3 . 7 7 1 3 . 9 2 1 4 . 0 1 1 4 . 0 9 1 4 . 1 8 1 4 . 3 5 1 4 . 4 7 1 4 . 5 3 1 4 . 5 8 1 4 . 6 4 1 4 . 7 4 1 4 . 8 7 1 4 . 9 1 1 4 . 9 6 1 5 . 0 1 1 5 . 0 6 1 5 . 1 1 1 5 . 2 0 1 5 . 2 7 1 5 . 3 9 1 5 . 4 8 1 5 . 6 2 1 5 . 7 8 1 5 . 9 2 1 6 . 0 7 1 6 . 1 5 1 6 . 2 5 1 6 . 3 3 1 6 . 4 5 1 6 . 5 5 1 6 . 6 9 1 6 . 8 1 1 6 . 9 5 1 7 . 0 6 1 7 . 1 8 1 7 . 2 5 1 7 . 3 7 1 7 . 4 9 1 7 . 5 9 1 7 . 6 6 1 7 . 7 4 1 7 . 8 1 1 7 . 8 9 1 8 . 0 0 1 8 . 1 2 1 8 . 2 1 1 8 . 2 8 1 8 . 3 7 1 8 . 4 4 1 8 . 5 5 1 8 . 6 7 1 8 . 7 4 1 8 . 8 6 1 8 . 9 1 1 9 . 0 3 1 9 . 0 5 1 9 . 1 5 1 9 . 1 7 1 9 . 2 0 1 9 . 2 4 1 9 . 3 1 1 9 . 3 4 1 9 . 3 7 1 9 . 4 1 1 9 . 4 4 1 9 . 5 0 1 9 . 5 4 1 9 . 5 7 1 9 . 6 3 1 9 . 6 6 1 9 . 6 9 1 9 . 7 3 1 9 . 7 6 1 9 . 7 9 1 9 . 8 2 1 9 . 8 8 1 9 . 8 9 1 9 . 9 2 1 9 . 9 5 2 0 . 0 0 2 0 . 0 2 2 0 . 0 5 2 0 . 0 9 2 0 . 1 2 2 0 . 1 6 2 0 . 1 9 2 0 . 2 3 2 0 . 2 6 2 0 . 2 9 2 0 . 3 2 2 0 . 3 5 2 0 . 3 9 2 0 . 4 1 2 0 . 4 4 2 0 . 4 8 2 0 . 5 2 2 0 . 5 5 2 0 . 5 8 2 0 . 6 1 2 0 . 6 5 2 0 . 6 8 2 0 . 7 0 2 0 . 7 4 2 0 . 7 7 2 0 . 8 7 2 0 . 9 1 2 0 . 9 3 2 0 . 9 5 2 0 . 9 7 2 1 . 0 1 2 1 . 0 8 2 1 . 1 1 2 1 . 1 4 2 1 . 2 0 2 1 . 2 4 2 1 . 2 8 2 1 . 3 1 2 1 . 3 7 2 1 . 4 0 2 1 . 4 4 2 1 . 5 1 2 1 . 5 5 2 1 . 5 9 2 1 . 6 8 2 1 . 7 1 2 1 . 7 6 2 1 . 8 0 2 1 . 8 5 2 1 . 8 9 2 1 . 9 1 2 1 . 9 4 2 1 . 9 6 2 1 . 9 8 2 2 . 0 1 2 2 . 0 4 2 2 . 0 6 2 2 . 0 8 2 2 . 1 1 2 2 . 1 4 2 2 . 2 0 2 2 . 2 3 2 2 . 2 5 2 2 . 2 8 2 2 . 2 9 2 2 . 3 3 2 2 . 4 3 2 2 . 4 9 2 2 . 5 3 2 2 . 5 8 2 2 . 6 1 2 2 . 6 2 2 2 . 6 6 2 2 . 6 8 2 2 . 7 1 2 2 . 7 3 2 2 . 7 7 2 2 . 7 9 2 2 . 8 2 2 2 . 8 4 2 2 . 8 7 2 2 . 9 5 2 3 . 0 2 2 3 . 0 8 2 3 . 1 2 2 3 . 1 5 2 3 . 1 8 2 3 . 2 0 2 3 . 2 5 2 3 . 2 9 2 3 . 3 1 2 3 . 3 7 2 3 . 4 3 2 3 . 4 6 2 3 . 4 9 2 3 . 5 1 2 3 . 5 4 2 3 . 5 6 2 3 . 6 0 2 3 . 6 4 2 3 . 6 6 2 3 . 7 0 2 3 . 7 2 2 3 . 7 7 2 3 . 8 4 2 3 . 8 9 2 3 . 9 1 2 3 . 9 5 2 3 . 9 8 2 4 . 0 2 2 4 . 0 4 2 4 . 0 8 2 4 . 1 0 2 4 . 1 2 2 4 . 1 8 2 4 . 2 4 2 4 . 2 7 2 4 . 3 3 2 4 . 3 6 2 4 . 4 2 2 4 . 4 5 2 4 . 4 9 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0031.RAW B14072051-011A ;0804HP3 , $HC-ARO-GRP-S, RR-V31 11 12 13 14 15 16 17 18 19 20 21 22 23 24 0 500 1000 1500 2000 2500 Page 111 of 117 B9 8-11 Batch ID: 81798 EPH ALIPHATICS (FID) ANALYSIS REPORT Sample Name: B14072051-012A ;0801HP3 , $HC-ALI-GRP-S, V36 Raw File: G:\org\HP3\DAT\HP3080114_b\0801HP3.0036.RAW Date & Time Acquired: 8/2/2014 11:31:28 PM Method File: g:\org\HP3\Methods\L3_EPH-LB-L%.met Calibration File: G:\Org\HP3\Cals\AL130823LB.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Aliphatic Hydrocarbons: 30415.23 Mean RF for C19 to C36 Aliphatic Hydrocarbons: 31274 Mean RF for Total Extractable Hydrocarbons: 30905.96 Rt range for Diesel Range Organics: 8.427999 to 20.231 Rt range for C9 to C18 Aliphatic Hydrocarbons: 6.638 to 16.417 Rt range for C19 to C36 Aliphatic Hydrocarbons: 16.442 to 23.523 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *1-Chloro-octadecane_____17.371 6.667 6.245 93.68 - DRO Area:6722982 DRO Amount: 14.50202 TEH Area:6.128016E+07 TEH Amount: 132.1863 Aliphatic Hydrocarbon Areas and Amounts: C9-C18 Area:2481295 C9-C18 Amount: 5.438711 C19-C36 Area:3.293001E+07C19-C36 Amount: 70.19678 4 . 7 6 4 . 8 4 5 . 0 5 5 . 2 0 5 . 4 6 5 . 6 0 5 . 8 9 6 . 0 5 7 . 0 7 7 . 2 9 7 . 3 7 7 . 4 9 7 . 5 9 7 . 7 6 7 . 8 6 7 . 9 8 8 . 0 8 8 . 2 6 8 . 4 9 8 . 7 7 8 . 9 2 9 . 0 0 9 . 1 1 9 . 1 8 9 . 2 8 9 . 3 9 9 . 4 9 9 . 5 8 9 . 8 3 1 0 . 0 0 1 0 . 0 8 1 0 . 1 9 1 0 . 2 7 1 0 . 3 7 1 0 . 4 2 1 0 . 6 1 1 0 . 8 3 1 0 . 9 7 1 1 . 1 4 1 1 . 2 0 1 1 . 4 0 1 1 . 6 1 1 1 . 7 5 1 1 . 9 0 1 2 . 0 4 1 2 . 1 8 1 2 . 2 6 1 2 . 3 3 1 2 . 3 8 1 2 . 4 9 1 2 . 5 9 1 2 . 6 8 1 2 . 7 6 1 2 . 8 1 1 2 . 8 9 1 2 . 9 7 1 3 . 0 9 1 3 . 1 7 1 3 . 2 1 1 3 . 2 6 1 3 . 3 0 1 3 . 4 4 1 3 . 5 1 1 3 . 5 6 1 3 . 6 5 1 3 . 7 4 1 3 . 7 7 1 3 . 8 7 1 3 . 9 3 1 4 . 0 8 1 4 . 1 3 1 4 . 2 0 1 4 . 2 5 1 4 . 2 9 1 4 . 3 8 1 4 . 4 6 1 4 . 5 1 1 4 . 5 3 1 4 . 6 2 1 4 . 7 0 1 4 . 7 9 1 4 . 8 3 1 4 . 9 6 1 5 . 0 4 1 5 . 1 2 1 5 . 2 1 1 5 . 3 2 1 5 . 4 4 1 5 . 5 3 1 5 . 6 1 1 5 . 6 6 1 5 . 7 6 1 5 . 8 5 1 5 . 9 5 1 6 . 0 0 1 6 . 0 8 1 6 . 1 4 1 6 . 1 9 1 6 . 2 4 1 6 . 4 2 1 6 . 5 3 1 6 . 5 8 1 6 . 6 8 1 6 . 7 6 1 6 . 8 6 1 6 . 9 2 1 7 . 0 3 1 7 . 1 3 1 7 . 2 3 1 7 . 3 0 1 7 . 3 7 1 7 . 5 5 1 7 . 5 9 1 7 . 7 1 1 7 . 7 8 1 7 . 8 3 1 7 . 9 4 1 8 . 0 1 1 8 . 1 4 1 8 . 2 0 1 8 . 2 7 1 8 . 3 5 1 8 . 4 7 1 8 . 5 8 1 8 . 6 2 1 8 . 6 8 1 8 . 8 6 1 8 . 9 2 1 9 . 0 8 1 9 . 2 2 1 9 . 3 1 1 9 . 4 6 1 9 . 5 8 1 9 . 6 8 1 9 . 8 2 1 9 . 9 7 2 0 . 0 6 2 0 . 1 7 2 0 . 4 2 2 0 . 5 1 2 0 . 7 8 2 0 . 8 6 2 0 . 9 3 2 1 . 0 0 2 1 . 0 7 2 1 . 1 6 2 1 . 2 2 2 1 . 3 0 2 1 . 5 1 2 1 . 6 1 2 1 . 7 5 2 1 . 8 0 2 1 . 8 4 2 1 . 8 8 2 2 . 0 1 2 2 . 0 6 2 2 . 1 9 2 2 . 3 2 2 2 . 3 5 2 2 . 4 3 2 2 . 5 4 2 2 . 5 9 2 2 . 8 2 2 2 . 9 4 2 3 . 0 3 2 3 . 0 9 2 3 . 1 5 2 3 . 2 6 2 3 . 3 1 2 3 . 4 0 2 3 . 4 8 2 3 . 5 2 2 3 . 5 9 2 3 . 7 0 2 3 . 7 4 2 3 . 8 1 2 4 . 0 7 2 4 . 2 3 2 4 . 3 3 2 4 . 4 2 2 4 . 5 3 2 4 . 6 7 2 4 . 7 6 2 4 . 8 4 2 4 . 8 9 2 4 . 9 2 2 5 . 2 4 2 5 . 3 5 2 5 . 4 0 2 5 . 6 8 2 5 . 8 4 2 6 . 2 0 2 6 . 2 6 2 6 . 4 9 2 6 . 5 3 2 6 . 5 7 2 6 . 6 2 2 6 . 7 5 2 6 . 8 6 2 7 . 0 1 2 7 . 2 7 2 7 . 3 1 2 7 . 4 0 2 7 . 4 8 2 7 . 6 5 2 7 . 7 0 2 7 . 7 8 2 7 . 8 6 2 8 . 0 0 2 8 . 0 3 2 8 . 1 3 2 8 . 1 8 2 8 . 2 3 2 8 . 2 6 2 8 . 3 2 2 8 . 4 7 2 8 . 6 1 2 8 . 6 9 2 8 . 7 5 2 8 . 8 4 2 8 . 9 1 2 9 . 0 6 2 9 . 1 5 2 9 . 2 2 2 9 . 3 0 2 9 . 3 7 2 9 . 6 1 2 9 . 6 5 2 9 . 6 9 2 9 . 7 4 2 9 . 8 1 2 9 . 8 4 2 9 . 9 0 2 9 . 9 6 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e * 2 - B r o m o n a p h t h a l e n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP3\DAT\HP3080114_b\0801HP3.0036.RAW B14072051-012A ;0801HP3 , $HC-ALI-GRP-S, V36 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 112 of 117 B9 8-11 Batch ID: 81798 EPH AROMATICS RANGE VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-012A ;0804HP3 , $HC-ARO-GRP-S, RR-V29 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0029.RAW Date & Time Acquired: 8/5/2014 1:15:10 PM Method File: g:\org\HP3\Methods\R3_EPH-080427-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 Mean RF EPH Aromatics: 32892.63 Rt range for EPH C11 to C22 Aromatics: 11.327 to 22.281 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *2-Fluorobiphenyl________13.288 6.667 6.158 92.37 - *2-Bromonaphthalene______14.155 6.667 6.432 96.48 - *o-Terphenyl_____________16.539 6.667 6.287 94.31 - *1-Chlorooctadecane______17.357 6.667 .523 7.84 - C11-C22 Aromatics Area:2.748029E+07 C11-C22 Aromatics Amount: 55.69695 EPH Aromatics total Area:1.223808E+08 EPH Aromatics Total Amount: 248.041 4 . 5 1 4 . 6 3 4 . 6 6 4 . 7 9 4 . 9 4 5 . 0 5 5 . 1 1 5 . 2 0 5 . 4 7 5 . 6 0 5 . 7 7 5 . 8 8 5 . 9 9 6 . 0 4 7 . 0 3 8 . 0 0 8 . 2 4 8 . 5 1 8 . 6 9 8 . 9 6 9 . 1 2 9 . 2 2 9 . 4 9 9 . 5 5 9 . 5 9 9 . 8 6 1 0 . 0 3 1 0 . 0 6 1 0 . 1 9 1 0 . 2 7 1 0 . 4 4 1 0 . 4 6 1 0 . 5 2 1 0 . 5 6 1 0 . 9 1 1 0 . 9 5 1 1 . 2 0 1 1 . 2 6 1 1 . 5 4 1 1 . 6 5 1 1 . 7 9 1 1 . 9 4 1 2 . 1 4 1 2 . 2 5 1 2 . 3 8 1 2 . 4 6 1 2 . 5 3 1 2 . 6 6 1 2 . 7 4 1 2 . 9 0 1 2 . 9 6 1 3 . 0 6 1 3 . 1 4 1 3 . 2 9 1 3 . 5 1 1 3 . 6 5 1 3 . 7 5 1 3 . 9 0 1 3 . 9 2 1 4 . 0 0 1 4 . 0 8 1 4 . 1 6 1 4 . 3 4 1 4 . 4 8 1 4 . 5 2 1 4 . 6 2 1 4 . 7 3 1 4 . 8 5 1 4 . 9 6 1 5 . 1 3 1 5 . 2 0 1 5 . 2 4 1 5 . 3 8 1 5 . 4 7 1 5 . 6 1 1 5 . 7 2 1 5 . 7 6 1 5 . 8 0 1 5 . 9 2 1 6 . 0 2 1 6 . 0 7 1 6 . 1 4 1 6 . 2 0 1 6 . 2 3 1 6 . 2 8 1 6 . 4 5 1 6 . 5 4 1 6 . 6 8 1 6 . 7 9 1 6 . 9 4 1 7 . 0 5 1 7 . 1 7 1 7 . 2 3 1 7 . 3 6 1 7 . 4 7 1 7 . 5 7 1 7 . 6 4 1 7 . 7 3 1 7 . 8 1 1 7 . 8 6 1 7 . 9 7 1 8 . 0 4 1 8 . 0 8 1 8 . 1 4 1 8 . 1 9 1 8 . 2 4 1 8 . 2 9 1 8 . 3 4 1 8 . 4 2 1 8 . 5 1 1 8 . 6 4 1 8 . 7 2 1 8 . 7 8 1 8 . 8 3 1 8 . 8 9 1 9 . 0 2 1 9 . 0 7 1 9 . 1 4 1 9 . 2 1 1 9 . 3 2 1 9 . 4 2 1 9 . 5 6 1 9 . 6 0 1 9 . 6 7 1 9 . 7 7 1 9 . 8 0 1 9 . 8 6 1 9 . 9 3 2 0 . 0 0 2 0 . 0 9 2 0 . 2 3 2 0 . 3 0 2 0 . 4 0 2 0 . 5 0 2 0 . 5 7 2 0 . 5 9 2 0 . 6 6 2 0 . 7 4 2 0 . 7 7 2 0 . 9 8 2 1 . 0 8 2 1 . 1 4 2 1 . 1 7 2 1 . 2 5 2 1 . 3 1 2 1 . 3 6 2 1 . 4 3 2 1 . 4 6 2 1 . 5 4 2 1 . 5 8 2 1 . 6 8 2 1 . 7 9 2 1 . 8 2 2 1 . 9 3 2 1 . 9 7 2 2 . 0 2 2 2 . 0 8 2 2 . 1 8 2 2 . 2 4 2 2 . 3 8 2 2 . 4 3 2 2 . 5 1 2 2 . 5 5 2 2 . 6 3 2 2 . 7 1 2 2 . 7 6 2 2 . 7 9 2 2 . 9 0 2 2 . 9 7 2 3 . 0 4 2 3 . 1 0 2 3 . 1 6 2 3 . 2 2 2 3 . 3 7 2 3 . 4 7 2 3 . 5 0 2 3 . 5 5 2 3 . 7 9 2 3 . 8 6 2 3 . 8 9 2 3 . 9 6 2 4 . 0 2 2 4 . 1 1 2 4 . 3 0 2 4 . 3 9 2 4 . 5 1 2 4 . 6 3 2 4 . 7 1 2 4 . 8 0 2 4 . 9 2 2 5 . 1 1 2 5 . 1 6 2 5 . 2 1 2 5 . 3 2 2 5 . 4 0 2 5 . 5 2 2 5 . 5 6 2 5 . 6 7 2 5 . 7 4 2 5 . 8 3 2 5 . 8 7 2 5 . 9 5 2 5 . 9 9 2 6 . 0 5 2 6 . 0 8 2 6 . 1 6 2 6 . 1 9 2 6 . 2 6 2 6 . 3 2 2 6 . 4 9 2 6 . 6 8 2 6 . 7 2 2 6 . 8 0 2 6 . 8 5 2 6 . 8 8 2 6 . 9 6 2 7 . 0 0 2 7 . 1 2 2 7 . 1 7 2 7 . 2 5 2 7 . 5 7 2 7 . 6 3 2 7 . 7 1 2 7 . 7 5 2 7 . 8 6 2 7 . 9 6 2 8 . 0 0 2 8 . 1 8 2 8 . 3 3 2 8 . 3 6 2 8 . 4 5 2 8 . 4 9 2 8 . 5 2 2 8 . 6 0 2 8 . 6 4 2 8 . 7 8 2 8 . 8 2 2 8 . 9 9 2 9 . 0 3 2 9 . 0 8 2 9 . 1 4 2 9 . 2 0 2 9 . 2 7 2 9 . 4 2 2 9 . 5 0 2 9 . 5 3 2 9 . 5 9 2 9 . 6 7 2 9 . 7 2 2 9 . 7 7 2 9 . 8 9 3 0 . 0 7 3 0 . 1 3 3 0 . 3 0 3 0 . 3 9 3 0 . 5 1 3 0 . 5 8 3 0 . 6 1 3 0 . 6 7 3 0 . 7 7 3 0 . 8 2 3 0 . 8 9 3 0 . 9 2 3 1 . 0 0 3 1 . 1 2 3 1 . 1 6 3 1 . 1 9 3 1 . 2 6 3 1 . 4 2 3 1 . 4 8 3 1 . 5 7 3 1 . 6 2 3 1 . 6 8 3 1 . 7 4 3 1 . 7 9 3 1 . 8 9 3 1 . 9 9 3 2 . 0 4 3 2 . 1 0 3 2 . 2 5 3 2 . 3 2 3 2 . 3 7 3 2 . 4 3 3 2 . 5 1 3 2 . 5 5 3 2 . 6 2 3 2 . 6 7 3 2 . 8 0 3 2 . 8 3 3 3 . 0 0 3 3 . 0 5 3 3 . 1 3 3 3 . 2 3 3 3 . 2 8 3 3 . 3 2 3 3 . 4 4 3 3 . 4 9 3 3 . 5 6 3 3 . 6 2 3 3 . 6 9 3 3 . 7 3 3 3 . 9 0 3 3 . 9 5 3 4 . 1 8 3 4 . 2 6 3 4 . 3 8 3 4 . 4 9 3 4 . 5 7 3 4 . 6 4 3 4 . 7 1 3 4 . 7 9 3 4 . 8 4 3 4 . 9 0 3 4 . 9 5 3 5 . 0 2 3 5 . 0 7 3 5 . 1 5 3 5 . 2 3 3 5 . 3 5 3 5 . 5 2 3 5 . 5 8 3 5 . 6 3 3 5 . 7 4 3 5 . 8 2 3 5 . 9 0 3 5 . 9 4 3 6 . 0 0 3 6 . 1 1 3 6 . 1 5 3 6 . 2 0 3 6 . 2 3 3 6 . 3 2 3 6 . 3 9 3 6 . 4 5 3 6 . 5 3 3 6 . 5 9 3 6 . 6 9 3 6 . 7 7 3 6 . 8 0 3 6 . 8 6 3 6 . 9 9 3 7 . 0 7 3 7 . 1 3 3 7 . 2 3 3 7 . 3 1 3 7 . 3 8 3 7 . 4 5 3 7 . 5 6 3 7 . 6 3 3 7 . 7 5 3 7 . 7 9 3 7 . 9 1 3 7 . 9 6 3 8 . 0 3 3 8 . 1 4 3 8 . 1 7 3 8 . 2 1 3 8 . 3 2 3 8 . 5 3 3 8 . 6 1 3 8 . 6 8 3 8 . 7 3 3 8 . 7 8 3 8 . 8 5 3 8 . 9 7 3 9 . 0 5 3 9 . 1 0 3 9 . 1 9 3 9 . 2 4 3 9 . 3 3 3 9 . 4 0 3 9 . 4 6 3 9 . 5 7 3 9 . 6 3 3 9 . 7 6 3 9 . 9 3 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0029.RAW B14072051-012A ;0804HP3 , $HC-ARO-GRP-S, RR-V29 0 5 10 15 20 25 30 35 40 0 500 1000 1500 2000 2500 3000 Page 113 of 117 B9 8-11 Batch ID: 81798 EPH AROMATICS TARGET VALUES (FID) ANALYSIS REPORT Sample Name: B14072051-012A ;0804HP3 , $HC-ARO-GRP-S, RR-V29 Raw File: G:\org\HP3\DAT\HP3080414_b\0804HP3.0029.RAW Date & Time Acquired: 8/5/2014 1:15:10 PM Method File: g:\org\HP3\Methods\RT_EPH-080429-LCa-L%.met Calibration File: G:\Org\HP3\Cals\AR130823LCa.CAL Sample Weight: 30 Dilution: 2 S.A.: 1 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG Naphthalene______________. . . .067 U 2-Methylnaphthalene______12.66 12.66 12.66 18185 .067 U Acenaphthylene___________13.925 13.925 13.925 18156 .067 U Acenaphthene_____________. . . .067 U Fluorene_________________14.849 -.698 -.694 27166 .056 J Phenanthrene_____________16.073 16.073 16.073 4476 .067 U Anthracene_______________16.135 16.135 16.135 9361 .067 U Fluoranthene_____________17.474 -3.297 -3.319 30702 .062 J Pyrene___________________17.726 -3.558 -3.57 50949 .101 Benzo(a)Anthracene_______19.137 19.137 19.137 2858 .067 U Chrysene_________________19.206 -5.055 -5.051 33491 .068 Benzo(b&k)Fluoranthe_____20.399 20.399 20.399 19075 .133 U Benzo(a)Pyrene___________20.684 20.684 20.684 5236 .067 U Indeno-Dibenzo___________21.884 21.884 21.884 8166 .133 U Benzo(g,h,i)Perylene_____22.179 22.179 22.179 10975 .067 U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS *2-Fluorobiphenyl________13.288 6.667 6.128 91.92 40-140 *2-Bromonaphthalene______14.155 6.667 6.243 93.65 40-140 *o-Terphenyl_____________16.539 6.667 6.278 94.18 40-140 *1-Chlorooctadecane______17.357 6.667 .445 6.67 40-140 1 0 . 5 2 1 0 . 5 6 1 0 . 9 1 1 0 . 9 5 1 1 . 2 0 1 1 . 2 6 1 1 . 5 4 1 1 . 6 5 1 1 . 7 9 1 1 . 9 4 1 2 . 1 4 1 2 . 2 5 1 2 . 3 8 1 2 . 4 6 1 2 . 5 3 1 2 . 6 6 1 2 . 7 4 1 2 . 9 0 1 2 . 9 6 1 3 . 0 6 1 3 . 1 4 1 3 . 2 9 1 3 . 5 1 1 3 . 6 5 1 3 . 7 5 1 3 . 9 0 1 3 . 9 2 1 4 . 0 0 1 4 . 0 8 1 4 . 1 6 1 4 . 3 4 1 4 . 4 8 1 4 . 5 2 1 4 . 6 2 1 4 . 7 3 1 4 . 8 5 1 4 . 9 6 1 5 . 1 3 1 5 . 2 0 1 5 . 2 4 1 5 . 3 8 1 5 . 4 7 1 5 . 6 1 1 5 . 7 2 1 5 . 7 6 1 5 . 8 0 1 5 . 9 2 1 6 . 0 2 1 6 . 0 7 1 6 . 1 4 1 6 . 2 0 1 6 . 2 3 1 6 . 2 8 1 6 . 4 5 1 6 . 5 4 1 6 . 6 8 1 6 . 7 9 1 6 . 9 4 1 7 . 0 5 1 7 . 1 7 1 7 . 2 3 1 7 . 3 6 1 7 . 4 7 1 7 . 5 7 1 7 . 6 4 1 7 . 7 3 1 7 . 8 1 1 7 . 8 6 1 7 . 9 7 1 8 . 0 4 1 8 . 0 8 1 8 . 1 4 1 8 . 1 9 1 8 . 2 4 1 8 . 2 9 1 8 . 3 4 1 8 . 4 2 1 8 . 5 1 1 8 . 6 4 1 8 . 7 2 1 8 . 7 8 1 8 . 8 3 1 8 . 8 9 1 9 . 0 2 1 9 . 0 7 1 9 . 1 4 1 9 . 2 1 1 9 . 3 2 1 9 . 4 2 1 9 . 5 6 1 9 . 6 0 1 9 . 6 7 1 9 . 7 7 1 9 . 8 0 1 9 . 8 6 1 9 . 9 3 2 0 . 0 0 2 0 . 0 9 2 0 . 2 3 2 0 . 3 0 2 0 . 4 0 2 0 . 5 0 2 0 . 5 7 2 0 . 5 9 2 0 . 6 6 2 0 . 6 8 2 0 . 7 7 2 0 . 9 8 2 1 . 0 8 2 1 . 1 4 2 1 . 1 7 2 1 . 2 5 2 1 . 3 1 2 1 . 3 6 2 1 . 4 1 2 1 . 4 6 2 1 . 5 4 2 1 . 5 8 2 1 . 6 8 2 1 . 7 9 2 1 . 8 2 2 1 . 8 8 2 1 . 9 7 2 2 . 0 2 2 2 . 0 8 2 2 . 1 8 2 2 . 2 4 2 2 . 3 8 2 2 . 4 3 2 2 . 5 1 2 2 . 5 5 2 2 . 6 3 2 2 . 7 1 2 2 . 7 6 2 2 . 7 9 2 2 . 9 0 2 2 . 9 7 2 3 . 0 4 2 3 . 1 0 2 3 . 1 6 2 3 . 2 2 2 3 . 3 7 2 3 . 4 7 2 3 . 5 0 2 3 . 5 5 2 3 . 7 9 2 3 . 8 6 2 3 . 8 9 2 3 . 9 6 2 4 . 0 2 2 4 . 1 1 2 4 . 3 0 2 4 . 3 9 N a p h t h a l e n e 2 - M e t h y l n a p h t h a l e n e * 2 - F l u o r o b i p h e n y l A c e n a p h t h y l e n e * 2 - B r o m o n a p h t h a l e n e A c e n a p h t h e n e F l u o r e n e P h e n a n t h r e n e A n t h r a c e n e * o - T e r p h e n y l * 1 - C h l o r o o c t a d e c a n e F l u o r a n t h e n e P y r e n e B e n z o ( a ) A n t h r a c e n e C h r y s e n e B e n z o ( b & k ) F l u o r a n t h e B e n z o ( a ) P y r e n e I n d e n o - D i b e n z o B e n z o ( g , h , i ) P e r y l e n e G:\org\HP3\DAT\HP3080414_b\0804HP3.0029.RAW B14072051-012A ;0804HP3 , $HC-ARO-GRP-S, RR-V29 11 12 13 14 15 16 17 18 19 20 21 22 23 24 0 500 1000 1500 2000 2500 Page 114 of 117 Shipping container/cooler in good condition? Custody seals intact on all shipping container(s)/cooler(s)? Custody seals intact on all sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? (Exclude analyses that are considered field parameters such as pH, DO, Res Cl, Sulfite, Ferrous Iron, etc.) Container/Temp Blank temperature: Water - VOA vials have zero headspace? Water - pH acceptable upon receipt? Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No No No No No No No No No No No Not Present Not Present Not Present No VOA vials submitted Not Applicable 4.5° C On Ice 7/23/2014 Leslie S. Cadreau Return-UPS Ground dlf Date Received: Received by: Login completed by: Carrier name: BL2000\tedwards 7/23/2014 Reviewed by: Reviewed Date: Contact and Corrective Action Comments: None Temp Blank received in all shipping container(s)/cooler(s)? Yes No Not Applicable Lab measurement of analytes considered field parameters that require analysis within 15 minutes of sampling such as pH, Dissolved Oxygen and Residual Chlorine, are qualified as being analyzed outside of recommended holding time. Solid/soil samples are reported on a wet weight basis (as received) unless specifically indicated. If moisture corrected, data units are typically noted as –dry. For agricultural and mining soil parameters/characteristics, all samples are dried and ground prior to sample analysis. Standard Reporting Procedures: Workorder Receipt Checklist MT DEQ-Lust B14072051 Page 115 of 117 Page 116 of 117 Page 117 of 117 Appendix C Laboratory Analytical Reports -Groundwater ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT ANALYTICAL SUMMARY REPORT The analyses presented in this report were performed by Energy Laboratories, Inc., 1120 S 27th St., Billings, MT 59101, unless otherwise noted. Any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, or the Case Narrative. The results as reported relate only to the item(s) submitted for testing. If you have any questions regarding these test results, please call. Lab ID Client Sample ID Collect Date Receive Date Matrix Test Report Approved By: B14080821-001 BZ/MW1 08/07/14 13:00 08/08/14 Aqueous Metals by ICP/ICPMS, Dissolved Mercury, Dissolved EPH-Liquid-Liquid Extraction Hydrocarbons, Extractable Petroleum Screen Volatile Petroleum Hydrocarbons Digestion, Mercury by CVAA 8260-Volatile Organic Compounds- Short List B14080821-002 BZ/MW2 08/07/14 14:15 08/08/14 Aqueous Same As Above B14080821-003 TB03052014B-TS SHP0263 08/07/14 13:00 08/08/14 Trip Blank 8260-Volatile Organic Compounds- Short List MT Dept of Transportation Project Name: Bozeman Yard Work Order: B14080821 PO Box 201001 Helena, MT 59620 August 22, 2014 Energy Laboratories Inc Billings MT received the following 3 samples for MT Dept of Transportation on 8/8/2014 for analysis. Page 1 of 31 LABORATORY ANALYTICAL REPORT Client: MT Dept of Transportation Project: Bozeman Yard Lab ID: B14080821-001 Client Sample ID: BZ/MW1 Collection Date: 08/07/14 13:00 Matrix: Aqueous Report Date: 08/22/14 DateReceived: 08/08/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers METALS, DISSOLVED 08/11/14 23:16 / amm 0.001 mg/L 0.003 Arsenic SW6020 08/11/14 23:16 / amm 0.05 mg/L 0.32 Barium SW6020 08/11/14 23:16 / amm 0.001 mg/L ND Cadmium SW6020 08/11/14 23:16 / amm 0.005 mg/L ND Chromium SW6020 08/15/14 20:17 / amm 0.001 mg/L ND Lead SW6020 08/11/14 15:28 / ser 0.0001 mg/L ND Mercury SW7470A 08/15/14 20:17 / amm 0.001 mg/L ND Selenium SW6020 08/21/14 11:03 / amm 0.001 mg/L ND Silver SW6020 VOLATILE ORGANIC COMPOUNDS J 08/11/14 21:07 / nl 1.0 ug/L 0.11 Benzene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Bromobenzene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Bromochloromethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Bromodichloromethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Bromoform SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Bromomethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Carbon tetrachloride SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Chlorobenzene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Chlorodibromomethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Chloroethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 2-Chloroethyl vinyl ether SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Chloroform SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Chloromethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,2-Dibromoethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 2-Chlorotoluene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 4-Chlorotoluene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Dibromomethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,2-Dichlorobenzene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,3-Dichlorobenzene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,4-Dichlorobenzene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Dichlorodifluoromethane SW8260B J 08/11/14 21:07 / nl 1.0 ug/L 0.19 1,1-Dichloroethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,2-Dichloroethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,1-Dichloroethene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND cis-1,2-Dichloroethene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND trans-1,2-Dichloroethene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,2-Dichloropropane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,3-Dichloropropane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 2,2-Dichloropropane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,1-Dichloropropene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND cis-1,3-Dichloropropene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND trans-1,3-Dichloropropene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Ethylbenzene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. J - Estimated value. The analyte was present but less than the reporting limit. Page 2 of 31 LABORATORY ANALYTICAL REPORT Client: MT Dept of Transportation Project: Bozeman Yard Lab ID: B14080821-001 Client Sample ID: BZ/MW1 Collection Date: 08/07/14 13:00 Matrix: Aqueous Report Date: 08/22/14 DateReceived: 08/08/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 08/11/14 21:07 / nl 20 ug/L ND Methyl ethyl ketone SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Methyl tert-butyl ether (MTBE) SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Methylene chloride SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Styrene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,1,1,2-Tetrachloroethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,1,2,2-Tetrachloroethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Tetrachloroethene SW8260B J 08/11/14 21:07 / nl 1.0 ug/L 0.19 Toluene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,1,1-Trichloroethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,1,2-Trichloroethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Trichloroethene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Trichlorofluoromethane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND 1,2,3-Trichloropropane SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Vinyl chloride SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND m+p-Xylenes SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND o-Xylene SW8260B 08/11/14 21:07 / nl 1.0 ug/L ND Xylenes, Total SW8260B 08/11/14 21:07 / nl 77-126 %REC 103 Surr: Dibromofluoromethane SW8260B 08/11/14 21:07 / nl 70-130 %REC 98.0 Surr: 1,2-Dichloroethane-d4 SW8260B 08/11/14 21:07 / nl 79-122 %REC 104 Surr: Toluene-d8 SW8260B 08/11/14 21:07 / nl 76-127 %REC 104 Surr: p-Bromofluorobenzene SW8260B PETROLEUM HYDROCARBONS-VOLATILE 08/13/14 14:34 / jp 1.0 ug/L ND Methyl tert-butyl ether (MTBE) MA-VPH 30 08/13/14 14:34 / jp 0.50 ug/L ND Benzene MA-VPH 5 08/13/14 14:34 / jp 0.50 ug/L ND Toluene MA-VPH 1000 08/13/14 14:34 / jp 0.50 ug/L ND Ethylbenzene MA-VPH 700 08/13/14 14:34 / jp 0.50 ug/L ND m+p-Xylenes MA-VPH 08/13/14 14:34 / jp 0.50 ug/L ND o-Xylene MA-VPH 08/13/14 14:34 / jp 0.50 ug/L ND Xylenes, Total MA-VPH 10000 08/13/14 14:34 / jp 1.0 ug/L ND Naphthalene MA-VPH 100 08/13/14 14:34 / jp 20 ug/L ND C9 to C10 Aromatics MA-VPH 1000 08/13/14 14:34 / jp 20 ug/L ND C5 to C8 Aliphatics MA-VPH 700 08/13/14 14:34 / jp 20 ug/L ND C9 to C12 Aliphatics MA-VPH 1000 08/13/14 14:34 / jp 20 ug/L ND Total Purgeable Hydrocarbons MA-VPH 1000 08/13/14 14:34 / jp 70-130 %REC 85.0 Surr: VPH Aromatics Surrogate MA-VPH 08/13/14 14:34 / jp 70-130 %REC 92.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 08/14/14 03:53 / amn 300 ug/L 861 Total Extractable Hydrocarbons SW8015M 1000 08/14/14 03:53 / amn 40-140 %REC 57.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. J - Estimated value. The analyte was present but less than the reporting limit. Page 3 of 31 LABORATORY ANALYTICAL REPORT Client: MT Dept of Transportation Project: Bozeman Yard Lab ID: B14080821-002 Client Sample ID: BZ/MW2 Collection Date: 08/07/14 14:15 Matrix: Aqueous Report Date: 08/22/14 DateReceived: 08/08/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers METALS, DISSOLVED 08/11/14 23:20 / amm 0.001 mg/L ND Arsenic SW6020 08/11/14 23:20 / amm 0.05 mg/L 0.17 Barium SW6020 08/11/14 23:20 / amm 0.001 mg/L ND Cadmium SW6020 08/11/14 23:20 / amm 0.005 mg/L ND Chromium SW6020 08/15/14 21:07 / amm 0.001 mg/L ND Lead SW6020 08/11/14 15:30 / ser 0.0001 mg/L ND Mercury SW7470A 08/15/14 21:07 / amm 0.001 mg/L 0.002 Selenium SW6020 08/21/14 11:19 / amm 0.001 mg/L ND Silver SW6020 VOLATILE ORGANIC COMPOUNDS 08/11/14 21:36 / nl 1.0 ug/L ND Benzene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Bromobenzene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Bromochloromethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Bromodichloromethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Bromoform SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Bromomethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Carbon tetrachloride SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Chlorobenzene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Chlorodibromomethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Chloroethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 2-Chloroethyl vinyl ether SW8260B J 08/11/14 21:36 / nl 1.0 ug/L 0.66 Chloroform SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Chloromethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,2-Dibromoethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 2-Chlorotoluene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 4-Chlorotoluene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Dibromomethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,2-Dichlorobenzene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,3-Dichlorobenzene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,4-Dichlorobenzene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Dichlorodifluoromethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,1-Dichloroethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,2-Dichloroethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,1-Dichloroethene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND cis-1,2-Dichloroethene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND trans-1,2-Dichloroethene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,2-Dichloropropane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,3-Dichloropropane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 2,2-Dichloropropane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,1-Dichloropropene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND cis-1,3-Dichloropropene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND trans-1,3-Dichloropropene SW8260B J 08/11/14 21:36 / nl 1.0 ug/L 0.15 Ethylbenzene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. J - Estimated value. The analyte was present but less than the reporting limit. Page 4 of 31 LABORATORY ANALYTICAL REPORT Client: MT Dept of Transportation Project: Bozeman Yard Lab ID: B14080821-002 Client Sample ID: BZ/MW2 Collection Date: 08/07/14 14:15 Matrix: Aqueous Report Date: 08/22/14 DateReceived: 08/08/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 08/11/14 21:36 / nl 20 ug/L ND Methyl ethyl ketone SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Methyl tert-butyl ether (MTBE) SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Methylene chloride SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Styrene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,1,1,2-Tetrachloroethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,1,2,2-Tetrachloroethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L 1.1 Tetrachloroethene SW8260B J 08/11/14 21:36 / nl 1.0 ug/L 0.45 Toluene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,1,1-Trichloroethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,1,2-Trichloroethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Trichloroethene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Trichlorofluoromethane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND 1,2,3-Trichloropropane SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Vinyl chloride SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND m+p-Xylenes SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND o-Xylene SW8260B 08/11/14 21:36 / nl 1.0 ug/L ND Xylenes, Total SW8260B 08/11/14 21:36 / nl 77-126 %REC 104 Surr: Dibromofluoromethane SW8260B 08/11/14 21:36 / nl 70-130 %REC 104 Surr: 1,2-Dichloroethane-d4 SW8260B 08/11/14 21:36 / nl 79-122 %REC 106 Surr: Toluene-d8 SW8260B 08/11/14 21:36 / nl 76-127 %REC 110 Surr: p-Bromofluorobenzene SW8260B - The sample was received in the laboratory with a pH > 2. The pH was 8. PETROLEUM HYDROCARBONS-VOLATILE 08/13/14 15:43 / jp 1.0 ug/L ND Methyl tert-butyl ether (MTBE) MA-VPH 30 08/13/14 15:43 / jp 0.50 ug/L ND Benzene MA-VPH 5 08/13/14 15:43 / jp 0.50 ug/L ND Toluene MA-VPH 1000 08/13/14 15:43 / jp 0.50 ug/L ND Ethylbenzene MA-VPH 700 08/13/14 15:43 / jp 0.50 ug/L ND m+p-Xylenes MA-VPH 08/13/14 15:43 / jp 0.50 ug/L ND o-Xylene MA-VPH 08/13/14 15:43 / jp 0.50 ug/L ND Xylenes, Total MA-VPH 10000 08/13/14 15:43 / jp 1.0 ug/L ND Naphthalene MA-VPH 100 08/13/14 15:43 / jp 20 ug/L ND C9 to C10 Aromatics MA-VPH 1000 08/13/14 15:43 / jp 20 ug/L ND C5 to C8 Aliphatics MA-VPH 700 08/13/14 15:43 / jp 20 ug/L ND C9 to C12 Aliphatics MA-VPH 1000 08/13/14 15:43 / jp 20 ug/L ND Total Purgeable Hydrocarbons MA-VPH 1000 08/13/14 15:43 / jp 70-130 %REC 76.0 Surr: VPH Aromatics Surrogate MA-VPH 08/13/14 15:43 / jp 70-130 %REC 74.0 Surr: VPH Aliphatics Surrogate MA-VPH - Note 1: The C5 to C8 Aliphatics value is corrected for aromatic constituents Benzene and Toluene. - Note 2: The C9 to C12 Aliphatics value is corrected for aromatic constituents Ethylbenzene, m+p-Xylenes, o-Xylene and C9 to C10 Aromatics. - The sample was received in the laboratory with a pH > 2. The pH was 7. EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN 08/16/14 00:30 / mdw 300 ug/L 373 Total Extractable Hydrocarbons SW8015M 1000 Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. J - Estimated value. The analyte was present but less than the reporting limit. S - Spike recovery outside of advisory limits. Page 5 of 31 LABORATORY ANALYTICAL REPORT Client: MT Dept of Transportation Project: Bozeman Yard Lab ID: B14080821-002 Client Sample ID: BZ/MW2 Collection Date: 08/07/14 14:15 Matrix: Aqueous Report Date: 08/22/14 DateReceived: 08/08/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN S 08/16/14 00:30 / mdw 40-140 %REC 39.0 Surr: o-Terphenyl SW8015M - Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time. - S=Surrogate recovery outside QC advisory limits. The sample contained a layer of sediment that may have strongly adsorbed the surrogate and/or reduced extraction efficiency. Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. S - Spike recovery outside of advisory limits. Page 6 of 31 LABORATORY ANALYTICAL REPORT Client: MT Dept of Transportation Project: Bozeman Yard Lab ID: B14080821-003 Client Sample ID: TB03052014B-TS SHP0263 Collection Date: 08/07/14 13:00 Matrix: Trip Blank Report Date: 08/22/14 DateReceived: 08/08/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 08/11/14 17:17 / nl 1.0 ug/L ND Benzene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Bromobenzene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Bromochloromethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Bromodichloromethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Bromoform SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Bromomethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Carbon tetrachloride SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Chlorobenzene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Chlorodibromomethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Chloroethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 2-Chloroethyl vinyl ether SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Chloroform SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Chloromethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,2-Dibromoethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 2-Chlorotoluene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 4-Chlorotoluene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Dibromomethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,2-Dichlorobenzene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,3-Dichlorobenzene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,4-Dichlorobenzene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Dichlorodifluoromethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,1-Dichloroethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,2-Dichloroethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,1-Dichloroethene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND cis-1,2-Dichloroethene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND trans-1,2-Dichloroethene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,2-Dichloropropane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,3-Dichloropropane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 2,2-Dichloropropane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,1-Dichloropropene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND cis-1,3-Dichloropropene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND trans-1,3-Dichloropropene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Ethylbenzene SW8260B 08/11/14 17:17 / nl 20 ug/L ND Methyl ethyl ketone SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Methyl tert-butyl ether (MTBE) SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Methylene chloride SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Styrene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,1,1,2-Tetrachloroethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,1,2,2-Tetrachloroethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Tetrachloroethene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Toluene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,1,1-Trichloroethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,1,2-Trichloroethane SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 7 of 31 LABORATORY ANALYTICAL REPORT Client: MT Dept of Transportation Project: Bozeman Yard Lab ID: B14080821-003 Client Sample ID: TB03052014B-TS SHP0263 Collection Date: 08/07/14 13:00 Matrix: Trip Blank Report Date: 08/22/14 DateReceived: 08/08/14 Prepared by Billings, MT Branch Analyses Result Units Analysis Date / By RL Method MCL/ QCL Qualifiers VOLATILE ORGANIC COMPOUNDS 08/11/14 17:17 / nl 1.0 ug/L ND Trichloroethene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Trichlorofluoromethane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND 1,2,3-Trichloropropane SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Vinyl chloride SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND m+p-Xylenes SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND o-Xylene SW8260B 08/11/14 17:17 / nl 1.0 ug/L ND Xylenes, Total SW8260B 08/11/14 17:17 / nl 77-126 %REC 102 Surr: Dibromofluoromethane SW8260B 08/11/14 17:17 / nl 70-130 %REC 95.0 Surr: 1,2-Dichloroethane-d4 SW8260B 08/11/14 17:17 / nl 79-122 %REC 106 Surr: Toluene-d8 SW8260B 08/11/14 17:17 / nl 76-127 %REC 104 Surr: p-Bromofluorobenzene SW8260B Report Definitions: RL - Analyte reporting limit. MCL - Maximum contaminant level. QCL - Quality control limit. ND - Not detected at the reporting limit. Page 8 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW6020 Analytical Run: ICPMS202-B_140821A Lab ID: QCS 08/21/14 10:00 Initial Calibration Verification Standard Silver 100 90 110 0.0010 0.0250 mg/L Lab ID: ICSA 08/21/14 10:10 Interference Check Sample A Silver 0.0010 0.000560 mg/L Lab ID: ICSAB 08/21/14 10:12 Interference Check Sample AB Silver 100 70 130 0.0010 0.0201 mg/L Method: SW6020 Batch: R229328 Lab ID: B14080821-001ADIL 08/21/14 11:06 Serial Dilution Run: ICPMS202-B_140821A Silver 0 0 10 0.0010 ND mg/L Lab ID: B14080821-001AMS 08/21/14 11:09 Sample Matrix Spike Run: ICPMS202-B_140821A Silver 42 75 125 0.0010 0.00842 mg/L S Lab ID: B14080821-001AMSD 08/21/14 11:11 Sample Matrix Spike Duplicate Run: ICPMS202-B_140821A Silver 44 75 125 20 0.0010 3.4 0.00871 mg/L S Lab ID: LFB 08/21/14 10:07 Laboratory Fortified Blank Run: ICPMS202-B_140821A Silver 103 85 115 0.0010 0.0206 mg/L Lab ID: LRB 08/21/14 10:22 Method Blank Run: ICPMS202-B_140821A Silver 3E-05 ND mg/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. S - Spike recovery outside of advisory limits. Page 9 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW6020 Analytical Run: ICPMS203-B_140815A Lab ID: QCS 08/15/14 14:19 Initial Calibration Verification Standard 2 Lead 96 90 110 0.0010 0.0482 mg/L Selenium 91 90 110 0.0010 0.0455 mg/L Lab ID: ICSA 08/15/14 14:36 Interference Check Sample A 2 Lead 0.0010 0.000240 mg/L Selenium 0.0010 0.000513 mg/L Lab ID: ICSAB 08/15/14 14:42 Interference Check Sample AB 2 Lead 0 00.0010 0.000235 mg/L Selenium 92 70 130 0.0010 0.00925 mg/L Method: SW6020 Batch: R229025 Lab ID: LFB 08/15/14 14:31 Laboratory Fortified Blank Run: ICPMS203-B_140815A 2 Lead 98 85 115 0.0010 0.0489 mg/L Selenium 90 85 115 0.0010 0.0452 mg/L Lab ID: LRB 08/15/14 15:16 Method Blank Run: ICPMS203-B_140815A 2 Lead 1.0E-05 ND mg/L Selenium 5E-05 ND mg/L Lab ID: B14080821-001ADIL 08/15/14 20:23 Serial Dilution Run: ICPMS203-B_140815A 2 Lead 0 0 10 0.0010 ND mg/L Selenium 0 0 10 0.0010 ND mg/L Lab ID: B14080821-001AMS 08/15/14 20:28 Sample Matrix Spike Run: ICPMS203-B_140815A 2 Lead 108 75 125 0.0010 0.0538 mg/L Selenium 91 75 125 0.0010 0.0454 mg/L Lab ID: B14080821-001AMSD 08/15/14 20:34 Sample Matrix Spike Duplicate Run: ICPMS203-B_140815A 2 Lead 99 75 125 20 0.0010 8.6 0.0494 mg/L Selenium 98 75 125 20 0.0010 7.6 0.0490 mg/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 10 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW6020 Analytical Run: ICPMS206-B_140811A Lab ID: QCS 08/11/14 18:07 Initial Calibration Verification Standard 4 Arsenic 101 90 110 0.0010 0.0506 mg/L Barium 102 90 110 0.0010 0.0511 mg/L Cadmium 102 90 110 0.0010 0.0256 mg/L Chromium 99 90 110 0.0010 0.0493 mg/L Lab ID: ICSA 08/11/14 18:20 Interference Check Sample A 4 Arsenic 0.0010 0.000402 mg/L Barium 0.0010 0.000199 mg/L Cadmium 0.0010 0.000304 mg/L Chromium 0.0010 0.00103 mg/L Lab ID: ICSAB 08/11/14 18:25 Interference Check Sample AB 4 Arsenic 102 70 130 0.0010 0.0102 mg/L Barium 0 00.0010 0.000143 mg/L Cadmium 98 70 130 0.0010 0.00977 mg/L Chromium 100 70 130 0.0010 0.0200 mg/L Method: SW6020 Batch: R228753 Lab ID: B14080808-001BDIL 08/11/14 22:13 Serial Dilution Run: ICPMS206-B_140811A 4 Arsenic 0 0 10 0.0025 0.00916 mg/L N Barium 0 0 10 0.050 0.0409 mg/L Cadmium 0 0 10 0.0010 ND mg/L Chromium 0 0 10 0.0050 0.00230 mg/L N Lab ID: B14080821-002AMS 08/11/14 23:38 Sample Matrix Spike Run: ICPMS206-B_140811A 4 Arsenic 94 75 125 0.0010 0.0475 mg/L Barium 81 75 125 0.050 0.214 mg/L Cadmium 92 75 125 0.0010 0.0461 mg/L Chromium 90 75 125 0.0050 0.0460 mg/L Lab ID: B14080821-002AMSD 08/11/14 23:43 Sample Matrix Spike Duplicate Run: ICPMS206-B_140811A 4 Arsenic 105 75 125 20 0.0010 11 0.0531 mg/L Barium 98 75 125 20 0.050 3.9 0.223 mg/L Cadmium 97 75 125 20 0.0010 5.4 0.0486 mg/L Chromium 104 75 125 20 0.0050 14 0.0529 mg/L Lab ID: LFB 08/11/14 18:16 Laboratory Fortified Blank Run: ICPMS206-B_140811A 4 Arsenic 95 85 115 0.0010 0.0477 mg/L Barium 98 85 115 0.0010 0.0490 mg/L Cadmium 94 85 115 0.0010 0.0470 mg/L Chromium 94 85 115 0.0010 0.0468 mg/L Lab ID: LRB 08/11/14 18:47 Method Blank Run: ICPMS206-B_140811A 4 Arsenic 0.00010 ND mg/L Barium 4E-05 ND mg/L Cadmium 1E-05 ND mg/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. N - The analyte concentration was not sufficiently high to calculate a RPD for the serial dilution test. Page 11 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW6020 Batch: R228753 Lab ID: LRB 08/11/14 18:47 Method Blank Run: ICPMS206-B_140811A 4 Chromium 2E-05 ND mg/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 12 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Count Prepared by Billings, MT Branch Method: SW7470A Analytical Run: HGCV202-B_140811A Lab ID: QCS 08/11/14 14:40 Initial Calibration Verification Standard Mercury 99 90 110 0.00010 0.00198 mg/L Method: SW7470A Batch: 82079 Lab ID: MB-82079 08/11/14 15:24 Method Blank Run: HGCV202-B_140811A Mercury 1E-05 ND mg/L Lab ID: LCS-82079 08/11/14 15:26 Laboratory Control Sample Run: HGCV202-B_140811A Mercury 98 80 120 0.00010 0.00195 mg/L Lab ID: B14080821-002AMS 08/11/14 15:33 Sample Matrix Spike Run: HGCV202-B_140811A Mercury 98 75 125 0.00010 0.00196 mg/L Lab ID: B14080821-002AMSD 08/11/14 15:35 Sample Matrix Spike Duplicate Run: HGCV202-B_140811A Mercury 99 75 125 20 0.00010 1.0 0.00198 mg/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 13 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: SW8260B Batch: R228680 Lab ID: LCS_081114 08/11/14 11:38 Laboratory Control Sample Run: SV5972.I_140811B Benzene 98 71 133 1.0 4.88 ug/L Bromobenzene 99 78 133 1.0 4.96 ug/L Bromochloromethane 111 68 131 1.0 5.56 ug/L Bromodichloromethane 102 67 138 1.0 5.08 ug/L Bromoform 121 64 136 1.0 6.04 ug/L Bromomethane 106 60 138 1.0 5.28 ug/L Carbon tetrachloride 98 61 144 1.0 4.92 ug/L Chlorobenzene 96 78 136 1.0 4.80 ug/L Chlorodibromomethane 106 72 136 1.0 5.32 ug/L Chloroethane 104 64 136 1.0 5.20 ug/L Chloroform 102 69 133 1.0 5.08 ug/L Chloromethane 119 63 149 1.0 5.96 ug/L 2-Chloroethyl vinyl ether 27 64 132 1.0 1.36 ug/L S 1,2-Dibromoethane 100 75 131 1.0 5.00 ug/L 2-Chlorotoluene 91 74 135 1.0 4.56 ug/L Dibromomethane 108 72 133 1.0 5.40 ug/L 1,2-Dichlorobenzene 96 78 129 1.0 4.80 ug/L 4-Chlorotoluene 91 79 135 1.0 4.56 ug/L 1,3-Dichlorobenzene 98 79 132 1.0 4.88 ug/L 1,4-Dichlorobenzene 100 78 131 1.0 5.00 ug/L Dichlorodifluoromethane 105 55 141 1.0 5.24 ug/L 1,1-Dichloroethane 110 72 130 1.0 5.52 ug/L 1,2-Dichloroethane 82 57 146 1.0 4.12 ug/L 1,1-Dichloroethene 83 66 142 1.0 4.16 ug/L cis-1,2-Dichloroethene 99 74 133 1.0 4.96 ug/L trans-1,2-Dichloroethene 87 76 138 1.0 4.36 ug/L 1,2-Dichloropropane 96 72 135 1.0 4.80 ug/L 1,3-Dichloropropane 98 75 134 1.0 4.88 ug/L 2,2-Dichloropropane 107 42 167 1.0 5.36 ug/L 1,1-Dichloropropene 94 72 140 1.0 4.72 ug/L cis-1,3-Dichloropropene 98 75 132 1.0 4.92 ug/L trans-1,3-Dichloropropene 104 77 145 1.0 5.20 ug/L Ethylbenzene 96 78 131 1.0 4.80 ug/L Methyl tert-butyl ether (MTBE) 73 58 151 1.0 3.66 ug/L Methyl ethyl ketone 110 55 145 20 55.2 ug/L Methylene chloride 80 73 126 1.0 4.00 ug/L Styrene 97 76 134 1.0 4.84 ug/L 1,1,1,2-Tetrachloroethane 99 75 135 1.0 4.96 ug/L 1,1,2,2-Tetrachloroethane 99 72 132 1.0 4.96 ug/L Tetrachloroethene 109 78 137 1.0 5.44 ug/L Toluene 98 78 134 1.0 4.92 ug/L 1,1,1-Trichloroethane 93 64 141 1.0 4.64 ug/L 1,1,2-Trichloroethane 98 72 133 1.0 4.92 ug/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. S - Spike recovery outside of advisory limits. Page 14 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: SW8260B Batch: R228680 Lab ID: LCS_081114 08/11/14 11:38 Laboratory Control Sample Run: SV5972.I_140811B Trichloroethene 95 75 138 1.0 4.76 ug/L Trichlorofluoromethane 98 58 139 1.0 4.88 ug/L 1,2,3-Trichloropropane 86 67 133 1.0 4.28 ug/L Vinyl chloride 111 66 140 1.0 5.56 ug/L m+p-Xylenes 92 78 133 1.0 9.20 ug/L o-Xylene 92 79 136 1.0 4.60 ug/L Surr: 1,2-Dichloroethane-d4 94 70 130 1.0 Surr: Dibromofluoromethane 102 77 126 1.0 Surr: p-Bromofluorobenzene 101 76 127 1.0 Surr: Toluene-d8 107 79 122 1.0 Lab ID: BLK_081114 08/11/14 12:35 Method Blank Run: SV5972.I_140811B Benzene 0.50 ND ug/L Bromobenzene 0.50 ND ug/L Bromochloromethane 0.50 ND ug/L Bromodichloromethane 0.50 ND ug/L Bromoform 0.50 ND ug/L Bromomethane 0.50 ND ug/L Carbon tetrachloride 0.50 ND ug/L Chlorobenzene 0.50 ND ug/L Chlorodibromomethane 0.50 ND ug/L Chloroethane 0.50 ND ug/L Chloroform 0.50 ND ug/L Chloromethane 0.50 ND ug/L 2-Chloroethyl vinyl ether 0.50 ND ug/L 1,2-Dibromoethane 0.50 ND ug/L 2-Chlorotoluene 0.50 ND ug/L Dibromomethane 0.50 ND ug/L 1,2-Dichlorobenzene 0.50 ND ug/L 4-Chlorotoluene 0.50 ND ug/L 1,3-Dichlorobenzene 0.50 ND ug/L 1,4-Dichlorobenzene 0.50 ND ug/L Dichlorodifluoromethane 0.50 ND ug/L 1,1-Dichloroethane 0.50 ND ug/L 1,2-Dichloroethane 0.50 ND ug/L 1,1-Dichloroethene 0.50 ND ug/L cis-1,2-Dichloroethene 0.50 ND ug/L trans-1,2-Dichloroethene 0.50 ND ug/L 1,2-Dichloropropane 0.50 ND ug/L 1,3-Dichloropropane 0.50 ND ug/L 2,2-Dichloropropane 0.50 ND ug/L 1,1-Dichloropropene 0.50 ND ug/L cis-1,3-Dichloropropene 0.50 ND ug/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 15 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: SW8260B Batch: R228680 Lab ID: BLK_081114 08/11/14 12:35 Method Blank Run: SV5972.I_140811B trans-1,3-Dichloropropene 0.50 ND ug/L Ethylbenzene 0.50 ND ug/L Methyl tert-butyl ether (MTBE) 0.50 ND ug/L Methyl ethyl ketone 10 ND ug/L Methylene chloride 0.50 ND ug/L Styrene 0.50 ND ug/L 1,1,1,2-Tetrachloroethane 0.50 ND ug/L 1,1,2,2-Tetrachloroethane 0.50 ND ug/L Tetrachloroethene 0.50 ND ug/L Toluene 0.50 ND ug/L 1,1,1-Trichloroethane 0.50 ND ug/L 1,1,2-Trichloroethane 0.50 ND ug/L Trichloroethene 0.50 ND ug/L Trichlorofluoromethane 0.50 ND ug/L 1,2,3-Trichloropropane 0.50 ND ug/L Vinyl chloride 0.50 ND ug/L m+p-Xylenes 0.50 ND ug/L o-Xylene 0.50 ND ug/L Xylenes, Total 0.50 ND ug/L Surr: 1,2-Dichloroethane-d4 96 70 130 1.0 Surr: Dibromofluoromethane 103 77 126 1.0 Surr: p-Bromofluorobenzene 105 76 127 1.0 Surr: Toluene-d8 106 79 122 1.0 Lab ID: B14080795-003B_MS 08/11/14 17:46 Sample Matrix Spike Run: SV5972.I_140811B Benzene 98 71 133 1.0 4.92 ug/L Bromobenzene 94 78 133 1.0 4.72 ug/L Bromochloromethane 111 68 131 1.0 5.56 ug/L Bromodichloromethane 99 67 138 1.0 4.96 ug/L Bromoform 113 64 136 1.0 5.64 ug/L Bromomethane 84 60 138 1.0 4.20 ug/L Carbon tetrachloride 98 61 144 1.0 4.88 ug/L Chlorobenzene 95 78 136 1.0 4.88 ug/L Chlorodibromomethane 104 72 136 1.0 5.20 ug/L Chloroethane 104 64 136 1.0 5.20 ug/L Chloroform 103 69 133 1.0 5.16 ug/L Chloromethane 132 63 149 1.0 6.60 ug/L 2-Chloroethyl vinyl ether 64 132 1.0 ND ug/L S 1,2-Dibromoethane 98 75 131 1.0 4.88 ug/L 2-Chlorotoluene 89 74 135 1.0 4.44 ug/L Dibromomethane 105 72 133 1.0 5.24 ug/L 1,2-Dichlorobenzene 91 78 129 1.0 4.56 ug/L 4-Chlorotoluene 86 79 135 1.0 4.28 ug/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. S - Spike recovery outside of advisory limits. Page 16 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: SW8260B Batch: R228680 Lab ID: B14080795-003B_MS 08/11/14 17:46 Sample Matrix Spike Run: SV5972.I_140811B 1,3-Dichlorobenzene 93 79 132 1.0 4.64 ug/L 1,4-Dichlorobenzene 96 78 131 1.0 4.80 ug/L Dichlorodifluoromethane 104 55 141 1.0 5.20 ug/L 1,1-Dichloroethane 114 72 130 1.0 5.72 ug/L 1,2-Dichloroethane 82 57 146 1.0 4.12 ug/L 1,1-Dichloroethene 86 66 142 1.0 4.32 ug/L cis-1,2-Dichloroethene 100 74 133 1.0 5.44 ug/L trans-1,2-Dichloroethene 89 76 138 1.0 4.44 ug/L 1,2-Dichloropropane 95 72 135 1.0 4.76 ug/L 1,3-Dichloropropane 98 75 134 1.0 4.88 ug/L 2,2-Dichloropropane 100 42 167 1.0 5.00 ug/L 1,1-Dichloropropene 94 72 140 1.0 4.72 ug/L cis-1,3-Dichloropropene 94 75 132 1.0 4.72 ug/L trans-1,3-Dichloropropene 103 77 145 1.0 5.16 ug/L Ethylbenzene 94 78 131 1.0 4.72 ug/L Methyl tert-butyl ether (MTBE) 82 58 151 1.0 4.12 ug/L Methyl ethyl ketone 104 55 145 20 52.0 ug/L Methylene chloride 82 73 126 1.0 4.12 ug/L Styrene 96 76 134 1.0 4.80 ug/L 1,1,1,2-Tetrachloroethane 98 75 135 1.0 4.88 ug/L 1,1,2,2-Tetrachloroethane 98 72 132 1.0 4.92 ug/L Tetrachloroethene 111 78 137 1.0 8.56 ug/L Toluene 96 78 134 1.0 4.80 ug/L 1,1,1-Trichloroethane 94 64 141 1.0 4.68 ug/L 1,1,2-Trichloroethane 99 72 133 1.0 4.96 ug/L Trichloroethene 93 75 138 1.0 5.24 ug/L Trichlorofluoromethane 94 58 139 1.0 4.72 ug/L 1,2,3-Trichloropropane 89 67 133 1.0 4.44 ug/L Vinyl chloride 110 66 140 1.0 5.48 ug/L m+p-Xylenes 91 78 133 1.0 9.12 ug/L o-Xylene 90 79 136 1.0 4.52 ug/L Surr: 1,2-Dichloroethane-d4 96 70 130 1.0 Surr: Dibromofluoromethane 102 77 126 1.0 Surr: p-Bromofluorobenzene 97 76 127 1.0 Surr: Toluene-d8 105 79 122 1.0 - 2-Chloroethyl vinyl ether is not recovered from acid-preserved samples. Lab ID: B14080795-003B_MSD 08/11/14 18:14 Sample Matrix Spike Duplicate Run: SV5972.I_140811B Benzene 101 71 133 20 1.0 2.4 5.04 ug/L Bromobenzene 102 78 133 20 1.0 7.3 5.08 ug/L Bromochloromethane 112 68 131 20 1.0 0.7 5.60 ug/L Bromodichloromethane 102 67 138 20 1.0 3.2 5.12 ug/L Bromoform 118 64 136 20 1.0 4.8 5.92 ug/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 17 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: SW8260B Batch: R228680 Lab ID: B14080795-003B_MSD 08/11/14 18:14 Sample Matrix Spike Duplicate Run: SV5972.I_140811B Bromomethane 98 60 138 20 1.0 15 4.88 ug/L Carbon tetrachloride 99 61 144 20 1.0 1.6 4.96 ug/L Chlorobenzene 96 78 136 20 1.0 1.6 4.96 ug/L Chlorodibromomethane 108 72 136 20 1.0 3.8 5.40 ug/L Chloroethane 101 64 136 20 1.0 3.1 5.04 ug/L Chloroform 106 69 133 20 1.0 2.3 5.28 ug/L Chloromethane 128 63 149 20 1.0 3.1 6.40 ug/L 2-Chloroethyl vinyl ether 64 132 20 1.0 ND ug/L S 1,2-Dibromoethane 102 75 131 20 1.0 4.8 5.12 ug/L 2-Chlorotoluene 92 74 135 20 1.0 3.5 4.60 ug/L Dibromomethane 106 72 133 20 1.0 1.5 5.32 ug/L 1,2-Dichlorobenzene 97 78 129 20 1.0 6.0 4.84 ug/L 4-Chlorotoluene 91 79 135 20 1.0 6.3 4.56 ug/L 1,3-Dichlorobenzene 98 79 132 20 1.0 5.0 4.88 ug/L 1,4-Dichlorobenzene 99 78 131 20 1.0 3.3 4.96 ug/L Dichlorodifluoromethane 98 55 141 20 1.0 6.3 4.88 ug/L 1,1-Dichloroethane 116 72 130 20 1.0 1.4 5.80 ug/L 1,2-Dichloroethane 84 57 146 20 1.0 1.9 4.20 ug/L 1,1-Dichloroethene 86 66 142 20 1.0 0.0 4.32 ug/L cis-1,2-Dichloroethene 102 74 133 20 1.0 1.5 5.52 ug/L trans-1,2-Dichloroethene 91 76 138 20 1.0 2.7 4.56 ug/L 1,2-Dichloropropane 100 72 135 20 1.0 4.9 5.00 ug/L 1,3-Dichloropropane 102 75 134 20 1.0 4.0 5.08 ug/L 2,2-Dichloropropane 101 42 167 20 1.0 0.8 5.04 ug/L 1,1-Dichloropropene 97 72 140 20 1.0 2.5 4.84 ug/L cis-1,3-Dichloropropene 98 75 132 20 1.0 4.1 4.92 ug/L trans-1,3-Dichloropropene 107 77 145 20 1.0 3.8 5.36 ug/L Ethylbenzene 98 78 131 20 1.0 3.3 4.88 ug/L Methyl tert-butyl ether (MTBE) 84 58 151 20 1.0 1.9 4.20 ug/L Methyl ethyl ketone 104 55 145 20 20 0.0 52.0 ug/L Methylene chloride 83 73 126 20 1.0 1.0 4.16 ug/L Styrene 100 76 134 20 1.0 4.1 5.00 ug/L 1,1,1,2-Tetrachloroethane 102 75 135 20 1.0 4.8 5.12 ug/L 1,1,2,2-Tetrachloroethane 105 72 132 20 1.0 6.3 5.24 ug/L Tetrachloroethene 111 78 137 20 1.0 0.0 8.56 ug/L Toluene 100 78 134 20 1.0 4.1 5.00 ug/L 1,1,1-Trichloroethane 96 64 141 20 1.0 2.5 4.80 ug/L 1,1,2-Trichloroethane 102 72 133 20 1.0 2.4 5.08 ug/L Trichloroethene 96 75 138 20 1.0 3.0 5.40 ug/L Trichlorofluoromethane 90 58 139 20 1.0 4.3 4.52 ug/L 1,2,3-Trichloropropane 94 67 133 20 1.0 5.3 4.68 ug/L Vinyl chloride 108 66 140 20 1.0 1.5 5.40 ug/L m+p-Xylenes 94 78 133 20 1.0 2.6 9.36 ug/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. S - Spike recovery outside of advisory limits. Page 18 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: SW8260B Batch: R228680 Lab ID: B14080795-003B_MSD 08/11/14 18:14 Sample Matrix Spike Duplicate Run: SV5972.I_140811B o-Xylene 94 79 136 20 1.0 3.5 4.68 ug/L Surr: 1,2-Dichloroethane-d4 94 70 130 1.0 Surr: Dibromofluoromethane 100 77 126 1.0 Surr: p-Bromofluorobenzene 100 76 127 1.0 Surr: Toluene-d8 107 79 122 1.0 - 2-Chloroethyl vinyl ether is not recovered from acid-preserved samples. Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 19 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: MA-VPH Analytical Run: R228888 Lab ID: CCV_0812PE117r-W 08/13/14 09:22 Continuing Calibration Verification Standard 1,2,4-Trimethylbenzene 99 75 125 1.0 24.8 ug/L 2,2,4-Trimethylpentane 97 75 125 1.0 24.2 ug/L 2-Methylpentane 98 75 125 1.0 24.4 ug/L n-Butylcyclohexane 93 75 125 1.0 23.2 ug/L n-Decane 94 75 125 1.0 23.5 ug/L Methyl tert-butyl ether (MTBE) 96 75 125 1.0 23.9 ug/L Benzene 99 75 125 0.50 24.8 ug/L Toluene 100 75 125 0.50 24.9 ug/L Ethylbenzene 97 75 125 0.50 24.3 ug/L m+p-Xylenes 101 75 125 0.50 50.6 ug/L o-Xylene 99 75 125 0.50 24.8 ug/L Naphthalene 99 75 125 1.0 24.9 ug/L n-Pentane 96 75 125 1.0 24.1 ug/L Surr: VPH Aromatics Surrogate 94 75 125 1.0 Surr: VPH Aliphatics Surrogate 93 75 125 1.0 Method: MA-VPH Batch: R228888 Lab ID: LCS_0812PE118r 08/13/14 09:57 Laboratory Control Sample Run: PE 1_140814A 1,2,4-Trimethylbenzene 98 70 130 1.0 24.6 ug/L 2,2,4-Trimethylpentane 100 70 130 1.0 24.9 ug/L 2-Methylpentane 90 70 130 1.0 22.4 ug/L n-Butylcyclohexane 90 70 130 1.0 22.4 ug/L n-Decane 84 70 130 1.0 21.0 ug/L Methyl tert-butyl ether (MTBE) 92 70 130 1.0 22.9 ug/L Benzene 96 70 130 0.50 24.1 ug/L Toluene 96 70 130 0.50 24.0 ug/L Ethylbenzene 95 70 130 0.50 23.7 ug/L m+p-Xylenes 100 70 130 0.50 50.0 ug/L o-Xylene 98 70 130 0.50 24.5 ug/L Naphthalene 99 70 130 1.0 24.8 ug/L Total Purgeable Hydrocarbons 88 70 130 20 330 ug/L n-Pentane 85 70 130 1.0 21.4 ug/L Surr: VPH Aromatics Surrogate 95 70 130 1.0 Surr: VPH Aliphatics Surrogate 96 70 130 1.0 Lab ID: MBLK_0812PE121r 08/13/14 11:41 Method Blank Run: PE 1_140814A Methyl tert-butyl ether (MTBE) 1.0 ND ug/L Benzene 0.50 ND ug/L Toluene 0.50 ND ug/L Ethylbenzene 0.50 ND ug/L m+p-Xylenes 0.50 ND ug/L o-Xylene 0.50 ND ug/L Xylenes, Total 0.50 ND ug/L Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 20 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: MA-VPH Batch: R228888 Lab ID: MBLK_0812PE121r 08/13/14 11:41 Method Blank Run: PE 1_140814A Naphthalene 1.0 ND ug/L C9 to C10 Aromatics 20 ND ug/L C5 to C8 Aliphatics 20 ND ug/L C9 to C12 Aliphatics 20 ND ug/L Total Purgeable Hydrocarbons 20 ND ug/L Surr: VPH Aromatics Surrogate 92 70 130 1.0 Surr: VPH Aliphatics Surrogate 96 70 130 1.0 Lab ID: B14080885-001BMS 08/13/14 12:15 Sample Matrix Spike Run: PE 1_140814A Methyl tert-butyl ether (MTBE) 93 70 130 2.0 46.7 ug/L Benzene 98 70 130 1.0 49.2 ug/L Toluene 98 70 130 1.0 49.0 ug/L Ethylbenzene 97 70 130 1.0 48.7 ug/L m+p-Xylenes 103 70 130 1.0 103 ug/L o-Xylene 101 70 130 1.0 50.4 ug/L Naphthalene 101 70 130 2.0 50.4 ug/L Total Purgeable Hydrocarbons 91 70 130 40 681 ug/L Surr: VPH Aromatics Surrogate 97 70 130 2.0 Surr: VPH Aliphatics Surrogate 95 70 130 2.0 Lab ID: B14080885-001BMSD 08/13/14 12:50 Sample Matrix Spike Duplicate Run: PE 1_140814A Methyl tert-butyl ether (MTBE) 93 70 130 20 2.0 0.1 46.7 ug/L Benzene 99 70 130 20 1.0 0.6 49.5 ug/L Toluene 100 70 130 20 1.0 1.9 49.9 ug/L Ethylbenzene 98 70 130 20 1.0 0.6 49.0 ug/L m+p-Xylenes 104 70 130 20 1.0 0.7 104 ug/L o-Xylene 101 70 130 20 1.0 0.6 50.7 ug/L Naphthalene 103 70 130 20 2.0 1.8 51.3 ug/L Total Purgeable Hydrocarbons 93 70 130 20 40 2.3 696 ug/L Surr: VPH Aromatics Surrogate 92 70 130 2.0 Surr: VPH Aliphatics Surrogate 94 70 130 2.0 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 21 of 31 BZ/MW1 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14080821-001C ;0812PE1 , $HC-VPH-MA-W, Raw File: G:\Org\PE1\DAT\PE1081214_b\0812PE1.0026.RAW Date & Time Acquired: 8/13/2014 2:34:37 PM Method File: G:\Org\PE1\Methods\140811V821-1%.MET Calibration File: G:\Org\PE1\Cals\140811VPH.CAL Sample Weight: 5 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 296.1283 Rt range for C9 to C10 Aromatics: 15.534 to 20.696 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:2896.094 C9-C10 Aromatics Amount: 1.955972 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . 1. U Benzene__________________7.602 7.602 7.602 269 .5 U Toluene__________________10.541 10.541 10.541 525 .5 U Ethylbenzene_____________14.222 14.222 14.222 206 .5 U m+p-Xylenes______________14.431 14.431 14.431 391 .5 U o-Xylene_________________15.435 15.435 15.435 226 .5 U 124-Trimethylbenzene_____17.595 17.595 17.595 377 .5 U Naphthalene______________20.745 20.745 20.745 416 1. U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______8.518 25. 21.182 84.73 70-130 2 . 3 1 4 . 0 1 4 . 7 1 5 . 3 5 5 . 8 7 5 . 9 9 7 . 6 0 8 . 5 2 1 0 . 5 4 1 1 . 5 7 1 3 . 2 9 1 4 . 2 2 1 4 . 4 3 1 5 . 4 3 1 5 . 7 9 1 6 . 6 5 1 6 . 9 6 1 7 . 2 2 1 7 . 4 8 1 7 . 6 0 1 7 . 8 2 1 8 . 3 2 1 8 . 5 7 1 9 . 0 3 1 9 . 2 6 1 9 . 4 0 2 0 . 1 3 2 0 . 4 9 2 0 . 7 4 2 1 . 6 4 2 1 . 9 0 2 3 . 1 8 2 3 . 4 3 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\PE1\DAT\PE1081214_b\0812PE1.0026.RAW B14080821-001C ;0812PE1 , $HC-VPH-MA-W, 2 4 6 8 10 12 14 16 18 20 22 24 -2 0 2 4 6 8 10 12 14 16 18 20 Page 22 of 31 BZ/MW1 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14080821-001C ;0812PE1 , $HC-VPH-MA-W, Raw File: G:\Org\PE1\DAT\PE1081214_b\0812PE1B.0026.RAW Date & Time Acquired: 8/13/2014 2:34:37 PM Method File: G:\Org\PE1\Methods\140811V821-1B%.MET Calibration File: G:\Org\PE1\Cals\140811VPHB.CAL Sample Weight: 5 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 438.727 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 395.9216 Mean RF for all calibrated compounds: 561.5421 Rt range for Gasoline Range Organics: 4.380837 to 16.76117 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.384128 to 13.59579 Rt range for C9 to C12 Aliphatic Hydrocarbons: 13.64579 to 20.69946 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________8.52 25. 22.902 91.61 - GRO Area:11151.95 GRO Amount: 3.9719 TPH Area:30750.53 TPH Amount: 10.95217 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:10485.21 C5-C8 Amount: 4.779834 C9-C12 Area:13855.72 C9-C12 Amount: 6.999224 3 . 2 0 3 . 4 8 3 . 8 4 4 . 0 1 4 . 2 4 4 . 4 8 4 . 7 3 5 . 0 9 5 . 3 8 5 . 5 2 5 . 8 8 5 . 9 9 6 . 7 4 7 . 0 7 7 . 3 3 7 . 6 1 8 . 2 4 8 . 5 2 9 . 6 2 1 0 . 5 4 1 1 . 5 7 1 3 . 7 2 1 4 . 2 2 1 4 . 4 4 1 4 . 8 8 1 5 . 0 9 1 5 . 4 4 1 5 . 7 5 1 6 . 0 6 1 6 . 6 6 1 6 . 9 6 1 7 . 2 2 1 7 . 4 8 1 7 . 5 9 1 7 . 7 6 1 7 . 8 3 1 8 . 2 3 1 8 . 3 3 1 8 . 4 6 1 8 . 5 8 1 8 . 8 6 1 9 . 0 3 1 9 . 2 4 1 9 . 3 9 1 9 . 5 5 1 9 . 7 9 1 9 . 9 1 1 9 . 9 9 2 0 . 1 4 2 0 . 3 2 2 0 . 4 5 2 0 . 5 0 2 0 . 6 2 2 0 . 7 7 2 0 . 8 7 2 0 . 9 9 2 1 . 3 2 2 1 . 6 2 2 1 . 7 9 2 1 . 9 1 2 2 . 1 2 2 2 . 2 1 2 3 . 4 2 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\PE1\DAT\PE1081214_b\0812PE1B.0026.RAW B14080821-001C ;0812PE1 , $HC-VPH-MA-W, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 23 of 31 BZ/MW2 VPH AROMATICS PHOTOIONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14080821-002C ;0812PE1 , $HC-VPH-MA-W, Raw File: G:\Org\PE1\DAT\PE1081214_b\0812PE1.0028.RAW Date & Time Acquired: 8/13/2014 3:43:52 PM Method File: G:\Org\PE1\Methods\140811V821-2%.MET Calibration File: G:\Org\PE1\Cals\140811VPH.CAL Sample Weight: 5 Dilution: 1 S.A.: 1 Mean RF for C9 to C10 Aromatic Hydrocarbons: 296.1283 Rt range for C9 to C10 Aromatics: 15.534 to 20.696 Aromatic Hydrocarbon Range Area and Quantitation: C9-C10 Aromatics Area:2521.421 C9-C10 Aromatics Amount: 1.702925 TARGET ANALYTES RT CAL RRT RRT AREA AMOUNT FLAG MTBE_____________________. . . 1. U Benzene__________________7.602 7.602 7.602 100 .5 U Toluene__________________10.541 10.541 10.541 328 .5 U Ethylbenzene_____________14.239 14.239 14.239 215 .5 U m+p-Xylenes______________14.434 14.434 14.434 344 .5 U o-Xylene_________________15.431 15.431 15.431 96 .5 U 124-Trimethylbenzene_____17.609 17.609 17.609 160 .5 U Naphthalene______________20.74 20.74 20.74 593 1. U SURROGATE COMPOUND RT ACTUAL MEASURED %REC QC LIMITS **TRIFLUOROTOLUENE_______8.518 25. 19.007 76.03 70-130 3 . 1 7 4 . 0 1 4 . 7 0 5 . 9 8 7 . 6 0 8 . 5 2 1 0 . 2 9 1 0 . 5 4 1 1 . 8 7 1 4 . 2 4 1 4 . 4 3 1 5 . 4 3 1 5 . 7 8 1 6 . 9 6 1 7 . 0 5 1 7 . 6 1 1 7 . 8 4 1 8 . 3 5 2 0 . 1 5 2 0 . 3 4 2 0 . 5 1 2 0 . 7 4 2 0 . 9 2 2 1 . 6 1 2 1 . 9 4 2 2 . 0 7 2 2 . 2 8 2 2 . 9 0 2 3 . 1 0 2 3 . 3 9 M T B E B e n z e n e * * T R I F L U O R O T O L U E N E T o l u e n e E t h y l b e n z e n e m + p - X y l e n e s o - X y l e n e 1 2 4 - T r i m e t h y l b e n z e n e N a p h t h a l e n e G:\Org\PE1\DAT\PE1081214_b\0812PE1.0028.RAW B14080821-002C ;0812PE1 , $HC-VPH-MA-W, 2 4 6 8 10 12 14 16 18 20 22 24 -2 0 2 4 6 8 10 12 14 16 18 20 Page 24 of 31 BZ/MW2 VPH ALIPHATICS FLAME IONIZATION DETECTOR CHROMATOGRAM REPORT Sample Name: B14080821-002C ;0812PE1 , $HC-VPH-MA-W, Raw File: G:\Org\PE1\DAT\PE1081214_b\0812PE1B.0028.RAW Date & Time Acquired: 8/13/2014 3:43:52 PM Method File: G:\Org\PE1\Methods\140811V821-2B%.MET Calibration File: G:\Org\PE1\Cals\140811VPHB.CAL Sample Weight: 5 Dilution: 1 S.A.: 1 Mean RF for C5 to C8 Aliphatic Hydrocarbons: 438.727 Mean RF for C9 to C12 Aliphatic Hydrocarbons: 395.9216 Mean RF for all calibrated compounds: 561.5421 Rt range for Gasoline Range Organics: 4.380837 to 16.76117 Rt range for C5 to C8 Aliphatic Hydrocarbons: 3.384128 to 13.59579 Rt range for C9 to C12 Aliphatic Hydrocarbons: 13.64579 to 20.69946 SURROGATE COMPOUND RT ACTUAL MEASURED %REC **TFT_______________8.521 25. 18.604 74.41 - GRO Area:6204.969 GRO Amount: 2.209975 TPH Area:11620.68 TPH Amount: 4.138847 Aliphatic Hydrocarbon Areas and Quantitations uncorrected for Aromatics: C5-C8 Area:6284.688 C5-C8 Amount: 2.864965 C9-C12 Area:3667.184 C9-C12 Amount: 1.85248 3 . 2 1 3 . 4 9 4 . 0 1 4 . 2 2 4 . 4 9 4 . 7 4 5 . 0 7 6 . 0 6 6 . 4 8 6 . 7 3 7 . 0 7 7 . 6 1 8 . 5 2 1 0 . 5 4 1 1 . 8 8 1 2 . 1 7 1 4 . 2 4 1 4 . 4 4 1 5 . 4 4 1 6 . 6 6 1 6 . 9 7 1 7 . 2 6 1 7 . 4 3 1 7 . 6 1 1 7 . 8 3 1 8 . 2 3 1 8 . 3 4 1 8 . 5 4 1 9 . 0 1 1 9 . 2 6 2 0 . 1 4 2 0 . 4 3 2 0 . 7 4 2 1 . 6 3 2 1 . 9 4 2 2 . 0 7 2 3 . 3 9 n - P e n t a n e 2 - M e t h y l p e n t a n e # M T B E 2 2 4 - T r i m e t h y l p e n t a n e # B e n z e n e * * T F T # T o l u e n e n - N o n a n e # E t h y l b e n z e n e # m + p - X y l e n e s # o - X y l e n e n - D e c a n e # 1 2 4 - T r i m e t h y l b e n z e n n - B u t y l c y c l o h e x a n e # N a p h t h a l e n e G:\Org\PE1\DAT\PE1081214_b\0812PE1B.0028.RAW B14080821-002C ;0812PE1 , $HC-VPH-MA-W, 0 2 4 6 8 10 12 14 16 18 20 22 24 0 5 10 15 20 25 30 35 40 45 Page 25 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: SW8015M Batch: 82093 Lab ID: LCS-82093 08/13/14 07:01 Laboratory Control Sample Run: GCFID-HP2-B_140811F Total Extractable Hydrocarbons 99 60 140 300 6160 ug/L Surr: o-Terphenyl 103 40 140 Lab ID: MB-82093 08/13/14 07:45 Method Blank Run: GCFID-HP2-B_140811F Total Extractable Hydrocarbons 300 ND ug/L Surr: o-Terphenyl 96 40 140 Lab ID: B14080780-001AMS 08/13/14 09:14 Sample Matrix Spike Run: GCFID-HP2-B_140811F Total Extractable Hydrocarbons 103 60 140 580 12400 ug/L Surr: o-Terphenyl 105 40 140 Lab ID: B14080780-001AMSD 08/13/14 09:57 Sample Matrix Spike Duplicate Run: GCFID-HP2-B_140811F Total Extractable Hydrocarbons 93 60 140 20 580 10 11200 ug/L Surr: o-Terphenyl 94 40 140 Method: SW8015M Analytical Run: R228921 Lab ID: CCV_0811HP280r-W 08/14/14 00:49 Continuing Calibration Verification Standard n-Nonane 98 75 125 196 ug/L n-Decane 102 75 125 204 ug/L n-Dodecane 101 75 125 202 ug/L n-Tetradecane 108 75 125 217 ug/L n-Hexadecane 104 75 125 208 ug/L n-Octadecane 103 75 125 207 ug/L n-Nonadecane 103 75 125 205 ug/L n-Eicosane 104 75 125 208 ug/L n-Docosane 103 75 125 206 ug/L n-Tetracosane 105 75 125 210 ug/L n-Hexacosane 105 75 125 209 ug/L n-Octacosane 105 75 125 210 ug/L n-Triacontane 106 75 125 211 ug/L n-Hexatriacontane 106 75 125 211 ug/L Surr: o-Terphenyl 102 75 125 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 26 of 31 Project: Bozeman Yard Client: MT Dept of Transportation Work Order: B14080821 QA/QC Summary Report 08/22/14 Report Date: Analyte Result %REC RPD Low Limit High Limit RPDLimit RL Units Qual Prepared by Billings, MT Branch Method: SW8015M Analytical Run: R229040 Lab ID: CCV_0814HP235r-W 08/15/14 17:01 Continuing Calibration Verification Standard n-Nonane 98 75 125 196 ug/L n-Decane 102 75 125 204 ug/L n-Dodecane 100 75 125 200 ug/L n-Tetradecane 102 75 125 205 ug/L n-Hexadecane 102 75 125 205 ug/L n-Octadecane 101 75 125 202 ug/L n-Nonadecane 100 75 125 200 ug/L n-Eicosane 101 75 125 202 ug/L n-Docosane 101 75 125 202 ug/L n-Tetracosane 102 75 125 205 ug/L n-Hexacosane 102 75 125 204 ug/L n-Octacosane 103 75 125 205 ug/L n-Triacontane 103 75 125 206 ug/L n-Hexatriacontane 103 75 125 206 ug/L Surr: o-Terphenyl 100 75 125 Qualifiers: RL - Analyte reporting limit. ND - Not detected at the reporting limit. Page 27 of 31 BZ/MW1 Batch ID: 82093 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14080821-001B ;0811HP2 , $HC-EPH-SCRN-W, V84 Raw File: G:\org\HP2\DAT\HP2081114_b\0811HP2.0084.RAW Date & Time Acquired: 8/14/2014 3:53:26 AM Method File: g:\org\HP2\Methods\S3_SCN-VH-L%.met Calibration File: G:\Org\HP2\Cals\SC110829VH.CAL Sample Weight: 1.01 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 27187.9 Mean RF for C19 to C36 Hydrocarbons: 27480.28 Mean RF for Total Extractable Hydrocarbons: 27334.08 Rt range for Diesel Range Organics: 6.137 to 16.297 Rt range for C9 to C18 Hydrocarbons: 5.13 to 11.9 Rt range for C19 to C36 Hydrocarbons: 11.935 to 18.375 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________11.98 198.02 131.551 66.43 - *1-Chloro-octadecane_____12.813 198.02 114.927 58.04 - DRO Area:7410429 DRO Amount: 536.8432 TEH Area:1.188025E+07 TEH Amount: 860.6559 C9-C18 Area:5270585 C9-C18 Amount: 383.8767 C19-C36 Area:3199089 C19-C36 Amount: 230.5228 3 . 4 3 3 . 9 7 4 . 7 9 4 . 8 3 4 . 8 7 4 . 9 6 6 . 7 4 6 . 8 4 7 . 4 6 7 . 5 8 7 . 9 9 8 . 0 4 8 . 0 8 8 . 1 4 8 . 2 0 8 . 2 9 8 . 9 4 9 . 0 8 9 . 3 1 9 . 6 0 9 . 6 5 9 . 7 3 9 . 8 2 9 . 9 2 1 0 . 1 6 1 0 . 3 0 1 0 . 3 9 1 0 . 4 5 1 0 . 6 4 1 0 . 6 8 1 0 . 8 0 1 0 . 9 3 1 1 . 0 3 1 1 . 0 9 1 1 . 1 9 1 1 . 2 8 1 1 . 4 7 1 1 . 6 2 1 1 . 6 6 1 1 . 7 1 1 1 . 8 3 1 1 . 8 8 1 1 . 9 8 1 2 . 2 8 1 2 . 4 0 1 2 . 7 3 1 2 . 8 1 1 3 . 1 8 1 3 . 7 2 1 4 . 1 2 1 4 . 4 0 1 4 . 5 1 1 4 . 7 3 1 4 . 8 9 1 5 . 2 5 1 5 . 4 6 1 5 . 6 0 1 5 . 7 3 1 5 . 9 4 1 6 . 0 7 1 6 . 1 7 1 6 . 2 6 1 6 . 4 5 1 6 . 5 9 1 6 . 8 9 1 7 . 0 6 1 7 . 2 1 1 7 . 3 0 1 7 . 3 7 1 7 . 5 0 1 7 . 8 6 1 8 . 0 9 1 8 . 3 0 1 8 . 4 8 1 8 . 6 9 1 8 . 9 0 1 8 . 9 5 1 9 . 0 7 1 9 . 1 9 1 9 . 3 3 1 9 . 5 9 1 9 . 6 9 1 9 . 9 6 2 0 . 0 2 2 0 . 1 7 2 0 . 3 2 2 0 . 3 9 2 0 . 5 8 2 0 . 6 3 2 0 . 7 7 2 0 . 8 2 2 1 . 0 1 2 1 . 0 8 2 1 . 1 3 2 1 . 2 6 2 1 . 3 5 2 1 . 5 1 2 1 . 5 9 2 1 . 6 6 2 1 . 7 3 2 1 . 7 6 2 1 . 9 2 2 2 . 1 5 2 2 . 2 7 2 2 . 4 7 2 2 . 7 1 2 2 . 7 7 2 2 . 8 0 2 2 . 9 3 2 3 . 1 3 2 3 . 2 1 2 3 . 2 7 2 3 . 3 5 2 3 . 4 1 2 3 . 4 8 2 3 . 5 2 2 3 . 6 0 2 3 . 6 7 2 4 . 7 9 2 4 . 8 6 2 4 . 9 6 2 5 . 0 2 2 5 . 2 1 2 5 . 2 6 2 5 . 3 3 2 5 . 4 0 2 5 . 5 2 2 5 . 6 0 2 5 . 6 8 2 5 . 8 4 2 5 . 9 0 2 6 . 0 1 2 6 . 1 6 2 6 . 2 2 2 6 . 3 0 2 6 . 3 4 2 6 . 4 3 2 6 . 4 8 2 6 . 5 6 2 6 . 6 2 2 6 . 8 0 2 6 . 8 6 2 6 . 9 3 2 7 . 0 0 2 7 . 0 5 2 7 . 1 8 2 7 . 2 9 2 7 . 5 1 2 7 . 7 5 2 7 . 8 5 2 7 . 8 9 2 7 . 9 3 2 8 . 0 2 2 8 . 0 6 2 8 . 2 3 2 8 . 3 6 2 8 . 4 5 2 8 . 5 6 2 8 . 6 7 2 8 . 7 2 2 8 . 7 6 2 8 . 8 7 2 9 . 0 6 2 9 . 1 8 2 9 . 2 3 2 9 . 2 7 2 9 . 4 4 2 9 . 4 8 2 9 . 6 0 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP2\DAT\HP2081114_b\0811HP2.0084.RAW B14080821-001B ;0811HP2 , $HC-EPH-SCRN-W, V84 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 28 of 31 BZ/MW2 Batch ID: 82093 EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM Sample Name: B14080821-002B ;0814HP2 , $HC-EPH-SCRN-W, RR-V45 Raw File: G:\org\HP2\DAT\HP2081414_b\0814HP2.0045.RAW Date & Time Acquired: 8/16/2014 12:30:52 AM Method File: g:\org\HP2\Methods\S3_SCN-081445-VJ-L%.met Calibration File: G:\Org\HP2\Cals\SC110829VJ.CAL Sample Weight: 1.02 Dilution: 2 S.A.: 1 Mean RF for C9 to C18 Hydrocarbons: 27187.9 Mean RF for C19 to C36 Hydrocarbons: 27480.28 Mean RF for Total Extractable Hydrocarbons: 27334.08 Rt range for Diesel Range Organics: 6.249 to 16.372 Rt range for C9 to C18 Hydrocarbons: 5.272 to 11.993 Rt range for C19 to C36 Hydrocarbons: 12.028 to 18.498 SURROGATE COMPOUND RT ACTUAL MEASURED %REC *o-Terphenyl_____________12.072 196.078 76.324 38.93 - *1-Chloro-octadecane_____12.887 196.078 70.567 35.99 - DRO Area:3979227 DRO Amount: 285.446 TEH Area:5194955 TEH Amount: 372.6551 C9-C18 Area:3886165 C9-C18 Amount: 280.2692 C19-C36 Area:945070.1 C19-C36 Amount: 67.43304 3 . 7 4 3 . 9 7 4 . 0 1 4 . 1 7 4 . 2 9 4 . 4 2 4 . 4 9 4 . 5 5 4 . 5 8 4 . 6 2 4 . 6 8 4 . 7 4 4 . 8 3 4 . 8 8 4 . 9 6 5 . 0 1 5 . 0 6 5 . 1 0 5 . 2 0 5 . 4 5 5 . 5 3 5 . 5 5 5 . 6 1 6 . 3 6 6 . 5 1 6 . 5 7 6 . 6 9 6 . 9 7 7 . 3 8 7 . 5 7 7 . 6 9 8 . 1 9 8 . 3 9 8 . 7 8 9 . 4 4 9 . 7 5 9 . 8 5 9 . 9 9 1 0 . 1 1 1 0 . 3 1 1 0 . 5 0 1 0 . 5 7 1 0 . 7 9 1 1 . 0 2 1 1 . 4 0 1 1 . 5 3 1 1 . 6 4 1 1 . 8 7 1 1 . 9 2 1 1 . 9 6 1 2 . 0 1 1 2 . 0 7 1 2 . 4 0 1 2 . 4 8 1 2 . 8 1 1 2 . 8 9 1 3 . 2 1 1 3 . 2 8 1 3 . 3 6 1 3 . 7 0 1 3 . 8 0 1 3 . 9 5 1 4 . 2 1 1 4 . 4 3 1 4 . 5 9 1 4 . 8 1 1 4 . 9 0 1 4 . 9 6 1 5 . 3 3 1 5 . 4 1 1 5 . 5 1 1 5 . 5 4 1 5 . 5 8 1 5 . 6 6 1 5 . 7 9 1 5 . 8 7 1 5 . 9 4 1 6 . 0 0 1 6 . 0 7 1 6 . 1 2 1 6 . 1 6 1 6 . 1 9 1 6 . 2 6 1 6 . 3 2 1 6 . 4 6 1 6 . 5 1 1 6 . 5 9 1 6 . 6 5 1 6 . 7 1 1 6 . 7 6 1 6 . 8 1 1 6 . 8 7 1 6 . 9 6 1 6 . 9 9 1 7 . 0 8 1 7 . 1 2 1 7 . 1 9 1 7 . 2 5 1 7 . 3 0 1 7 . 3 2 1 7 . 4 4 1 7 . 5 8 1 7 . 8 9 1 7 . 9 4 1 8 . 1 9 1 8 . 2 5 1 8 . 3 6 1 8 . 3 9 1 8 . 4 9 1 8 . 5 5 1 8 . 6 3 1 8 . 6 7 1 8 . 8 4 1 9 . 0 1 1 9 . 1 2 1 9 . 2 2 1 9 . 4 4 1 9 . 5 1 2 0 . 0 3 2 0 . 0 8 2 0 . 2 2 2 0 . 2 9 2 0 . 4 0 2 0 . 6 2 2 0 . 9 0 2 0 . 9 6 2 1 . 0 3 2 1 . 1 1 2 1 . 2 9 2 1 . 4 2 2 1 . 6 7 2 1 . 7 9 2 1 . 8 5 2 1 . 8 8 2 1 . 9 8 2 2 . 2 6 2 2 . 3 0 2 2 . 3 7 2 2 . 5 7 2 2 . 6 9 2 2 . 8 6 2 2 . 9 7 2 3 . 0 6 2 3 . 1 7 2 3 . 2 0 2 3 . 2 6 2 3 . 3 1 2 3 . 4 2 2 3 . 5 3 2 3 . 5 9 2 3 . 7 2 2 3 . 8 0 2 4 . 2 0 2 4 . 3 4 2 4 . 4 2 2 4 . 4 6 2 4 . 5 8 2 4 . 6 6 2 4 . 7 6 2 4 . 8 2 2 4 . 9 3 2 5 . 0 4 2 5 . 0 8 2 5 . 1 6 2 5 . 2 1 2 5 . 3 7 2 5 . 4 8 2 5 . 6 7 2 5 . 7 7 2 5 . 8 7 2 6 . 0 1 2 6 . 0 5 2 6 . 1 1 2 6 . 1 4 2 6 . 2 0 2 6 . 3 4 2 6 . 4 3 2 6 . 6 3 2 6 . 6 7 2 6 . 8 2 2 6 . 9 3 2 7 . 0 7 2 7 . 1 3 2 7 . 1 8 2 7 . 2 5 2 7 . 3 1 2 7 . 3 4 2 7 . 4 0 2 7 . 4 5 2 7 . 5 5 2 7 . 6 3 2 7 . 7 9 2 7 . 8 4 2 7 . 8 9 2 7 . 9 6 2 8 . 0 7 2 8 . 1 5 2 8 . 2 4 2 8 . 4 6 2 8 . 5 1 2 8 . 5 7 2 8 . 7 5 2 8 . 7 8 2 8 . 8 3 2 8 . 9 0 2 8 . 9 9 2 9 . 0 7 2 9 . 1 7 2 9 . 3 9 2 9 . 5 4 2 9 . 6 8 n - N o n a n e n - D e c a n e n - D o d e c a n e n - T e t r a d e c a n e n - H e x a d e c a n e n - O c t a d e c a n e n - N o n a d e c a n e * o - T e r p h e n y l n - E i c o s a n e * 1 - C h l o r o - o c t a d e c a n e n - D o c o s a n e n - T e t r a c o s a n e n - H e x a c o s a n e n - O c t a c o s a n e n - T r i a c o n t a n e n - H e x a t r i a c o n t a n e G:\org\HP2\DAT\HP2081414_b\0814HP2.0045.RAW B14080821-002B ;0814HP2 , $HC-EPH-SCRN-W, RR-V45 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 0 500 1000 1500 2000 2500 3000 Page 29 of 31 Shipping container/cooler in good condition? Custody seals intact on all shipping container(s)/cooler(s)? Custody seals intact on all sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? (Exclude analyses that are considered field parameters such as pH, DO, Res Cl, Sulfite, Ferrous Iron, etc.) Container/Temp Blank temperature: Water - VOA vials have zero headspace? Water - pH acceptable upon receipt? Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No No No No No No No No No No No Not Present Not Present Not Present No VOA vials submitted Not Applicable 4.7° C On Ice 8/8/2014 Tabitha Edwards Return-UPS Ground kl Date Received: Received by: Login completed by: Carrier name: BL2000\lcadreau 8/11/2014 Reviewed by: Reviewed Date: Contact and Corrective Action Comments: None Temp Blank received in all shipping container(s)/cooler(s)? Yes No Not Applicable Lab measurement of analytes considered field parameters that require analysis within 15 minutes of sampling such as pH, Dissolved Oxygen and Residual Chlorine, are qualified as being analyzed outside of recommended holding time. Solid/soil samples are reported on a wet weight basis (as received) unless specifically indicated. If moisture corrected, data units are typically noted as –dry. For agricultural and mining soil parameters/characteristics, all samples are dried and ground prior to sample analysis. Standard Reporting Procedures: Workorder Receipt Checklist MT Dept of Transportation B14080821 Page 30 of 31 Page 31 of 31 Appendix D Laboratory Analytical Reports – Soil Vapor 2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com LABORATORY REPORT August 28, 2014 Aaron Anderson Montana Department of Transportation P.O. Box 201001 Helena, MT 59620-1001 RE: BZN - MDT Dear Aaron: Enclosed are the results of the sample submitted to our laboratory on August 15, 2014. For your reference, these analyses have been assigned our service request number P1403305. All analyses were performed according to our laboratory’s NELAP and DoD-ELAP-approved quality assurance program. The test results meet requirements of the current NELAP and DoD-ELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP and DoD-ELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. Results are intended to be considered in their entirety and apply only to the samples analyzed and reported herein. If you have any questions, please call me at (805) 526-7161. Respectfully submitted, ALS | Environmental Kate Aguilera Project Manager RIGHT SOLUTIONS | RIGHT PARTNER 1 of 33 2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com Client: Montana Department of Transportation Service Request No: P1403305 Project: BZN - MDT _______________________________________________________________________________ CASE NARRATIVE The sample was received intact under chain of custody on August 15, 2014 and were stored in accordance with the analytical method requirements. Please refer to the sample acceptance check form for additional information. The results reported herein are applicable only to the condition of the sample at the time of sample receipt. Air-Phase Petroleum Hydrocarbons (APH) Analysis The sample was analyzed for total aliphatic and aromatic gasoline range hydrocarbons by gas chromatography/mass spectrometry according to the Method for the Determination of Air-Phase Petroleum Hydrocarbons (APH), Massachusetts Department of Environmental Protection, Revision 1, December, 2009. This method is not included on the laboratory’s DoD-ELAP or AIHA-LAP scope of accreditation. Significant non-petroleum related peaks (i.e. halogenated, oxygenated, terpenes, etc.) are subtracted from the hydrocarbon range areas when present. Any internal/tuning standards and target APH analytes eluting in the hydrocarbon ranges are also subtracted. Additionally, C 9 -C 10 Aromatic Hydrocarbons are excluded from the C 9 -C 12 Aliphatic Hydrocarbon range. Volatile Organic Compound Analysis The sample was also analyzed for selected volatile organic compounds in accordance with EPA Method TO- 15 from the Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Second Edition (EPA/625/R-96/010b), January, 1999. This procedure is described in laboratory SOP VOA- TO15. The analytical system was comprised of a gas chromatograph / mass spectrometer (GC/MS) interfaced to a whole-air preconcentrator. This method is not included on the laboratory’s AIHA-LAP scope of accreditation. Any analytes flagged with an X are not included on the laboratory’s NELAP or DoD-ELAP scope of accreditation. The Summa canister was cleaned, prior to sampling, down to the method reporting limit (MRL) reported for this project. Please note, projects which require reporting below the MRL could have results between the MRL and method detection limit (MDL) that are biased high. ______________________________________________________________________________________ The results of analyses are given in the attached laboratory report. All results are intended to be considered in their entirety, and ALS Environmental (ALS) is not responsible for utilization of less than the complete report. Use of ALS Environmental (ALS)’s Name. Client shall not use ALS’s name or trademark in any marketing or reporting materials, press releases or in any other manner (“Materials”) whatsoever and shall not attribute to ALS any test result, tolerance or specification derived from ALS’s data (“Attribution”) without ALS’s prior written consent, which may be withheld by ALS for any reason in its sole discretion. To request ALS’s consent, Client shall provide copies of the proposed Materials or Attribution and describe in writing Client’s proposed use of such Materials or Attribution. If ALS has not provided written approval of the Materials or Attribution within ten (10) days of receipt from Client, Client’s request to use ALS’s name or trademark in any Materials or Attribution shall be deemed denied. ALS may, in its discretion, reasonably charge Client for its time in reviewing Materials or Attribution requests. Client acknowledges and agrees that the unauthorized use of ALS’s name or trademark may cause ALS to incur irreparable harm for which the recovery of money damages will be inadequate. Accordingly, Client acknowledges and agrees that a violation shall justify preliminary injunctive relief. For questions contact the laboratory. RIGHT SOLUTIONS | RIGHT PARTNER 2 of 33 2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com ALS Environmental – Simi Valley Certifications, Accreditations, and Registrations Agency Web Site Number AIHA http://www.aihaaccreditedlabs.org 101661 Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0694 DoD ELAP http://www.pjlabs.com/search-accredited-labs L14-2 Florida DOH (NELAP) http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E871020 Maine DHHS http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp- services/labcert/labcert.htm 2014025 Minnesota DOH (NELAP) http://www.health.state.mn.us/accreditation 643428 New Jersey DEP (NELAP) http://www.nj.gov/dep/oqa/ CA009 New York DOH (NELAP) http://www.wadsworth.org/labcert/elap/elap.html 11221 Oregon PHD (NELAP) http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaborat oryAccreditation/Pages/index.aspx CA200007 Pennsylvania DEP http://www.depweb.state.pa.us/labs 68-03307 (Registration) Texas CEQ (NELAP) http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704413- 14-5 Utah DOH (NELAP) http://www.health.utah.gov/lab/labimp/certification/index.html CA01627201 4-4 Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C946 Analyses were performed according to our laboratory’s NELAP and DoD-ELAP approved quality assurance program. A complete listing of specific NELAP and DoD-ELAP certified analytes can be found in the certifications section at www.alsglobal.com, or at the accreditation body’s website. Each of the certifications listed above have an explicit Scope of Accreditation that applies to specific matrices/methods/analytes; therefore, please contact the laboratory for information corresponding to a particular certification. RIGHT SOLUTIONS | RIGHT PARTNER 3 of 33 P1403305_Detail Summary_1408271607_RG.xls - DETAIL SUMMARY Client:Montana Department of Transportation Service Request:P1403305 Project ID:BZN - MDT Date Received:8/15/2014 Time Received:10:10 Client Sample ID Lab Code Matrix Date Collected Time Collected Container ID Pi1 (psig) Pf1 (psig) BZN-MDT-VP1 P1403305-001 Air 8/14/2014 13:10 SC00822 -4.89 3.73 X X ALS ENVIRONMENTAL DETAIL SUMMARY REPORT TO - 1 5 - V O C C a n s MA A P H 1 . 0 - M A V O C P H C a n 4 of 33 5 o f 3 3 8/28/14 9:10 AMP1403305_Resource Technologies_BZN - MDT.xls - Page 1 of 1 ALS Environmental Sample Acceptance Check Form Client:Resource Technologies Work order:P1403305 Project:BZN - MDT Sample(s) received on:8/15/14 Date opened:8/15/14 by:RMARTENIES Note: This form is used for all samples received by ALS. The use of this form for custody seals is strictly meant to indicate presence/absence and not as an indication of compliance or nonconformity. Thermal preservation and pH will only be evaluated either at the request of the client and/or as required by the method/SOP. Yes No N/A 1 Were sample containers properly marked with client sample ID? 2 Container(s) supplied by ALS? 3 Did sample containers arrive in good condition? 4 Were chain-of-custody papers used and filled out? 5 Did sample container labels and/or tags agree with custody papers? 6 Was sample volume received adequate for analysis? 7 Are samples within specified holding times? 8 Was proper temperature (thermal preservation) of cooler at receipt adhered to?  9 Was a trip blank received? 10 Were custody seals on outside of cooler/Box? Location of seal(s)?Sealing Lid? Were signature and date included? Were seals intact? Were custody seals on outside of sample container? Location of seal(s)?Sealing Lid? Were signature and date included? Were seals intact? 11  Is there a client indication that the submitted samples are pH preserved? Were VOA vials checked for presence/absence of air bubbles?  12 Tubes: Are the tubes capped and intact? Do they contain moisture? 13 Badges: Are the badges properly capped and intact? Are dual bed badges separated and individually capped and intact? Lab Sample ID Container Required Received Adjusted VOA Headspace Description pH *pH pH (Presence/Absence)Comments 6.0 L Source Can RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4) Do containers have appropriate preservation, according to method/SOP or Client specified information? Does the client/method/SOP require that the analyst check the sample pH and if necessary alter it? Receipt / Preservation P1403305-001.01 Explain any discrepancies: (include lab sample ID numbers): 6 of 33 APH..XLS - Page No.:P1403305_APH_1408251501_SC.xls - Sample ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Montana Department of Transportation Client Sample ID:BZN-MDT-VP1 ALS Project ID:P1403305 Client Project ID:BZN - MDT ALS Sample ID:P1403305-001 Test Code:Massachusetts APH, Revision 1, December 2009 Date Collected:8/14/14 Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:8/15/14 Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.040 Liter(s) Test Notes: Container ID:SC00822 Initial Pressure (psig):-4.89 Final Pressure (psig):3.73 Canister Dilution Factor:1.88 Compound Result MRL Data µg/m³µg/m³ Qualifier 63,000 940 4,700 470 ND 120 Significant non-petroleum related peaks (i.e. halogenated, oxygenated, terpenes, etc.) are subtracted from the hydrocarbon range areas when present. ¹Hydrocarbon Range data from total ion chromatogram excluding any internal/tuning standards eluting in that range. ²C5-C8 Aliphatic Hydrocarbons exclude the concentration of Target APH analytes eluting in that range. ³C9-C12 Aliphatic Hydrocarbons exclude concentration of Target APH Analytes eluting in that range and concentration of C9-C10 Aromatic Hydrocarbons. ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. C5 - C8 Aliphatic Hydrocarbons1,2 C9 - C12 Aliphatic Hydrocarbons1,3 C9 - C10 Aromatic Hydrocarbons 7 of 33 APH..XLS - Page No.:P1403305_APH_1408251501_SC.xls - MBlank ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Montana Department of Transportation Client Sample ID:Method Blank ALS Project ID:P1403305 Client Project ID:BZN - MDT ALS Sample ID:P140823-MB Test Code:Massachusetts APH, Revision 1, December 2009 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:1.00 Liter(s) Test Notes: Compound Result MRL Data µg/m³µg/m³ Qualifier ND 20 ND 10 ND 2.5 Significant non-petroleum related peaks (i.e. halogenated, oxygenated, terpenes, etc.) are subtracted from the hydrocarbon range areas when present. ¹Hydrocarbon Range data from total ion chromatogram excluding any internal/tuning standards eluting in that range. ²C5-C8 Aliphatic Hydrocarbons exclude the concentration of Target APH analytes eluting in that range. ³C9-C12 Aliphatic Hydrocarbons exclude concentration of Target APH Analytes eluting in that range and concentration of C9-C10 Aromatic Hydrocarbons. ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. C5 - C8 Aliphatic Hydrocarbons1,2 C9 - C12 Aliphatic Hydrocarbons1,3 C9 - C10 Aromatic Hydrocarbons 8 of 33 APH..XLS - Page No.:P1403305_APH_1408251501_SC.xls - LCS ALS ENVIRONMENTAL LABORATORY CONTROL SAMPLE SUMMARY Page 1 of 1 Client:Montana Department of Transportation Lab Control Sample ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P140823-LCS Test Code:Massachusetts APH, Revision 1, December 2009 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.125 Liter(s) Test Notes: Compound Data Qualifier C5 - C8 Aliphatic Hydrocarbons C9 - C12 Aliphatic Hydrocarbons C9 - C10 Aromatic Hydrocarbons Client Sample ID: Client Project ID: ALS Acceptance Limits Spike Amount µg/m³ Result µg/m³ % Recovery 210 212 416 195 195 367 93 92 88 70-130 70-130 70-130 9 of 33 Massachusetts APH ICAL Method: M13Q70S14,.M ICAL Date: 718121'14' lnstrumentlD: ;MS13 Hydrocarbon Ranges ~ masses C5-C8 Ali11hatics 0.5 1· 5 25 50 100 0.5 1 5 25 50 100 lsopentane 71968 126254 551023 2682637 5123482 9977142 0.535 1.07 5.35 26.75 53.5 107 n-Hexane 79042 126474 543616 2576727 4919310 9649330 0.525 1.05 5.25 26.25 52.5 105 Cyclohexane 77006 139055 626767 3090071 5921650 11489405 0.530 1.06 5.30 26.50 53.0 106 2,3-Dimethylpentane 79873 144996 636180 3153721 6026620 11661737 0.565 1.13 5.65 28.25 56.5 113 n-Heptane 74059 132682 586382 2869520 5458584 10679433 0.530 1.06 5.30 26.50 53.0 106 n-Octane 83438 147724 660928 3288101 6275076 12256759 0.550 1.10 5.50 27.50 55.0 110 area sum: 465386 817185 3604896 17660777 33724722 65713806 sum: 3.235 6.470 32.35 161.75 323.50 647.00 C9·C12 Ali11hatics 0.5 1 5 25 .50 100 0.5 1 5 25 50 100 2,3-Dimethylheptane 86977 159998 716889 3598113 6888394 13322230 0.525 1.05 5.25 26.25 52.5 105 n-Nonane 87063 156528 702402 3439435 6576692 12824326 0.530 1.06 5.30 26.50 53.0 106 n-Decane 92363 167752 754551 3684733 7033147 13755552 0.525 1.05 5.25 26.25 52.5 105 Butylcyclohexane 111028 200517 894948 4401863 8434492 16442258 0.530 1.06 5.30 26.50 53.0 106 n-Undecane 90519 172908 796905 3732681 7054959 13833073 0.505 1.01 5.05 25.25 50.5 n-Dodecane 85049 170579 819076 3495954 6549961 12888154 0.520 1.04 5.20 26.00 52.0 104 area sum: 552999 1028282 4684771 22352779 42537645 83065593 sum: 3.135 6.270 31.35 156.75 313.50 627.00 C9-C10 Aromatics 0.5 1 5 25 50 100 0.5 1 5 25 50 100 lsopropylbenzene 14256 25867 111848 548492 1046083 2015831 0.530 1.06 5.30 26.50 53.0 106 3-Ethyltoluene 15056 28857 127080 618440 1174043 2284037 0.510 1.02 5.10 25.50 51.0 102 1,3,5-Trimethylbenzene 21369 38346 175064 839865 1598507 3103160 0.525 1.05 5.25 26.25 52.5 105 1,2,3-Trimethylbenzene 22331 41667 189336 903237 1725524 3441728 0.520 1.04 5.20 26.00 52.0 104 p-lsopropyltoluene 12459 22920 103617 494884 934560 1849380 0.500 1.00 5.00 25.00 50.0 100 area sum: 85471 157657 706945 3404918 6478717 12694136 sum: 2.585 5.170 25.85 129.25 258.50 517.00 l:\MS13\MAPH\maph icals\maph_icaf_M13070814\HCR ICAL Si -7bhd 1 0 o f 3 3 ICAL Date: Instrument ID: MS13 ~ Internal Standards (TIC} 1 5 25 Brom~chloromethane (IS 1) 828932 831 720160 736686 703410 739516 1,4-Difluorobenzene (IS2) 1859548 1843210 1633026 1633659 1596939 1659286 Chlorobenzene-d5 <153) 18081 1808923 1608336 1609513 1533932 1615376 Bromochloromethane (IS1) 148215 149987 142914 147982 1 ,4-Difluorobenzene (IS2) 837485 830565 739272 734171 718955 749743 Chlorobenzene-d5 (IS3) 609969 607619 540367 534704 507186 536409 Surrogates me} 1 5 25 50 100 1,2-Dichloroethane-d4 805321 804525 718711 722170 693973 732083 17885 1879751 1868492 1816851 1898259 1 1434036 1313371 1404136 RRFs Aliohatics 1 5 25 50 100 RRFw9 %RSD 1.8842 1.8590 1.8125 1.6934 1.883 Alh>hatics 1 5 50 100 RRF,KG %RSD 3.4568 3.3337 3.3441 3.0872 3.368 5.13 Aromatics 1 5 25 50 100 RRfav.g %RSD 0.6326 0.6158 0.6177 0.5722 0.624 5.44 ~\MAPH\m!:lnh lcals\maph_ical_M13070814\HCR JiiJI-..., h /1tL 1 1 o f 3 3 l:\MS13\DATA\2014_08\23\08231403.D Massachusetts APH Continuing Calibration Verification Check Sheet Data File Name: 08231403.D Data File Path: l:\MS13\DATA\2014_08\22\ Operator; WA Date Acquired: 8/23/2014 5:47 Acq. Method File: T015.M Sample Name: 25ng T0-15 MAPH STD Misc Info: S29-07171401/S29-07021404 (8/31) Instrument Name: MS13 I Enter RRFs from current /CAL! rnternal Standards 7) 1,4-Difluorobenzene {182) 16) Chlorobenzene-d5 (183) RT 13.15 17.48 Area 433185 321326 C5-C8 Aliphatics RT Area RRF !19 3) lsopentane 6.92 1505689 1.787 153.5 4) n-Hexane 11.15 1468185 9) Cyclohexane 13.06 1755949 10) 2, 3-Dimethylpentane 13.34 1786096 Spike JCAL 11) n-Heptane 14.20 16367 46 Amt (ng) RRF 14) nMOctane 16.72 1863906 161.75 1.883 10016571 C9-C12 Aliphatics RT Area RRF fill 18) 2,3-Dimethylheptane 17.98 2030496 3.222 150.0 19) n-Nonane 18.74 1946397 25) n-Decane 20.27 2101442 28) Butylcyclohexane 20.84 2488564 Spike JCAL 29) n-Undecane 21.50 2178892 Amt (ng) RRF 30) n-Dodecane 22.52 2237967 156.75 3.368 12983758 C9-C10 Aromatics RT Area RRF D.9. 22) lsopropylbenzene 19.08 317917 0.592 122.7 23) 1-Methyl-3-ethylbenzene 19.67 356815 24) 1,3,5-Trimethylbenzene 19.77 488211 26) p-lsopropyltol uene 20.59 283581 Spike ICAL 27) 1,2,3-Trimethylbenzene 20.58 521173 Amt(ng) RRF 1967697 129.25 0.624 %0 LCL UCL Pass/Fai ..S.10 -30 30 Pass %0 -4.33 -30 30 Pass %0 .. 5.09 -30 30 Pass Page 1 of 1 l:\MS13\0~lnstrument lnfo\0-Security Certificates\CCV _M111814 __ 070814.CRT 8/23/2014 1:14 PM 12 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - Sample ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 5 Client:Montana Department of Transportation BZN-MDT-VP1 ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P1403305-001 Test Code:EPA TO-15 Date Collected:8/14/14 Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:8/15/14 Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.040 Liter(s) Test Notes: Container ID:SC00822 Initial Pressure (psig):-4.89 Final Pressure (psig):3.73 Canister Dilution Factor:1.88 CAS #Compound MRL MRL Data µg/m³ ppbV Qualifier 115-07-1 Propene 40 24 24 14 75-71-8 Dichlorodifluoromethane (CFC 12)ND 24 ND 4.8 74-87-3 Chloromethane ND 24 ND 11 76-14-2 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114)ND 24 ND 3.4 75-01-4 Vinyl Chloride ND 24 ND 9.2 106-99-0 1,3-Butadiene ND 24 ND 11 74-83-9 Bromomethane ND 24 ND 6.1 75-00-3 Chloroethane ND 24 ND 8.9 64-17-5 Ethanol ND 240 ND 120 75-05-8 Acetonitrile ND 24 ND 14 107-02-8 Acrolein ND 94 ND 41 67-64-1 Acetone ND 240 ND 99 75-69-4 Trichlorofluoromethane ND 24 ND 4.2 67-63-0 2-Propanol (Isopropyl Alcohol)ND 240 ND 96 107-13-1 Acrylonitrile ND 24 ND 11 75-35-4 1,1-Dichloroethene ND 24 ND 5.9 75-09-2 Methylene Chloride ND 24 ND 6.8 107-05-1 3-Chloro-1-propene (Allyl Chloride)ND 24 ND 7.5 76-13-1 Trichlorotrifluoroethane ND 24 ND 3.1 ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Result µg/m³ Result ppbV Client Sample ID: Client Project ID: 13 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - Sample ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 2 of 5 Client:Montana Department of Transportation BZN-MDT-VP1 ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P1403305-001 Test Code:EPA TO-15 Date Collected:8/14/14 Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:8/15/14 Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.040 Liter(s) Test Notes: Container ID:SC00822 Initial Pressure (psig):-4.89 Final Pressure (psig):3.73 Canister Dilution Factor:1.88 CAS #Compound MRL MRL Data µg/m³ ppbV Qualifier 75-15-0 Carbon Disulfide ND 240 ND 75 156-60-5 trans-1,2-Dichloroethene ND 24 ND 5.9 75-34-3 1,1-Dichloroethane 32 24 7.8 5.8 1634-04-4 Methyl tert-Butyl Ether ND 24 ND 6.5 108-05-4 Vinyl Acetate ND 240 ND 67 78-93-3 2-Butanone (MEK)ND 240 ND 80 156-59-2 cis-1,2-Dichloroethene ND 24 ND 5.9 141-78-6 Ethyl Acetate ND 47 ND 13 110-54-3 n-Hexane ND 24 ND 6.7 67-66-3 Chloroform ND 24 ND 4.8 109-99-9 Tetrahydrofuran (THF)ND 24 ND 8.0 107-06-2 1,2-Dichloroethane ND 24 ND 5.8 71-55-6 1,1,1-Trichloroethane ND 24 ND 4.3 71-43-2 Benzene 38 24 12 7.4 56-23-5 Carbon Tetrachloride ND 24 ND 3.7 110-82-7 Cyclohexane ND 47 ND 14 78-87-5 1,2-Dichloropropane ND 24 ND 5.1 75-27-4 Bromodichloromethane ND 24 ND 3.5 79-01-6 Trichloroethene ND 24 ND 4.4 ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Result ppbV Result µg/m³ Client Sample ID: Client Project ID: 14 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - Sample ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 3 of 5 Client:Montana Department of Transportation BZN-MDT-VP1 ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P1403305-001 Test Code:EPA TO-15 Date Collected:8/14/14 Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:8/15/14 Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.040 Liter(s) Test Notes: Container ID:SC00822 Initial Pressure (psig):-4.89 Final Pressure (psig):3.73 Canister Dilution Factor:1.88 CAS #Compound MRL MRL Data µg/m³ ppbV Qualifier 123-91-1 1,4-Dioxane ND 24 ND 6.5 80-62-6 Methyl Methacrylate ND 47 ND 11 142-82-5 n-Heptane ND 24 ND 5.7 10061-01-5 cis-1,3-Dichloropropene ND 24 ND 5.2 108-10-1 4-Methyl-2-pentanone ND 24 ND 5.7 10061-02-6 trans-1,3-Dichloropropene ND 24 ND 5.2 79-00-5 1,1,2-Trichloroethane ND 24 ND 4.3 108-88-3 Toluene ND 24 ND 6.2 591-78-6 2-Hexanone ND 24 ND 5.7 124-48-1 Dibromochloromethane ND 24 ND 2.8 106-93-4 1,2-Dibromoethane ND 24 ND 3.1 123-86-4 n-Butyl Acetate ND 24 ND 4.9 111-65-9 n-Octane ND 24 ND 5.0 127-18-4 Tetrachloroethene ND 24 ND 3.5 108-90-7 Chlorobenzene ND 24 ND 5.1 100-41-4 Ethylbenzene ND 24 ND 5.4 179601-23-1 m,p-Xylenes ND 47 ND 11 75-25-2 Bromoform ND 24 ND 2.3 100-42-5 Styrene ND 24 ND 5.5 ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Result Result ppbVµg/m³ Client Project ID: Client Sample ID: 15 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - Sample Client:Montana Department of Transportation BZN-MDT-VP1 ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P1403305-001 Test Code:EPA TO-15 Date Collected:8/14/14 Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:8/15/14 Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.040 Liter(s) Test Notes: Container ID:SC00822 Initial Pressure (psig):-4.89 Final Pressure (psig):3.73 Canister Dilution Factor:1.88 CAS #Compound MRL MRL Data µg/m³ ppbV Qualifier 95-47-6 o-Xylene ND 24 ND 5.4 111-84-2 n-Nonane ND 24 ND 4.5 79-34-5 1,1,2,2-Tetrachloroethane ND 24 ND 3.4 98-82-8 Cumene ND 24 ND 4.8 80-56-8 alpha-Pinene ND 24 ND 4.2 103-65-1 n-Propylbenzene ND 24 ND 4.8 622-96-8 4-Ethyltoluene ND 24 ND 4.8 108-67-8 1,3,5-Trimethylbenzene ND 24 ND 4.8 95-63-6 1,2,4-Trimethylbenzene ND 24 ND 4.8 100-44-7 Benzyl Chloride ND 24 ND 4.5 541-73-1 1,3-Dichlorobenzene ND 24 ND 3.9 106-46-7 1,4-Dichlorobenzene ND 24 ND 3.9 95-50-1 1,2-Dichlorobenzene ND 24 ND 3.9 5989-27-5 d-Limonene ND 24 ND 4.2 96-12-8 1,2-Dibromo-3-chloropropane ND 24 ND 2.4 120-82-1 1,2,4-Trichlorobenzene ND 24 ND 3.2 91-20-3 Naphthalene ND 24 ND 4.5 87-68-3 Hexachlorobutadiene ND 24 ND 2.2 75-37-6 1,1-Difluoroethane ND 24 ND 8.7 X ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. X = See case narrative. ppbV ResultResult µg/m³ Client Project ID: Client Sample ID: ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 4 of 5 16 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - TIC ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 5 of 5 Client:Montana Department of Transportation Client Sample ID:BZN-MDT-VP1 ALS Project ID:P1403305 Client Project ID:BZN - MDT ALS Sample ID:P1403305-001 Tentatively Identified Compounds Test Code:EPA TO-15 Date Collected:8/14/14 Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:8/15/14 Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.040 Liter(s) Test Notes:T Container ID:SC00822 Initial Pressure (psig):-4.89 Final Pressure (psig):3.73 Canister Dilution Factor:1.88 GC/MS Compound Identification Concentration Data Retention Time µg/m³Qualifier 8.91 2,2-Dimethylbutane 1,500 9.95 2,3-Dimethylbutane 2,000 10.58 3-Methylpentane 1,100 11.95 2,2-Dimethylpentane 1,800 12.14 2,4-Dimethylpentane 5,700 12.32 2,2,3-Trimethylpentane 830 12.93 3,3-Dimethylpentane 1,100 13.35 2,3-Dimethylpentane 3,000 13.96 Isooctane 24,000 14.90 1,1,3-Trimethylcyclopentane 580 15.07 2,5-Dimethylhexane 770 15.13 2,4-Dimethylhexane 1,400 15.34 1,2,4-Trimethylcyclopentane 620 15.59 2,3,4-Trimethylpentane 5,500 15.73 2,3,3-Trimethylpentane 3,600 T = Analyte is a tentatively identified compound, result is estimated. 17 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - MBlank ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 5 Client:Montana Department of Transportation Method Blank ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P140823-MB Test Code:EPA TO-15 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:1.00 Liter(s) Test Notes: Canister Dilution Factor:1.00 CAS #Compound MRL MRL Data µg/m³ ppbV Qualifier 115-07-1 Propene ND 0.50 ND 0.29 75-71-8 Dichlorodifluoromethane (CFC 12)ND 0.50 ND 0.10 74-87-3 Chloromethane ND 0.50 ND 0.24 76-14-2 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114)ND 0.50 ND 0.072 75-01-4 Vinyl Chloride ND 0.50 ND 0.20 106-99-0 1,3-Butadiene ND 0.50 ND 0.23 74-83-9 Bromomethane ND 0.50 ND 0.13 75-00-3 Chloroethane ND 0.50 ND 0.19 64-17-5 Ethanol ND 5.0 ND 2.7 75-05-8 Acetonitrile ND 0.50 ND 0.30 107-02-8 Acrolein ND 2.0 ND 0.87 67-64-1 Acetone ND 5.0 ND 2.1 75-69-4 Trichlorofluoromethane ND 0.50 ND 0.089 67-63-0 2-Propanol (Isopropyl Alcohol)ND 5.0 ND 2.0 107-13-1 Acrylonitrile ND 0.50 ND 0.23 75-35-4 1,1-Dichloroethene ND 0.50 ND 0.13 75-09-2 Methylene Chloride ND 0.50 ND 0.14 107-05-1 3-Chloro-1-propene (Allyl Chloride)ND 0.50 ND 0.16 76-13-1 Trichlorotrifluoroethane ND 0.50 ND 0.065 ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Result µg/m³ Client Sample ID: Client Project ID: Result ppbV 18 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - MBlank ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 2 of 5 Client:Montana Department of Transportation Method Blank ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P140823-MB Test Code:EPA TO-15 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:1.00 Liter(s) Test Notes: Canister Dilution Factor:1.00 CAS #Compound MRL MRL Data µg/m³ ppbV Qualifier 75-15-0 Carbon Disulfide ND 5.0 ND 1.6 156-60-5 trans-1,2-Dichloroethene ND 0.50 ND 0.13 75-34-3 1,1-Dichloroethane ND 0.50 ND 0.12 1634-04-4 Methyl tert-Butyl Ether ND 0.50 ND 0.14 108-05-4 Vinyl Acetate ND 5.0 ND 1.4 78-93-3 2-Butanone (MEK)ND 5.0 ND 1.7 156-59-2 cis-1,2-Dichloroethene ND 0.50 ND 0.13 141-78-6 Ethyl Acetate ND 1.0 ND 0.28 110-54-3 n-Hexane ND 0.50 ND 0.14 67-66-3 Chloroform ND 0.50 ND 0.10 109-99-9 Tetrahydrofuran (THF)ND 0.50 ND 0.17 107-06-2 1,2-Dichloroethane ND 0.50 ND 0.12 71-55-6 1,1,1-Trichloroethane ND 0.50 ND 0.092 71-43-2 Benzene ND 0.50 ND 0.16 56-23-5 Carbon Tetrachloride ND 0.50 ND 0.080 110-82-7 Cyclohexane ND 1.0 ND 0.29 78-87-5 1,2-Dichloropropane ND 0.50 ND 0.11 75-27-4 Bromodichloromethane ND 0.50 ND 0.075 79-01-6 Trichloroethene ND 0.50 ND 0.093 ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Result µg/m³ Client Project ID: Result ppbV Client Sample ID: 19 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - MBlank ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 3 of 5 Client:Montana Department of Transportation Client Sample ID:Method Blank ALS Project ID:P1403305 Client Project ID:BZN - MDT ALS Sample ID:P140823-MB Test Code:EPA TO-15 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:1.00 Liter(s) Test Notes: Canister Dilution Factor:1.00 CAS #Compound MRL MRL Data µg/m³ ppbV Qualifier 123-91-1 1,4-Dioxane ND 0.50 ND 0.14 80-62-6 Methyl Methacrylate ND 1.0 ND 0.24 142-82-5 n-Heptane ND 0.50 ND 0.12 10061-01-5 cis-1,3-Dichloropropene ND 0.50 ND 0.11 108-10-1 4-Methyl-2-pentanone ND 0.50 ND 0.12 10061-02-6 trans-1,3-Dichloropropene ND 0.50 ND 0.11 79-00-5 1,1,2-Trichloroethane ND 0.50 ND 0.092 108-88-3 Toluene ND 0.50 ND 0.13 591-78-6 2-Hexanone ND 0.50 ND 0.12 124-48-1 Dibromochloromethane ND 0.50 ND 0.059 106-93-4 1,2-Dibromoethane ND 0.50 ND 0.065 123-86-4 n-Butyl Acetate ND 0.50 ND 0.11 111-65-9 n-Octane ND 0.50 ND 0.11 127-18-4 Tetrachloroethene ND 0.50 ND 0.074 108-90-7 Chlorobenzene ND 0.50 ND 0.11 100-41-4 Ethylbenzene ND 0.50 ND 0.12 179601-23-1 m,p-Xylenes ND 1.0 ND 0.23 75-25-2 Bromoform ND 0.50 ND 0.048 100-42-5 Styrene ND 0.50 ND 0.12 ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Result µg/m³ppbV Result 20 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - MBlank Client:Montana Department of Transportation Method Blank ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P140823-MB Test Code:EPA TO-15 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:1.00 Liter(s) Test Notes: Canister Dilution Factor:1.00 CAS #Compound MRL MRL Data µg/m³ ppbV Qualifier 95-47-6 o-Xylene ND 0.50 ND 0.12 111-84-2 n-Nonane ND 0.50 ND 0.095 79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 ND 0.073 98-82-8 Cumene ND 0.50 ND 0.10 80-56-8 alpha-Pinene ND 0.50 ND 0.090 103-65-1 n-Propylbenzene ND 0.50 ND 0.10 622-96-8 4-Ethyltoluene ND 0.50 ND 0.10 108-67-8 1,3,5-Trimethylbenzene ND 0.50 ND 0.10 95-63-6 1,2,4-Trimethylbenzene ND 0.50 ND 0.10 100-44-7 Benzyl Chloride ND 0.50 ND 0.097 541-73-1 1,3-Dichlorobenzene ND 0.50 ND 0.083 106-46-7 1,4-Dichlorobenzene ND 0.50 ND 0.083 95-50-1 1,2-Dichlorobenzene ND 0.50 ND 0.083 5989-27-5 d-Limonene ND 0.50 ND 0.090 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 ND 0.052 120-82-1 1,2,4-Trichlorobenzene ND 0.50 ND 0.067 91-20-3 Naphthalene ND 0.50 ND 0.095 87-68-3 Hexachlorobutadiene ND 0.50 ND 0.047 75-37-6 1,1-Difluoroethane ND 0.50 ND 0.19 X ND = Compound was analyzed for, but not detected above the laboratory reporting limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. X = See case narrative. Client Sample ID: Result ppbV Result µg/m³ Client Project ID: ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 4 of 5 21 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - MBlank TIC ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 5 of 5 Client:Montana Department of Transportation Client Sample ID:Method Blank ALS Project ID:P1403305 Client Project ID:BZN - MDT ALS Sample ID:P140823-MB Tentatively Identified Compounds Test Code:EPA TO-15 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:1.00 Liter(s) Test Notes: Canister Dilution Factor:1.00 GC/MS Compound Identification Concentration Data Retention Time µg/m³Qualifier No Compounds Detected 22 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - Surrogates ALS ENVIRONMENTAL SURROGATE SPIKE RECOVERY RESULTS Page 1 of 1 Client:Montana Department of Transportation BZN - MDT ALS Project ID:P1403305 Test Code:EPA TO-15 Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date(s) Collected:8/14/14 Analyst:Wida Ang Date(s) Received:8/15/14 Sample Type:6.0 L Summa Canister(s)Date(s) Analyzed:8/23/14 Test Notes: Client Sample ID ALS Sample ID Acceptance Data Limits Qualifier P140823-MB 70-130 P140823-LCS 70-130 P1403305-001 70-130 Surrogate percent recovery is verified and accepted based on the on-column result. Reported results are shown in concentration units and as a result of the calculation, may vary slightly from the on-column percent recovery. Client Project ID: 101 Toluene-d8 Percent Recovered 100 1,2-Dichloroethane-d4 Percent Recovered Bromofluorobenzene Method Blank 110 Percent Recovered Lab Control Sample BZN-MDT-VP1 103 97 110 110 88 109 23 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - LCS ALS ENVIRONMENTAL LABORATORY CONTROL SAMPLE SUMMARY Page 1 of 4 Client:Montana Department of Transportation Lab Control Sample ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P140823-LCS Test Code:EPA TO-15 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.125 Liter(s) Test Notes: CAS #Compound Data Qualifier 115-07-1 Propene 58-139 75-71-8 Dichlorodifluoromethane (CFC 12)63-115 74-87-3 Chloromethane 58-122 76-14-2 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114)65-115 75-01-4 Vinyl Chloride 64-122 106-99-0 1,3-Butadiene 57-141 74-83-9 Bromomethane 68-122 75-00-3 Chloroethane 66-120 64-17-5 Ethanol 58-126 75-05-8 Acetonitrile 64-136 107-02-8 Acrolein 58-129 67-64-1 Acetone 60-114 75-69-4 Trichlorofluoromethane 62-107 67-63-0 2-Propanol (Isopropyl Alcohol)54-118 107-13-1 Acrylonitrile 72-143 75-35-4 1,1-Dichloroethene 69-119 75-09-2 Methylene Chloride 64-113 107-05-1 3-Chloro-1-propene (Allyl Chloride)59-131 76-13-1 Trichlorotrifluoroethane 69-117 Laboratory Control Sample percent recovery is verified and accepted based on the on-column result. Reported results are shown in concentration units and as a result of the calculation, may vary slightly. 192 200 196 200 207 244 253 200 203 ALS Acceptance Limits % RecoverySpike Amount µg/m³ Client Sample ID: Client Project ID: 224 942 214 Result µg/m³ 208 201 210 201 204 195 198 179 915 218 219 208 206 1,080 1040 204 214 378 216 233 403 224 203 214 205 205 99 98 104 102 104 97 86 107 96 108 97 96 90 96 91 100 96 96 105 24 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - LCS ALS ENVIRONMENTAL LABORATORY CONTROL SAMPLE SUMMARY Page 2 of 4 Client:Montana Department of Transportation Lab Control Sample ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P140823-LCS Test Code:EPA TO-15 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.125 Liter(s) Test Notes: CAS #Compound Data Qualifier 75-15-0 Carbon Disulfide 65-115 156-60-5 trans-1,2-Dichloroethene 70-126 75-34-3 1,1-Dichloroethane 68-116 1634-04-4 Methyl tert-Butyl Ether 69-120 108-05-4 Vinyl Acetate 58-160 78-93-3 2-Butanone (MEK)70-127 156-59-2 cis-1,2-Dichloroethene 70-119 141-78-6 Ethyl Acetate 72-129 110-54-3 n-Hexane 63-115 67-66-3 Chloroform 68-110 109-99-9 Tetrahydrofuran (THF)60-126 107-06-2 1,2-Dichloroethane 69-118 71-55-6 1,1,1-Trichloroethane 68-120 71-43-2 Benzene 69-117 56-23-5 Carbon Tetrachloride 65-134 110-82-7 Cyclohexane 69-114 78-87-5 1,2-Dichloropropane 70-116 75-27-4 Bromodichloromethane 71-126 79-01-6 Trichloroethene 71-119 Laboratory Control Sample percent recovery is verified and accepted based on the on-column result. Reported results are shown in concentration units and as a result of the calculation, may vary slightly. 220 216 206 416 Client Sample ID: Client Project ID: 192 984 1140 212 214 Spike Amount µg/m³ 210 222 208 202 220 100 Result µg/m³ % Recovery ALS Acceptance Limits 208 208 220 192 220 212 428 453 216 205 218 193 212 202 394 210 202 215 200 210 215 206 195 206 97 94 95 95 92 106 106 96 97 101 116 98 95 99 95 99 87 98 25 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - LCS ALS ENVIRONMENTAL LABORATORY CONTROL SAMPLE SUMMARY Page 3 of 4 Client:Montana Department of Transportation Lab Control Sample ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P140823-LCS Test Code:EPA TO-15 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.125 Liter(s) Test Notes: CAS #Compound Data Qualifier 123-91-1 1,4-Dioxane 72-126 80-62-6 Methyl Methacrylate 75-136 142-82-5 n-Heptane 70-117 10061-01-5 cis-1,3-Dichloropropene 75-132 108-10-1 4-Methyl-2-pentanone 70-133 10061-02-6 trans-1,3-Dichloropropene 78-136 79-00-5 1,1,2-Trichloroethane 72-119 108-88-3 Toluene 65-116 591-78-6 2-Hexanone 62-132 124-48-1 Dibromochloromethane 66-140 106-93-4 1,2-Dibromoethane 69-130 123-86-4 n-Butyl Acetate 63-136 111-65-9 n-Octane 66-118 127-18-4 Tetrachloroethene 63-123 108-90-7 Chlorobenzene 66-118 100-41-4 Ethylbenzene 66-119 179601-23-1 m,p-Xylenes 64-118 75-25-2 Bromoform 64-140 100-42-5 Styrene 68-132 Laboratory Control Sample percent recovery is verified and accepted based on the on-column result. Reported results are shown in concentration units and as a result of the calculation, may vary slightly. 212 182 238 225 198 208 Spike Amount µg/m³ Client Project ID: 222 227 210 197 216 206 420 412 240 195 198 210 218 210 204 196 Client Sample ID: ALS 212 183 Limits % RecoveryResult µg/m³ Acceptance 86 184 408 362 226 208 210 202 210 187 192 171 212 221 212 89 89 102 98 95 106 88 92 94 95 89 104 96 93 81 86 96 96 26 of 33 TO15SCAN_2M.XLS - NL - PageNo.:P1403305_TO15_1408251501_SC.xls - LCS ALS ENVIRONMENTAL LABORATORY CONTROL SAMPLE SUMMARY Page 4 of 4 Client:Montana Department of Transportation Lab Control Sample ALS Project ID:P1403305 BZN - MDT ALS Sample ID:P140823-LCS Test Code:EPA TO-15 Date Collected:NA Instrument ID:Tekmar AUTOCAN/Agilent 5975Binert/6890N/MS13 Date Received:NA Analyst:Wida Ang Date Analyzed:8/23/14 Sample Type:6.0 L Summa Canister Volume(s) Analyzed:0.125 Liter(s) Test Notes: CAS #Compound Data Qualifier 95-47-6 o-Xylene 65-120 111-84-2 n-Nonane 64-117 79-34-5 1,1,2,2-Tetrachloroethane 63-128 98-82-8 Cumene 65-121 80-56-8 alpha-Pinene 66-123 103-65-1 n-Propylbenzene 65-121 622-96-8 4-Ethyltoluene 64-122 108-67-8 1,3,5-Trimethylbenzene 64-125 95-63-6 1,2,4-Trimethylbenzene 64-131 100-44-7 Benzyl Chloride 67-146 541-73-1 1,3-Dichlorobenzene 64-130 106-46-7 1,4-Dichlorobenzene 61-124 95-50-1 1,2-Dichlorobenzene 63-126 5989-27-5 d-Limonene 62-133 96-12-8 1,2-Dibromo-3-chloropropane 62-155 120-82-1 1,2,4-Trichlorobenzene 59-146 91-20-3 Naphthalene 56-143 87-68-3 Hexachlorobutadiene 58-133 Laboratory Control Sample percent recovery is verified and accepted based on the on-column result. Reported results are shown in concentration units and as a result of the calculation, may vary slightly. 84 214 206 182 ALS Acceptance Limits % Recovery 178 202 179 210 212 179 196 185 202 180 196 173 202 182 214 224 179 Client Sample ID: Client Project ID: µg/m³ Spike Amount µg/m³ Result 214 190 214 175 210 189 208 179 212 186 212 170 190 169 212 168 82 79 86 88 90 80 89 87 89 89 88 88 89 105 84 88 94 27 of 33 Method Path : I:\MS13\METHODS\ Method File : R13072514.M Response Factor Report MS13 Title : EPA T0-15 per SOP VOA-T015 (CASS T0-15/GC-MS) Last Update : Sat Jul 26 07:09:59 2014 Response Via : Initial Calibration Calibration Files 0.08=07251421.D 0.10=07251422.D 0.20=07251423.D 0.40=07251424.D 1.0 =07251425 D 5_0 =07251426.D 25 =07251427.D 50 =07251428.D 100 =07251429.D 1) IR 2) T 3) T 4) T 5) T 6) T 7) T 8) T 9) T 10) T 11) T 12) T 13) T 14) T 15) T 16) T 17) T 18) T 19) T 20) T 21) T 22) T 23) T 24) T 25) T 26) T 27) T 28) T 29) T 30) T 31) T 32) T 33) s 34) T 35) T 36) T Compound 0.08 0.10 0.20 0.40 1.0 5.0 25 50 100 Avg Bromochloromethane ... ----------------ISTD--------------------- Propene 1.333 1.316 1.351 1.373 1.245 1.275 1.372 1.324 Dichlorodifluo ... 3.938 4.004 3.568 3.961 3.809 3.737 3.701 3.502 3.194 3.713 Chloromethane 1.903 2.131 1.874 1.937 2.092 1.729 1.511 1.882 1,2-Dichloro-l ... 1.532 2.243 1.823 1.946 1.964 1.924 1.864 1.688 1.533 1.835 Vinyl Chloride 1.612 2.024 1.875 2.159 2.058 2.161 2.129 1.929 1.714 1.962 1,3-Butadiene l.094 1.144 1.185 1.270 1.325 1.493 1.544 1.397 1.291 1.305 Bromomethane 1.221 1.361 1.466 1.441 1.412 1.334 1.194 1.347 Chloroethane 0.826 0.712 0.828 1.010 0.941 0.989 0.987 0.944 0.870 0.901 Ethanol 0.758 0.762 0.916 0.943 0.932 0.908 0.937 0.890 0.835 0.876 Acetonitrile 2.197 2.025 2.052 2.291 2.221 2.174 2.230 2.160 2.070 2.158 Acrolein 0.561 0.734 0.688 0.754 0.728 0.678 0.691 Acetone 0.868 0.924 0.928 0.931 0.889 0.822 0.751 0.874 Trichlorofluor .. _ 3.176 3.277 2.932 3.189 3.098 3.156 2.923 2.800 2.578 3.014 2-Propanol (Is ... 2.787 2.560 3.150 3.428 3.224 3.223 3.598 3.294 2.740 3.112 Acrylonitrile 1.504 1.579 1.675 1.692 1.630 1.550 1.605 1,1-Dichloroet ... 1.454 1.127 1.146 1.299 1.316 1.372 1.345 1.283 1.203 1.283 2-Methyl-2-Pro ... 3.320 3.377 3.446 3.727 3.557 3.518 3.970 3.683 3.137 3.526 Methylene Chlo... 1.553 1.449 1.270 1.276 1.256 1.205 1.096 1.301 3-Chloro-l-pro ... 1.437 1.252 1.363 1.606 1.644 1.776 1.867 1.798 1.698 1.604 Trichlorotrifl ... 1.371 1.562 1.367 1.604 1.417 1.422 1.391 1.330 1.243 1.412 Carbon Disulfide 6.043 6.265 5.247 5.373 4.809 4.716 4.605 4.458 4.159 5.075 trans-1,2-Dich .•. 1.635 1.633 1.678 1.940 1.874 1.980 2.006 1.940 1.821 1.834 1,1-Dichloroet ... 2.487 2.460 2.358 2.532 2.496 2.502 2.454 2.355 2.204 2.427 Methyl tert-Bu ... 4.114 4.317 4.320 4.362 4.483 4.481 4.446 4.281 3.956 4.307 Vinyl Acetate 0.194 0.221 0.250 0.304 0.294 0.277 0.257 2-Butanone (MEK) 0.734 0.785 0.867 0.864 0.836 0.780 0.811 cis-1,2-Dichlo ... 1.945 1.823 1.814 1.922 1.880 1.917 1.906 1.831 1.717 1.862 Diisopropyl Ether 1.208 1.184 1.266 1.368 1.334 1.393 1.296 1.219 1.123 1.266 Ethyl Acetate 0.304 0.344 0.422 0.446 0.430 0.416 0.391 0.393 n-Hexane 2.131 2.167 2.024 2.021 1.807 1.757 1.686 1.942 Chloroform 2.714 2.635 2.366 2.671 2.580 2.609 2.542 2.435 2.260 2.535 1,2-Dichloroet ... 1.825 1.839 1.840 1.851 1.870 1.853 1.810 1.773 1.744 1.823 Tetrahydrofura... 0.752 0.854 0.814 0.854 0.852 0.824 0.772 0.817 Ethyl tert-But ... 1.505 1.882 1.579 1.785 1.750 1.734 1.750 1.674 1.560 1.691 1,2-Dichloroet ... 2.111 2.101 2.076 2.212 2.094 2.145 2.161 2.061 1.906 2.096 37) IR l,4-Difluorobenzen ... ----------------ISTD---------------------- 38) T 1,1,1-Trichlor ... 0.533 0.530 0.494 0.539 0.547 0.535 0.544 0.516 0.484 0.525 Rl3072514.M Sat Aug 23 13:06:02 2014 %RSD 3.66 7.02 11.28 12.32 10.07 11.73 7.84 10.98 8.34 4.19 10.09 7.64 7.46 11.04 4.57 8.37 6.99 11. 75 13.17 7.87 14.12 8.17 4.29 4.06 16.77 6.56 3.86 7.10 13.07 9.79 5.96 2.24 5.05 7.20 4.05 4.27 Page: 1 2 8 o f 3 3 Response Factor Report MS13 Method Path : I:\MS13\METHODS\ Method File : Rl3072514.M Title : EPA T0-15 per SOP VOA-T015 (CASS T0-15/GC-MS) 39) T Isopropyl Acetate 0.132 O.l48 0~130 0.149 0.149 0.147 0.150 0.144 0,136 0.143 5.56 40) T 1-Butanol 0.190 0.227 0.222 0.274 0.268 0.258 0.240 13.55 41) T Benzene 1.355 1.200 1.098 l.099 1.015 1.004 0.981 0.928 0.852 1.059 14.23 42) T Carbon Tetrach ... 0.429 0.413 0.413 0.427 0.440 0.448 0.468 0.447 0.419 0.434 4.23 43) T Cyclohexane 0.430 0.428 0.395 0.424 0.401 0.407 0.397 0.374 0.349 0.401 6.59 44) T tert-Amyl Meth ... 0.913 0.874 0.741 0.825 0.809 0.827 0.848 0.814 0.770 0.825 6.23 45) T 1,2-Dichloropr ... 0.295 0.245 0.230 0. 2 67 0.252 0.245 0.251 0.242 0.231 0.251 7.98 4 6) T Bromodichlorom ... 0.405 0.463 0.382 0.424 0.401 0.429 0.438 0.421 0.394 0.417 5.95 47) T Trichloroethene 0.347 0.357 0.316 0.338 0.333 0.330 0.322 0.307 0.285 0.326 6.65 48) T 1,4-Dioxane 0.184 0.213 0.223 0.224 0.244 0.232 0.217 0.220 8.47 4 9} T 2,2,4-Trimethy ... 1.088 1.175 l.008 1.094 1.055 1.062 1.061 1.011 0.955 1.056 5.91 50) T Methyl Methacr~~* 0.113 0.113 0.114 0.119 0.113 0.106 0.113 3.51 51) T n-Heptane 0.257 0.275 0.226 0.261 0.251 0.252 0.242 0.233 0.221 0.246 7.ll 52) T cis-1,3-Dichlo ... 0.348 0.397 0.359 0.404 0.416 0.443 0.459 0.446 0.426 0.411 9.33 53) T 4-Methyl-2-pen~-· 0.203 0.223 0.230 0.252 0.243 0.230 0.230 7.44 54) T trans-1,3-Dich ... 0.366 0.379 0.433 0.462 0.446 0.426 0.419 9.11 55) T 1,1,2-Trichlor ... 0.291 0.289 0.251 0.278 0.257 0.279 0.276 0.264 0.251 0.271 5.68 56) IR Chlorobenzene-dS { ... ----------------ISTD--------------------- 57) s Toluene-dB (SS2) 2.341 2.282 2.326 2.297 2.281 2.305 2.270 2.255 2.274 2.292 1.22 58) T Toluene 3.466 3.077 2.812 2.993 2.937 3.016 2.897 2.753 2.637 2.954 8.01 59) T 2-Hexanone 1.180 1.381 1.426 1.557 1.742 l.667 1.600 1.508 12.74 60) T Dibromochlorom .. , 0.911 0.766 0.845 0.890 0.923 0.990 1.020 0.971 0.926 0.916 8.43 61) T 1,2-Dibrornoethane 0.706 0.685 0.738 0.789 0.814 0.856 0.884 0.838 0.799 0.790 8.60 62) T n-Butyl Acetate 1.258 1.382 1.483 1.557 1.804 1.714 1.646 1.549 12.31 63) T n-Octane 0.572 0.533 0.542 0.559 0.562 0.576 0.566 0.537 0.513 0.551 3.79 64) T Tetrachloroethene 0.988 0.998 0.998 0.994 0.992 1.005 0.993 0.935 0.894 0.978 3.83 65) T Chlorobenzene 2.278 2.156 1.986 2.015 1.976 2.048 2.020 1. 908 1. 808 2.022 6.69 66) T Ethylbenzene 3.472 3.716 3.170 3.497 3.406 3.501 3.496 3.307 3.117 3.409 5.44 67) T m-& p-Xylenes 3.024 2.886 2.761 2.933 2.800 2.929 2.901 2.726 2.572 2.837 4.80 68) T Bromoform 0.613 0.688 0.632 0.723 0.71.8 0.805 0.859 0.827 0.792 0.740 ll.70 69) T Styrene 1.866 1.886 1.662 l.934 2.049 2.148 2.179 2.056 1.950 1. 970 8.10 70) T o-Xylene 2.999 2.966 2.767 2.869 2.904 2.998 2.974 2.798 2.619 2.877 4.48 71) T n-Nonane 1.344 1. 281 1.174 1.391 1.297 1.356 1.347 L286 1.242 1.302 5.10 72) T 1,1,2,2-Tetrac ... 1.195 1.000 0.981 1.201 l.165 1.239 l.289 1.229 1.173 1.164 9.02 73) s Bromofluoroben ... 0.860 0.850 0.857 0.859 0.874 0.868 0.851 0.859 0.865 0.860 0.92 74) T Cumene 3.881 3.744 3.617 3.763 3.788 3.903 3.841 3.612 3.379 3.725 4.45 75) T alpha-Pinene 1.885 1.781 1.646 1.900 1.808 1.852 1.883 1.788 1.686 1.803 4-96 76) T n-Propylbenzene 4.601 4.562 4.071 4.400 4.416 4.579 4.545 4.260 3.971 4.378 5.29 77) T 3-Ethyltoluene 3.529 3.452 3.379 3.756 3.547 3.686 3.868 3.544 3.404 3.574 4.62 78) T 4-Ethyltoluene 3.629 3.473 3.397 3.389 3.572 3.605 3.455 3.357 3.024 3.434 5.30 79) T 1,3,5-Trimethy ... 3.312 3.176 2.906 3.169 3.119 3.179 3.190 3.024 2.828 3.100 4.93 80} T alpha-Methylst ... 1.363 1.286 1.325 1.552 1.582 L 629 1. 688 1.590 1.496 1.501 9.55 81) T 2-Ethyltoluene 3.628 3.620 3.291 3.697 3.466 3.616 3.612 3.386 3.156 3.497 5.27 82) T l,2,4-Trimethy ... 3.074 3.083 2.799 3.179 3.065 3.148 3.175 2.979 2.817 3.036 4.72 83) T n-Decane 1.477 1.386 1.236 l.471 1.405 l.439 1.444 1.361 1.310 l.392 5.72 84) T Benzyl Chloride 1.499 1.824 2.032 2.378 2.805 2.676 2.541 2.251 21.34 85) T l,3-Dichlorobe ... 1.790 1.614 1.666 1.743 1.719 1.792 1.797 1.677 1.567 1.707 4.84 86) T 1,4-Dichlorobe ... 2.236 1.943 1.676 1.942 1.846 1.948 1.943 1.829 1.719 1.898 8.57 R13072514.M Sat Aug 23 13:06:02 2014 Page: 2 2 9 o f 3 3 Response Factor Report MS13 Method Path : I:\MS13\METHODS\ Method File : R13072514.M Title : EPA T0-15 per SOP VOA-T015 (CASS T0-15/GC-MS) 87) T sec-Butylbenzene 4.218 3.749 3.728 4.105 4.044 4.038 4.053 3.777 3.522 3.915 5.81 88) T 4-Isopropyltol ... 3.753 3.759 3.430 3.864 3.846 3.857 3.867 3.617 3.382 3.708 5.11 89) T 1,2,3-Trimethy ... 3.332 3.075 3.053 3.283 3.245 3.376 3.385 3.181 2.997 3.214 4.52 90) T 1,2-Dichlorobe ... 1.745 1.714 1. 567 1.727 1.707 1.762 1.753 1.628 1.532 1.682 5.06 91) T d-Limonene 0.822 0.894 0.963 1.055 1.087 1.062 1.113 1.060 1.046 1.011 9.65 92) T l,2-Dibromo-3-... 0.537 0.531 0.619 0.713 0.687 0.655 0.624 12.21 93) T n-Undecane 1. 453 l. 458 1.258 1.477 1.480 1.435 1.555 1.469 1.414 1.444 5.55 94) T 1,2,4-Trichlor ... 1.426 1.372 1.074 1.296 l.289 1.308 1.437 1.358 1.290 1.317 8.15 95) T Naphthalene 3.161 3.235 3.823 3.974 4.585 4. 264 3.946 3.855 13.35 96) T n-Dodecane 1.228 1.359 1.141 1.522 1.457 1.430 1. 356 10.72 97) T Hexachlorobuta ... 1.091 0.955 0.818 0.866 0.868 0.861 0.914 0.860 0.817 0.895 9.56 98) T Cyclohexanone 0.755 0.801 0.784 0.793 0.867 0.837 1.051 1.001 0.955 0.871 12.13 99) T tert-Butylbenzene 3.119 3.023 2.854 3.047 3.036 3.072 3.056 2.862 2.691 2.973 4.70 100) T n-Butylbenzene 2.919 2.970 2.630 2.904 2.978 3.120 3.258 3.051 2.865 2.966 5.90 ---------------------------------------------------------------------------- (#) Out of Range Rl3072514.M Sat Aug 23 13:06:02 2014 Page: 3 3 0 o f 3 3 Evaluate Continuing Calibration Report Data File Acq On Sample Mis·c I:\MS13\DATA\2014 08\23\08231402.D 23 Aug 2014 5:1l 25ng T0-15 CCV STD S29-07171401/S29-08061406 (9/4) Quant Time: Aug 23 07:55:29 2014 Quant Method I:\MS13\METHODS\R13072514.M Vial: 16 Operator: WA Inst MS13 Quant Title : EPA T0-15 per SOP VOA-T015 (CASS T0-15/GC-MS) QLast Update : Sat Jul 26 07:09:59 2014 Response via : Initial Calibration DataAcq Meth:T015.M Min. RRF Max. RRF Dev 0.000 Min. Rel. Area 50% Max. R.T. Dev 0.33min 200% 1 IR 2 T 3 T 4 T 5 T 6 T 7 T 8 T 9 T 10 T 11 T 12 T 13 T 14 T 15 T 16 T 17 T 18 T 19 T 20 T 21 T 22 T 23 T 24 T 25 T 26 T 27 T 28 T 29 T 30 T 31 T 32 T 33 s 34 T 35 T 36 T 37 IR 38 T 39 T 40 T 41 T 42 'l' 43 T 44 T 45 T 46 T 47 T 48 T 49 T 50 T 51 T 30% Max. Rel. Area Compound Bromochloromethane (ISl) Propene Dichlorodif luoromethane (CF Chl.oramethane 1,2-Dichloro-1,1,2,2-tetraf Vinyl Chloride 1,3-Butadiene Bromomethane Chloroethane Ethanol .Acetonitrile Acrolein Acetone Trichlorof luoromethane 2-Propanol (Isopropanol) Acrylonitrile 1,1-Dichloroethene 2-Methyl-2-Propanol (tert-B Methylene Chloride 3-Chloro-1-propene (Allyl C Trichlorotrifluoroethane Carbon Disul:f ide trans-1,2-Dichloroethene 1,1-Dichloroethane Methyl tert-Butyl Ether Vinyl Acetate 2-Butanone (MEK) cis-1,2-Dichloroethene Diisopropyl Ether Ethyl Acetate n-Hexane Chloroform 1,2~Dichloroethane-d4(SS1) Tetrahydrofuran (THF) Ethyl tert-Butyl Ether 1,2-Dichloroethane 1,4-Difluorobenzene (IS2) 1,1,1-Trichloroethane Isopropyl Acetate 1-Butanol Benzene Carbon Tetrachloride Cyclohexane tert-Amyl Methyl Ether 1,2-Dichloropropane Bromodichlorornethane Trichloroethene 1,4-Dioxane 2,2,4-Trimethylpentane (Iso Methyl Methacrylate n-Heptane AvgRF 1.000 1.324 3.713 1.882 1.835 1. 962 1.305 1.347 0.901 0.876 2.158 0.691 0.874 3.014 3.112 1.605 1.283 3.526 1.301 1.604 1.412 5.075 1.834 2.427 4.307 0.257 0. 811 1.862 1.266 0.393 1.942 2.535 1.823 0.817 1.691 2.096 1.000 0.525 0.143 0.240 1.059 0.434 0.401 0.825 0.251 0.417 0.326 0.220 1.056 0 .113 0.246 R13072514.M Sat Aug 23 13:05:57 2014 CCRF 1.000 1.241 3.632 1.898 1.764 1.948 1.407 1. 379 0.942 0.896 2.116 0.702 0.849 2.861 3.329 1.593 l.291 3.652 l.214 1. 763 1.370 '1.423 1.945 2.364 4.337 0.295 0.827 1.827 1.255 0.411 1.775 2.451 1.890 0.803 1.700 2.072 l.000 0.508 0.137 0.237 0.930 0.440 0.375 0.793 0.233 0.412 0.303 0.220 0.996 0.109 0.226 %Dev Area% Dev(min) 0.0 6.3 2.2 -0.9 3.9 0.7 -7.8 -2.4 -4.6 -2.3 L9 -1. 6 2.9 5.1 -7.0 0.7 -0.6 -3.6 6.7 -9.9 3.0 12.8 -6. 1 2.6 -0.7 -14.8 -2.0 1. 9 0.9 -4.6 8.6 3.3 -3.7 1. 7 -0.5 1.1 0.0 3.2 4.2 1. 3 12.2 -1. 4 6.5 3.9 7.2 1.2 7.1 0.0 5.7 3.5 8.1 79 -0.02 78 -0.02 77 -0.02 71 -0.02 74 -0.02 72 -0.02 72 -0.02 77 -0.03 75 -0.02 75 -0.08 74 -0.05 73 -0.03 75 -0.05 77 -0.02 73 -0.06 74 -0.03 75 -0.02 72 -0.06 76 -0.02 74 -0.02 77 -0.01 75 -0.02 76 -0.01 76 -0.02 77 -0.01 76 -0.03 75 -0.03 75 -0.01 76 -0.02 75 -0.02 77 -0.01 76 -0.02 82 -0.02 74 0.00 76 -0.01 75 -0.01 Bl 0.00 75 -0.01 74 -0.01 70 -0.04 77 -0.01 76 -0.01 76 0.01 75 0.00 75 -0.01 76 -0.01 76 0.00 73 -0.02 76 o.oo 74 -0.01 75 -0.01 Page: 1 31 of 33 Evaluate Continuing Calibration Report Data File Acq On Sample Misc I:\MSl3\DATA\2014 08\23\08231402.D 23 Aug 2014 5:ll 25ng T0-15 CCV STD 829-07171401/529-08061406 (9/4) Quant Time: Aug 23 07:55:29 2014 Quant Method I:\MS13\METHODS\R13072514.M Vial: 16 Operator: WA Inst MS13 Quant Title : EPA T0-15 per SOP VOA-T015 (CASS T0-15/GC-MS) QLast Update : Sat Jul 26 07:09:59 2014 Response via : Initial Calibration DataAcq Meth:T015.M Min. RRF Max. RRF Dev 0.000 Min. Rel. Area 50% Max. R.T. Dev 0.33min 200% 52 T 53 T 54 T 55 T 56 IR 57 s 58 T 59 T 60 7 61 T 62 T 63 T 64 T 65 T 66 T 67 T 68 T 69 T 70 T 71 T 72 T 73 s 74 T 75 T 76 T 77 T 78 T 79 T 80 T 81 T 82 T 83 T 84 T 85 T 86 T 87 T 88 T 89 T 90 T 91 T 92 T 93 T 94 T 95 T 96 T 97 T 98 T 99 T 100 T 30% Max. Rel. Area Compound cis-1,3-Dichloropropene 4-Methyl-2-pentanone trans-1,3-Dichloropropene 1,1,2-Trichloroethane Chlorobenzene-d5 (IS3) Toluene-d8 (SS2) Toluene 2-Hexanone Dibromochloromethane 1,2-Dibromoethane n-Butyl Acetate n-Octane Tetrachloroethene Chlorobenzene Ethylbenzene m-& p-Xylenes Brornoform Styrene a-Xylene n-Nonane 1,1,2,2-Tetrachloroethane Brornofluorobenzene (SS3) Cumene alpha-Pinene n-Propylbenzene 3-Ethyltoluene 4-Ethyltoluene 1,3,5-Trimethylbenzene alpha-Methyl styrene 2-Ethyltoluene 1,2,4-Trimethylbenzene n-Decane Benzyl Chloride 1,3-Dichlorobenzene 1,4-Dichlorobenzene sec-Butylbenzene 4-Isopropyltoluene (p-Cymen 1,2,3-Trimethylbenzene 1,2-Dichlorobenzene d-Limonene 1,2-Dibromo-3-Chloropropane n-Undecane 1,2,4-Trichlorobenzene Naphthalene n-Dodecane Hexachlorobutadiene Cyclohexanone tert-Butylbenzene n-Butylbenzene AvgRF 0.411 0.230 0.419 0.271 1.000 2.292 2.954 1.508 0.916 0.790 1.549 0.551 0.978 2.022 3.409 2.837 0.740 1.970 2.877 1.302 1.164 0. 8 60 3.725 1.803 4.378 3 .. 574 3.434 3.100 1.501 3.497 3.036 1.392 2.251 1.707 1.898 3.915 3.708 3.214 1.682 1.011 0.624 1.444 1.317 3.855 1.356 0.895 0.871 2.973 2.966 CCRF 0.433 0.222 0.427 0.261 1.000 2.234 2.548 1.387 0.892 0.764 1.414 0.489 0.872 1. 767 3. 065 2.538 0.750 1.897 2.608 1.167 1.124 0.960 3.372 1.641 3.941 3.152 3.229 2.814 1.457 3.152 2.767 1.237 2.436 1.565 1.690 3.513 3.378 2.939 1.536 0.953 0.615 1.326 1.240 3.875 1.285 0.787 0.798 2.649 2.792 %Dev Area% Dev(rnin) -5.4 3.5 -l. 9 3.7 0.0 2.5 13.7 8.0 2.6 3.3 8.7 11. 3 10.8 12.6 10.1 10.5 -1.4 3.7 9.4 10.4 3.4 -11.6 9.5 9.0 10.0 11. 8 6.0 9.2 2.9 9.9 8.9 11.1 -8.2 8.3 11. 0 10.3 8.9 8.6 8.7 5.7 1. 4 8.2 5.8 -0.5 5.2 12.1 8.4 10.9 5.9 76 0.00 71 -0.01 75 0.00 76 -0.01 87 0.00 85 -0.01 76 0.00 69 -0.01 76 0.00 75 0.00 68 -0.01 75 0.00 76 0.00 76 0.00 76 0.00 76 -0.01 76 -0.01 75 0.00 76 -0.01 75 0.00 76 -0.01 98 0.00 76 0.00 75 0.00 75 0.00 71 0.00 81 0.00 76 0.00 75 0.00 76 0.00 75 -0.01 74 0.00 75 -0.01 75 o.oo 75 -0.01 75 0.00 76 0.00 75 -0.01 76 0.00 74 o.oo 75 0.00 74 0.00 75 0.00 73 0.00 73 0.00 74 0.00 66 -0.01 75 -0.01 74 0.00 -------------------------------------~-----------------~------------------ R13072514.M Sat Aug 23 13:05:57 2014 Page: 2 32 of 33 Evaluate Continuing Calibration Report I:\MS13\DATA\2014 08\23\08231402.D 23 Aug 2014 5:1l Vial: 16 Operator: WA Data File Acq On Sample Misc 25ng T0-15 CCV STD S29-07171401/S29-08061406 (9/4) Inst MS13 Quant Time: Aug 23 07:55:29 2014 Quant Method I:\MS13\METHODS\R13072514.M Quant Title : EPA T0-15 per SOP VOA-T015 (CASS T0-15/GC-MS) QLast Update : Sat Jul 26 07:09:59 2014 Response via : Initial Calibration DataAcq Meth:T015.M Min. RRF Max. RRF Dev 0.000 Min. Rel. Area 30% Max. Rel. Area 50% Max. R.T. Dev 0.33min 200% Compound AvgRF CCRF %Dev Area% Dev(min) (#) = Out of Range SPCC's out = 0 CCC's out= 0 Rl3072514.M Sat Aug 23 13:05:57 2014 Page: 3 33 of 33